From hydrocarbon to hydrogen–carbon to hydrogen economy

In the near- to medium-term future, hydrogen production will continue to rely on fossil fuels, and will, therefore, remain a potential source of significant CO₂ emissions into the atmosphere. Conventional CO₂ sequestration strategies offer rather expensive and ecologically uncertain solutions. The objective of this paper is to explore novel approaches to solving energy and environmental problems associated with the production of hydrogen from fossil fuels. The paper discusses the technological, environmental and economical aspects of large-scale production of hydrogen and carbon by the catalytic dissociation of natural gas (NG). The authors propose a scenario of fossil-based “hydrogen–carbon” infrastructure, where the hydrogen component of NG is used as a clean energy carrier (e.g., in transportation) and the carbon component is used in several application areas: structural materials, power generation, soil amendment and environmental remediation. This scenario will allow a smooth transition from the current hydrocarbon-based economy to a hydrogen–carbon economy as a half-way point to the ultimate hydrogen-from-renewables economy of the future.     

Prospects and challenges of renewable hydrogen generation in Bangladesh

The collective endeavor in reaching net-zero emissions by 2050 and halting the impending effects of global warming has found a promising solution-hydrogen, a clean energy carrier with diversified applications. It is practical to transition H₂ production at scale from fossil fuels to renewable sources. The choice of appropriate hydrogen production route from renewables would regionally vary, depending on various factors. While a majority of the developed countries have kickstarted their transition towards a hydrogen economy, developing countries like Bangladesh have been lagging. This review explores the potential of a hydrogen-based energy system for Bangladesh - commencing with a technological comparison of existing production paths from renewable resources; then moving on to a preliminary analysis of its available resources and technology options. Finally, a roadmap toward a hydrogen economy is envisioned, as the foundation for further study and public policy initiatives aimed at hastening Bangladesh's transition to a carbon-free energy system.     

Carbon black and hydrogen production process analysis

The adoption of new environmentally responsible technologies, as well as, energy efficiency improvements in equipment and processes help to reduce CO2 rate emission into the atmosphere, contributing in delaying the consequences of intensive use of fossil fuels. For more effective actions, it is necessary to make the transition from the fossil-based to the renewable source economy. In this context, hydrogen fuel has a special role as clean vector of energy. Hydrogen has the potential to be decisive in mitigating greenhouse gas emissions, but fossil fuels high profitability due to global energy dependency actually drives the global economy.While renewable energy sources are not worldwide fully established, new technologies should be developed and used for the recovery of energetic streams nowadays wasted, to decarbonize hydrocarbons and to improve systems efficiency creating a path that can help nations and industries in the needed energy economy transition. Hydrogen gas can be generated by various methods from different sources such as coal and water. Currently, almost all of the hydrogen production is for industrial purpose and comes from the Steam Reforming, while the use of hydrogen in fuel cells is only incipient.The article analysis the plasma pyrolysis of hydrocarbons as a decarbonization option to contribute as a step towards hydrogen economy. It presents the Carbon Black and Hydrogen Process (CB&H Process) as an alternative option for hydrogen generation at large scale facility, suitable for supplying large amounts of high-purity carbon in elemental form. CB&H Process refers to a plant with hydrogen thermal plasma reactor able to decompose Hydrocarbons (HC's) into Hydrogen (H2) and Carbon Black (CB), a cleaner technology than its competing processes, capable of generating two products with high added value. Considering the Brazilian context in which more than 80% of the generated electricity comes from renewable sources, the use of electricity as one of the inputs in the process does not compromise the objective of reducing greenhouse gas emissions. It is important to consider that the use of renewable energy to produce two products derived from fossil fuels in a clean way represents integration of technologies into a more efficient system and an arrangement that contributes to the transition from fossil fuels to renewables.The economic viability of the CB&H process as a hydrogen generation unit (centralized) for refining applications also depends on the cost of hydrogen production by competing processes. Steam Methane Reforming (SMR) is a widespread method that produces twice the amount of hydrogen generated by natural gas plasma pyrolysis, but it emits CO2 gas and consumes water, while CB&H process produces solid carbon. For this reason, the paper seeks the carbon production cost by plasma pyrolysis as a breakeven point for large-scale hydrogen generation without water consumption and carbon dioxide emissions.     

