Bonding performance of heat treated wood with structural adhesives

Bonding of untreated, intermediate (hydro-thermolysed) and heat treated wood with melamine-urea-formaldehyde (MUF), phenol-resorcinol-formaldehyde (PRF) and polyurethane (PUR) adhesives was studied. An industrial heat treatment process (Plato ^®) was used, which included two separate heat treatment stages and a drying stage in-between. Laminated beams having four lamellas were prepared from untreated and treated timber for mechanical testing of the bond lines. The results of the tests showed that heat treatment affected the shear strength and the delamination of the laminated wood depending on the adhesive system used for bonding. The PUR and MUF adhesives performed in a rather similar way, and better than the PRF adhesive. The shear strength of laminated wood bonded with the waterborne MUF and PRF adhesives decreased for the specimens made of hydro-thermolysed timber and decreased further for the specimens made of fully heat treated timber. The difference in adhesive bond shear strength between untreated, intermediate and fully treated wood was less obvious in the case of the PUR adhesive. Delamination of the PRF bond line decreased drastically for all the specimens made of heat treated timber.     

Effect of short-term thermomechanical densification of wood veneers on the properties of birch plywood

In this study, the physical and mechanical properties of plywood panels made from pre-compressed birch (Betula verrucosa Ehrh.) veneer were evaluated. Veneer sheets underwent short-term thermo-mechanical (STTM) compression at temperatures of 150 or 180 °C and at pressures of 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 or 3.5 MPa for a period of 1 min prior to adhesive being applied and pressed into panels using phenol formaldehyde adhesive at 100 g/m² spread rate; this was one-third less than the adhesive spread used for the control panels (150 g/m²). The pressing pressure was 1.0 MPa, which was almost half of the pressure used for the control panels (1.8 MPa); and pressing time was 3 min, also half of the pressing time used for the control panels (6 min). The results showed that surface roughness of compressed veneer, water absorption and thickness swelling of plywood panels made from compressed veneer were significantly improved. The shear strength values of plywood panels made from compressed birch veneer even with reduced adhesive spread were higher than those of plywood panels made from uncompressed veneer. The findings in this study indicated that compression of birch veneer could be considered as an alternative to produce more eco-friendly (owing to smaller adhesive spread) value-added material with enhanced properties.     

Improvement of tensile shear strength and wood failure percentage of 1C PUR bonded wooden joints at wet stage by means of DMF priming

Tensile shear tests according to EN 302-1 for load-bearing timber structures were performed on European beech wood (Fagus sylvatica L.) and Douglas fir [Pseudotsuga menziesii (Mirb.) Franco] bonded by means of a one-component polyurethane adhesive (1C PUR). Results reveal a substantial loss of tensile shear strength (TSS) and wood failure percentage (WFP) at the wet stage compared to the dry stage. As can be seen from microscopic images, this is accompanied by a loss of adhesion at the boundary layer. Therefore, the aim of this work was to find a priming fluid that improves the load transmission between adhesive and adherend at the wet stage without introducing formaldehyde into the gluing process. A substantial improvement of TSS and WFP was achieved by means of the hygroscopic organic solvent N,N-dimethylformamide (DMF). In addition, contact angle measurements were carried out, revealing that DMF heavily enhances the wettability of the joining surface. Furthermore, it was attempted to integrate the outcomes into the swelling strain model stated by Frihart in 2009. By way of comparison a hydroxymethylated resorcinol coupling agent, a mixture of diphenylmethane-4,4′-diisocyanate isomers and water were also tested as priming fluids. The data confirm that TSS and WFP of 1C PUR bonded wooden joints do not correlate, whilst WFP is mostly not normally (at wet stage often bimodally) distributed.     

