共查询到19条相似文献,搜索用时 125 毫秒
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正丙醇—水—乙酸钾体系汽液平衡数据的测定及关联 总被引:4,自引:0,他引:4
正丙醇-水-乙酸钾体系汽液平衡数据的测定及关联武文良张雅明王延儒时钧(南京化工大学化学工程系,南京210009)关键词正丙醇乙酸钾汽液平衡1引言正丙醇是重要的化工原料和有机溶剂,在常压下与水形成恒沸物(含水56.83mol%),用普通方法难以分离。... 相似文献
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对丙酮一步法生产甲基异丁基酮(MIBK)部分精馏流程进行了工艺分析,MIBK脱轻塔进料液中少量水的存在使MIBK脱轻塔运行不稳定,进而影响MIBK合成液的整个分离过程.针对这个问题,提出了精馏-渗透汽化集成的工艺方案,省去MIBK脱轻塔.建立了渗透汽化小试实验,研究了NaA分子筛膜的渗透汽化过程以及分离性能.用Aspen Plus软件对精馏-渗透汽化集成工艺进行了模拟,与精馏过程相比,在MIBK产品质量与收率相同情况下,操作成本降低了20%,总成本可降低15%. 相似文献
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阐述了硫酸钡生产过程中固液分离工艺的现状。提出了用卧式沉降离心机来代替该行业常用的真空叶滤机或箱式压滤机来分离沉淀硫酸钡,并优化卧式沉降离心机的工艺参数:转速3000r/min,溢流直径138mm.差转速30r/min。在该条件下,经过卧式沉降离心机分离后的硫化钠水溶液质量分数为4.46%~5.30%,硫酸钡钡饼含硫化钠碱液质量分数22%~25%,碱回收率大于95%。该设备用于沉淀硫酸钡生产中固液分离,完全能够满足工艺要求。 相似文献
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醇-水-醋酸钠/碘化钾体系汽液平衡 总被引:5,自引:0,他引:5
用改进的Othmer汽液平衡釜测定了101.3kPa下盐摩尔分率x3=0.008、0.012、0.02乙醇—水—醋酸钠/碘化钾体系;x3=0.01异丙醇/正丙醇—水—醋酸钠/碘化钾体系,共10组汽液平衡数据,并用Mock模型、Sander模型、Macdo模型和Kikic模型对这10组实验数据分别进行了关联,结果良好,基本上满足工程设计要求。其中,Mock模型明显好于其他三类模型,所需模型参数也较少,Sander模型与Macedo模型精度相仿,但Macedo模型消除了D-H项中的不一致性。 相似文献
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Zhigang Lei Jianwei Li Chengyue Li Biaohua Chen 《Korean Journal of Chemical Engineering》2006,23(2):264-270
The separation process of synthesizing MIBK (methyl isobutyl ketone) by an isopropanol one-step method, in which the multi-component
mixture contains AC (acetone), IPA (isopropanol), water, MIBK, MIBC (methyl isobutyl carbinol), DIBK (di-isobutyl ketone),
etc., was studied. As a high-purity of MIBK over 99.5 wt% is required in industry, the development of an effective separation
method is urgent. In this work, first, by means of VLE (vapor-liquid equilibrium) experiments and PROII simulation, the possible
azeotropes formed in the investigated system were tested. Then, the separation process was simulated with the result that
the calculated and designed values were in good agreement, which indicated that the calculated results were reliable. On this
basis, the original separation process was improved. In the original separation process, the yield of MIBK for a concentration
of MIBK over 99.5 wt% was small, only 32.5%. In the improved separation process (step two), two columns (one extractive distillation
column and the other solvent recovery column) were added and some simplification was made so as to recycle MIBK. In this case
the yield of MIBK was 91.7%. Moreover, about 27.6% water stream per kilogram MIBK product is saved. 相似文献
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针对某煤气化厂酚回收工艺流程净化废水中酚含量未达到生化处理要求的问题,分析认为主要是由于原萃取剂二异丙基醚(DIPE)对酚分配系数过低。然后以对酚的分配系数更高的甲基异丁基酮(MIBK)为萃取剂,重新设计工艺流程并确定新流程的工艺参数同时对其进行模拟计算,结果显示,净化废水酚含量降至362mg/L,能够满足后续生化段要求;与原流程相比,新流程的粗酚回收量约多0.96 t/d。新旧流程经济核算表明,采用MIBK为萃取剂的流程处理每吨水的价格比DIPE为萃取剂低1.6元。 相似文献
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对丙酮一步法生产甲基异丁基酮(MIBK)部分精馏流程进行了工艺分析,MIBK脱轻塔进料液中少量水的存在使MI-BK脱轻塔运行不稳定,进而影响MIBK合成液的整个分离过程。针对这个问题,提出了精馏-渗透汽化集成的工艺方案,省去MIBK脱轻塔。建立了渗透汽化小试实验,研究了NaA分子筛膜的渗透汽化过程以及分离性能。用Aspen Plus软件对精馏-渗透汽化集成工艺进行了模拟,与精馏过程相比,在MIBK产品质量与收率相同情况下,操作成本降低了20%,总成本可降低15%。 相似文献