Utilization of green ammonia as a hydrogen energy carrier for decarbonization in spark ignition engines

Rising concerns about the dependence of modern energy systems on fossil fuels have raised the requirement for green alternate fuels to pave the roadmap for a sustainable energy future with a carbon-free economy. Massive expectations of hydrogen as an enabler for decarbonization of the energy sector are limited by the lack of required infrastructure, whose implementation is affected by the issues related to the storage and distribution of hydrogen energy. Ammonia is an effective hydrogen energy carrier with a well-established and mature infrastructure for long-distance transportation and distribution. The possibility for green ammonia production from renewable energy sources has made it a suitable green alternate fuel for the decarbonization of the automotive and power generation sectors. In this work, engine characteristics for ammonia combustion in spark ignition engines have been reported with a detailed note on engines fuelled with pure ammonia as well as blends of ammonia with gasoline, hydrogen, and methane. Higher auto-ignition temperature, low flammability, and lower flame speed of ammonia have a detrimental effect on engine characteristics, and it could be addressed either by incorporating engine modifications or by enhancing the fuel quality. Literature shows that the increase in compression ratio from 9.4:1 to 11.5:1 improved the maximum power by 59% and the addition of 10% hydrogen in supercharged conditions improved the indicated efficiency by 37%. Challenges and strategies for the utilization of ammonia as combustible fuel in engines are discussed by considering the need for technical advancements as well as social acceptance. Energy efficiency for green ammonia production is also discussed with a due note on techniques for direct synthesis of ammonia from air and water.     

Trends in dark biohydrogen production strategy and linkages with transition towards low carbon economy: An outlook,cost-effectiveness,bottlenecks and future scope

The conventional fossil fuel showed a persistent and intense decline steadily over the past two decades have led to global deterioration of limited sustainable energy supplies. Furthermore, price fluctuations and its serious ecological consequences had piqued the interest of researchers mostly in domain of alternative renewable energy. Among all existing fuels, biohydrogen is documented because of its carbon-neutral, simple and sustainable output, low carbon emissions, and large energy density. Hydrogen (H₂) generation from dark fermentation of biowaste is an enticing sustainable method which promotes in the creation of low carbon economy. This review details the overview of hydrogen yield form renewable feedstock through dark fermentation. It also detailed the recent trends such as pretreatment, addition of various additives, integrated options, etc., employed towards the enhancement of fermentation process to enrich the hydrogen production. Discussion about the inhibitory substances that affects the performance of fermentation process was incorporated. In addition, it elaborates the economic feasibility, challenges and limitation of the process along with future scope for the development of sustainable hydrogen economy.     

Elementary science teacher candidates’ views on hydrogen as future energy carrier

Current energy infrastructure is not sustainable due to highly dependence to fossil fuels. Increasing energy usage obliges people to find new, economic, environmental friendly and safe energy options. Recent studies indicate that there are many alternative ways for fossil fuels such as solar, geothermal, wind and biomass. By using these renewable sources in tri-generation or multigeneration energy systems, the desired energy infrastructure can be set. On the other hand, hydrogen is seen as future energy carrier because of its advantages. There are many options to benefit from hydrogen such as fuel cells, direct combustion, or store as gas or liquid. However, awareness of society of the renewable energy usage and also hydrogen as energy carrier is not sufficient. In order to increase the awareness of the society, teachers have high responsibility. In this study, views of elementary science teacher candidates on hydrogen as future energy carrier are evaluated by using qualitative phenomenological research. Ten students from elementary science teacher department in Afyon Kocatepe University are selected for semi structured interview. The results of these interviews are analyzed by using content analysis method.     

Political,economic and environmental impacts of biomass-based hydrogen

The purpose of this study is to assess the political, economic and environmental impacts of producing hydrogen from biomass. Hydrogen is a promising renewable fuel for transportation and domestic applications. Hydrogen is a secondary form of energy that has to be manufactured like electricity. The promise of hydrogen as an energy carrier that can provide pollution-free, carbon-free power and fuels for buildings, industry, and transport makes it a potentially critical player in our energy future. Currently, most hydrogen is derived from non-renewable resources by steam reforming in which fossil fuels, primarily natural gas, but could in principle be generated from renewable resources such as biomass by gasification. Hydrogen production from fossil fuels is not renewable and produces at least the same amount of CO₂ as the direct combustion of the fossil fuel. The production of hydrogen from biomass has several advantages compared to that of fossil fuels. The major problem in utilization of hydrogen gas as a fuel is its unavailability in nature and the need for inexpensive production methods. Hydrogen production using steam reforming methane is the most economical method among the current commercial processes. These processes use non-renewable energy sources to produce hydrogen and are not sustainable. It is believed that in the future biomass can become an important sustainable source of hydrogen. Several studies have shown that the cost of producing hydrogen from biomass is strongly dependent on the cost of the feedstock. Biomass, in particular, could be a low-cost option for some countries. Therefore, a cost-effective energy-production process could be achieved in which agricultural wastes and various other biomasses are recycled to produce hydrogen economically. Policy interest in moving towards a hydrogen-based economy is rising, largely because converting hydrogen into useable energy can be more efficient than fossil fuels and has the virtue of only producing water as the by-product of the process. Achieving large-scale changes to develop a sustained hydrogen economy requires a large amount of planning and cooperation at national and international alike levels.     

