磁流体的制备与性质研究

报道了采用十二烷基硫酸钠进行磁性颗粒的二次改性通过胶溶法制备稳定的磁流体。应用X射线衍射、透射电镜对磁性颗粒的结构、粒径、形貌进行了表征,并探讨了制备条件对磁流体性质的影响。     

酸碱度对纳米Fe_3O_4磁性流体性能的影响

采用化学共沉淀法制备纳米Fe3O4磁性颗粒,并用油酸钠对其进行包覆改性,以煤油为基液制备出煤油基Fe3O4磁流体。对比分析了pH值=5和10.5条件下油酸钠包覆的Fe3O4磁性颗粒的性能差异,得出油酸钠在pH值=5时可以更好地包覆在Fe3O4磁性颗粒表面,其饱和磁化强度为58.0A·m2/kg,在此基础上制备出的磁流体的饱和磁化强度为20.2A·m2/kg,并且Fe3O4磁性颗粒分散较均匀。而油酸钠在pH值=10.5时包覆的Fe3O4磁性颗粒,其饱和磁化强度虽然高一些(67.8A·m2/kg),但制备出的磁流体稳定性较差,出现较为明显的沉降现象。     

Cu_xFe_（1-x）O·Fe_2O_3磁流体纳米微粒的制备与性能分析

为增强磁流体在肿瘤治疗中的靶向性,本研究在制备磁流体过程中加入Cu2＋,利用超声乳化法制备纳米CuxFe1-xO.Fe2O3颗粒,采用壳聚糖作为表面活性剂制备出分散均匀、稳定性好的水基磁流体,研究了不同的Cu2＋加入量和不同的壳聚糖用量对磁流体磁性能的影响.结果表明：壳聚糖成功包覆于磁性CuxFe1-xO.Fe2 O3...     

硅油基磁流体的制备及表征

以具有憎水、憎油特性的硅油作为磁性液体基液,以硅酸钠作为磁性粒子在基液中的包覆分散剂,六甲基硅氧烷为稳定剂,制备出硅油基磁流体。对其制备条件及其性能做了研究,结果表明,当反应温度为80℃,溶液pH=9,硅酸钠的加入量为3.6mol时,制得的硅油基磁流体的分散稳定性最好,磁性颗粒的平均颗粒为8nm。     

新型磁性材料──Co－Fe_3O_4磁流体的研制

本文途述了化学法制备Ｃｏ－Ｆｅ＿３Ｏ＿４磁流体的试验结果。在适宜的工作条件下，只要活性剂和载液选择得当，且与磁性颗粒之间的配比合理，就可以制备出磁性强和稳定性好的Ｃｏ－Ｆｅ＿３Ｏ＿４磁流体。通过对主要操作变量参数的研究，确定了最佳工艺条件。对相同操作条件下制备的Ｃｏ－Ｆｅ＿３Ｏ＿４磁流体和Ｆｅ＿３Ｏ＿４磁流体进行了比较，结果表明：前者的饱和磁化强度远大于后者。本试验研究为研制高质量的磁流体提供了依据。     

不同形貌纳米Fe3O4颗粒磁流体的传动性能

选用无规则、正八面体和六方片状形貌的纳米Fe3O4磁性颗粒制备的磁流体,通过设计、组装磁流体传动性能测试仪,探讨了磁流体传动性能与传动盘间距、传动盘之间的转速差的关系,并研究了磁流体中纳米磁性颗粒的形貌对磁流体传动性能的影响。结果表明,在传动盘间隙一定时,磁流体传递扭矩的大小在磁性粒子未达到其饱和磁化强度时,传递扭矩大小随感应磁场强度增大而迅速增大,但随着磁感应强度的进一步加大,磁性粒子逐步达到其饱和磁化强度,磁流体传递扭矩大小的增长减缓,最后几乎不再增大;传动盘之间的间隙对磁流体传递扭矩的大小影响很大,间隙越大,传递的扭矩越小;传动盘之间的转速差对磁流体传递扭矩的大小影响较小,在低转速差下传递的扭矩随转速差的增加而有所增加,但超过一定的转速差后,由于磁流体的剪切稀化效应,传递的扭矩将有所减小。另外,磁流体中磁性粒子的形貌对磁流体传递扭矩的大小有一定的影响,正八面体形貌的磁性粒子相对于无规则和六方片状形貌的磁性粒子,其磁流体能够传递更大的扭矩。     

