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1.
Flame temperatures (T), surface emissive powers (SEP) and irradiances (E) of large-scale JP-4 pool fires (d=2, 8, 16, 25 m) and di-tert-butyl peroxide (DTBP) pool fires (d=1.12 m, 3.4 m) are investigated experimentally and by CFD simulation. As experimental methods an infrared thermographic camera system with video-mixing unit is used for the determination of T, SEP and an ellipsoidal radiometer for the determination of E. The maximum frequency of time-averaged emission temperatures for JP-4 pool fire (d=16 m) are in a range of $ 793\,\mathrm{K} < \overline{T} < 1033$ and for DTBP pool fire (d=1.12 m) are a range of $ 1040\,\mathrm{K} < \overline{T} < 1480\,\mathrm{K}$ . For DTBP pool fire (d=1.12 m), the measurements result in $ \overline{\text{SEP}}\approx 130\,\mathrm{kW/m^{2}}$ which is up to a factor of ≈6 larger in comparison to hydrocarbon pool fires (d≈1 m). In a case of DTBP pool fire (d=3.4 m) with $ \overline{\text{SEP}} \approx 250\,\mathrm{kW/m^{2}}$ this factor is ≈5 compared to $ \overline{\text{SEP}} \approx 50\,\mathrm{kW/m^{2}}$ of LNG pool fire (d=4 m). By increasing the relative distance ?y/d from the pool rim, measured time averaged irradiances $ \overline{E}$ (?y/d) decrease and agree well with CFD predicted $ \overline{E}_{\text{CFD}}$ (?y/d). Also, there is a good agreement between the measured time averaged $ \overline{T}$ and $ \overline{\text{SEP}}$ of hydrocarbons and DTBP pool fires, with the predicted $ \overline{T}_{\text{CFD}}$ and $ \overline{\text{SEP}}_{\text{CFD}}$ values. The possibilities and nowadays limitations of CFD simulation of large pool fires are discussed. This study has shown that the risk potential of accidental pool fires referring to thermal radiation can be predicted much better than in the past.  相似文献   

2.
Inverse gas chromatography at infinite dilution was applied to determine the thermodynamic interactions of poly(l-lactide) (PLLA) and the composite of biphasic calcium phosphate and PLLA (BCP/PLLA). The specific retention volumes, $ V_{\text{g}}^{0} $ , of 11 organic compounds of different chemical nature and polarity (non-polar, donor or acceptor) were determined in the temperature range of 308–378 K for PLLA and 308–398 K for BCP/PLLA. The weight fraction activity coefficients of test sorbates, $ \Omega_{1}^{\infty } $ , and the Flory–Huggins interaction parameters, $ \chi_{12}^{\infty } $ , were estimated and discussed in terms of interactions of the sorbates with PLLA and BCP/PLLA. Also, the partial molar free energy, $ \Delta G_{1}^{\infty } $ , the partial molar heat of mixing, $ \Delta H_{1}^{\infty } $ , the sorption molar free energy, $ \Delta G_{1}^{\text{S}} $ , the sorption enthalpy, $ \Delta H_{1}^{\text{S}} $ , and the sorption entropy, $ \Delta S_{1}^{\text{S}} $ , were analyzed. A different chromatographic behavior of the two investigated samples, PLLA and BCP/PLLA, was observed. The values of $ \Omega_{1}^{\infty } $ indicated n-alkanes, diethyl ether, tetrahydrofurane (THF), cyclohexane, benzene, dioxane (except for 338 K), and ethyl acetate (EtAc) (except for 338 K) as non-solvents, and chloroform (CHCl3) as good solvent (except for 378 K) for PLLA. For BCP/PLLA, CHCl3, EtAc (for 378 K), dioxane (except for 378 K), and THF were indicated as good solvents.  相似文献   