Pathways to a more sustainable production of energy: sustainable hydrogen—a research objective for Shell

Towards a sustainable energy supply is a clear direction for exploratory research in Shell. Examples of energy carriers, which should be delivered to the envisaged sustainable energy markets, are bio-fuels, produced from biomass residues, and hydrogen (or electricity), produced from renewable sources. In contrast to the readily available ancient sunlight stored in fossil fuels, the harvesting of incident sunlight will be intermittent, efficient electricity and hydrogen storage technologies need to be developed. Research to develop those energy chains is going on, but the actual transformation from current fossil fuel based to sustainable energy markets will take a considerable time. In the meantime the fossil fuel based energy markets have to be transformed to mitigate the impact of the use of fossil fuels. Some elements in this transformation are fuels for ultra-clean combustion (hydrocarbons and oxygenates), hydrogen from fossil fuels, fuels for processors for fuel cells, carbon sequestration.     

A review of hydrogen utilization in power generation and transportation sectors: Achievements and future challenges

Decarbonizing the power generation and transportation sectors, responsible for ∼65% of Green House Gas (GHG) emissions globally, constitutes a crucial step to addressing climate change. Accordingly, the energy paradigm is shifting towards carbon-free and low-emission alternative fuels. Even though the current decarbonization using hydrogen is not large since 96% of global hydrogen production is relying on conventional fossil fuels that produce GHGs in the process, hydrogen fuel has been considered a promising fuel for fuel cell and combustion engines. Various renewable approaches utilizing biomass and water have been investigated to produce green hydrogen. With this, recent developments showed viability to achieve deep decarbonization in the power generation and transportation sectors. Hydrogen-powered vehicles are commercially available in many countries, and over 300,000 fuel cell appliances were sold to produce hot water and electricity. This review aims to provide an overview of the potential role of hydrogen in power generation and transportation systems, recent achievements in research development, and technical challenges to successfully applying hydrogen as a primary fuel. Especially this review will focus on the hydrogen application in power generation and transportation sectors using fuel cells, gas turbines, and internal combustion engines (ICEs).     

Transition to renewable energy systems with hydrogen as an energy carrier

Unlike the present energy system based on fossil fuels, an energy system based on renewable energy sources with hydrogen and electricity as energy carriers would be sustainable. However, the renewable energy sources in general have less emergy than the fossil fuels, and their carriers have lower net emergy. Because of that they would not be able to support continuous economic growth, and would eventually result in some kind of a steady-state economy. An early transition to renewable energy sources may prove to be beneficial in the long term, i.e., it may result in a steady state at a higher level than in the case of a transition that starts later. Once the economy starts declining it will not be able to afford transition to a more expensive energy system, and transition would only accelerate the decline. Similarly, if a transition is too fast it may weaken and drain economy too much and may result in a lower steady state. If a transition is too slow, global economy may be weakened by the problems related to utilization of fossil fuels (such as global warming and its consequences) before transition is completed and the result again would be a lower steady state. Therefore, there must be an optimal transition rate; however, its determination would require very complex models and constant monitoring and adjustment of parameters.     

Thermal cracking of methane into Hydrogen for a CO2-free utilization of natural gas

The transition to a low-Carbon Hydrogen production will unavoidably follow a path where fossil fuels are going to play a fundamental role in the short term. The technological development of Hydrogen production based on sustainable, renewable energies (wind, solar, biomass) will most likely characterize the gradual substitution of fossil-based Hydrogen production in the long term. In this transition, the environmental concerns regarding greenhouse gas emissions to the atmosphere are a crucial issue, fostering the development of Hydrogen production scenarios in which either carbon capture and sequestration or decarburation could be implemented as mitigation or adaptation measures in order to avoid CO₂ release from the utilization of fossil fuels. Therefore, the development of CO₂-free technologies enabling fossil fuels exploitation is a must to make compatible their utilization with emission reductions. New innovative solutions should be put into practice. In this regard, methane cracking is a promising alternative and its potentials are highlighted and analyzed in this paper.     

