共查询到19条相似文献,搜索用时 125 毫秒
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本文主要报道Sb2O3杂质对ZnO基陶瓷性能的影响。在ZnO基陶瓷中添加Sb2O3杂质可以改善此种瓷的压敏性和介电性。 相似文献
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本文通过在Fe0.5Sr0.5CoO3酒敏陶瓷基体中掺杂不同量的Nb2O5、CdO、La2O3、SnO2等,研究了氧化物掺杂对酒敏陶瓷灵敏度峰值温度的影响。结果表明:这四种掺杂物都能一定程度降低Fe0.5Sr0.5CoO3酒敏陶瓷的灵敏度峰值温度,且掺杂量为3%(摩尔比)左右时,该陶瓷的敏感度最好。 相似文献
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ZnO压敏陶瓷的非线性功能添加剂 总被引:4,自引:0,他引:4
本文采用单元掺杂与多元掺杂的方法,系统研究了几种过渡金属氧化物添加剂在控制ZnO压敏陶瓷非线性方面的作用,并根据金属阳离子外壳层电子结构稳定性和缺陷化学反应进行了分析,认为阳离子具有不饱和外层电子结构且半径与Zn^2+离子相近的过渡金属氧化物能改善ZnO压敏陶瓷非线性。 相似文献
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中温烧结MgO—TiO2—ZnO系陶瓷结构和性能的研究 总被引:2,自引:0,他引:2
本文在研究中温烧结MgO-TiO-ZnO系陶瓷基础上,获得了温度系数接近于零的瓷料(NPO)。XRD证明其主晶相为正钛酸镁(2MgO.TiO2)还有正钛酸锌(2ZnO.TiO2)和CaTiO3附加晶相,同时研究了各组分的不同含量对介电性能的影响。 相似文献
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掺杂中温烧结BaTiO_3陶瓷的壳-芯结构与组成、工艺的关系 总被引:1,自引:0,他引:1
研究了添加少量Nb,Bi,CO杂质及B,Zn玻璃相的BaTiO_3系陶瓷介电性能与其组成、工艺及结构的关系。发现晶粒壳的K-T曲线为单峰,峰值在80℃左右。陶瓷K-T曲线的双峰现象不随Nb,Bi添加量的增加而消失,但随Co,Zn添加量增加或烧结温度的提高而向单峰过渡。研究结果表明Nb,Bi主要决定壳的成份,Co可促进Nb,Bi离子向晶粒内部扩散,添加Zn,Co或改变烧结工艺对壳的厚度及成份均有较大影响。 相似文献
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近20年来,有关ZnO压敏陶瓷研究方面的报道很多,本文从ZnO压敏陶瓷的导电机理及掺杂氧化物的作用方面进行了综合评述。 相似文献
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氧化铟对ZnO压敏陶瓷压敏特性及微观结构的影响 总被引:1,自引:0,他引:1
用粒度为0.1-0.3mm的氧化锌偻末为原料,制得了氧化锌压敏陶瓷片,研究了In2O3掺杂对其压敏特性和微观结构的影响。结果表明;这种氧化锌粉末具有很高的烧结活性,适合作低压压敏电阻器。 相似文献
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掺杂中温烧结BaTiO3陶瓷的壳—芯结构与组成,工艺的关系 总被引:1,自引:0,他引:1
研究了添加少量Nb,Bi,Co杂质及B,Zn玻璃相的BaTiO3系陶瓷介电性能与其组成、工艺及结构的关系,发现晶粒壳的K-T曲线为单峰,峰值在80℃左右,陶瓷KT-T曲线的双峰现象不随Nb,Bi添加量的增加而消失,但随Co,Zn添加量增加或烧结温度的提高而向单峰过渡,研究结果表明Nb,Bi主要决定壳的成份,Co可促进Nb,Bi离子向晶粒向部扩散,添加Zn,Co或改变烧结工艺对壳的厚度及成份均有较大 相似文献
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Sb2O3掺杂对ZnO压敏陶瓷晶界特性和电性能的影响 总被引:7,自引:1,他引:6
制备了掺有Sb2O3不同掺杂量ZnO压敏陶瓷样品,采用扫描电镜对样品进行显微结构分析,研究了Sb2O3掺杂浓度对ZnO压缩电阻显微结构和性能的影响,测量了样品的电性能,由样品C-V特性的测量计算出晶界参数,并由此讨论了陶瓷性能与晶界特性的相关性。研究发现,在ZnO压敏陶瓷样品中掺杂适量的Sb2O3可以提高ZnO压敏陶瓷样品的非线性性能,但当Sb2O3的摩尔分数超过0.088%时,电性能反而优化,这是因为Sb2O3掺杂浓度不同会引起晶界势垒高度、施主浓度与陷阱密度的变化,因此Sb2O3掺杂量要控制在适当的范围内。 相似文献
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Varistor Performance of ZnO-Based Ceramics Related to Their Densification and Structural Development
Maria Cecilia S. Nobrega Walter A. Mannheimer 《Journal of the American Ceramic Society》1996,79(6):1504-1508
Electrical potential barriers are often observed in ZnO-based ceramics. Earlier studies on ZnO photoconduction have shown that the narrow regions, where the sintered grains have grown together, control the resistance of the entire sample. In those regions, the surface/volume ratio is sufficiently high for the acceptor concentration (which occurs because of adsorbed oxygen) to exceed the donor concentration inside the ZnO grains. More recent works have shown that Schottky barriers result from interface states because of the chemisorbed oxygen ion at the ZnO-ceramic grain boundaries. The work reported in this paper involves the relationship between the densification of the microstructure and the varistor performance of ZnO ceramics. The emphasis of densification percentage as an indicator of the degree of sintering shows the desirability of continuity across ZnO grain boundaries, without the presence of voids or films of second phases, in optimizing varistor behavior. The effect of oxygen partial pressure on the development of varistor microstructure and electrical properties, as well the kinetics of grain growth, during the sintering process have been determined and are discussed. 相似文献
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High Nonlinearity and High Voltage Gradient ZnO Varistor Ceramics Tailored by Combining Ga2O3, Al2O3, and Y2O3 Dopants
