净化对非晶形成能力和非晶热稳定性的影响SCIEI

采用玻璃熔体净化法和电磁悬浮循环过热法消除Ni_(75),B_(17)Si_R合金液内的异质核心,研究了净化对该合金液非晶形成能力和所形成的非晶合金热稳定性的影响。采用净化和忽冷相结合的工艺制备出了20×10×0.5mm的Ni_(75)B_(17)Si_8非晶试样,试样的厚度较净化前提高了4倍。     

深过冷合金再辉与凝固组织的研究

发现深过冷Ni_(68)B_(21)Si_(11)合金液形核过程中的多次再辉现象,揭示了二次和三次再辉的过冷条件,以及对凝固组织的影响。研究结果表明,深过冷Ni_(68)B_(21)Si_(11)合金液存在两种凝固机制:一是NilB,Nj‘si,B和Ni,B的三相共晶生长;另一个是以NilB为领先相的枝晶簇生长。当过冷度低于200K或超过310K时,合金液凝固仅伴生一次再辉,其晶体生长以第一种凝固方式进行。其他过冷范围内的合金液则发生多次再辉和枝晶簇凝固。     

BRITTLE-DUCTILE TRANSITION OF ANNEALEMBRITTLED Fe_(75)Si_(10)B_(15)METALLIC GLASS

Studies were made of the effect of mechanical pulverization on relaxation,crystallizationand brittle-ductile transition of the anneal-embrittled Fe_(75)Si_(10)B_(15) metallic glass rib-bon.Results show that the Curie temperature,T_C,decreases and the total enthalpy ofrelaxation increases gradually with variation of pulverized time.DSC traces reveal anextra exothermic peak,T_X_1,and a distinct glass transition endothermic peak,T_g_1,withincreasing pulverized time,T_C,T_X_1,and T_g_1 decrease simultaneously,and the exother-mic peak area corresponding to T_X_1 increases gradually.The surface slip-steps of flakyparticles and their corresponding shear are produced by pulverizing the pre-embrittledamorphous glass.The lost ductility of the glass may restore during annealing.     

退火变脆Fe75Si10B15金属玻璃的脆韧性转变

研究了机械研磨对退火变脆Fe_(75)Si_(10)B_(15)金属玻璃的弛豫过程,晶化行为及脆韧性转变的影响。发现退火变脆的Fe_(75)Si_(10)B_(15)金属玻璃,经不同时间机械研磨,Curie温度T_C逐渐回落,总的弛像焓ΔH_?逐渐回升。在DSC曲线上观察到明显的玻璃转变温度T_(g_1)和一个附加的宽放热峰T_(x_1),随着研磨时间的增加,T_(x_1),T_(x_1),T_C同步降低,与T_(x_1)对应的放热面积ΔH_(x_1)逐渐增大,并在片状粒子表面形成切变带以及与其对应的剪切带,玻璃在退火过程中失掉的韧性逐渐得到恢复。     

深过冷Ni基六元合金的孪晶生长

采用熔融玻璃自分离净化工艺,使得合金(Ni_(0.53)Fe_(0.33)Co_(0.14))_(73)B_(17)Si_8Nb_2获取深过冷观察到孪晶生长方式的凝固特征通过相成分及组织结构和形貌的分析,并结合深过冷液态合金凝固过程的特点,对孪晶的形成和长大机理作了初步的探讨     

