太阳能热发电站熔盐储罐首次充盐策略研究

通过计算流体动力学(CFD)模拟计算分析某实际工程设计阶段的充盐策略参数,对储罐内熔盐温度和储罐壁面温度的影响,通过分析模拟结果后确定在项目具体实施阶段采用预热系统及电加热器系统配合的充盐策略.通过将此充盐策略用于实际商业项目第1次充盐过程,效果良好,储罐整体温度较为均匀,同时也发现在第1次充盐过程中储罐基础存在较为明...     

大直径高温熔盐储罐罐顶接管的强度及罐体稳定性分析

随着可再生能源技术的大力发展与应用,对太阳能热发电站中持久储热的钢制储罐的安全性能进行研究具有重要意义.以青海省某塔式太阳能热发电站中直径为25 m的高温熔盐储罐(储热罐)为例,利用ANSYS软件的平面实体轴对称单元建立了储罐有限元模型,着重对储罐顶部与熔盐管道接口处进行了强度和稳定性分析,通过对管道连接部位进行局部精...     

Investigation of boiling heat transfer for improved performance of metal hydride thermal energy storage

The inherent nature concerning the intermittency of concentrating solar power (CSP) plants can be overcome by the integration of efficient thermal energy storage (TES) systems. Current CSP plants employ molten salts as TES materials although metal hydrides (MH) have proven to be more efficient due to their increased operating temperatures. Nonetheless, the heat exchange between the MH bed and the heat transfer medium used to operate a heat engine is a critical factor in the overall efficiency of the TES system. In this work, a computational study is carried out to investigate the performance of a magnesium hydride TES packed bed using a multiphase (boiling) medium instead of single-phase heat absorption methods. The boiling heat transfer behaviour is simulated by using the Eulerian two-fluid framework. The simulations are conducted at a transient state using SST-k-ω Reynolds-Averaged Navier-Stokes equations. It is observed that, unlike the single-phase heat collection method, the multiphase heat absorption method maintains a constant temperature in the heat transfer fluid throughout the reactor. Consequently, a higher temperature gradient is realised between the MH bed and heat transfer fluid (HTF), leading to improvements in the overall reaction rate of the hydrogenation process.     

The potential of metal hydrides paired with compressed hydrogen as thermal energy storage for concentrating solar power plants

Concentrating solar power (CSP) plants require thermal energy storage (TES) systems to produce electricity during the night and periods of cloud cover. The high energy density of high-temperature metal hydrides (HTMHs) compared to state-of-the-art two-tank molten salt systems has recently promoted their investigation as TES systems. A common challenge associated with high-temperature metal hydride thermal energy storage systems (HTMH TES systems) is storing the hydrogen gas until it is required by the HTMH to generate heat. Low-temperature metal hydrides can be used to store the hydrogen but can comprise a significant proportion of the overall system cost and they also require thermal management, which increases the engineering complexity. In this work, the potential of using a hydrogen compressor and large-scale underground hydrogen gas storage using either salt caverns or lined rock caverns has been assessed for a number of magnesium- and sodium-based hydrides: MgH₂, Mg₂FeH₆, NaMgH₃, NaMgH₂F and NaH. Previous work has assumed that the sensible heat of the hydrogen released from the HTMH would be stored in a small, inexpensive regenerative material system. However, we show that storing the sensible heat of the hydrogen released would add between US$3.6 and US$7.5/kWh_th to the total system cost for HTMHs operating at 565 °C. If the sensible heat of released hydrogen is instead exploited to perform work then there is a flow-on cost reduction for each component of the system. The HTMHs combined with underground hydrogen storage all have specific installed costs that range between US$13.7 and US$26.7/kWh_th which is less than that for current state-of-the-art molten salt heat storage. Systems based on the HTMHs Mg₂FeH₆ or NaH have the most near term and long term potential to meet SunShot cost targets for CSP thermal energy storage. Increasing the operating temperature and hydrogen equilibrium pressure of the HTMH is the most effective means to reduce costs further.     

