Pyrheliometric determination of atmospheric turbidity in the harmattan season over Ile-Ife, Nigeria

Measurements of direct solar radiation intensity, using an Angström compensation pyrheliometer carried out over three harmattan seasons (1985–1987) at Ile-Ife (7°29′N, 4°34′E), Nigeria, have been used to determine atmospheric turbidity based on five different models of turbidity viz:: Schüepp (B), Angstrom (β), Kastrov (C), Unsworth (τ_a) and Linke (T). The five parameters indicate high aerosol loading of the atmosphere during the period and high correlation is established between them: (0.919 r 0.999). An inverse relationship has been noticed between horizontal visibility and atmospheric turbidity: (−0.80 r −0.76).     

Global, direct and diffuse solar irradiance in Riyadh, Saudi Arabia

The regression coefficient of the well-known Angstrom correlation are determined for Riyadh city (the capital of Saudi Arabia) longitude 46° 14′E 24°55′N The relationship of the daily and monthly variation of the fraction of the diffuse solar irradiation to extrateresstrial and the clearness index are obtained. The variation of the values of the average daily global solar radiation against the month of the year is reported. The value of K_n defined as the ratio of direct normal Insolation, H_bn measured in Riyadh to direct normal solar extraterrestrial radiation with the K_T and K_d were obtained. The daily diffused ratio and the daily clearness index are shown as a function of the month of the year.     

First solar radiation atlas for the Arab world

In the year 1998, the Arab League Educational, Cultural and Scientific Organization (ALESCO), Directorate of Science and Scientific Research, Tunis, had launched the “Solar Radiation Atlas for the Arab World”. This atlas contains three sets of maps (using Mercator projection) for monthly means, where each stands for one month. These are sunshine duration, global solar radiation and diffuse solar radiation. The atlas contains data for nearly 280 stations from 19 Arab states which cover latitudes from 0° (tropic) to 37°N and longitudes 19°E to nearly 60°E with different elevations from the sea level. It also contains useful tables of the monthly recorded means of the direct, diffuse and global solar radiation as well as the sunshine duration for 16 Arab states including 207 cities.The maximum recorded annual mean (10 years) of the global solar radiation in the Arab world was 6.7 kW h/m²/day in Nouakchott (latitude 20°56′N, longitude 17°02′E), Mauritania, and 6.6 kW h/m²/day in Tamenraset (latitude 36°11′N and longitude 5°31′E), Algeria, while the lowest recorded annual mean global solar radiation was 4.1 kW h/m²/day in Mosul (latitude 43°N and longitude 36°E), Iraq. Furthermore, the maximum recorded annual mean sunshine duration in the Arab world was 10.7 h in Aswan (latitude 23°58′N, longitude 32°47′E), Egypt, and the lowest was 7.5 h in Tunis (latitude 36°50′N, longitude 10°14′E), Tunisia.     

Contact resistivities of sputtered TiN and Ti---TiN metallizations on solar-cell-type-silicon

Contact resistivities of TiN and Ti---TiN contacts on a shallow junction solar-cell-type silicon substrate have been investigated. The contact materials were sputter-deposited. The method of the transmission line model was applied for contact resistivity measurements. The contact resistivity of the n⁺Si---TiN contact system was 2 × 10⁻³ Ωcm² ± 50 per cent and remained constant after annealing up to 700°C for 30 min. For the n⁺Si---Ti---TiN system, the contact resistivity of 9 × 10⁻⁴ Ωcm² ± 50 per cent was measured. A heat treatment of 700°C. 30 min decreases this value by one order of magnitude and the interposed Ti fully reacts with Si and forms a TiSi₂ layer. The voltage drop caused by the n⁺Si---TiN contact system in a standard non-concentrator solar cell is negligible. The n⁺Si---TiSi₂---TiN contact system should be acceptable for Si solar cells used at up to 100 times solar concentration.     

Equations for estimating global solar radiation in data sparse regions

The knowledge of the amount of solar radiation in an area/region is very essential in the field of Solar Energy Physics. In this work two equations are put forward for estimating global solar radiation from common climate variables in data sparse regions. The first is the Hargreaves equation, R_s=0.16R_aT_d^0.5 where R_a is the extraterrestrial solar radiation and T_d is the temperature difference (maximum minus minimum), while the second is the Angstrom equation, R_s=R_a(0.28+0.39n/N) where n and N are the measured sunshine hours and the maximum daylight duration respectively. The global solar radiation estimated by the two equations for three sites, Owerri (5°28′N, 7°2′E), Umudike (5°29′N, 7°33′E) and Ilorin (8°32′N, 4°46′E), located in different climate zones of in Nigeria, West Africa, are in agreement with those of earlier workers and that from Photovoltaic Geographic Information System (PVGIS) project. The implication of this in solar photovoltaic applications has been stressed.     