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针对丙酮一步法生产MIBK装置的副产物(丙酮、异丙醇、水、MIBK混合物),采用间歇精馏分离得到纯度〉98%的丙酮、纯度〉99%的异丙醇和水恒沸物、纯度〉90%的MIBK。对分离得到的纯度〉99%的异丙醇和水恒沸物用乙二醇作为萃取剂进行萃取精馏分离得到纯度99.5%异丙醇,同时减压精馏回收乙二醇。 相似文献
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以纳米二氧化锆为载体的Pd催化剂制备及还原缩合性能研究 总被引:8,自引:0,他引:8
考察了不同制备方法得到的纳米二氧化锆为载体担载Pd催化剂对丙酮还原缩合的影响。纳米二氧化锆的制备方法对二氧化锆的物理性质和催化性能有较大的影响。不同的沉淀方法、陈化环境制备的纳米ZrO2,对不同的产物有不同的选择性,其中,在母液中373K陈化的二氧化锆为载体的催化剂对二异丁基酮(DIBK)的选择性较高,为61 43%;沉淀剂滴加到盐溶液中得到的二氧化锆为载体的催化剂对甲基异丁基酮(MIBK)的选择性较高,为63 70%。催化剂的酸性和Pd分散度表征结果表明,较高的Pd分散度、合适的酸性有利于MIBK的生成,较高的Pd分散度、较强的酸性有利于DIBK的生成。 相似文献
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《Applied Catalysis A: General》2001,205(1-2):61-69
The surface-phase oxides of niobia on silica substrate ((Nb2O5/SiO2), NS(x)) were prepared and characterized. Such oxides were used as supports for palladium catalysts. The one-step synthesis of methyl isobutyl ketone (MIBK) from acetone and hydrogen in liquid phase was also investigated over Pd/NS(x) catalysts. Experimental results indicate that these catalysts were effective for the formation of MIBK; since little of the parallel by-product of isopropanol (IPA) was formed, these catalysts reached selectivities of 88–92% MIBK and 2–3% IPA at 30–35% conversion. The reactivity of Pd/NS(x) declined obviously with an increase of water content that accumulated in a semi-batch reaction system. The water could be partially expelled and the deactivation of catalysts could be improved by using a fixed bed continuous flow reaction system. 相似文献
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《分离科学与技术》2012,47(6):1169-1177
Abstract Selective extraction of Mercury(II) using 1‐naphthylthiourea–methyl isobutyl ketone (ANTU‐MIBK) system from hydrochloric acid solutions (0.1–10 M) has been studied. Influence of foreign ions, acid and ligand concentrations has been investigated. Addition of ANTU in MIBK enhanced, extraction capacity of MIBK to several times. Low effect of foreign ions and high separation factors for a number of metal ions determined at 0.5 M hydrochloric acid concentration evaluated the proposed method efficient and selective. The experimental data obtained from application of the method for extraction of mercury from a synthetic aqueous solution reveal that more than 99% mercury can be separated from cadmium, zinc and selenium in a single step with five minutes equilibration. 相似文献
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To study the characteristic of liquid-liquid extraction equilibrium of lithium from brine sources,the complexes formed from tributyl phosphate(TBP) and methyl isobutyl ketone(MIBK) with lithium were investi-gated using FeCl3 as coextracting agent.Liquid-liquid extraction reaction mechanisms were proposed and the stoichiometry of tetrachloroferrate(III) complex with lithium was obtained by regressing the experimental data.It is found that the stoichiometry of tetrachloroferrate(III) to lithium in the complex is 1︰1 with either TBP or MIBK as extractant in kerosene.The stoichiometry of the complex of TBP with Li was 1︰1 and that of MIBK with Li was 2︰1.The formed complexes of TBP and MIBK with lithium are determined to be LiFeCl4?TBP and LiFeCl4?2MIBK,respectively,according to the rule of neutralization. 相似文献