Economic implications of thermal energy storage for concentrated solar thermal power

Solar energy is an attractive renewable energy source because the sun's energy is plentiful and carbon-free. However, solar energy is intermittent and not suitable for base load electricity generation without an energy backup system. Concentrated solar power (CSP) is unique among other renewable energy options because it can approach base load generation with molten salt thermal energy storage (TES). This paper describes the development of an engineering economic model that directly compares the performance, cost, and profit of a 110-MW parabolic trough CSP plant operating with a TES system, natural gas-fired backup system, and no backup system. Model results are presented for 0–12 h backup capacities with and without current U.S. subsidies. TES increased the annual capacity factor from around 30% with no backup to up to 55% with 12 h of storage when the solar field area was selected to provide the lowest levelized cost of energy (LCOE). Using TES instead of a natural gas-fired heat transfer fluid heater (NG) increased total plant capital costs but decreased annual operation and maintenance costs. These three effects led to an increase in the LCOE for PT plants with TES and NG backup compared with no backup. LCOE increased with increasing backup capacity for plants with TES and NG backup. For small backup capacities (1–4 h), plants with TES had slightly lower LCOE values than plants with NG backup. For larger backup capacities (5–12 h), plants with TES had slightly higher LCOE values than plants with NG backup. At these costs, current U.S. federal tax incentives were not sufficient to make PT profitable in a market with variable electricity pricing. Current U.S. incentives combined with a fixed electricity price of $200/MWh made PT plants with larger backup capacities more profitable than PT plants with no backup or with smaller backup capacities. In the absence of incentives, a carbon price of $100–$160/tonne CO_2eq would be required for these PT plants to compete with new coal-fired power plants in the U.S. If the long-term goal is to increase renewable base load electricity generation, additional incentives are needed to encourage new CSP plants to use thermal energy storage in the U.S.     

Experimental investigation of a molten salt thermocline storage tank

Thermal energy storage is considered as an important subsystem for solar thermal power stations. Investigations into thermocline storage tanks have mainly focused on numerical simulations because conducting high-temperature experiments is difficult. In this paper, an experimental study of the heat transfer characteristics of a molten salt thermocline storage tank was conducted by using high-temperature molten salt as the heat transfer fluid and ceramic particle as the filler material. This experimental study can verify the effectiveness of numerical simulation results and provide reference for engineering design. Temperature distribution and thermal storage capacity during the charging process were obtained. A temperature gradient was observed during the charging process. The temperature change tendency showed that thermocline thickness increased continuously with charging time. The slope of the thermal storage capacity decreased gradually with the increase in time. The low-cost filler material can replace the expensive molten salt to achieve thermal storage purposes and help to maintain the ideal gravity flow or piston flow of molten salt fluid.     

Modelling and simulation of a molten salt loop of a solar tower power plant in a Modelica environment

CSP（concentrated solar power）系统通过聚焦太阳光进行光热发电,主要工作介质包括导热油及熔盐。由于太阳能的不连续性,为了提供更稳定的能量输出,发展出了采用熔盐为储热工质进行蓄热的系统,该系统同时也提供了与其它能源系统耦合的可行性。该系统的熔盐回路主要由3个部分构成,分别为集热器、高低温储热罐和蒸汽发生器。通过对50 MW塔式太阳能的热发电系统熔盐回路的各个组件的模型进行建立,设计一套与之相应的控制系统,并针对不同工况下,各个组件及整个系统的响应进行了模拟,得出熔盐回路的瞬态响应特性。由于其熔盐回路与熔盐反应堆具有一定的相似性,本研究也可为熔盐反应堆核能综合利用中储能系统提供参考。     

Development of graphite foam infiltrated with MgCl2 for a latent heat based thermal energy storage (LHTES) system