3.
The Al–7.5 wt% Ni alloy was directionally solidified upwards with different temperature gradients, $G$ ( $0.86\,\text{ K}~{\cdot }~ \text{ mm}^{-1}$ to $4.24\,\text{ K}~{\cdot }~\text{ mm}^{-1})$ at a constant growth rate, $V$ ( $8.34\,\upmu \text{ m}~{\cdot }~\text{ s}^{-1})$ . The dependence of dendritic microstructures such as the primary dendrite arm spacing ( $\lambda _{1}$ ), the secondary dendrite arm spacing ( $\lambda _{2}$ ), the dendrite tip radius ( $R$ ), and the mushy zone depth ( $d$ ) on the temperature gradient were analyzed. The dendritic microstructures in this study were also compared with current theoretical models, and similar previous experimental results. Measurements of the microhardness (HV) and electrical resistivity ( $\rho $ ) of the directionally solidified samples were carried out. Variations of the electrical resistivity ( $\rho $ ) with temperature ( $T$ ) were also measured by using a standard dc four-point probe technique. And also, the dependence of the microhardness and electrical resistivity on the temperature gradient was analyzed. According to these results, it has been found that the values of HV and $\rho $ increase with increasing values of $G$ . But, the values of HV and $\rho $ decrease with increasing values of dendritic microstructures ( $\lambda _{1}, \lambda _{2}, R,$ and $d$ ). It has been also found that, on increasing the values of temperature, the values of $\rho $ increase. The enthalpy of fusion ( $\Delta {H}$ ) for the Al–7.5 wt%Ni alloy was determined by a differential scanning calorimeter from a heating trace during the transformation from solid to liquid.  相似文献   

4.
DuPont’s perfluoropolyether oil Krytox $^{\textregistered }$ GPL 102 is a promising candidate for the high-temperature, high-pressure Deepwater viscosity standard (DVS). The preferred DVS is a thermally stable liquid that exhibits a viscosity of roughly 20  $\hbox {mPa} \cdot \hbox {s}$ at 533 K and 241 MPa; a viscosity value representative of light oils found in ultra-deep formations beneath the deep waters of the Gulf of Mexico. A windowed rolling-ball viscometer designed by our team is used to determine the Krytox $^{\textregistered }$ GPL 102 viscosity at pressures to 245 MPa and temperatures of 311 K, 372 K, and 533 K. At 533 K and 243 MPa, the Krytox $^{\textregistered }$ GPL 102 viscosity is $(27.2 \pm 1.3)\,\hbox {mPa} \cdot \hbox {s}$ . The rolling-ball viscometer viscosity results for Krytox $^{\textregistered }$ GPL 102 are correlated with an empirical 10-parameter surface fitting function that yields an MAPD of 3.9 %. A Couette rheometer is also used to measure the Krytox $^{\textregistered }$ GPL 102 viscosity, yielding a value of $(26.2 \pm 1)\,\hbox {mPa} \cdot \hbox {s}$ at 533 K and 241 MPa. The results of this exploratory study suggest that Krytox $^{\textregistered }\, \hbox {GPL}$ 102 is a promising candidate for the DVS, primarily because this fluoroether oil is thermally stable and exhibits a viscosity closer to the targeted value of 20 mPa $\cdot $ s at 533 K and 241 MPa than any other fluid reported to date. Nonetheless, further studies must be conducted by other researcher groups using various types of viscometers and rheometers on samples of Krytox GPL $^{\textregistered }$ 102 from the same lot to further establish the properties of Krytox GPL $^{\textregistered }$ 102.  相似文献   