APPROACH TO TRANSITION OF NON-CRYSTALLINE METAL GLASSES WITH AID OF METHOD OF POLYMER TRANSITION RESEARCH

对某些金属和类金属按一定比例在高温下熔融混合,并急速冷却,可以得到性能极为特殊的非晶态金属。我们根据高聚物转变理论,用研究高聚物的扭辫仪、线膨胀仪,再结合DSC和X射线衍射仪,对非晶态金属[Fe_(0.1)Ni_(0.35)Co_(0.55)]_(78)Si_8B_(14),[Fle_(0.1)Ni_(0.30)Co_(0.55)Mo_(0.05)]_(78)Si_8B_(14)和[Fe_(0.1)Ni_(0.30)Co_(0.55)Nb_(0.05)]_(78)Si_8B_(14)的玻璃化转变及晶化转变的自由体积、激活能、内耗与热效应等进行了研究,观测到玻璃化温度及晶化温度、玻璃化转变激活能及晶化激活能均与合金元素原子半径有关,转变时的热效应与内耗峰值有一定的对应关系。讨论了玻璃化转变及晶化转变的机理,可供设计非晶态金属时参考。     

Crystallization Behavior of Metallic GlassCo_（65．1）Fe_（4．7）Ni_（4．6）Si_（10．2）B_（15．4）

ＣｒｙｓｔａｌｌｉｚａｔｉｏｎＢｅｈａｖｉｏｒｏｆＭｅｔａｌｌｉｃＧｌａｓｓＣｏ＿（６５．１）Ｆｅ＿（４．７）Ｎｉ＿（４．６）Ｓｉ＿（１０．２）Ｂ＿（１５．４）ＬｉＺｏｎｇｑｕａｎ；ＱｉｎＹｏｎｇａｎｄＨｅＹｉｚｈｅｎ（李宗全），（秦勇）（何怡贞）（...     

Ti53Cu27Ni12Hf3Al7Si3B1大块金属玻璃的制备及性能研究

用单辊甩带法和铜模铸造法制备了新型Ti基大块金属玻璃Ti53Cu27Ni12Hf3Al7Si3B1.DSC、DTA研究表明该合金具有较高的热力学稳定性,其第1晶化温度Tx1、玻璃转变温度Tg、过冷液相区间ΔTx以及约化转变温度Trg分别为705、750、45、0.63 K.压缩性能研究其压缩断裂强度、弹性模量和压缩塑性变形量分别为2 304 MPa、120 GPa和1.1%.研究发现,具有复杂拓扑结构的原子配比提高了Ti53Cu15Ni18.5Al7Hf3Si3B0.5大块金属玻璃的力学性能和热力学性能.     

RECALESCENCES AND SOLIDIFICATION MICROSTRUCTURE OF HIGHLY UNDERCOOLED Ni_(68)B_(21)Si_(11) ALLOY

One,two and three recalescence events in the solidification of highly undercooledNi_68B_21Si_11 alloy melt and the conditions of undercooling together with the effect onsolidification morphologies were revealed.The solidification morphologies of the undercooledalloy may be examined in the light of two aspects,i.e,growth of either Ni_3B,Ni_6Si_2B andNi_2B ternary eutectic or dendrite cluster with Ni_3B as leading phase.When the degree ofundercooling below 200 or over 310 K,the alloy solidifies to accompany one recalescence only,and the crystals grow according to the first mode of solidification.While undercooling at othertemperatures,two or three events of recalescence may occur and the dendrite cluster may so-lidify.     

HEAT CAPACITIES OF Fe_（40）Ni_（40）B_（20） GLASSY ALLOY MEASURED BY ENTHALPY METHOD

ＨＥＡＴＣＡＰＡＣＩＴＩＥＳＯＦＦｅ_（４０）Ｎｉ_（４０）Ｂ_（２０）ＧＬＡＳＳＹＡＬＬＯＹＭＥＡＳＵＲＥＤＢＹＥＮＴＨＡＬＰＹＭＥＴＨＯＤ￥ＪＩＡＮＧＱｉｎｇ;ＺＨＡＯＭｉｎｇ;ＬＩＪｉａｎｃｈｅｎ（ＪｉｌｉｎＵｎｉｖｅｒｓｉｔｙｏｆＴｅｃｈｎｏｌ?..     