Thermal energy storage (TES) systems that are compatible with high temperature power cycles for concentrating solar power (CSP) require high temperature media for transporting and storing thermal energy. To that end, TES systems have been proposed based on the latent heat of fusion of the phase change materials (PCMs). However, PCMs have relatively low thermal conductivities. In this paper, use of high-thermal-conductivity graphite foam infiltrated with a PCM (MgCl₂) has been investigated as a potential TES system. Graphite foams with two porosities were infiltrated with MgCl₂. The infiltrated composites were evaluated for density, heat of fusion, melting/freezing temperatures, and thermal diffusivities. Estimated thermal conductivities of MgCl₂/graphite foam composites were significantly higher than those of MgCl₂ alone over the measured temperature range. Furthermore, heat of fusion, melting/freezing temperatures, and densities showed comparable values to those of pure MgCl₂. Results of this study indicate that MgCl₂/graphite foam composites show promise as storage media for a latent heat thermal energy storage system for CSP applications.     

Comparative system analysis of direct steam generation and synthetic oil parabolic trough power plants with integrated thermal storage

Parabolic trough power plants are currently the most commercially applied systems for CSP power generation. To improve their cost-effectiveness, one focus of industry and research is the development of processes with other heat transfer fluids than the currently used synthetic oil. One option is the utilization of water/steam in the solar field, the so-called direct steam generation (DSG).Several previous studies promoted the economic potential of DSG technology (Eck et al., 2008b, Price et al., 2002, Zarza, 2002). Analyses’ results showed that live steam parameters of up to 500 °C and 120 bars are most promising and could lead to a reduction of the levelized electricity cost (LEC) of about 11% (Feldhoff et al., 2010). However, all of these studies only considered plants without thermal energy storage (TES).Therefore, a system analysis including integrated TES was performed by Flagsol GmbH and DLR together with Solar Millennium AG, Schott CSP GmbH and Senior Berghöfer GmbH, all Germany. Two types of plants are analyzed and compared in detail: a power plant with synthetic oil and a DSG power plant. The design of the synthetic oil plant is very similar to the Spanish Andasol plants (Solar Millennium, 2009) and includes a molten salt two-tank storage system. The DSG plant has main steam parameters of 500 °C and 112 bars and uses phase change material (PCM) for the latent and molten salt for the sensible part of the TES system. To enable comparability, both plants share the same gross electric turbine capacity of 100 MWel, the same TES capacity of 9 h of full load equivalent and the same solar multiple of the collector field of about two.This paper describes and compares both plants’ design, performance and investment. Based on these results, the LEC are calculated and the DSG plant’s potential is evaluated. One key finding is that with currently proposed DSG storage costs, the LEC of a DSG plant could be higher than those of a synthetic oil plant. When considering a plant without TES on the other hand, the DSG system could reduce the LEC. This underlines the large influence of TES and the still needed effort in the development of a commercial storage system for DSG.     

Comparative study of single and multi-layered packed-bed thermal energy storage systems for CSP plants

The Multi-layered Thermal Energy Storage (TES) tank consists of three regions–top and bottom part is packed with suitable Phase Change Materials (PCM) and low-cost pebbles are placed in the middle region, whereas entire tank portion is filled by solid fillers in Single-layered tank system. For a storage tank operating between 563 and 663 K with bed dimensions of 12 and 14.38 m using Solar salt as Heat Transfer Fluid (HTF), it is observed that the duration of discharge for multi-layered tank is 5.32 h whereas it is 4.19 h for single-layered tank with a Reynolds number of 10. The effect of intermediate melting temperature range of PCMs are also analyzed by taking PCMs with sharp as well as intermediate melting ranges. Further, comparison of single and multi-layered systems is carried out by analyzing the temperature profiles and width of both PCM layers. The width of top and bottom PCM layers of tank is varied from 0 to 30% to analyze its effect on the discharging duration. It is observed that multi-layered system provides extra discharge of 1 h with introduction of PCM at top and bottom with a width of 10%. Discharge duration increases with increase in PCM width whereas the percentage increase in duration of discharge with increase in PCM width is comparatively less. It is also seen that PCMs with sharp melting point performs better compared to one having intermediate range of melting temperatures. Multi-layered configuration concept offers best possibilities as integration to CSP plants with desired efficiency.     