Total suspended particles and solar radiation over Cairo and Aswan

Measurements were carried out at Cairo (30.05°N, 31.17°E) and Aswan (23.58°N, 32.47°E) in Egypt for three years (1990–1992) by the Egyptian Meteorological Authority. The measurements were done using an Eppley ultraviolet radiometer to measure the global ultraviolet solar radiation (UV), Eppley pyranometers to measure the global solar radiation (G) and the pyrgeometers with silicon dome from Eppley to measure the atmospheric infrared radiation (IR). The clearness index (K_t) and the diffuse fraction (K_d) for both regions have been calculated. Finally the total suspended particles for Cairo and Helwan and their interaction with the solar radiation has been found.     

Investigation of solar radiation in Botswana and some anomalous phenomena observed

Daily global insolation on a horizontal surface in Botswana is recorded continuously at several synoptic stations and at the University of Botswana's Physics Department. Over a number of years, daily total insolation on a tilted surface (β = −30°) was recorded at the Botswana Technology Centre. Hourly, and instantaneous direct normal, global, diffuse and UV-components are continuously recorded at the University of Botswana. All these measurements are done with standard EPLAB equipment.It is found out that the instantaneous direct normal radiation at Solar noon can be as high as 1150 W·m⁻²; and that at 30 min before sunset it can be above 600 W·m⁻²; and it can also be as high as 100 W·m⁻² at sunset or sunrise moments (i.e. with half of the solar disk under the horizon).Daily direct normal solar radiation can exceed 45 MJ·m⁻². Mean daily global radiation varies from 31 MJ·m⁻² in December to 16 MJ·m⁻² in June. Such big values of daily direct normal and global radiation are explained by low humidity and low turbidity.Cases of an anomalous phenomenon which lead to an abnormally big phase shift when direct normal radiation is increasing greatly after Solar noon are observed, and discussed. It is also found that when humidity is low and visibility is high, hourly I_g values recorded with a pyranometer can be less than I_bn (cosθ_z) + I_d-values. This discrepancy could be quite common for regions where humidity and turbidity are low. The trend in the behaviour of the UV-component during the last five years is also analyzed and discussed. The conclusion is made that the ozone layer over Botswana is continuously being depleted.     

A study of Canadian diffuse and total solar radiation data—II Monthly average hourly horizontal radiation

Optimum collector slope for a liquid base active solar heating system employing flat-plate collectors was investigated. The optimum collector slope was studied as a function of (a) collector area, (b) yearly total heating load and (c) the ratio of space heating load to service hot water load. Collectors facing equator only were considered. Such a system was studied in four different Canadian locations having widely different climates. Under the above conditions, optimum collector slope varied with the amount of collector area employed. The optimum collector slope was invariant with the yearly total load itself, or the space heating to hot water load ratio. Contrary to the widely held belief, for the four locations investigated, the optimum collector slope varied from lat. − 10° to lat. + 15°; depending upon f_y, the fraction of load supplied by the solar system. When f_y is in 10–20 per cent range, optimum collector slope is lat. − 10° and increases almost linearly to lat.+ 15° at f_y in 80 per cent range. Consequently, when the fraction of load by the solar system is low, a flat roof may be profitably employed. On the other hand, when the fraction by the solar system is high, a south facing (for northern hemisphere) vertical wall may be profitably employed.     