Renewable Energy Policies in the Gulf countries: A case study of the carbon-neutral “Masdar City” in Abu Dhabi

The Gulf countries are largely dependent on exporting oil and natural gas for their national budgets. They mainly use domestic fossil fuels for their domestic energy supply. In spite of favorable geographic conditions, especially for solar energy, renewable energies are still a niche application. Abu Dhabi, besides Dubai, the most important emirate in the United Arab Emirates (UAE), has now started a process of “transforming oil wealth into renewable energy leadership,” and has set the long-term goal of a “transition from a 20th Century, carbon-based economy into a 21st Century sustainable economy.” This article is a case study about “Masdar City,” a planned carbon-neutral town in Abu Dhabi. The article describes the key characteristics of Masdar City, analyses the drivers behind the project, identifies the main actors for its implementation, and seeks obstacles to creation and development as well as the policy behind Masdar City. Finally, a first judgment of possible diffusion effects of the project is done.     

A global survey of hydrogen energy research,development and policy

Several factors have led to growing interest in a hydrogen energy economy, especially for transportation. A successful transition to a major role for hydrogen will require much greater cost-effectiveness, fueling infrastructure, consumer acceptance, and a strategy for its basis in renewable energy feedstocks. Despite modest attention to the need for a sustainable hydrogen energy system in several countries, in most cases in the short to mid term hydrogen will be produced from fossil fuels. This paper surveys the global status of hydrogen energy research and development (R&D) and public policy, along with the likely energy mix for making it. The current state of hydrogen energy R&D among auto, energy and fuel-cell companies is also briefly reviewed. Just two major auto companies and two nations have specific targets and timetables for hydrogen fuel cells or vehicle production, although the EU also has an aggressive, less specific strategy. Iceland and Brazil are the only nations where renewable energy feedstocks are envisioned as the major or sole future source of hydrogen. None of these plans, however, are very certain. Thus, serious questions about the sustainability of a hydrogen economy can be raised.     

A transition toward a market expansion phase: Policies for promoting wind power in Taiwan

Considering the significant issues on global warming and environmental protection, the energy sector needs a long-term policy, by which renewable energies gradually replace conventional fossil fuels. In terms of an energy system, the development of renewable energies implies a challenge to existing energies like fossil fuels and nuclear power that have been for decades equipped with sound infrastructure and regulations. And a transformation of the energy system cannot expect any achievement without overcoming considerable opposition from vested interests involved with the fossil fuels technologies.     

The future of hydrogen energy: Bio-hydrogen production technology

The widespread use of non-renewable energy has caused serious environmental problems such as global warming and the depletion of fossil fuels. Hydrogen, as a well-known carbon-free gaseous fuel, has become the most promising energy carrier for future energy. Hydrogen has an excellent mass-basis calorific value and no carbon atom contained, which makes it to be an attractive fuel for various power devices (like the internal combustion engine, gas turbine, and fuel cell). Nowadays, the production of hydrogen is still predominated by fossil-based techniques, which is considered undesirable due to low conversion efficiency and release of greenhouse gases. It is necessary to find green and sustainable hydrogen production routes with low energy consumption and cost. In this paper, the different hydrogen production technologies via fossil routes or non-fossil routes are reviewed in general, and it is found that bio-hydrogen production has certain environmental advantages and broad prospects compared with other hydrogen production technologies. Then, the characteristics and research status of different bio-hydrogen production technologies are discussed in depth. It is found that each bio-hydrogen production technique has its own advantages, challenges, and applicability. The economic analysis of bio-hydrogen energy is also performed from the aspects of production, storage, and transportation. The results show that bio-hydrogen production technology could be a good possibility way for producing renewable hydrogen, which is of high efficiency and thus competitive over other hydrogen production methods both in economics and environmental benefits.     