熔融盐斜温层蓄热的热特性研究

对熔融盐高温斜温层蓄热过程进行较深入的理论与实验研究,建立熔融盐单相流体斜温层蓄热的瞬态热分析模型,模型考虑熔融盐的变物性。利用Fluent软件,通过求解N-S方程与能量方程,对熔融盐单相流体斜温层蓄热罐在各工况条件下的传热蓄热过程进行数值模拟。研究时间进程、初始条件以及结构尺寸等对蓄热性能的影响。结果表明:斜温层的厚度随时间的推移而增加,达到一定厚度后增加量趋缓;流体进口流速、长径比等是影响有效蓄热容量的主要因素,当进口速度为0.001m/s级、长径比为2∶1时,将减少斜温层厚度。     

A literature review on some engineering issues of high temperature molten salt thermal energy storage systems

高温熔盐蓄热单元对平衡太阳能热发电过程中的能量供求和延长日落后的发电时间有着不可替代的作用,并已经成为现代太阳能热发电站中的一个不可或缺的子系统。本文作者结合所在重点实验室的850 ℃的二元碳酸优态盐高温熔盐蓄热实验系统的安装与操作经验,讨论了高温熔融盐蓄热系统中常见的一些工程问题,包括熔盐输送管道的连接、熔盐回路的预防凝固和加热保温、熔盐的充装与排放、熔盐长轴泵、事故工况的研究和预防等。     

Advances in thermal energy storage development at the German Aerospace Center(DLR)

Thermal energy storage(TES)is a key technology for renewable energy utilization and the improvement of the energy efficiency of heat processes.Sectors include industrial process heat and conventional and renewable power generation.TES systems correct the mismatch between supply and demand of thermal energy.In the medium to high temperature range(100~1000℃),only limited storage technology is commercially available and a strong effort is needed to develop a range of storage technologies which are efficient and economical for the very specific requirements of the different application sectors.At the DLR's Institute of Technical Thermodynamics,the complete spectrum of high temperature storage technologies,from various types of sensible over latent heat to thermochemical heat storages are being developed.Different concepts are proposed depending on the heat transfer fluid(synthetic oil,water/steam,molten salt,air)and the required temperature range.The aim is the development of cost effective,efficient and reliable thermal storage systems.Research focuses on characterization of storage materials,enhancement of internal heat transfer,design of innovative storage concepts and modelling of storage components and systems.Demonstration of the storage technology takes place from laboratory scale to field testing(5 kW^1 MW).The paper gives an overview on DLR's current developments.     

Experimental characterisation of a thermal energy storage system using temperature and power controlled charging

The experimental set-up and technical aspects for charging a thermal energy storage (TES) of a proposed solar cooker at constant temperature and variable electrical power are presented. The TES is developed using a packed pebble bed. An electrical hot plate simulates the concentrator which heats up oil circulating through a copper coil absorber charging the TES system. A computer program to acquire data for monitoring the storage system and to maintain a nearly constant outlet charging temperature is developed using Visual Basic. The input power to the hot plate is also controlled to simulate the variation of the daily solar radiation by using another Visual Basic program. A combined internal model control (IMC) and proportional, integral and derivative (PID) temperature control structure is tested on the TES system under varying conditions and its performance is reasonable within a few degrees of the set temperature points. Results of the charging experiments are used to characterise the storage system. The different experiments indicate various degrees of stratification in the storage tank.     

Design and analysis of a solar tower power plant integrated with thermal energy storage system for cogeneration

In the current study, a solar tower–based energy system integrated with a thermal energy storage option is offered to supply both the electricity and freshwater through distillation and reverse osmosis technologies. A high‐temperature thermal energy storage subsystem using molten salt is considered for the effective and efficient operation of the integrated system. The molten salt is heated up to 565°C through passing the solar tower. The thermal energy storage tanks are designed to store heat up to 12 hours. The temperature variations in the storage tanks are studied and compared accordingly for evaluation. The effect of operating temperatures on the freshwater production and overall system efficiency is determined. About 24.46 MW electricity is generated in the steam turbine under sunny conditions. Furthermore, the storage subsystem stores heat during sunny hours to utilize later in cloudy hours and night time. The produced power decreases to 20.17 MW in discharging hours due to temperature decrease in the tank. The electricity generated by the system is then used to produce freshwater through the reverse osmosis units and also to supply electricity for the residential use. A total flowrate of 240.02 kg/s freshwater is obtained by distillation and reverse osmosis subsystems.     

