InSe Schottky Diodes Based on Van Der Waals Contacts

2D semiconductors are excellent candidates for next‐generation electronics and optoelectronics thanks to their electrical properties and strong light‐matter interaction. To fabricate devices with optimal electrical properties, it is crucial to have both high‐quality semiconducting crystals and ideal contacts at metal‐semiconductor interfaces. Thanks to the mechanical exfoliation of van der Waals crystals, atomically thin high‐quality single‐crystals can easily be obtained in a laboratory. However, conventional metal deposition techniques can introduce chemical disorder and metal‐induced mid‐gap states that induce Fermi level pinning and can degrade the metal‐semiconductor interfaces, resulting in poorly performing devices. In this article, the electrical contact characteristics of Au–InSe and graphite–InSe van der Waals contacts, obtained by stacking mechanically exfoliated InSe flakes onto pre‐patterned Au or graphite electrodes without the need for lithography or metal deposition is explored. The high quality of the metal‐semiconductor interfaces obtained by van der Waals contact allows to fabricate high‐quality Schottky diodes based on the Au–InSe Schottky barrier. The experimental observation indicates that the contact barrier at the graphite–InSe interface is negligible due to the similar electron affinity of InSe and graphite, while the Au–InSe interfaces are dominated by a large Schottky barrier.     

Erosion and contact resistance performance of materials for slidingcontacts under arcing

In our previous work, we have investigated copper sliding switching contacts for automotive power applications. In order to improve their reliability, we have studied in this present paper, alternative materials to copper such as silver based materials (Ag, AgSnO₂, AgC, and AgCNi). Their performance was evaluated by measuring mass variations and contact resistance stability during sliding. The contacts are operated in a test machine during 50000 sliding operations, under inductive loads which produce long arcs, or under lamp loads which produce a short arc. In most cases, we have seen a significant wear of the anode compared to the cathode. We believe that the wear process for the sliding contact is the abrasion of the track by a rough contact surface. This roughness is produced and renewed by material transfer because of arcing. Regarding this wear, we show the medium performance of Ag and Cu contacts, while the worst performance is obtained with AgC and AgCNi, which make these latter materials unsuitable. Regarding contact resistance, we have measured low values <1 mΩ for AgC, AgCNi, and Ag. With AgSnO₂ and Cu contacts, the resistance ran reach high values, especially with an inductive load, which make these latter materials unsuitable. Concerning the effect of operating parameters, we show that polarity may emphasize the already poor performance of a high wear anode by disturbing the sliding motion. In addition, contact force and shape size are found to act on material performance: low force and large shape (cylinder) reduce wear and enhance resistance whereas high force and small shape increases wear and lowers contact resistance     

Influence of Thiol Self‐Assembled Monolayer Processing on Bottom‐Contact Thin‐Film Transistors Based on n‐Type Organic Semiconductors

The performance of bottom‐contact thin‐film transistor (TFT) structures lags behind that of top‐contact structures owing to the far greater contact resistance. The major sources of the contact resistance in bottom‐contact TFTs are believed to reflect a combination of non‐optimal semiconductor growth morphology on the metallic contact surface and the limited available charge injection area versus top‐contact geometries. As a part of an effort to understand the sources of high charge injection barriers in n‐channel TFTs, the influence of thiol metal contact treatment on the molecular‐level structures of such interfaces is investigated using hexamethyldisilazane (HMDS)‐treated SiO₂ gate dielectrics. The focus is on the self‐assembled monolayer (SAM) contact surface treatment methods for bottom‐contact TFTs based on two archetypical n‐type semiconductors, α,ω‐diperfluorohexylquarterthiophene (DFH‐4T) and N,N′bis(n‐octyl)‐dicyanoperylene‐3,4:9,10‐bis(dicarboximide) (PDI‐8CN₂). TFT performance can be greatly enhanced, to the level of the top contact device performance in terms of mobility, on/off ratio, and contact resistance. To analyze the molecular‐level film structural changes arising from the contact surface treatment, surface morphologies are characterized by atomic force microscopy (AFM) and scanning tunneling microscopy (STM). The high‐resolution STM images show that the growth orientation of the semiconductor molecules at the gold/SAM/semiconductor interface preserves the molecular long axis orientation along the substrate normal. As a result, the film microstructure is well‐organized for charge transport in the interfacial region.     