Forecasting based on neural network approach of solar potential in Turkey

As Turkey lies near the sunny belt between 36 and 42°N latitudes, most of the locations in Turkey receive abundant solar energy. Average annual temperature is 18–20 °C on the south coast, falls down to 14–16 °C on the west coast, and fluctuates 4–18 °C in the central parts. The yearly average solar radiation is 3.6 kW h/m² day, and the total yearly radiation period is 2610 h. The main focus of this study is put forward to solar energy potential in Turkey using artificial neural networks (ANNs). Scaled conjugate gradient (SCG), Pola-Ribiere conjugate gradient (CGP), and Levenberg–Marquardt (LM) learning algorithms and logistic sigmoid transfer function were used in the network. In order to train the neural network, meteorological data for last 4 years (2000–2003) from 12 cities (Çanakkale, Kars, Hakkari, Sakarya, Erzurum, Zonguldak, Balıkesir, Artvin, Çorum, Konya, Siirt, Tekirdağ) spread over Turkey were used as training (nine stations) and testing (three stations) data. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, and mean temperature) is used as input to the network. Solar radiation is the output. The maximum mean absolute percentage error was found to be less than 6.78% and R² values to be about 99.7768% for the testing stations. These values were found to be 5.283 and 99.897% for the training stations. The trained and tested ANN models show greater accuracy for evaluating solar resource posibilities in regions where a network of monitoring stations have not been established in Turkey. The predictions from ANN models could enable scientists to locate and design solar energy systems in Turkey and determine the best solar technology.     

Performance of solar driven methanol–water combined ejector–absorption cycle in the Athens area

The performance of a solar driven CH₄O-H₂O combined ejector– absorption unit, operating in conjunction with intermediate temperature solar collectors in Athens, is predicted along the five months (May–September) in case of the unit working as heat pump in an industrial area. The operation of the unit and the related thermodynamics are simulated by suitable computer codes and the required local climatological data are determined by statistical processings over a considerable number of years. It is found that the heat gain factor varies in the range from 2.1330 to 2.4481 for the above period of time. The maximum HGF of about 2.4481 is obtained in July at 14.25 hrs with corresponding specific heat gain power 915 W/m². The maximum Q_gain of about 1086 W/m² is obtained in June at 12.54 hrs with corresponding HGF 2.3572. Also the maximum value of HGF was estimated by correlation of three temperatures: generator temperature (85.0°C–97.2°C), condenser temperature (43.3°C–47.6°C) and evaporator temperature (12.6°C–25.4°C).     

High-temperature optical properties and stability of AlxOy–AlNx–Al solar selective absorbing surface prepared by DC magnetron reactive sputtering

Al_xO_y–AlN_x–Al selective absorbing surface was prepared by DC magnetron reactive sputtering with aluminum alloy (LY13)¹ in air and argon. The studies were carried out to access the high-temperature (400°C–600°C) optical properties and stability of the coatings. The coatings were found to withstand heating at 600°C for 30 min in 4.5×10⁻³ Pa vacuum with absorptance 0.94 and emittance 0.07 after annealing. After heating at 450°C for 10 h, the specimen still had good performance whose absorptance and emittance was 0.93 and 0.07, respectively. Auger electron spectroscopy was used to analyse the structure of the solar selective surface before and after annealing.     

The obstructed diffusion of the I3 ion in mesoscopic TiO2 membranes

The diffusional permeability of I⁻₃ ion in acetonitrile in free standing TiO₂ membrane with a porosity of 55% was examined. The apparent diffusion coefficient, D_app at 25°C of the ion was found to be 3.4×10⁻⁶ cm^{2 −1}, an order of magnitude smaller than the free diffusion at the same temperature. The temperature dependency of D_app was measured in the range 0–30°C and analysed in terms of the Walden product. The diffusional activation energy was found to be 13.5 kJ/mol. The parameters of interest for the efficiency of mesoscopic wet solar cells are discussed. A back of an envelope calculation shows that although the obstructed diffusion coefficient of the I⁻₃ ion was an order of magnitude smaller than the free diffusion the diffusional flux is still sufficient to meet a current density of 50 mA cm⁻². At incident photon flux of 1 kW m⁻² and at a photopotential of 0.6 V this would correspond to a solar energy efficiency of approximately 30%.     

Spatial estimation of global solar radiation using geostatistics

The number of radiation data collection stations is limited due to economic reasons. Hence, there is a need for the spatially continuous mapping of solar radiation by estimation. This paper utilizes a geostatistical technique for the estimation of solar radiation in Saudi Arabia. This technique includes five steps: (i) data collection, (ii) univariate analysis, (iii) experimental variogram calculations and model fitting, (iv) estimation using kriging, and (v) plotting contour maps. Variogram models are fitted to measured variograms for each month of the year. Estimates were obtained at 1500 grid points (30 × 50) between a longitude of 36.58°E and 50.00°E, and latitude of 17.17°N and 31.33°N for a grid resolution of 55 × 33 km. These values were used to plot the contour maps of solar radiation for each month of the year. To test the performance of the technique, estimates were obtained at the 41 known locations by systematically excluding one of these points from the known data. The error analysis showed a maximum mean deviation between measured and estimated values of 0.0037 (January) and a minimum of 0.0013 (March and October). The mean percent errors were found to vary between a minimum of 0.5% and a maximum of 1.7%. This technique may be expanded for the spatial estimation of solar radiation on regional and continental scales.     