Application of High Pressure for Selective Activity Regulation of Starter Cultures Aminopeptidases Involved in Ripening of Brined Cheeses

The combined effect of high pressure processing and temperature on aminopeptidases activity of lactic acid bacteria used as starter cultures in brined cheese manufacturing, in order to find the optimum process conditions for acceleration of the significant long-duration cheese ripening step, was investigated.The effect of high hydrostatic pressure (HP) (100–450 MPa) combined with temperature (20–40 °C) on the activity of five aminopeptidases (PepN, PepX, PepY, PepC, and PepA) of Streptococcus thermophilus ACA-DC 0022 and Lactococcus lactis ACA-DC 0049, used as the starter culture for white Greek brine cheese (feta) production, was studied. S. thermophilus aminopeptidases PepN, PepX, PepA, and PepC were activated at pressures up to 200 MPa, and all studied temperatures (20–40 °C), while for L. lactis, PepN, X, and Y were activated at pressures up to 300 MPa and temperatures up to 30 °C and PepA at the same temperature range but milder pressures (up to 200 MPa). For L. lactis, PepC an increase in activity was observed at all studied pressures but only at 20 °C. A multi-parameter equation was used for predicting the activation of all aminopeptidases in the pressure and temperature domain. Overall, processing at 200 MPa and 20 °C may be selected as the optimum conditions for maximum activation of all aminopeptidases of both S. thermophilus ACA-DC 0022 and L. lactis ACA-DC 0049. A 20-min treatment at these conditions leads to an average threefold increase in activity which could lead to better and faster maturation of white cheese.     

Influence of processing parameters and wood properties on the edge gluing of green <Emphasis Type="Italic">Eucalyptus grandis</Emphasis> with a one-component PUR adhesive

The predominant plantation hardwood species in South Africa Eucalyptus grandis is, despite relatively good strength and stiffness properties, seldom used for lumber production due to low dimensional stability, splitting, and cracking of the wood. As critical defects often develop or aggravate during the drying process, the edge gluing of Eucalyptus grandis lumber in its wet state, before kiln-drying, was considered a potential inhibiting factor for this behaviour. The objective of this study was to determine how certain material and processing variables influence the bond quality of unseasoned, edge-glued, Eucalyptus grandis, using a moisture-curing one-component polyurethane adhesive. The study considered the effect of four parameters, namely wood density, moisture content, adhesive spread rate and pressure, on the shear strength of bondlines. Micro computed tomography scanning was used to observe adhesive penetration behaviour. Overall, the bonding quality was satisfactory proving the feasibility of edge gluing of this wood in the wet state. Multiple ANOVA showed that generally better results were obtained for samples with a higher moisture content of roughly 60% compared to specimens with lower moisture content around fibre saturation point. Results indicated that the lower spread rate tested (150 g m^?2) should be preferred to the higher one (250 g m^?2), since it will likely give more stable shear strength results and it would be preferable from an economic point of view. Increasing pressure did not increase the shear strength significantly.     

Artificial ageing of softwood joints and its effect on internal bond strength with special consideration of flat-to-end grain joints

The effect of ageing processes on internal bond strength of three-part specimens produced from Norway spruce wood (Picea abies Karst.) bonded with one-component polyurethane (PUR), two-component emulsion polymer isocyanate (EPI), melamine-urea-formaldehyde (MUF) or phenol-resorcinol-formaldehyde (PRF) adhesive was studied. By varying the grain angle of the middle part from 0° (parallel to grain of the surface layers) to 90° (perpendicular to grain of the surface layers) in incremental steps of 10° the effect of grain direction was investigated. The specimens were exposed to a three-step ageing cycle lasting for seven days (50°C/95% relative humidity (rH), ?20°C/65?C70% rH and 75°C/15% rH) which was repeated twelve and twenty-four times, respectively. In general, a decrease in internal bond strength of the exposed specimens was observed. For all tested adhesive systems, influence of ageing processes was more pronounced for flat-to-end grain joints compared to longitudinal joints. For samples bonded with PUR adhesive strength reduction was lower compared to the other adhesives used.     

Curing behavior and bonding strength of two-component fast-setting adhesives prepared with phenol-liquefied <Emphasis Type="Italic">Cryptomeria japonica</Emphasis> wood