Electro–Chemo–Mechanical Issues at the Interfaces in Solid‐State Lithium Metal Batteries

Effective solid‐state interfacial contact of both the cathode and lithium metal anode with the solid electrolyte (SE) are required to improve the performance of solid‐state lithium metal batteries (SSBs). Electro–chemo–mechanical coupling (ECMC) strongly affects the interfacial stability of SSBs. On one hand, mechanical stress strongly influences interfacial contact and causes side reactions. On the other hand, electrochemical reactions such as lithium deposition cause mechanical deformation and stress at electrode/SE interfaces. To solve the degradation/failure problems of interfaces and provide guidelines to construct high‐performance SSBs, the ECMC at electrode/SE interfaces should be comprehensively investigated. In this review, the problems associated with ECMC at electrode/SE interfaces are summarized. The interfacial degradation/failure mechanisms, including the contact and electrochemical stability of interfaces, are introduced. Mechanical factors affecting interfacial contact and lithium deposition are highlighted. Experimental observation and computational analysis methods for electrode/SE interfaces are then summarized. Strategies to construct stable electrode/SE interfaces, such as assembling stress and wetting layers to improve interfacial contact, 3D SE structure, and plating stress relief to suppress lithium dendrite formation, are reviewed. The remaining challenges to better understanding ECMC and related solutions to aid SSB development are discussed.     

Flexible Stable Solid‐State Al‐Ion Batteries

Rechargeable aluminum‐ion batteries (AIBs) are regarded as promising candidates for post‐lithium energy storage systems (ESSs). For addressing the critical issues in the current liquid AIB systems, here a flexible solid‐state AIB is established using a gel‐polymer electrolyte for achieving robust electrode–electrolyte interfaces. Different from utilization of solid‐state systems for alleviating the safety issues and enhancing energy density in lithium‐ion batteries, employment of polymeric electrolytes mainly focuses on addressing the essential problems in the liquid AIBs, including unstable internal interfaces induced by mechanical deformation and production of gases as well as unfavorable separators. Particularly, such gel electrolyte enables the solid‐state AIBs to present an ultra‐fast charge capability within 10 s at current density of 600 mA g^?1. Meanwhile, an impressive specific capacity ≈120 mA h g^?1 is obtained at current density of 60 mA g^?1, approaching the theoretical limit of graphite‐based AIBs. In addition to the well‐retained electrochemical performance below the ice point, the solid‐state AIBs also hold great stability and safety under various critical conditions. The results suggest that such new prototype of solid‐state AIBs with robust electrode–electrolyte interfaces promises a novel strategy for fabricating stable and safe flexible ESSs.     

PID-type sliding mode-based adaptive motion control of a 2-DOF piezoelectric ultrasonic motor driven stage

This paper presents a new scheme of adaptive sliding mode control (ASMC) for a piezoelectric ultrasonic motor driven X–Y stage to meet the demand of precision motion tracking while addressing the problems of unknown nonlinear friction and model uncertainties. The system model with Coulomb friction and unilateral coupling effect is first investigated. Then the controller is designed with adaptive laws synthesized to obtain the unknown model parameters for handling parametric uncertainties and offsetting friction force. The robust control term acts as a high gain feedback control to make the output track the desired trajectory fast for guaranteed robust performance. Based on a PID-type sliding mode, the control scheme has a simple structure to be implemented and the control parameters can be easily tuned. Theoretical stability analysis of the proposed novel ASMC is accomplished using a Lyapunov framework. Furthermore, the proposed control scheme is applied to an X–Y stage and the results prove that the proposed control method is effective in achieving excellent tracking performance.     