磁性聚苯乙烯微球的制备与表征

采用化学共沉淀法制备了Fe3O4纳米颗粒,以PEG-4000为表面活性剂进行表面修饰,制备了分散性良好的纳米Fe3O4磁流体.磁流体存在时,采用分散聚合法,以苯乙烯为单体制备了磁性高分子微球.TEM研究表明,Fe3O4纳米颗粒的平均粒径约为10nm,分散聚合所制备的磁性聚苯乙烯微球的平均粒径约为80nm;VSM研究表明,合成的Fe3O4纳米颗粒及磁性聚苯乙烯微球具有超顺磁性;FT-IR研究表明,Fe3O4纳米颗粒很好地包覆于聚苯乙烯中;XRD结果表明,分散聚合前后,Fe3O4纳米颗粒的晶体结构没有发生变化.     

化学共沉淀法制备水基磁流体的研究进展

简单地介绍了水基磁流体的组成、应用和特性,全面阐述了用化学共沉淀法制备水基磁流体的各种制备方法,重点介绍了用表面活性剂对磁性粒子进行二次包覆后,制备水基磁流体,以及该方法中表面活性剂的作用和加入时机。     

纳米Fe3O4油基磁流体制备及性质研究

用共沉淀法制备磁流体的磁核一纳米Fe3O4，液体石蜡作基液和混合表面活性剂作分散介质而成功地制备出满足制备磁性药物微球需要的油基磁流体。研究了纳米Fe3O4、液体石蜡用量，表面活性剂的种类和组成比以及不同温度对磁流体性质的影响。并用XRD、TEM、旋转粘度计、磁天平等对磁流体的物相、粘度、磁性以及稳定性等进行了表征。     

Dy_(0.15)Fe_(1.85)O_3磁颗粒的有机改性对其硅油基磁流体磁性能及稳定性的影响

采用共沉淀—相转化法制备出Dy0.15Fe1.85O3纳米磁颗粒,用月桂酸进行了在线有机改性,干燥后用中间体包覆,在超声振荡下将其分散在硅油中,得到硅油基磁流体。研究了月桂酸用量(wt)对磁颗粒性能及中间体用量(wt)对磁流体稳定性的影响。用TEM、XRD对磁颗粒进行表征、用SQUID、VSM对样品的磁性能进行测试。结果表明:在n(Fe2+)/n(Fe3+)/n(Dy3+)=1:2:0.011,反应温度为50℃,月桂酸用量为0.05g/g(磁颗粒),中间体用量为(0.42~0.58)g/g(磁颗粒)的条件下,制得的磁流体具有较强的稳定性和优异的磁性能。     

Fe_3O_4水基磁性液体的制备及性能研究

采用化学共沉法制备磁粒子Fe_3O_4,选用表面活性剂油酸进行一次包覆,乳化剂OP(烷基酚聚氧乙烯醚)进行二次包覆制备出稳定的水基磁性液体。利用XRD和TEM分析了样品的结构、形貌及粒径;运用VSM技术研究了样品磁性能;重点考察了油酸和OP用量对水基磁性液体稳定性的影响。结果表明,所制备的Fe_3O_4粒子为球形,颗粒的粒径较均匀细小,在10nm左右;磁性液体显示超顺磁性,饱和磁化强度M_s=54.636A·m~2/kg;油酸和OP用量对磁性液体的稳定性有重要影响,当n(Fe_O_4):n(油酸):n(OP)=5:2:4时,磁性液体的稳定性能最好。     

Thermal behaviour and particle size evaluation of primary clusters in a water-based magnetic fluid

This paper reports the experimental research on thermal behaviour and particle size evaluation of primary clusters of ferromagnetic nano-particles in a water-based magnetic fluid. The magnetic fluids are suspensions of ultra fine particles coated with a molecular layer of dispersant in a liquid carrier such as water or kerosene. The particles are coated with single- or double-layer of surfactant to achieve stable dispersion. Numerous experimental studies have indicated the existence of the primary cluster of ferromagnetic nano-particles in a water-based magnetic fluid. The purpose of this research is to evaluate the particle size of the primary clusters by applying the Einstein's equation for Brownian motion assuming that the primary cluster has a spherical-shape. The thermal behaviour of ferromagnetic nano-particles in magnetic fluids is investigated through the micro visualization using the optical darkfield microscope system and particle tracking velocimetry data processing system. Real-time visualization of the Brownian motion of primary clusters in a water-based magnetic fluid was carried out. The experimental results clarified that the primary cluster size depends upon the concentration of the ferromagnetic nano-particle in the magnetic fluid.     