Honeymoon adhesive is a special adhesive system that contains two components which are applied onto two substrates separately for glulam manufacturing to provide a fast-setting capability. It has been confirmed that phenol-liquefied wood can be used as a raw material for preparing phenolic resins. In this study, liquefied wood (LW) was obtained by liquefying Cryptomeria japonica wood in phenol with sulfuric acid as a catalyst. Resorcinol–formaldehyde resin (RF), phenol-resorcinol–formaldehyde resins (PRF), LW–PF and LW–PRF (synthesized using LW as a raw material), and RF/LW and RF/LW–PF (blended RF with LW and LW–PF) were prepared. The properties such as non-volatile content, pH, viscosity gelation time and DSC curing behavior of these resins were measured. The results show all resins can be cured at room temperature when paraformaldehyde is added as a hardener, except for the LW–PF. The honeymoon adhesive was prepared by using RF and PRF that contains 10% paraformaldehyde as the A-component and LW–PRF, RF/LW and RF/LW–PF without paraformaldehyde as the B-component. After mixing the A-component and B-component, the gelation time of RF and PRF can be shortened. The glued lumber was prepared by separately applying the A-component and B-component on the surface of two wood strips and combining them. The result shows using RF/LW–PF as the B-component has faster bonding strength development than others. When PRF and RF are used as the A-component, they have a bonding strength of over 5.4 MPa, the requirement of CNS 11031 standard for the glued lumber of C. japonica, at pressing times of 2 and 4 h, respectively.     

Investigation of drying characteristics in superheated steam drying of UF-impregnated Chinese fir

Urea formaldehyde (UF) resin-impregnated Chinese fir (Cunninghamia lanceolata (Lamb.)Hook.) was dried at different temperatures in an atmospheric pressure superheated steam dryer. Drying characteristics, moisture content, drying rate, temperature profile, drying defects, and color change were investigated. The moisture content was reduced from 66.21 to 11.79% within 30 h without causing severe drying defects; in contrast, the conventional hot air process required 7–8 days. After 25 h of drying, the temperatures at both the center and the surface of wood remained stable. After 34.5 h, the surface temperature gradually approached the steam temperature. The color of the superheated steam dried Chinese fir appeared slightly more intense yellow and red than the control. Investigation of the UF-impregnated Chinese fir wood by scanning electron microscopy (SEM) revealed that the majority of the lumens and voids, including the microvoids in wood structure, was filled with urea formaldehyde resin.     

胶黏剂种类对人造板内结合强度检测结果的影响

使用聚乙酸乙烯酯乳液(PVAc)、单组份聚氨酯(PUR)和热熔胶(EVA)3种胶黏剂粘结金属卡头与试件,检测并分析它们对强化木地板和地板基材用纤维板内结合强度检测结果的影响。结果表明:使用PUR粘结时检测的内结合强度值比使用PVAc、EVA高,其中强化木地板内结合强度高出0.47MPa,地板基材用纤维板内结合强度高出约0.40MPa。     

Feasibility study of utilization of commercially available polyurethane resins to develop non-biocidal wood preservation treatments

Evaluation of commercially available polyurethane resins used up to now for coating applications to develop non-biocidal wood preservation treatments has been conducted. A simple method of vacuum impregnation of these resins into beech wood (Fagus sylvatica L.) and pine wood (Pinus sylvestris L.) samples followed by varied curing processes at ambient temperature, 103, and 200 °C has been performed. Based on the analysis of weight percent gain before and after leaching, treatment resistance to leaching, anti-swelling efficiency, wettability and decay durability measured for treated and untreated blocks after leaching with the white-rot fungus Coriolus versicolor for both wood species and the brown-rot fungi Poria placenta and Gloeophyllum trabeum for pine wood, it can be concluded that such treatment can be considered as potential valuable non-biocidal treatments.     

Inactivation Kinetics of the Most Baro-Resistant Enzyme in High Pressure Processed Litchi-Based Mixed Fruit Beverage

This work focused on a litchi-based mixed fruit beverage, comprising of coconut water and lemon juice, mixed in an optimized proportion. Based on preliminary studies, three resistant spoilage enzymes were identified in the beverage, viz. polyphenol oxidase (PPO), peroxidase (POD), and pectin methyl esterase (PME). The response surface methodology (RSM) based on central composite face-centered design (FCCD) screened out PPO as the most resistant enzyme within the high pressure processing (HPP) domain of 200–600 MPa/30–70 °C/0–20 min. A detailed kinetic study was conducted on PPO inactivation within the same HPP domain along with a set of thermal treatments (0.1 MPa/30–70 °C). A synergistic effect of pressure and temperature on PPO inactivation was observed, throughout the HPP domain. However, PPO was almost completely inactivated at 500 MPa/70 °C/20 min. The inactivation order (n) values for PPO were 1.10 and 1.25 for thermal and HPP treatments, respectively. For every 10 °C rise in temperature, the inactivation rate constant (k, U^n-1 min^?1) increased approximately by 1.5 times, within 50–70 °C (at 0.1 MPa), while a 10-fold increase was obtained in the case of HPP treatments. The activation energy (E _a ) and the activation volume (V _a), depicting the temperature and pressure dependence of k, was found to decrease slightly, with an increase in pressure and temperature, respectively. The PPO inactivation rate constant was modeled as a function of both temperature and pressure conditions by combining both Arrhenius and Eyring equations.     