浅谈电刷-导电环摩擦副使用寿命的影响因素

主要从电刷-导电环材料配对和工作环境两方面探讨了电刷-导电环电接触滑动摩擦副使用寿命的影响因素,认为其使用寿命是多种因素综合作用的结果,包括电刷-导电环配对材料的选择,周围气体环境和湿度环境,电接触摩擦副的压力以及相对滑动速度,电刷的加工方法和烧结密度及其中石墨的含量、晶粒大小和晶粒取向等。对于获得高可靠长寿命的滑环具有一定的指导意义。     

Direct‐Current Triboelectric Generator

The first direct‐current triboelectric generator (DC‐TEG) based on sliding electrification for harvesting mechanical energy from rotational motion is reported. The DC‐TEG consists of two rotating wheels and one belt for connecting them, which are made of distinctly different triboelectric materials with a specific requirement. During the rotation, the contact‐induced electrification and the relative sliding between the two wheels and the belt can induce a continuous increase of the accumulated positive and negative triboelectric charges at the two rotating wheels, respectively, resulting in a Corona discharge and producing the observed current through an external load. The DC‐TEG can deliver an open‐circuit voltage of larger than 3200 V and a maximum power of 100 μW under an external load of 60 MΩ at a rotational speed of 1000 r min^–1. By designing a point metal discharge electrode near the accumulated positive charges on the metal wheel, the instantaneous short‐circuit current can be up to 0.37 mA. The DC‐TEG can be utilized as a direct power source to light up 1020 serially connected commercial light‐emitting diodes (LEDs) and the produced energy can also be stored in a capacitor for other uses. This work presents a DC‐TEG technology to harvest mechanical energy from rotational motion for self‐powered electronics.     

Electrically Conductive Thin Films Prepared from Layer‐by‐Layer Assembly of Graphite Platelets

Layer‐by‐layer (LBL) assembly of carbon nanoparticles for low electrical contact resistance thin film applications is demonstrated. The nanoparticles consist of irregularly shaped graphite platelets, with acrylamide/ββ‐methacryl‐oxyethyl‐trimethyl‐ammonium copolymer as the cationic binder. Nanoparticle zeta (ζζ) potential and thereby electrostatic interactions are varied by altering the pH of graphite suspension as well as that of the binder suspension. Film thickness as a function of zeta potential, immersion time, and the number of layers deposited is obtained using Monte Carlo simulation of the energy dispersive spectroscopy measurements. Multilayer film surface morphology is visualized via field‐emission scanning electron microscopy and atomic‐force microscopy. Thin film electrical properties are characterized using electrical contact resistance measurements. Graphite nanoparticles are found to self‐assemble onto gold substrates through two distinct yet overlapping mechanisms. The first mechanism is characterized by logarithmic carbon uptake with respect to the number of deposition cycles and slow clustering of nanoparticles on the gold surface. The second mechanism results from more rapid LBL nanoparticle assembly and is characterized by linear weight uptake with respect to the number of deposition cycles and a constant bilayer thickness of 15 to 21 nm. Thin‐film electrical contact resistance is found to be proportional to the thickness after equilibration of the bilayer structure. Measured values range from 1.6 mΩ cm^?2 at 173 nm to 3.5 mΩ cm^?2 at 276 nm. Coating volume resistivity is reduced when electrostatic interactions are enhanced during LBL assembly.     