Ethanol steam reforming heated up by molten salt CSP: Reactor assessment

In this paper hydrogen production via reforming of ethanol has been studied in a novel hybrid plant consisting in a ethanol reformer and a concentrating solar power (CSP) plant using molten salt as heat carrier fluid. The heat needed for the reforming of ethanol has been supplied to the system by molten salts heated up by solar energy. The molten salt stream temperature drop for supplying hydrogen production process heat duty is less than 20 K, making the molten salt stream still suitable for steam and electricity production in a co-generative plant (clean hydrogen and electricity).     

熔盐储罐预热过程优化研究

基于CFD方法研究阶梯式预热过程中熔盐储罐温度分布和热应力分布,并分析温度端差和预热气体入口流量等参数对预热时间和罐体最大热应力的影响。结果表明：温度端差和质量流量各增加1倍时,预热时间分别缩短78.1%和61.5%,温度端差比质量流量对熔盐储罐预热过程的影响更显著。     

Innovative configuration of a hybrid nuclear-parabolic trough solar power plant

This paper proposes a combination of a nuclear and a concentrated solar power (CSP) plant. Most of today’s operating nuclear reactor systems are producing saturated steam at relatively low pressure. This, in turn, limits their thermodynamic efficiency. Superheating of nuclear steam with solar thermal energy has the potential to overcome this drawback. An innovative configuration of a hybrid nuclear-CSP plant is assembled and simulated. It brings together a small pressurised water reactor and a parabolic trough solar field. The solar heat is transferred to nuclear steam to raise its temperature. Continuous superheating is provided through molten salts-based thermal energy storage (TES). The results from design point calculations show that solar superheating has the potential to increase nuclear plant electric efficiency significantly. Solar heat to electricity conversion efficiency defined as the ratio of extra generated power to collected solar energy reaches unprecedented rates of 52%. An off-design model was used to simulate 24-h operation for one year by simulating 8760 cases. Due to TES non-stop operation is manageable.     

Recent Developments in Integrated Solar Combined Cycle Power Plants

Global concern for depleting fossil fuel reserves have been compelling for evolving power generation options using renewable energy sources. The solar energy happens to be a potential source for running the power plants among renewable energy sources. Integrated Solar Combined Cycle(ISCC) power plants have gained popularity among the thermal power plants. Traditional ISCC power plants use Direct Steam Generation(DSG) approach. However, with the DSG method, the ISCC plant’s overall thermal efficiency does not increase significantly due to variations in the availability of solar energy. Thermal Energy Storage(TES) systems when integrated into the solar cycle can address such issues related to energy efficiency, process flexibility, reducing intermittency during non-solar hours. This review work focuses and discusses the developments in various components of the ISCC system including its major cycles and related parameters. The main focus is on CSP technologies, Heat Transfer Fluid(HTF), and Phase Change Material(PCM) used for thermal energy storage. Further, study includes heat enhancement methods with HTF and latent heat storage system. This study will be beneficial to the power plant professionals intending to modify the solar-based Combined Cycle Power Plant(CCPP) and to retrofit the existing Natural Gas Combined Cycle(NGCC) plant with the advanced solar cycle.     

Potential applications of thermal energy storage in electric power generation sector (Ⅱ)

简要介绍了储热技术在电力系统中最有潜力的四种具体应用技术,包括太阳能热发电,压缩空气储能,深冷储能,热泵储电,指出了太阳能热发电储热技术在短期内具有很大发展潜力,目前双罐式液体显热储热(储冷)具有较好的整体效率,将在电力系统储热技术中发挥重要的作用.