5.
Fe?CNi films were electrodeposited on ITO glass substrates from the electrolytes with different molar ratio of Ni $^{\boldsymbol{2+}}$ /Fe $^{\boldsymbol{2+}}$ and different pH values (2 $\boldsymbol{\cdot}$ 1, 2 $\boldsymbol{\cdot}$ 9, 3 $\boldsymbol{\cdot}$ 7 and 4 $\boldsymbol{\cdot}$ 3) at 25 $\boldsymbol{^\circ}$ C. The properties of Fe?CNi alloy films depend on both Ni $^{\boldsymbol{2+}}$ and Fe $^{\boldsymbol{2+}}$ concentrations in electrolyte and pH values. The content of Ni increases from 38% to 84% as the mole ratio of NiSO $_{\boldsymbol{4}}$ /FeSO $_{\boldsymbol{4}}$ increasing from 0 $\boldsymbol{\cdot}$ 50/0 $\boldsymbol{\cdot}$ 50 to 0 $\boldsymbol{\cdot}$ 90/0 $\boldsymbol{\cdot}$ 10 in electrolyte and slightly decreases from 65% to 42% as the pH values increase from 2 $\boldsymbol{\cdot}$ 1 to 4 $\boldsymbol{\cdot}$ 3. The X-ray diffraction analysis reveals that the structures of the films strongly depend on the Ni content in the binary films. The magnetic performance of the films shows that the saturation magnetization ( $\boldsymbol{M}_{\boldsymbol{\rm s}})$ decreases from 1775 $\boldsymbol{\cdot}$ 01 emu/cm $^{\boldsymbol{3}}$ to 1501 $\boldsymbol{\cdot}$ 46 emu/cm $^{\boldsymbol{3}}$ with the pH value increasing from 2 $\boldsymbol{\cdot}$ 1 to 4 $\boldsymbol{\cdot}$ 3 and the saturation magnetization ( $\boldsymbol{M}_{\boldsymbol{\rm s}})$ and coercivity ( $\boldsymbol{H}_{\boldsymbol{\rm c}})$ move up from 1150 $\boldsymbol{\cdot}$ 44 emu/cm $^{\boldsymbol{3}}$ and 58 $\boldsymbol{\cdot}$ 86 Oe to 2498 $\boldsymbol{\cdot}$ 88 emu/cm $^{\boldsymbol{3}}$ and 93 $\boldsymbol{\cdot}$ 12 Oe with the increase of Ni $^{\boldsymbol{2+}}$ concentration in the electrolyte, respectively.  相似文献   

6.
The effects of fluorine co-doping by means of a post-thermal annealing process of iron-doped BST thin films in a fluorine-containing atmosphere have been investigated. XPS and ToF-SIMS sputter depth profiling verified a homogeneous fluorine distribution in the thin films. By employing EPR, it was shown that singly charged ( $ {\text{Fe}}_{\text{Ti}}^{\prime } $ $ {\text{V}}_{\text{O}}^{ \cdot \cdot } $ )· defect complexes, as well as ‘isolated’ $ {\text{Fe}}_{\text{Ti}}^{\prime } $ centres with a distribution of $ {\text{F}}_{\text{O}}^{ \cdot } $ sites in remote coordination spheres exist in the fluorinated films. Tunability enhancement due to fluorine co-doping as well as a Q-factor enhancement due to iron doping is demonstrated.  相似文献   

7.
We report on the plasma-assisted molecular-beam epitaxy of semipolar $\hbox{AlN}(11\bar{2}2)$ and GaN( $11\bar{2}2$ ) films on $(1\bar{1}00)$ m-plane sapphire. AlN deposited on m-sapphire settles into two main crystalline orientation domains, $\hbox{AlN}(11\bar{2}2)$ and $\hbox{AlN}(10\bar{1}0),$ whose ratio depends on the III/V ratio. Growth under moderate nitrogen-rich conditions enables to isolate the $(11\bar{2}2)$ orientation. The in-plane epitaxial relationships of $\hbox{AlN}(11\bar{2}2)$ on m-plane sapphire are $[11\bar{2}\bar{3}]_{\rm AlN} \vert \vert [0001]_{\rm sapphire}$ and $[1\bar{1}00]_{\rm AlN} \vert \vert [11\bar{2}0]_{\rm sapphire}.$ GaN deposited directly on m-sapphire results in ( $11\bar{2}2$ )-oriented layers with ( $10\bar{1}\bar{3}$ )-oriented inclusions. A ~100 nm-thick AlN( $11\bar{2}2$ ) buffer imposes the ( $11\bar{2}2$ )-orientation for the GaN layer grown on top. By studying the Ga-desorption on GaN( $11\bar{2}2$ ), we conclude that these optimal growth conditions corresponds to a Ga excess of one monolayer on the GaN( $11\bar{2}2$ ) surface.  相似文献   