Inkjet‐Printed Flexible Gold Electrode Arrays for Bioelectronic Interfaces

Bioelectronic interfaces require electrodes that are mechanically flexible and chemically inert. Flexibility allows pristine electrode contact to skin and tissue, and chemical inertness prevents electrodes from reacting with biological fluids and living tissues. Therefore, flexible gold electrodes are ideal for bioimpedance and biopotential measurements such as bioimpedance tomography, electrocardiography (ECG), electroencephalography (EEG), and electromyography (EMG). However, a manufacturing process to fabricate gold electrode arrays on plastic substrates is still elusive. In this work, a fabrication and low‐temperature sintering (≈200 °C) technique is demonstrated to fabricate gold electrodes. At low‐temperature sintering conditions, lines of different widths demonstrate different sintering speeds. Therefore, the sintering condition is targeted toward the widest feature in the design layout. Manufactured electrodes show minimum feature size of 62 μm and conductivity values of 5 × 10 ⁶ S m^?1. Utilizing the versatility of printing and plastic electronic processes, electrode arrays consisting of 31 electrodes with electrode‐to‐electrode spacing ranging from 2 to 7 mm are fabricated and used for impedance mapping of conformal surfaces at 15 kHz. Overall, the fabrication process of an inkjet‐printed gold electrode array that is electrically reproducible, mechanically robust, and promising for bioimpedance and biopotential measurements is demonstrated.     

Interface microstructure effects in Au thermosonic ball bonding contacts by high reliability wire materials

Palladium-doped and (Cu, Pt)-doped high reliability gold wires were used to form wire bond interconnects on aluminum IC metallization. By isothermal annealing of wire bond samples the formation of intermetallic Au–Al phases was stimulated. SEM/EBSD investigations of the phase regions exhibited significantly slower isothermal growth rates compared to a reference gold wire. Correlated TEM, STEM–EDXS and nanobeam diffraction analyses revealed that Pd is preferentially incorporated into the Au₈Al₃ intermetallic forming a new stable phase but additionally can obviously form a new Pd-rich ternary intermetallic. In comparison, Cu dopants are also accumulated into a new Al–Au–Cu phase while Pt is rather found agglomerating within grain boundaries and interfaces. These results suggest a diffusion barrier model that allows discussing how wire doping can affect the bond contact microstructure, thus increasing the lifetime of bond contacts.     

Highly Aligned Plasmonic Gold Nanorods in a DNA Matrix

Since the Lycurgus Cup was made in the 4th century, metal nanoparticles have attracted much interest due to the characteristics of the plasmonic and metamaterials that show beautiful colors. Despite these fascinating properties, the practical use is limited because it is difficult to control the orientation of the plasmonic nanoparticles. Here, highly aligned plasmonic gold nanorods are obtained using self‐assembled DNA material. Simple mechanical shearing results in long‐range DNA–gold nanorod arrays which show parallel, perpendicular, and zigzag configurations due to the competition between the shear force and DNA elasticity. The resulting surface plasmonic resonance properties of the aligned DNA–gold nanorods film show highly polarization‐dependent behavior in a large area, which is critical for optical and photonic applications. This simple way to form anisotropic plasmonic films can be used for plasmonic nanoparticles in potential applications such as displays and sensors.     

Ultrafast Charging and Stable Cycling Dual-Ion Batteries Enabled via an Artificial Cathode–Electrolyte Interface

Low-cost and environment-friendly dual-ion batteries (DIBs) with fast-charging characteristics facilitate the development of high-power energy storage devices. However, the incompatibility between the cathode and electrolyte at high voltage results in low Coulombic efficiency (CE) and short lifespan. Here, the addition of ≈ 0.5 wt% lithium difluoro(oxalate) borate salt into the electrolyte forms a robust and durable cathode–electrolyte interface (CEI) in situ on the graphite surface, which enables remarkable cycling of the graphite || Li battery with 87.5% capacity retention after 4000 cycles at 5 C and ultrafast rate capability with 88.8% capacity retention under 40 C (4 A g⁻¹), delivering high-power of 0.4–18.8 kW kg⁻¹ at energy densities of 422.7–318.8 Wh kg⁻¹. Taking advantage of this robust CEI, a graphite || graphite full battery demonstrates high reversible capacities of 97.6, 92.8, 88.7, and 85.4 mAh (g cathode)⁻¹ at current rates of 10, 20, 30, and 40 C, respectively. The full battery also shows a long cycling life of over 6500 cycles with 92.4% capacity retention and an average CE of ≈ 99.4% at 1 A g⁻¹, which is superior to other dual-graphite (carbon) batteries in the literature. This work offers an effective interface-stabilizing strategy on protecting graphite cathodes and a promising approach for developing DIBs with high-power capability.     