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Hongfeng Zhao Jun Hu Shuiming Chen Qingyun Xie Jinliang He 《Journal of the American Ceramic Society》2016,99(3):769-772
This paper deals with the electrical characteristics of rare‐earth‐doped ZnO varistor ceramics. Multiple donor dopants (Al3+, Ga3+, and Y3+) were employed to improve the comprehensive performance of ZnO varistor ceramics. The leakage current of rare‐earth‐doped ZnO varistor ceramics decreased noticeably with Ga2O3 dopants. The Ga3+ dopant occupies the defect sites of grain boundaries and increases the barrier potential of ZnO varistor ceramics, so the leakage current is effectively inhibited. Y2O3 is primarily located around the grains, which restrains ZnO grain growth, increasing the voltage gradient. The Al3+ goes into the lattices of ZnO grains, decreasing the grain resistance; thus, the residual voltage ratio can be controlled at low levels under a high impulse current. With the combined incorporation of Al3+, Ga3+, and Y3, excellent electrical properties of ZnO varistor ceramics can be acquired with a nonlinearity coefficient of 87, voltage gradient of 517 V/mm, leakage current of 0.96 μA/cm2, and residual voltage ratio of 1.60. These rare multiple donor dopants can aid in engineering high‐quality ZnO varistors. 相似文献
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ABSTRACTIt is difficult to dope Al into main grains of ZnO varistor ceramics, especially for small doping amount. Generally, all raw materials including Al dopant are directly mixed together and sintered into ceramics. However, in this direct doping process, Al is apt to stay in grain boundaries, and almost does not enter grains. This does harm to the electrical properties of ZnO varistors. In this paper, we proposed a two-step doping process. Al2O3 powder was first mixed only with a part of the ZnO powder and pre-sintered. The pre-sintered powder was mixed with other additives such as Bi2O3 and the rest ZnO. Then ZnO varistor ceramics were prepared via solid state sintering processes. Results showed that two-step doped ZnO varistors exhibited improved electrical properties with a significant increased nonlinear coefficient and a great decreased leakage current compared to directly doped ones because more Al was incorporated into ZnO grains. 相似文献
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A ZnO varistors in series connected with a semi‐insulating GaAs photoconductive switches (SI‐GaAs PCSS's), a test method for ultrafast pulse response characteristics of ZnO varistor ceramics with DC bias was presented for the first time. The DC voltage distribution of the PCSS's and the varistors was measured in a dark state and the pulse response characteristics of the ZnO varistor ceramics was examined by a nanosecond laser pulse illuminating the PCSS's. The results indicate that the electric pulse output from the varistors includes capacitive current and conduction current and there is a time delay between their peaks. It is revealed that ZnO varistors has a nonlinear conductivity for the nanosecond electric impulse excitation and the barrier capacitance decay constant of the ceramics sample is 105 ns, which is explained through the analysis of examining the material structure and the conductive mechanisms. 相似文献
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综述了添加剂对钛酸镁陶瓷性能影响的研究现状,烧结及介电性能等方面的进展。研究结果中可以看出,Bi2O3-V2O5、Co2O3、ZnO等氧化物及氧化物玻璃料的添加可以不同程度地大幅降低陶瓷的烧结温度。在Mg2TiO4中掺杂不同添加剂可适当改变其介电常数,满足其介电常数材料的应用需要;在MgTiO3中掺入不同添加剂可不同程度改变其介电常数,得到具有较高Q*f值且τf≈0的钛酸镁基陶瓷材料。从当前研究现状可以看出,掺杂改性是获得所需性能材料的强有力手段,也是今后对钛酸镁基陶瓷性能优化的主要研究方向之一。 相似文献