Shape- and dimensional stability of solid wood panels made from heat-treated lime wood strips

The paper presents the results of an experimental research performed with solid wood panels made from heat-treated and untreated lime wood (Tilia cordata Mill.) strips and then subjected to open-air exposure for 3 months. The dimensions of the panels were measured by means of an OPTODesQ Measurement Table, first after conditioning and sanding, then after each month of open-air exposure in order to assess their shape- and dimensional stability. After 3 months, the panels made from heat-treated wood strips showed up to 70% lower volumetric swelling and up to 143% lower flatness deviation than the panels made from untreated strips.     

Structural bonding of ash (Fraxinus excelsior L.): resistance to delamination and performance in shearing tests

The utilization of ash (Fraxinus excelsior L.) allows for a significant enhancement of the load-bearing capacity in structural laminated products. However, such applications fundamentally require high-strength and durable bonds between lamellas and in finger joints. Therefore, the aim of the present survey was to evaluate ash bondings in terms of resistance to delamination (EN 302-2) and shear performance (EN 392). Investigations were performed with five adhesives: phenol-resorcinol-formaldehyde (PRF), melamine-urea-formaldehyde (MUF-1, MUF-2), polyurethane (PUR), emulsion polymer isocyanate (EPI) and varying closed assembly times as key bonding parameter. For all tested adhesives and closed assembly times, the shear test showed high wood failure percentages and bond strength values that compare to solid ash. In contrast, for resistance to delamination, significant differences were found between the adhesives as well as between closed assembly times, with improving resistance to delamination for increasing closed assembly times. The best performance was determined for the PRF-adhesive and long closed assembly times. However, standard requirements for resistance to delamination could not be met by any of the adhesives. The resistance to delamination showed no correlation with the shear performance for any of the adhesives. Microscopic examination of the bonded joints revealed that both the penetration behavior of the adhesives and glueline thicknesses clearly correlated with the closed assembly time.     

Influence of thermo-vacuum treatment on thermal degradation of various wood species

Solid wood has a certain amount of resistance to fire exposure. Recently, there is also great interest in characterization of the thermal behaviour of treated wood due to increasing demand of such products within the perspective of sustainability of environment. The objective of this study was to evaluate and predict the thermal decomposition process of samples from different wood species, Norway spruce (Picea abies Karst.), common ash (Fraxinus excelsior L.) and Turkey oak (Quercus cerris L.), so that such data can be used for enhanced design of wood products for more effective and better utilization in different applications. Spruce and ash samples were treated at a temperature of 190 °C for 2 h while Turkey oak specimens were steamed at a temperature of 110 °C for 24 h before they were thermally treated at a temperature of 160 °C for 3 h. A thermo-gravimetric analysis of the samples highlighted intraspecific differences in mass loss and the stage of thermal degradation between treated and untreated specimens. The degradation of the wood was characterized by twofold reaction stages, with an exception of Norway spruce samples, which exhibited a one-stage reaction. In addition, thermal treatments affected chemical composition of wood. The obtained results will be helpful in determining the applicability of these materials according to their thermal degradation properties.     