8.
We present a new generation of a scanning microSQUID microscope operating in an inverted dilution refrigerator. The microSQUIDs have a size of 1.21 $ \ \upmu $ m $^{2}$ and a magnetic flux sensitivity of 120 $\upmu \Phi _{0} / \sqrt{\text {Hz}}$ and thus a field sensitivity of 550 $ \ \upmu \text {G}/ \sqrt{\text {Hz}}$ . The scan range at low temperatures is about 80 $\upmu $ m and a coarse displacement of 5 mm in x and y direction has been implemented. The microSQUID-to-sample distance is regulated using a tuning fork based force detection. A microSQUID-to-sample distance of 420 nm has been obtained. The reliable knowledge of this distance is necessary to obtain a trustworthy estimate of the absolute value of the superconducting penetration depth. An outlook will be given on the ongoing direction of development.  相似文献   

9.
The mass-transfer behavior through grain boundaries (GBs) in alumina was systematically investigated using four types of alumina bicrystals. The alumina bicrystal wafers were exposed to the constant oxygen potential gradient $ \left( {\Updelta P_{{{\text{O}}_{ 2} }} } \right) $ generated by the combination of two different oxygen partial pressures $ P_{{{\text{O}}_{ 2} }} \left( {\text{II}} \right) $ and $ P_{{{\text{O}}_{ 2} }} \left( {\text{I}} \right) $ of 105 and 1?Pa, respectively, at 1923?K. Ridges were formed along the GBs on the surface subjected to $ P_{{{\text{O}}_{ 2} }} \left( {\text{II}} \right) $ , and deep GB ditches were developed on the $ P_{{{\text{O}}_{ 2} }} \left( {\text{I}} \right) $ surface mainly during the migration of aluminum thorough GBs from the $ P_{{{\text{O}}_{ 2} }} \left( {\text{I}} \right) $ surface to $ P_{{{\text{O}}_{ 2} }} \left( {\text{II}} \right) $ surface. The surface morphology changes in the vicinity of the GBs were observed by atomic force microscopy. It was found that the surface morphology changes indicative of the aluminum GB diffusion were strongly dependent on the GB characteristics. The GB diffusion coefficients of aluminum estimated from the volume of the GB ridges showed a clear correlation to the local bonding environments of GB cores estimated from theoretical calculations reported previously.  相似文献   

10.
This paper presents measurements of the thermal conductivity and the dynamic viscosity of $\mathrm{Al}_{2}\mathrm{O}_{3}$ Al 2 O 3 –ethylene glycol and $\mathrm{TiO}_{2}$ TiO 2 –ethylene glycol (1 % to 3 % particle volume fraction) nanofluids carried out in the temperature range from $0\,^{\circ }$ 0 ° C to $50\,^{\circ }$ 50 ° C. The thermal-conductivity measurements were performed by using a transient hot-disk TPS 2500S apparatus instrumented with a 7577 probe (2.001 mm in radius) having a maximum uncertainty $(k=2)$ ( k = 2 ) lower than 5.0 % of the reading. The dynamic-viscosity measurements and the rheological analysis were carried out by a rotating disk type rheometer Haake Mars II instrumented with a single-cone probe (60 mm in diameter and $1^{\circ }$ 1 ° ) having a maximum uncertainty $(k=2)$ ( k = 2 ) lower than 5.0 % of the reading. The thermal-conductivity measurements of the tested nanofluids show a great sensitivity to particle volume fraction and a lower sensitivity to temperature: $\mathrm{TiO}_{2}$ TiO 2 –ethylene glycol and $\mathrm{Al}_{2}\mathrm{O}_{3}$ Al 2 O 3 –ethylene glycol nanofluids show a thermal-conductivity enhancement (with respect to pure ethylene glycol) from 1 % to 19.5 % and from 9 % to 29 %, respectively. $\mathrm{TiO}_{2}$ TiO 2 –ethylene glycol and $\mathrm{Al}_{2}\mathrm{O}_{3}$ Al 2 O 3 –ethylene glycol nanofluids exhibit Newtonian behavior in all the investigated temperature and particle volume fraction ranges. The relative viscosity shows a great sensitivity to the particle volume fraction and weak or no sensitivity to temperature: $\mathrm{TiO}_{2}$ TiO 2 –ethylene glycol and $\mathrm{Al}_{2}\mathrm{O}_{3}$ Al 2 O 3 –ethylene glycol nanofluids show a dynamic viscosity increase with respect to ethylene glycol from (4 to 5) % to 30 % and from 14 % to 50 %, respectively. Present experimental measurements were compared both with available measurements carried out by different researchers and computational models for thermophysical properties of nanofluids.  相似文献   