Optimization of process parameters in a large-area hot-wire CVD reactor for the deposition of amorphous silicon (a-Si:H) for solar cell application with highly uniform material quality

Scale-up of a-Si:H-based thin film applications such as solar cells, entirely or partly prepared by hot-wire chemical vapor deposition (HWCVD), requires research on the deposition process in a large-area HWCVD system. The influence of gas supply and filament geometry on thickness uniformity has already been reported, but their influence on material quality is systematically studied for the first time. The optimization of deposition parameters for obtaining best material quality in our large-area HWCVD system resulted in an optimum filament temperature, T_fil≈1600°C, pressure, p=8 mTorr and silane flow, F(SiH₄)=100 sccm, keeping the substrate temperature at T_S=200°C. A special gas supply (gas shower with tiny holes of uniform size) and a filament grid, consisting of six filaments with an interfilament distance, d_fil=4 cm were used. The optimum filament-to-substrate distance was found to be d_fil–S=8.4 cm. While studying the influence of different d_fil and gas supply configurations on the material quality, the above-mentioned setup and parameters yield best results for both uniformity and material quality. With the setup mentioned, we could achieve device quality a-Si:H films with a thickness uniformity of ±2.5% on a circular area of 20 cm in diameter. The material, grown at a deposition rate of r_d≈4 Å/s, was characterized on nine positions of the 30 cm×30 cm substrate area, and revealed reasonable uniformity of the opto-electronic properties, e.g photosensitivity, σ_Ph/σ_D=(2.46±0.7)×10⁵, microstructure factor, R=0.17±0.05, defect densities, N_d(PDS)=(2.06±0.6)×10¹⁷ cm⁻³ and N_d(CPM)=(2.05±0.5)×10¹⁶ cm⁻³ (film properties are given as mean values and standard deviations). Finally, we fabricated pin solar cells, with the i-layer deposited on small-area p-substrates distributed over an area of 20 cm×20 cm in this large-area deposition system, and achieved high uniformity of the cell parameters with initial efficiencies of η=(6.1±0.2)% on the 20 cm×20 cm area.     

Correlation between global ultraviolet (290–385nm) and global irradiation in Valencia and Cordoba (Spain)

This paper analyses hourly data of global ultraviolet (290–385nm) and global irradiation over a horizontal surface. The data was taken in Valencia (39.5°N, 0.341W) and Córdoba (37.51°N, 4°48W), (Spain) during the years 1996–1999. In order to estimate the ultraviolet solar radiation using global solar radiation values over a horizontal surface, the method of Foyo-Moreno et al. (Foyo-Moreno, I., J. Vida and L. Alados-Arboleda. J. Appl. Meteor. 1998, 38, 1020–1026) has been used. The results obtained with this method are satisfactory with a determination ratio r²=0.98, RMSE=9.3%, MBE=0.5% for Valencia and r²=0.99, RMSE=6.2%, MBE=0.3% for Córdoba.     

Prediction and Performance Assessment of Mean Hourly Global Radiation

Using a large dataset of 135 stations encompassing very diverse geographic locations (82.5°N to 67.6°S) and climates, two new models are presented to predict the monthly-average hourly global irradiation distribution from its daily counterpart. It is found that a quadratic in the sine of solar elevation fits the data very well at all locations. Other parameters include the mean monthly clearness index, K_t, the average day length, and the daily average solar elevation. Based on this dataset, a detailed performance assessment is conducted for these new models, as well as for six models of the literature. Their respective performance is discussed, particularly with respect to the latitudinal effect. The proposed models appear to correctly predict irradiations even for a very low sun typical of near-polar night conditions. The accurate predictions of the newly proposed ‘daily integration model’ translate into the lowest yearly-average and site-average Root Mean Square Difference, a statistic obtained by comparison with 21 722 measured hourly irradiations. However, it is stressed that the performance of this kind of model is seriously limited by artefacts due to shading (e.g., from mountains), and, more importantly, by strong morning/afternoon radiative asymmetries due to local or climatological influences, which cannot be predicted from just daily irradiation data.     