EVALUATION OF PERMEABILITY STABILITY OF SEVERAL AMORPHOUS FERROMAGNETIC ALLOYS

The evaluation of the relative stability of initial permeability has been made of the pre-an-nealed amorphous ferromagnetic alloys Fe_(76)Si_(10)B_(14),Fe_(40)Ni_(38)Mo_4B_(18) and(Fe_(0.1)Ni_(0.35)Co_(0.55))_78Si_8B_(14) by the experimental values of average activation energy and fre-quency factors on the basis of the empirical expression deduced by experimental data of thekinetics of their permeability decay.Calculated results show that the relative stability ofpermeability is sufficient for practical uses in the temperature range within 100℃,althoughthe permeability instability can not be substantially eliminated.In other words,thepermeability decay is considerably small within a period of considerable length.     

EFFECTIVE PARAMETER FOR CRYSTALLIZATION STUDY OF AMORPHOUS MAGNETIC ALLOYS——ANOMALOUS HALL COEFFICIENT

<正> 本工作研究不同退火温度的Fe_(62) Ni_(16)Si_8 B_(14), Fe_(40)Ni_(40) P_(12)B_8, Fe_(7.8)Co_(46.8)Ni_(23.4)Si_8B_(14)非晶磁性合金的Hall效应和电阻率ρ,发现这三种合金由非晶态向晶态转变时,反常Hall系数R_1和电阻率ρ发生变化,但R_1的相对变化较之ρ的相对变化大。 实验证明,磁性材料的Hall电阻率ρ_H为: ρ_H=V_Hd/I=R_0B_e+4πR_sM式中R_0和R_s为正常和自发Hall系数,V_H为Hall电压,d和M为试样的厚度和磁化强度,B_e为外磁场,I为通过试样的电流。第一项是传导电子在磁场作用下由Lorentz力引起的正常Hall效应,第二项是传导电子在自旋-轨道耦合作用下由偏散射和旁跳     

THE PHENOMENON OF THE LOW TEMPERATURE STRUCTURAL IN AMORPHOUS ALLOY (Fe_(0.1)Ni_(0.5)Co_(0.4))_(78)Si_8 B_(14)

利用磁导率减落的自动测量仪,测量了非晶合金(Fe_(0.1)Ni_(0.5)Co_(0.4))_(78)Si_8B_(14)等温时效时退磁不能恢复的减落。以此考查了低温结构弛豫动力学行为,计算了弛豫激活能和弛豫谱。结果表明,低温结构弛豫是平均激活能低的多弛豫过程,在这个过程中发展了化学短程序(CSRO)。     

POSITRON ANNIHILATION IN Fe_(38)Ni_(40)Mo_4B_(18) GLASS

<正> 实验用非晶态Fe_(38)Ni_(40)Mo_4B_(18)合金系液态合金急冷法制得的薄带。将该合金在550℃,0.5h退火制得晶态样品。两种样品都经X射线衍射验证。 用滴在厚1.2μm镍箔上的~(22)Na作为正电子源,用多层合金样品迭合后再和源成夹层排列。应用快-快符合寿命谱仪,时间分辨率(FWHM)为290ps,在+138℃到-174℃温度区间测量正电子湮没寿命谱。每个寿命谱的累计计数为10~6。应用计算机程序POSITRONFIT处理寿命     

EFFECT OF MAGNETIC FIELD-AND TENSIONANNEALING ON MAGNETIC PROPERTIES OF AN Fe_(78)Si_(10)B_(12) METALLIC GLASS

通过磁场和张力退火对金属玻璃Fe_(78)Si_(10)B_(12)磁导率影响的研究,发现存在磁化感生和应变感生的两种磁各向异性,二者分别具有正值和负值的各向异性常数。     

MOSSBAUER STUDY ON MAGNETIC ANISOTROPY OF AMORPHOUS ALLOY Fe_(71)Ni_(10)B_(13)Si_4C_2

Magnetic anisotropies of the amorphous alloy Fe_(71)Ni_(10)B_(13)Si_(14)C_2 annealed in magnetic fieldhave been studied using Mossbauer spectroscopy and X-ray diffraction.It is shown that thedistribution of moments in the annealed sample are determined by both stress-produced andthermomagnetic treatment-induced magnetic anisotropies.     