11.
Glass-transition kinetics of $\mathrm{Se}_{80}\mathrm{In}_{20-\mathrm{x}}\mathrm{Pb}_{\mathrm{x}}$ ( $x =$ 0, 5, 10, and 15) chalcogenide glasses have been carried out at different heating rates by using differential scanning calorimeter (DSC) under the non-isothermal condition. The glass-transition temperature $T_{\mathrm{g}}$ and peak glass-transition temperature $T_{\mathrm{pg}}$ have been determined from DSC thermograms. The reduced glass temperature $T_{\mathrm{rg}}$ , total relaxation time $\tau _{T_{g}}$ thermal-stability parameters $K^{l}$ and $S$ , the activation energy of glass transition $E_{\mathrm{g}}$ , the fragility index $F_{\mathrm{i}}$ , and the average coordination number $\langle Z\rangle $ have been calculated on the basis of the experimental results. The temperature differences $(T_{\mathrm{c}}-T_{\mathrm{g}}), K_{\mathrm{gl}}, K^{l}, S$ , and $E_{\mathrm{g}}$ are found to be maxima for $\mathrm{Se}_{80}\mathrm{In}_{10}\mathrm{Pb}_{10}$ glass. This indicates that $\mathrm{Se}_{80}\mathrm{In}_{10}\mathrm{Pb}_{10}$ glass has the highest thermal stability and glass-forming ability in the investigated compositional range. These results could be explained on the basis of modification of the chemical bond formation due to incorporation of Pb in the Se–In glassy matrix.  相似文献   

12.
Thermal Conductivity of Standard Sands. Part III. Full Range of Saturation   总被引:1,自引:0,他引:1  
The thermal conductivity $(\lambda )$ ( λ ) of three unsaturated standard quartz sands (Ottawa C-109 and C-190, and Toyoura) was measured by a transient thermal-conductivity probe, at room temperature of approximately $25\,^{\circ }\text{ C }$ 25 ° C and at loose and tight compactions. The measurements were carried out at different degrees of saturation $(S_\mathrm{r})$ ( S r ) from dryness to full saturation. In general, a sharp $\lambda $ λ increase was observed at low $S_\mathrm{r}$ S r , followed by a moderate rise until full saturation. However, experiments on loosely compacted C-190 samples revealed $\lambda $ λ deviation from a general trend ( $\lambda $ λ vs $S_\mathrm{r})$ S r ) caused by water percolation. Alternatively, successful experiments were carried out on loosely packed unsaturated C-190 samples using 1 % agar gel. For loosely compacted C-109 and Toyoura, $\lambda $ λ data obtained from 1 % agar gel closely agreed with $\lambda $ λ data for water as a saturation medium. The measured data were used to verify a model by de Vries for unsaturated soils. The model largely underestimates experimental data at $S_\mathrm{r}<0.5$ S r < 0.5 and produces an overall root-mean-square error of about $0.2\, \text{ W }~{\cdot }~\text{ m }^{-1}~{\cdot }~\text{ K }^{-1}$ 0.2 W · m ? 1 · K ? 1 . Measured $\lambda $ λ data agreed with data by a steady-state technique (a guarded hot-plate apparatus) at dryness and full saturation and exceeded the steady-state data in the unsaturated region. However, TCP data can be considered more reliable due to a lower temperature increase during $\lambda $ λ measurements and a shorter testing time. Consequently, in the case of unsaturated soils, evaporation and migration of water and steam can be avoided.  相似文献   