Comparison of mechanical properties of oriented strand board made from trembling aspen and paper birch

This study compared the performance of oriented strand boards (OSB) made from trembling aspen, a low-density hardwood species, and OSB made from paper birch, a medium-density hardwood species. The birch strands were thinner than the aspen strands to ensure a comparable specific surface. Three levels of adhesive content were used: 3.5%, 5.0%, and 7.0%. Internal bond (IB) and modulus of elasticity (MOE) and modulus of rupture (MOR) for flatwise and edgewise bending were determined. Both species performed equally well in IB (3.5% adhesive content: 0.46 MPa, 5.0%: 0.60 MPa, and 7.0%: 0.65 MPa). The values of MOE in flatwise bending were slightly lower for birch than for aspen panels (11.8 GPa for aspen and 10.6 GPa for birch), and the MOR values were not significantly different (combined 68.3 MPa). Edgewise bending properties were not significantly different for the two species with a MOE of 10.5 GPa and a MOR of 43.2 MPa.     

Swelling restraint of thermally modified ash wood perpendicular to the grain

The paper reports on creep of ash wood (Fraxinus excelsior L.) thermally modified at 180 and 200 °C, and subsequently subjected to compression in tangential and radial directions and simultaneously wetted, from the moisture content (MC) of 6% to above the fibre saturation point (FSP). The compressing load made 0.00, 0.25, 0.50 and 0.75 of impact stress at the proportional limit (R_c). The compression stress needed to restrain the swelling of wood, the so-called swelling pressure, was indirectly determined from isochrones of mechano-sorptive creep. The most important finding was that thermal modification reduces the strain of ash wood subjected to compression perpendicular to the grain to a degree proportional to the mass loss. The compression stress needed to restrain the swelling of thermally modified wood is ca. 10 and 20% smaller in the tangential and radial directions, respectively. This effect leads to a reduction in the anisotropy of swelling pressure of thermally modified wood perpendicular to the grain. Moreover, although upon thermal modification the mass loss of wood takes place, at the MC of 6% it shows practically the same modulus of elasticity (MOE) and Rc as the unmodified wood. After wetting to MC higher than the FSP, the thermally modified wood at 200 °C shows significantly higher MOE and Rc than the wood modified at 180 °C and untreated wood. Reduction of wood hygroscopicity, an inevitable effect of thermal modification, also reduces the range of changes in mechanical properties of wood caused by the increase in its MC to the FSP.     

Effect of end pressure on performance of structural finger-joined lumber fabricated using a short joint profile

This study was to examine the effect of end pressure on the mechanical properties and delamination resistance of structural black spruce (Picea mariana) finger-joined lumber made of a short (12.7-mm-long) finger profile. End pressures used were 2.00, 3.43, 6.00 and 8.00 MPa. 8.00 MPa yielded the greatest 5th percentile ultimate tensile strength, but caused cracks at tips of a joint. It was recommended that 2.00 MPa be used as the optimized end pressure from the viewpoint of energy saving.     

胶黏剂种类对人造板内结合强度检测结果的影响

使用聚乙酸乙烯酯乳液（PVAc）、单组份聚氨酯（PUR）和热熔胶（EVA）3种胶黏剂粘结金属卡头与试件,检测并分析它们对强化木地板和地板基材用纤维板内结合强度检测结果的影响。结果表明：使用PUR粘结时检测的内结合强度值比使用PVAc、EVA高,其中强化木地板内结合强度高出0.47MPa,地板基材用纤维板内结合强度高出约0.40MPa。     

Utilization of bark flours as additive in plywood manufacturing

Increasing demand for wood based panel products and shortage of wood as raw material have triggered many efforts to utilize residues generated annually by the forest industries including a large portion of bark in panel production. In this study, the effects of using bark flours as additives obtained from different wood species (walnut, chestnut, fir and spruce), having much polyphenol content, on some physical and mechanical properties and formaldehyde emission of plywood panels were examined. Wheat flour, which has been used widely as additive in plywood manufacturing, served as control. Plane tree (Platanus orientalis) logs were obtained for veneer manufacturing. Urea formaldehyde (UF) resin with 55 % solids content was used as adhesive. The bonding shear strength, bending strength, modulus of elasticity (MOE), density, equilibrium moisture content and formaldehyde emission of plywood panels were determined according to related standards. It was found that the use of flours obtained from the barks of chestnut and fir trees in the glue mixture decreased the formaldehyde emission of panels. The bonding strength values of the test panels made using the glue mixture including the flour of walnut and spruce barks as additive were lower than those of the panels with adhesive containing the flour of fir and chestnut barks. The panels manufactured with adhesives including the flour of fir bark gave the highest bending strength and modulus of elasticity values.