Ni对C－B_4C－SiC复合材料显微结构与性能的影响

本文研究了烧结助剂Ｎｉ对Ｃ－Ｂ_４Ｃ－ＳｉＣ复合材料显微结构与性能的影响．Ｘ射线衍射表明Ｎｉ在烧结温度下与ＳｉＣ，Ｂ_４Ｃ人发生反应在晶界生成Ｎｉ_（４．６）Ｓｉ_２Ｂ，并产生液相，有效地促进了Ｃ－Ｂ_４Ｃ－ＳｉＣ复合材料的烧结，抑制了晶粒的长大，使复合材料密度与强度大幅度地增加，电阻率下降；同时Ｎｉ_（４．６）Ｓｉ_２Ｂ在氧化时生成致密的２ＮｉＯ·Ｂ_２Ｏ_３，包裹了易氧化的Ｂ_４Ｃ和Ｃ，有效地防止了复合材料的氧化，从而大大提高了制品的抗氧化性能．     

Ni/Co比例及微量Dy对FeCoNiBSiNb块体非晶合金玻璃形成能力和磁性能的影响

采用水冷铜模吸铸工艺制备了一系列的(Fe0.5Co1-xNix)72B19.2Si4.8Nb4(x=0,0.05,0.1,0.15,0.2,0.25,0.3,0.4)块体非晶合金.并采用X射线衍射仪(XRD)、差热分析仪(DTA)、振动样品磁强计(VSM)测试了块体非晶合金的结构、热稳定性和软磁性能.探讨了不同Ni/Co比例及添加稀土元素Dy对FeCoNiBSiNb系合金玻璃形成能力(GFA)、热稳定性及磁性能的影响.结果表明:当x=0.05,0.1,0.15,0.2时可制备出直径2mm的非品合金棒,但不能获得3mm非晶合金棒,x=0.25,0.3,0.4均不能获得直径2mm的非晶合金棒,且随Ni/Co比例的增大,即随Ni含量的增加,热稳定性先增加,后逐渐减小,过冷液相区△Tx逐渐减小,非晶合金的玻璃形成能力呈下降趋势,非晶合金的饱和磁化强度(Ms)下降.添加1 at%Dy后,提高了合金的非晶形成能力,可制备出直径3mm的[(Fe0.5Co0.4Ni0.1)72B19.2Si4.8Nb4]99Dy1非晶合金棒,但合金的Ms下降.     

激光熔覆大厚度Fe57Co8Ni8Zr10Si4B13非晶表层及其微结构研究

利用激光熔覆制备出１．２ｍｍ厚的Ｆｅ５７Ｃｏ８Ｎｉ８Ｚｒ１０Ｓｉ４Ｂ１３大厚度非晶表层。用ＸＲＤ,ＥＤＳ,ＴＥＭ,ＤＳＣ及硬度仪对获得的非晶表层进行了多种分析,研究了非晶合金表层的微结构与非晶形成能力,初步探讨了大厚度非晶表层的形成机制。     

EFFECT OF PREPARATION CONDITION ON THERMAL EXPANSION ANISOTROPY FOR AMORPHOUS Fe_(78)B_(13)Si_9 ALLOY

The thermal expansion along the longitudinal and transverse directions for amorphousFe_(78)B_(13)Si_9 alloy prepared under various preparing conditions were investigated.The thermalexpansion anisotropy appears in all specimens.The expansion along the longitudinal directionis less than that along the transverse direction.The cooling rate,the melt temperature beforejet casting and the cycling temperature affect the thermal expansion coefficients andanisotropy.The amisotropy of thermal expansion originates from the orientation of atomicinteraction force,the atomic oscillatory frequency and short range order structure or thedirectional arrangement of defects in the alloy.