13.
Speeds of sound of (l-alanine/l-glutamine/glycylglycine $\,+\, 0.512\, {\mathrm{mol}}\cdot {\mathrm{kg}}^{-1}$ + 0.512 mol · kg ? 1 aqueous ${\mathrm{KNO}}_{3}/0.512\, {\mathrm{mol}}\cdot {\mathrm{kg}}^{-1}$ KNO 3 / 0.512 mol · kg ? 1 aqueous ${\mathrm{K}}_{2}{\mathrm{SO}}_{4}$ K 2 SO 4 ) systems have been measured for several molal concentrations of amino acid/peptide at different temperatures: $T$ T = (298.15 to 323.15) K. Using the speed-of-sound and density data, the parameters, partial molar isentropic compressibilities $\phi _{\kappa }^{0}$ ? κ 0 and transfer partial molar isentropic compressibilities $\Delta _{\mathrm{tr}} \phi _{\kappa }^{0}$ Δ tr ? κ 0 , have been computed. The trends of variation of $\phi _{\kappa }^{0}$ ? κ 0 and $\Delta _{\mathrm{tr}} \phi _{\kappa }^{0}$ Δ tr ? κ 0 with changes in molal concentration of the solute and temperature have been discussed in terms of zwitterion–ion, zwitterion–water dipole, ion–water dipole, and ion–ion interactions operative in the systems.  相似文献   

14.
Laser-induced photoacoustic (PA) spectroscopy for the spectral measurements of extremely weak absorption such as a forbidden transition of lanthanide ions in liquids has been established. In spectroscopy, a pulsed Nd:YAG laser connected with a MOPO series optical parametric oscillator which emits a broad spectrum covering UV and visible regions is used as the excitation source, and the induced PA signals are detected by an optimized PA piezoelectric transducer. The absorption spectra of trivalent lanthanide ions ( $\text{ Pr}^{3+}, \text{ Ho}^{3+}$ , and $\text{ Nd}^{3+})$ in aqueous solutions have been obtained by the detection system with a detection-limit absorbance of $1.3\times 10^{-5}\,\text{ cm}^{-1}$ at room temperature. In addition, the effects of different binding environments on the band shapes and oscillator strengths of the hypersensitive transitions of $\text{ Nd}^{3+}$ ions, i.e., $\text{ Nd}(\text{ CH}_{3}\text{ COO})_{3}$ $\cdot $ $\text{ H}_{2}\text{ O}$ dissolved in $0.1\,{\text{ mol}} \cdot \text{ l}^{-1}$ acetic acid and $\text{ Nd(3-butanedione)}_{3}{\cdot } 2\text{ H}_{2} \text{ O}$ dissolved in triglycol compared with $\text{ NdCl}_{3}$ in $0.1\,{\text{ mol}}\cdot \text{ l}^{-1}$ hydrochloric acid, are observed. The results show that the chemical environment around the lanthanide ions has great impact on 4f–4f transitions, which is rationalized as the impact in terms of ligand (or solvent) special structures and coordination properties.  相似文献   

15.
Quartz and kaolin were partially substituted by sand stone dust (a siliceous byproduct of Indian stone cutting and polishing industries) in a traditional triaxial porcelain composition consisting of kaolin, quartz and feldsper. The effect of substitution upon heating at different temperatures (1050–1150 $\boldsymbol{^\circ}$ C) were studied by measuring the linear shrinkage, bulk density, porosity and flexural strength. Qualititative phase and microstructural analysis on selected samples were carried out using XRD and SEM/EDX technique. The results show that the samples of all the batches achieved higher density (2 $\boldsymbol\cdot$ 50 g/cc) and almost full vitrification ( $\boldsymbol <$ 0 $\boldsymbol{\cdot}$ 1% apparent porosity) at around 1115 $\boldsymbol{^\circ}$ C compared to around 1300 $\boldsymbol{^\circ}$ C for traditional triaxial porcelain composition. As high as 70 MPa flexural strength was obtained in most of the vitrified samples. No significant variation in physico-mechanical properties was observed in between the composition. XRD studies on selected samples show presence of mainly quartz phase both at low and high temperatures. SEM photomicrographs of the 1115 $\boldsymbol{^\circ}$ C heated specimen show presence of quartz grain and glassy matrix. Few quartz grains (20–40 $\boldsymbol{\mu}$ m) are associated with circumferential cracks around them.  相似文献   