Vertical Phase Separated Cesium Fluoride Doping Organic Electron Transport Layer: A Facile and Efficient “Bridge” Linked Heterojunction for Perovskite Solar Cells

In perovskite solar cells (PSCs), the interfaces of the halide perovskite/electron transport layer (ETL) and ETL/metal oxide electrode (MOE) always attract and trap free carriers via the surface electrostatic force, altering quasi‐Fermi level (E_Fq) splitting of contact interfaces, and significantly limit the charge extraction efficiency and intrinsic stability of devices. Herein, a graded “bridge” is first reported to link the MOE and perovskite interfaces by self vertical phase separation doping (PSD), diminishing the side effect of notorious ionic defects via both reinforced interface E_bi and the vacancies filling. Experimental and theoretical results prove that the inhomogeneous distribution of CsF in the bulk or surface of PC₆₁BM would not only form metal–oxygen (M–O) dipole on MOE, reinforcing the interface E_bi, but also create a graded energy bridge to alleviate the disadvantage of band offset raised by the enhanced interface E_bi, which significantly avoid the carrier accumulation and recombination at defective interfaces. Employing PSD, the power conversion efficiency of the devices approaches 21% with a high open‐circuit voltage (1.148 V) and delivers a high stability of 89% after aging 60 days in atmosphere without encapsulation, which is the highest efficiency of organic electron transport layers for n–i–p PSCs.     

Nanomaterials in Superlubricity

The vanishing friction, known as superlubricity, is potentially a significant performance indicator in the development of nanostructured materials and has become increasingly important for realizing energy saving and extending the life of mechanical components. Herein, a systematic review of recent progress in nanomaterials for achieving the superlubric state is provided, beginning with a brief introduction of nanostructured materials in superlubricity and its wide potential applications. Subsequently, a detailed discussion of experimental and simulation works on the different spatial structures of nanomaterials associated with size effects ranging from 0D to 3D nanostructures is given, with an emphasis on solid and liquid superlubricity. Finally, this work concludes with perspectives on the challenges and future directions for developing nanomaterials in the field of superlubricity.     

Liquid–Solid Triboelectric Probes for Real-Time Monitoring of Sucrose Fluid Status

Triboelectric probes have rapidly developed as an efficient tool for understanding contact electrification at liquid–solid interfaces. However, the liquid–solid electrification process is susceptible to interference from chemical components in mixed solutions, severely limiting the potential applications of triboelectric probes in various liquid environments. This study for the first time reports a triboelectric probe capable of sucrose solution concentration sensing, finding that the dissolution of sucrose destroys the hydrogen bond network between water molecules and forms sucrose–water hydrogen bonds, which alters the fluid mechanics characteristics of the solution and enhances its conductivity, thereby reducing the droplet size and causing an ion charge shielding effect that significantly affects the electron transfer in liquid–solid contact electrification. Owing to the feedback of the triboelectric probe on the sucrose concentration gradient-type sensing electrical signals, efficient sensing of sucrose solution was achieved (sensitivity of −0.0038%⁻¹, response time of 90 ms). The triboelectric probe is also used as a wireless smart terminal to enable real-time detection of sucrose solution. This work contributes to the understanding of the structure–function relationship between micro hydrogen bonding and macro performance, and provides a promising solution for building sustainable intelligent sensors.     