Thermal behaviour and particle size evaluation of primary clusters in a water-based magnetic fluid

This paper reports the experimental research on thermal behaviour and particle size evaluation of primary clusters of ferromagnetic nano-particles in a water-based magnetic fluid. The magnetic fluids are suspensions of ultra fine particles coated with a molecular layer of dispersant in a liquid carrier such as water or kerosene. The particles are coated with single- or double-layer of surfactant to achieve stable dispersion. Numerous experimental studies have indicated the existence of the primary cluster of ferromagnetic nano-particles in a water-based magnetic fluid. The purpose of this research is to evaluate the particle size of the primary clusters by applying the Einstein’s equation for Brownian motion assuming that the primary cluster has a spherical-shape. The thermal behaviour of ferromagnetic nano-particles in magnetic fluids is investigated through the micro visualization using the optical darkfield microscope system and particle tracking velocimetry data processing system. Real-time visualization of the Brownian motion of primary clusters in a water-based magnetic fluid was carried out. The experimental results clarified that the primary cluster size depends upon the concentration of the ferromagnetic nano-particle in the magnetic fluid.     

Agglomeration response of nanoparticles in magnetic fluid via monitoring of light transmission

We systemically investigate the chain formation speed in magnetic fluid (MF) at various volume fractions, temperatures, and magnetic fields. Experiments are carried out on a water-based Fe(3)O(4) MF to investigate the agglomeration response of the nanoparticles under an applied magnetic field. The transmission of light is monitored to determine the response time undergoing a squared pulsed external magnetic field. The results reveal that enhancement of the response performance of photonic devices based on MF can be realized by properly adjusting the physical parameters, which are essential for both the physics of chain formation and practical applications.     

水基磁流变液的制备及其性能研究

以经过表面处理的微米级羰基铁粉、亚微米级四氧化三铁粉末为悬浮相,去离子水为悬浮介质,加入适当的添加剂,通过一定的工艺制备出综合性能良好的水基磁流变液.研究了几种含有不同悬浮相粒子和不同添加剂的磁流变液的剪切性能和沉降稳定性能,分析了悬浮相的组成对磁流变液磁流变性能的影响以及添加剂对改善磁流变液抗沉降团聚稳定性的作用.     

基于改性酪素制备水性油墨连接料的现状与展望

对酪素及水性油墨连接料的性质和特点分别进行了简介,综述了近年来国内外在改性酪素和水性油墨连接料方面的研究现状,并对改性酪素在制备水性油墨连接料领域中的前景进行了展望。     

Effect of a magnetic field on natural convection in an inclined half-annulus enclosure filled with Cu–water nanofluid using CVFEM

In this paper, the effect of a magnetic field on natural convection in a half-annulus enclosure with one wall under constant heat flux using control volume based finite element method. The fluid in the enclosure is a water-based nanofluid containing Cu nanoparticles. The effective thermal conductivity and viscosity of nanofluid are calculated using the Maxwell–Garnetts (MG) and Brinkman models, respectively. Numerical simulations were performed for different governing parameters namely the Hartmann number, Rayleigh number and inclination angle of enclosure. The results indicate that Hartmann number and the inclination angle of the enclosure can be control parameters at different Rayleigh number. In presence of magnetic field velocity field retarded and hence convection and Nusselt number decreases.     

Metal nanofibers with highly tunable electrical and magnetic properties via highly loaded water-based electrospinning

Nanofibers are synthesized by electrospinning highly loaded water-based precursor-polymer hybrid solutions followed by thermal treatment to control crystal structure. Electrical conductivity and magnetic coercivity, as shown, are tested displaying independent magnetic and electrical property control from coercive to superparamagnetic and resistive to near-bulk conductivity at room temperature.