16.
A comparative study of spherical and rod-like nanocrystalline Gd $_{\boldsymbol 2}$ O $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ (Gd $_{\boldsymbol{1\cdot92}}$ Eu $_{\boldsymbol{0\cdot08}}$ O $_{\boldsymbol 3}$ ) red phosphors prepared by solution combustion and hydrothermal methods have been reported. Powder X-ray diffraction (PXRD) results confirm the as-formed product in combustion method showing mixed phase of monoclinic and cubic of Gd $_{\boldsymbol 2}$ O $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ . Upon calcinations at 800 $^{\boldsymbol\circ}$ C for 3?h, dominant cubic phase was achieved. The as-formed precursor hydrothermal product shows hexagonal Gd(OH) $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ phase and it converts to pure cubic phase of Gd $_{\boldsymbol 2}$ O $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ on calcination at 600 $^{\boldsymbol \circ}$ C for 3?h. TEM micrographs of hydrothermally prepared cubic Gd $_{\boldsymbol 2}$ O $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ phase shows nanorods with a diameter of 15?nm and length varying from 50 to 150?nm, whereas combustion product shows the particles to be of irregular shape, with different sizes in the range 50?C250?nm. Dominant red emission (612?nm) was observed in cubic Gd $_{\boldsymbol 2}$ O $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ which has been assigned to $^{\boldsymbol 5}{\bf \textit{D}}_{\boldsymbol 0}$ $\boldsymbol \to$ $^{\boldsymbol 7}{\bf \textit{F}}_{\boldsymbol 2}$ transition. However, in hexagonal Gd(OH) $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ , emission peaks at 614 and 621?nm were observed. The strong red emission of cubic Gd $_{\boldsymbol 2}$ O $_{\boldsymbol 3}$ :Eu $^{\boldsymbol{3+}}$ nanophosphors by hydrothermal method are promising for high performance display materials. The variation in optical energy bandgap ( $\boldsymbol{E}_{\boldsymbol{\rm g}}$ ) was noticed in as-formed and heat treated systems in both the techniques. This is due to more ordered structure in heat treated samples and reduction in structural defects.  相似文献   

17.
We report the results of directional point-contact measurements in Mg(B $_{1-x}$ C $_{x})_{2}$ single crystals. The amplitudes of the gaps, $\Delta_{\pi}$ and $\Delta_{\sigma}$ , were determined for each C content by fitting the experimental low-temperature normalized conductance curves of our “soft” point contacts with the BTK model generalized to the two-band case. We found that, on increasing the carbon content, $\Delta_{\sigma}$ decreases almost linearly with $T_{c}$ and $\Delta_{\pi}$ slightly increases until, at $x=0.132$ (where $T_{c}=19$ K), they assume the same value $\Delta =3.2 \pm 0.9$ meV. This result is confirmed by the temperature and magnetic-field dependence of the conductance curves at this C content, which do not show any evidence of two distinct gap values. In particular, the Δ versus T curve follows very well a standard BCS curve, with a gap ratio $2\Delta /k_{B} T_{c}=3.9$ . These experimental findings are compared to the theoretical predictions of the two-band model in the Eliashberg formulation.  相似文献   

