高能球磨制备Al3Ti/Al块体纳米晶复合材料

通过对Al Ti系和Al TiO2 系进行高能球磨和压制烧结制备了固态原位反应生成的纳米晶块体Al3Ti/Al复合材料。研究表明 :Al Ti合金系高能球磨后 ,各组元晶粒得到细化 ,并且Ti在Al中发生了强制超饱和固溶 ,烧结时原位反应形成纳米晶Al3Ti/Al复合材料 ;而Al TiO2 反应体系高能球磨仅发生组分晶粒细化 ,烧结时TiO2 部分还原并和Al原位反应生成纳米晶 (Ti2 O3 Al3Ti) /Al复合材料。     

高能球磨法制备SiC/Al复合材料

采用高能球磨法制备了SiC颗粒增强Al基复合材料,研究了SiC含量对该复合材料力学性能的影响。结果表明,SiC/Al复合材料的硬度、屈服强度以及抗拉强度随SiC含量的增加而增大,而伸长率随之减小;SiC/Al复合材料呈延性断裂和脆性断裂混合断裂;随着SiC含量的增加,材料延性断裂特征减少。     

高能球磨制备纳米CeO2/Al复合粉末

采用高能球磨法制备了纳米CeO2／Al复合粉末，并利用X射线衍射(XRD)、场发射显微镜(FEM)、扫描电镜(SEM)以及能谱分析(EDS)等测试分析手段，对球磨过程中复合粉末相结构、组织形貌和成分分布的变化进行了研究。结果表明：随着球磨时间的增加，纳米CeO2团聚体逐渐进入Al颗粒中，并被很好地分散开来，呈均匀弥散分布；Al晶粒尺寸不断细化。     

高能反应球磨制备氧化铝/碳化钛纳米复合粉体

研究了以二氧化钛、铝和石墨为原料,采用高能球磨制备α-Al2OdTiC纳米复合材料的可行性.对球磨不同时间后的粉末进行X射线衍射分析,并利用扫描电镜观察其微观形貌.结果表明:以微米尺寸的TiO2、A1和C为原料,利用高能反应球磨法可以制备出纳米尺寸的α-Al2O3/TiC复合粉末;球磨250 min后,原料粉完全反应,合成的α-A12OdiC复合粉体晶粒尺寸为15nm.     

反应球磨制备TiC/Cu复合材料

采用反应球磨制备Cu／TiC复合粉末，然后进行压制和烧结，制备了TiC弥散强化铜基复合材料；描述了球磨过程中混合粉末的物理化学变化，研究了压制压强与材料致密度和硬度之间的关系。材料的显微组织表明。TiC在铜基体中有着均匀的分布。     

液氮球磨制备纳米SiCp/Al基复合材料的研究

利用液氮球磨技术制备了纳米SiC颗粒增强铝基复合材料粉末,对该纳米粉末进行真空热压和热挤压,获得纳米铝基复合材料块体.采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)研究了纳米SiC粉和Al-Zn-Mg-Cu粉在液氮球磨过程中形貌、组织和相组成等.结果表明,液氮球磨可以使复合材料粉末达到纳米级,且纳米SiC可均匀地分布于铝合金中.     

高能球磨制备超细TiH_2粉研究

利用氢化钛的氢脆性,在室温下通过高能球磨制备超细氢化钛粉。研究不同球磨条件对粉末粒度和形貌的影响,并对制备的粉末进行了扫描电镜分析。结果表明,球磨时间对粉末粒度的影响很大,粉末粒度在球磨初期迅速减小,球磨2min粉末迅速细化,粒度约为5μm~10μm。粒度为40μm的氢化钛粉,用庚烷保护湿磨30min时粒度达到1μm以下,球磨60min即可制得粒度为0.1μm的超细氢化钛粉。     

烧结工艺对SiC_P/Al复合材料性能的影响

通过机械球磨法制备了SiCP/Al复合材料,采用粒径分析研究了复合粉末的粒度变化以及最优化的球磨时间。对复合粉末进行压片烧结处理,研究了烧结温度和保温时间对复合材料物相、形貌与性能的影响。结果表明:该复合材料的性能受烧结温度与保温时间的影响显著,烧结温度过高或保温时间过长会使材料过烧,晶粒发生异常长大,使该复合材料的硬度、电阻率和气孔率降低;烧结工艺为550℃×2 h时,该复合材料的硬度、电阻率和气孔率最佳。     

高能球磨制备纳米级WC/Cu复合粉末的研究

利用XRD、SEM等分析研究了高能球磨时间对WC／Cu复合粉末结构、形貌及相的影响。结果表明,随球磨时间的延长复合粉末发生细化达到纳米级粒度,球磨24h可获得稳定晶粒尺寸,最小晶粒尺寸为21．5nm。其中WC粉末晶粒细化速率较Cu的慢;球磨过程中,有少量的WC固溶于Cu中,形成Cu(WC)固溶体。     

高能球磨制备纳米TiO2/纳米晶Cu超细复合粉体

采用高能球磨法制备了TiO2/Cu复合粉体并采用X射线衍射(XRD)、显微图像分析仪等测试分析方法,对球磨过程中复合粉末相结构、组织形貌和粒度分布的变化进行了研究.结果表明:球磨24 h后可形成纳米TiO2粉体/纳米晶Cu复合粉体,Cu粉晶粒达59 nm;随着球磨时间的增加,纳米TiO2团聚体逐渐嵌入Cu颗粒中,被很好地分散开,呈弥散分布;同时复合粉体粒度细化到300 nm以下,比表面积大大增加,粉体也由球形逐渐地过渡到多角形.     