Thermochemical hydrogen production by a redox system of ZrO2-supported Co(II)-ferrite

The thermochemical two-step water splitting was examined on ZrO₂-supported Co(II)-ferrites below 1400 °C, for purpose of converting solar high-temperature heat to clean hydrogen energy as storage and transport of solar energy. The ferrite on the ZrO₂-support was thermally decomposed to the reduced phase of wustite at 1400 °C under an inert atmosphere. The reduced phase was reoxidized with steam on the ZrO₂-support to generate hydrogen below 1000 °C in a separate step. The ZrO₂-supporting alleviated the high-temperature sintering of iron oxide. As the results, the ZrO₂-supported ferrite realized a greater reactivity and a better repeatability of the cyclic water splitting than the conventional unsupported ferrites. The Co_xFe_3−xO₄/ZrO₂ with the x value of around 0.4–0.7 was found to be the promising working material for the two-step water splitting when thermally reduced at 1400 °C under an inert atmosphere.     

Angular distribution of clear sky short wavelength radiance

Over 3000 scans of the clear sky short wavelength (0.3–3.0 μm) radiance were used to produce sky radiance contour maps for solar zenith angles 32° to 80°. The radiance contours are symmetrical about the solar meridian with minimum radiance in the solar meridian at approximately 90° to 110° from the sun. There is no significant change in contour for a change in aerosol optical depth from 0.1 to 0.5. The clear sky radiance is given analytically by N(ψ) = (1.63 + 53.7e−5.49ψ + 2.04 cos² ψ cos θ^*) (1 − e^{−1.90 sec θ}) (1 − e^{−0.53 sec θ}*) where θ^* is the solar zenith angle, θ the zenith angle of the sky radiance direction, and Ψ is the scattering angle between sky and sun directions.     

Spectrally selective laminated glazing consisting of solar control and heat mirror coated glass: preparation, characterization and modelling of heat transfer

In this study, solar control coatings were prepared by sequential depositions of thin films of ZnS (40 nm)–CuS (150 nm) and ZnS (40 nm)–Bi₂S₃ (75 nm)–CuS (150 nm) from chemical baths on 3 mm thick commercial sheet glass. These were laminated to 3 mm thick clear glass or commercially available SnO₂ based heat mirror coating of sheet resistance 15 Ω on float glass of 3 mm thickness using a poly(ethylene vinyl acetate), EVA, sheet of 0.36 mm thickness in a vacuum process at 120 °C for 30 min. In total, the thickness of the glazing was 6.35 mm. The glazings possess visible transmittance, weighted for D65 solar spectra and sensitivity of the human eye for daylight vision, of 36% or 14% with solar absorptance of 71% or 78% depending on the coating type, i.e ZnS–CuS or ZnS–Bi₂S₃–CuS-heat mirror respectively. The solar heat gain coefficient (SHGC) was evaluated for these glazings at exterior temperatures of 15 and 32 °C for an exterior convective heat transfer coefficient (h_ex) of 6–100 Wm⁻² K⁻¹ using a mathematical model. The model predicts the extent of reduction in SHGC through the presence of the heat mirror coating as a function of h_ex and hence helps to decide on the relative benefit, which may be derived through their use in different locations. Though the deposition technique mentioned here involves longer duration compared with vacuum techniques, it may be developed into a low throughput, low-capital alternate technology for small-scale production.     

Intergration of evacuated tubular solar collectors with lithium bromide absorption cooling systems

By surrounding the absorber-heat exchanger component of a solar collector with a glass-enclosed evacuated space and by providing the absorber with a selective surface, solar collectors can operate at efficiencies exceeding 50 per cent under conditions of ΔT/H_T = 75°C m²/kW (ΔT = collector fluid inlet temperature minus ambient temperature, H_T = incident solar radiation on a tilted surface). The high performance of these evacuated tubular collectors thus provides the required high temperature inputs (70–88°C) of lithium bromide absorption cooling units, while maintaining high collector efficiency. This paper deals with the performance and analysis of two types of evacuated tubular solar collectors intergrated with the two distinct solar heating and cooling systems installed on CSU Solar Houses I and III.