Pseudoelasticity of Metal Nanoparticles Is Caused by Their Ultrahigh Strength

An assembly of hemispherical Ag nanoparticles is prepared by solid‐state dewetting of thin Ag film deposited on the sapphire substrate. The in situ nanomechanical compression testing of the particles with a flat diamond punch inside the scanning electron microscope demonstrates the deformation behavior typical for the nucleation‐controlled plasticity: high elastic deformation followed by an abrupt particles collapse. The latter is associated with the dislocations nucleation in otherwise pristine particle. The average contact pressure in the contact zone at the onset of dislocation‐controlled plasticity is about 8 GPa, and does not depend on particle size. This observation supports the hypothesis that the pseudoelasticity of much smaller Ag nanoparticles is intrinsically related to their ultrahigh strength. A stress‐induced diffusion along the particle–substrate and particle–punch interfaces is identified as a factor controlling the pseudoelastic deformation. The corresponding diffusion model allows estimating the room‐temperature self‐diffusion coefficient of Ag along the Ag–W and Ag–zirconia interfaces, which is quite close to the estimated value of the grain boundary self‐diffusion coefficient in Ag. Based on this finding, the map of pseudoelastic deformation of crystalline materials is proposed.     

Controllable Patterning of Different Cells Via Optical Assembly of 1D Periodic Cell Structures

Flexible patterning of different cells into designated locations with direct cell–cell contact at single‐cell patterning precision and control is of great importance, however challenging, for cell patterning. Here, an optical assembly method for patterning of different types of cells via direct cell–cell contact at single‐cell patterning precision and control is demonstrated. Using Escherichia coli and Chlorella cells as examples, different cells are flexibly patterned into 1D periodic cell structures (PCSs) with controllable configurations and lengths, by periodically connecting one type of cells with another by optical force. The patterned PCSs can be flexibly moved and show good light propagation ability. The propagating light signals can be detected in real‐time, providing new opportunities for the detection of transduction signals among patterned cells. This patterning method is also applicable for cells of other kinds, including mammalian/human cells.     

Analysis of thermal characteristics and mechanism of degradation of flip-chip high power LEDs

The purpose of this study is to investigate the thermal behavior at the die-attached interfaces of flip-chip GaN high-power light emitting diodes (LEDs) using a combination of theoretical and experimental analyses. The results indicate that contact thermal resistance increased dramatically at the die-attached interfaces with aging time and stress, degrading the luminous flux. The junction temperature and thermal uniformity of the flip-chip structure both strongly depend on the arrangement of gold bumps. Local hot spots effectively reduce light output under high electric and thermal stress, influencing the long-term performance of the LED device. The results were validated using finite element analysis and in experiments using an infrared and an emission microscope. A two-step thermal transient degradation mode was identified under various aging stresses. A simulation further optimized the bump configuration that was associated to yield a low junction temperature and high temperature uniformity of the LED chip. Accordingly, the results are helpful in enhancing the performance and reliability of high-power LEDs.     

Lateral stabilization of a four wheel independent drive electric vehicle on slippery roads

In this paper, a new controller is proposed for lateral stabilization of four wheel independent drive electric vehicles without mechanical differential. The proposed controller has three levels including high, medium and low control levels. Desired vehicle dynamics such as reference longitudinal speed and reference yaw rate are determined by higher level of controller. Moreover, using a neural network observer and a fuzzy logic controller, a novel reference longitudinal speed generator system is presented. This system guarantees the vehicle’s stable motion on the slippery roads. In this paper, a new sliding mode controller is proposed and its stability is proved by Lyapunov stability theorem. This sliding mode control structure is faster, more accurate, more robust, and with smaller chattering than classic sliding mode controller. Based on the proposed sliding mode controller, the medium control level is designed to determine the desired traction force and yaw moment. Therefore, suitable wheel forces are calculated. Finally, the effectiveness of the introduced controller is investigated through conducted simulations in CARSIM and MATLAB software environments.