3Fe/Al混合粉末的高能球磨及环境介质的相互作用

利用Fritsch Pulversitte 5型行星式球磨机、扫描电子显微镜、X射线光电子能谱仪和X射线衍射仪研究了3Fe/Al元素混合粉末的机械球磨过程以及球磨过程中混合粉末与环境介质的相互作用.研究证实,球磨过程中存在颗粒断裂、冷焊机制,球磨20h产物为α-Fe(Al)固溶体,其表面生成一层由Fe2O3和Al2O3组成的氧化膜.     

Effect of high energy ball milling on displacement reaction and sintering of Al−Mg/SiO2 composite powders

High-energy ball milling and low temperature sintering were successfully employed to fabricate a metal matrix composite of Al reinforced with Al₂O₃ particulate. Nano- and/or submicro-sized SiO₂ particles embedded in an Al−Mg matrix particle can be obtained by high-energy ball milling. No new phases were found in the high-energy ball milled Al-0.4 wt.% Mg-14 wt.%SiO₂ powder. Milling of the Al−Mg−SiO₂ powder increased the sintering rate and decreased the sintering temperature. The hardness ofthe sintered Al−Mg−SiO₂ composite using the ball-milled powder was about twice that of a sintered composite using a mixed powder due to the fine and homogeneous distribution of Al₂O₃ particles formed by the displacement reaction between Al and SiO₂ during sintering.     

高能球磨制备Ti-50%Al复合粉末的表征(英文)

采用高能球磨法制备了Ti-50%Al(摩尔分数)复合粉末,利用SEM、TEM、HREM、HAADF-STEM分析手段对复合粉末颗粒的表面形貌、结构及组成进行了表征。在球磨过程中钛、铝之间逐渐发生反应并形成无序的Ti/Al相;球磨9h后铝逐渐融入钛中,产生纳米晶钛铝固溶体,同时引起大量高密度位错。合金化后粉末的元素组成接近原始成分,但分布极不均匀。     

Bulk Al/SiC nanocomposite prepared by ball milling and hot pressing method

Nano-sized Al/SiC powders were prepared by mechanical alloying method. Two sorts of SiC particle, i.e., nano-sized and popular micron-sized SiC were utilized. The particle size and microstructure of the milled powder were characterised. Effects of the particle size and agglomerate state of SiC, as well as the microstructure of Al/SiC nanocomposite were studied by SEM and TEM. The results show that nano-sized SiC particles is dispersed in aluminium uniformly after ball milled for only 2 h, whereas the similar process need about 10 h for popular micron-sized SiC particle. The bulk Al/SiC nanocomposite can be fabricated by hot pressing the nano-sized Al/SiC powders at temperature about 723 K under pressure of 100 MPa.     

HA/Ti composite for biomedical application by mechanical milling

In order to overcome the poor mechanical properties of HA and the low bioactivity of Ti,HA/Ti composites with various compositions were prepared by mechanical milling.The effects of milling condition and the composition on the microstructure,the density and the hardness of the composites were studied.The results show that during the ball milling process.Ti particles are refined and the homogeneity of the HA/Ti mixtures is improved;HA will partially decompose due to the existence of Ti and high sintering temperature.The microstructure of HA/Ti composites is highly dependent on the milling condition and the composition.In the microstructure.Ti phase connects to be a continuous network,and HA/Ti mixtures disperse in the network.The longer the milling time,the finer the network will be.The density of HA/T composites decreases with the content of HA increasing and the milling time prolonging,because HA deteriorates the sinterability of Ti.The hardness of HA/Ti composites increases firstly with the content of HA increasing,and then drops when the content of HA exceeds 30%.Addition of HA will strengthen the HA/T composite but will decrease the density of the composite,which accounts for the effect of HA on the hardness of the composites.     

WC粉体的高能球磨超细化

采用高能球磨工艺对WC粉体进行超细研磨。研究了粉体颗粒度及晶粒度的大小随球磨时间的变化关系。发现随球磨时间的增加 ,粉体颗粒度不断细化 ,最后趋于稳定 (0 .4μm) ;粒度分布曲线出现明显的三峰特征 ,分别位于细 (微米 )区、超细 (亚微米 )区和极细 (纳米 )区。研磨细化的WC粒子具有纳米晶 (1 0nm)结构。探讨了WC粉体高能球磨细化机理与纳米晶结构特性。     

W-Ni-Fe nanostructure materials synthesized by high energy ball milling

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Preparing nano-crystalline rare earth doped WC/Co powder by high energy ball milling

The nano-crystalline rare earth doped WC/Co powder was prepared by high energy ball milling. The nano-crystalline powders were characterized by means of XRD (X-ray diffraction), SEM (scanning electron microscope) and DTA (differential thermal analysis). The results show that adding trace rare earth elements into carbides is effective to minish the grain size of WC/Co powder. The grain size of rare earth doped powder became two times smaller as compared with the undoped powder within ball milling times of 25–45 h. The XRD peak of Co phase disappeared after 25 h ball milling. A sharp peak of heat release at the temperature of 597 °C was emerged in DTA curve within the range of heating temperature. After consolidated the rare earth doped WC/Co alloy by high energy ball milling exhibits ultra-fine grain sizes and better mechanical properties.     

高能球磨制备Fe-Cu纳米晶过饱和固溶体

对Fe-20at%Cu合金粉末进行了高能球磨,并利用XRD对Fe-Cu二元合金粉末在球磨过程中的物相变化进行了分析。结果表明,球磨30 h后形成了Fe(Cu)纳米晶过饱和固溶体。热力学计算分析指出,Fe-Cu二元系不具有形成过饱和固溶体的热力学驱动力。高能球磨在Fe-Cu二元互不溶体系中扩展固溶度的驱动力是动力学驱动。在随后的退火过程中,纳米晶过饱和固溶体发生分解。