18.
Yu Liu 《Granular Matter》2014,16(1):133-139
A theoretical calculation method for the flow rate of granular matter from an inclined orifice is discussed in this article and for the inclination angles at $\theta \le 90^{\circ }$ , a theoretical relation between the flow rate $Q$ and inclination angle $\theta $ is derived; and for the inclination angles at $\theta >90^{\circ }$ , a semi-theoretical relation is established. From the relations, we found that the ratio of the flow rate from a vertical orifice, $Q_{90}$ , to that from a horizontal orifice, $Q_{0}$ , is equal to the sine of the angle of repose $\theta _{\mathrm{r}}$ , i.e., $Q_{90} /Q_0 =\sin \theta _{\mathrm{r}} $ . The theoretical relations are tested by means of the experimental data and the results indicate that the theoretical calculating values are in good agreement with the experimental data over a wide range of the inclination angles. Therefore, the formula proposed in this article can be used for the theoretical calculation of the flow rate of granular matter from an inclined orifice. The relation $Q_{90} /Q_0 =\sin \theta _{\mathrm{r}}$ may be used as an alternative approach to obtaining $\theta _{\mathrm{r}}$ : measuring $Q_{90}$ and $Q_{0}$ , and then calculating $\theta _{\mathrm{r}} $ by using formula $\theta _{\mathrm{r}} =\arcsin (Q_{90} /Q_0 )$ .  相似文献   

19.
$\mathrm{Bi}_{5}\mathrm{Ti}_{3}\mathrm{FeO}_{15}$ Bi 5 Ti 3 FeO 15 magnetoelectric (ME) ceramics have been synthesized and investigated. The ME effect can be described as an induced electric polarization under an external magnetic field or an induced magnetization under an external electric field. The materials in the ME effect are called ME materials, and they are considered to be a kind of new promising materials for sensors, processors, actuators, and memory systems. Multiferroics, the materials in which both ferromagnetism and ferroelectricity can coexist, are the prospective candidates which can potentially host the gigantic ME effect. $\mathrm{Bi}_{5}\mathrm{Ti}_{3}\mathrm{FeO}_{15}$ Bi 5 Ti 3 FeO 15 , an Aurivillius compound, was synthesized by sintering a mixture of $\mathrm{Bi}_{2}\mathrm{O}_{3}, \mathrm{Fe}_{2}\mathrm{O}_{3}$ Bi 2 O 3 , Fe 2 O 3 , and $\mathrm{TiO}_{2}$ TiO 2 oxides. The precursor materials were prepared in a high-energy attritorial mill for (1, 5, and 10) h. The orthorhombic $\mathrm{Bi}_{5}\mathrm{Ti}_{3}\mathrm{FeO}_{15}$ Bi 5 Ti 3 FeO 15 ceramics were obtained by a solid-state reaction process at 1313 K. The ME voltage coefficient ( $\alpha _\mathrm{ME}$ α ME ) was measured using the dynamic lock-in method. The highest ME voltage coefficient ( $\alpha _\mathrm{ME} = 8.28\,\text{ mV }{\cdot }\text{ cm }^{-1}{\cdot }\text{ Oe }^{-1})$ α ME = 8.28 mV · cm ? 1 · Oe ? 1 ) is obtained for the sample milled for 1 h at $H_\mathrm{DC }= 4$ H DC = 4  Oe (1 Oe = 79.58  $\text{ A }{\cdot }\text{ m }^{-1})$ A · m ? 1 ) .  相似文献   

20.
The structural and electronic properties of the cubic fluoroperoveskite $\text{ CsBeF}_{3}$ and $\text{ CsMgF}_{3}$ have been investigated using the full-potential-linearized augmented plane wave method within the density functional theory. The exchange-correlation potential was treated with the local density approximation and the generalized gradient approximation. The calculations of the electronic band structures show that $\text{ CsBeF}_{3 }$ has an indirect bandgap, whereas $\text{ CsMgF}_{3}$ has a direct bandgap. Through the quasi-harmonic Debye model, in which the phononic effects are considered, the effect of pressure $P$ and temperature $T$ on the lattice parameter, bulk modulus, thermal expansion coefficient, Debye temperature, and the heat capacity for $\text{ CsBeF}_{3}$ and $\text{ CsMgF}_{3}$ compounds are investigated for the first time.  相似文献   

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