Global challenges in energy

Environmental and security concerns are stimulating global interest in hydrogen power, renewable energy, and advanced transportation technologies, but no significant movement away from oil and a carbon-based world economy is expected soon. Over the longer-term, however, a transition from fossil fuels to a non-carbon-based economy will likely occur, affecting the type of environment future generations may encounter. Key challenges will face the world's energy industry over the next few decades to ensure a smooth transition—challenges which will require government and industry solutions beginning as early as today. This paper identifies four critical challenges in energy and the choices which will have to be made on how best to confront growing pollution caused by fossil fuels and how to facilitate an eventual revolutionary-like transition to a non-carbon-based global economy.     

Techno-economic analysis of hydrogen transportation infrastructure using ammonia and methanol

The transformation from a fossil fuels economy to a low carbon economy reshapes how energy is transmitted. Since most renewable energy is harvested in the form of electricity, hydrogen obtained from water electrolysis using green electricity is considered a promising energy vector. However, the storage and transportation of hydrogen at large scales pose challenges to the existing energy infrastructures, both regarding technological and economic aspects. To facilitate the distribution of renewable energy, a set of candidate hydrogen transportation infrastructures using methanol and ammonia as hydrogen carriers were proposed. A systematical analysis reveals that the levelized costs of transporting hydrogen using methanol and ammonia in the best cases are $1879/t-H₂ and $1479/t-H₂, respectively. The levelized cost of energy transportation using proposed infrastructures in the best case is $10.09/GJ. A benchmark for hydrogen transportation infrastructure design is provided in this study.     

Climate changes,biofuels and the sustainable future

Climate change is one of the most dangerous problems of the contemporary world. We can either adapt to the corresponding changes or try to reduce their impact by significantly reducing fossil fuel burning. A hydrogen-based economy using energy from biomass, solar, wind and other renewable sources and/or nuclear energy seems to be a viable alternative. Here we analyse the possibilities of the biofuels to replace fossil fuels and their potential to contribute to hydrogen economy.     

Assessment of offshore liquid hydrogen production from wind power for ship refueling

Green hydrogen from electrolysis has become the most attractive energy carrier for making the transition from fossil fuels to carbon-free energy sources possible. Especially in the naval sector, hydrogen has the potential to address environmental targets due to the lack of low-carbon fuel options. This study aims at investigating an offshore liquefied green hydrogen production plant for ship refueling. The plant comprises a wind farm for renewable electricity generation, an electrolyzer stack for hydrogen production, a water treatment unit for demineralized water production, and a hydrogen liquefaction plant for hydrogen storage and distribution to ships. A pre-feasibility study is addressed to find the optimal capacities of the plant that minimize the payback time. The model results show that the electrolyzer capacity shall be set equal to a value between 80% and 90% of the wind farm capacity to achieve the minimum payback times. Additionally, the wind farm capacity shall be higher than about 150 MW to limit the payback time to values lower than 11 years for a fixed hydrogen price of 6 €/kg. The Levelized Cost of Hydrogen results to be below 4 €/kg for a wide range of plant capacities for a lifetime of the plant of 25 years. Thus, the model shows that this plant is economically feasible and can be reproduced similarly for different locations by rescaling the different selected technologies. In this way, the naval sector can be decarbonized thanks to a new infrastructure for the production and refueling of liquified green hydrogen directly provided on the sea.     

Hydrogen production using methane: Techno-economics of decarbonizing fuels and chemicals

In the near-to-medium future, hydrogen production will continue to rely on reforming of widely available and relatively low-cost fossil resources. A techno-economic framework is described that compares the current best practice steam methane reforming (SMR) with potential pathways for low-CO₂ hydrogen production; (i) Electrolysis coupled to sustainable renewable electricity sources; (ii) Reforming of hydrocarbons coupled with carbon capture and sequestration (CCS) and; (iii) Thermal dissociation of hydrocarbons into hydrogen and carbon (pyrolysis). For methane pyrolysis, a process based on a catalytic molten Ni-Bi alloy is described and used for comparative cost estimates. In the absence of a price on carbon, SMR has the lowest cost of hydrogen production. For low-CO₂ hydrogen production, methane pyrolysis is significantly more economical than electrochemical-based processes using commercial renewable power sources. At a carbon price exceeding $21 t^?1 CO₂ equivalent, pyrolysis may represent the most cost-effective means of producing low-CO₂ hydrogen and competes favorably to SMR with carbon capture and sequestration. The current cost disparity between renewable and fossil-based hydrogen production suggests that if hydrogen is to fulfil an expanding role in a low CO₂ future, then large-scale production of hydrogen from methane pyrolysis is the most cost-effective means during the transition period while infrastructure and end-use applications are deployed.