巴基管粒度对其复合镀层摩擦学性能影响的研究

用无电解复合镀方法,在４５号钢基体上镀了一层镍－磷－巴基管复合镀层。本文详细实验研究了粒度对镍－磷－巴基管复合镀层摩擦学性能的影响。结果表明：巴基管复合镀层具有极优的摩擦学性能,而且巴基管的粒径愈小,复合镀层的摩擦学性能则愈优。     

两种化学复合镀层的耐磨性能之比较

本文用化学复合镀技术,在４５钢基体上沉积了镍－磷－巴基管和镍－磷－碳化硅两种复合镀层。作者详细实验研究了此两种复合镀层的摩擦,磨损工进行了比较。结果表明,两种复合镀层均具有优异的耐磨特性。并且镍－磷－巴基管复合镀层的耐磨特性更佳。     

Ni—P—Si3N4复合镀层的磨损特性

本文通过Ｘ射线衍射分析、电子探针分析和摩擦磨损试验，分析了电沉积Ｎｉ－Ｐ－Ｓｉ３Ｎ４复合镀层的结构性能和磨损特性，并比较了不同弥散微粒的影响。结果表明，在油润滑条件下，复合镀层中的Ｓｉ３Ｎ４微粒在支承载荷的同时，有利于边界润滑膜的形成，避免粘着磨损。同时由于Ｓｉ３Ｎ４微粒本身具有的结构特征，提高了复合镀层的耐磨性能。     

油润滑条件下镍基纳米Al2O3复合刷镀层磨粒的铁谱分析及其磨损机制研究

为研究纳米颗粒复合电刷镀层在含沙粒油润滑条件下的磨损机制，首先制备了镍基纳米Al2O3复合电刷镀层，采用T-11球盘式磨损试验机进行复合刷镀层在含沙粒油润滑条件下的磨损试验，采用FTP-X2型分析式铁谱仪对复合镀层磨损试验后的润滑油中的磨粒形貌进行了研究。结果表明，含磨粒油润滑条件下，复合镀层的磨屑表现出以下3种形貌特征：切削状磨粒、蠕虫状磨粒和岩石状磨粒。这说明，在本实验条件下，复合刷镀层的磨损失效机制主要有磨粒磨损、粘着磨损和疲劳剥层。     

多孔性镍基石墨复合电镀层的摩擦学特性研究

作者等在对石墨粒子以表面活性剂进行润温处理后，利用电镀的方法制取了多孔性Ni-石墨复合镀层。该镀层的孔隙率高且分布均匀，容易被油润湿，故其润滑性能良好。本文比较详细地研究了这种镀层的摩擦学特性，并以电感耦合等离子体发射光谱法研究了电解液中石墨粒子的吸附特性，且以X-射线透反射法证明了石墨粒子在镀层中具有择优取向性，同时讨论了镀层的表面及新面形貌。文章还对镀层的形成过程进行了理论分析与探讨。     

化学复合镀制备Ni-Co-P-PTFE自润滑镀层的工艺研究

对Ni-Co-P-PTFE化学复合镀制备自润滑镀层的工艺过程进行了研究。探讨了实验因素对镀层的摩擦因数和显微硬度的影响情况，得到的最佳工艺条件是电镀时间2h，镀液温度90℃，pH值5，PTFE乳液加入量10g/L，镀液中CoSO4与NiSO4的摩尔配比为1：1。实验表明，该复合镀层具有优异的润滑性能。     

影响PS304高温固体润滑镀层性能因素的分析

为了减少在25～850℃工况下因滑移接触造成的摩擦和磨损,美国NASA格林研究中心开发了由镍铬合金、铬氧化物、氟化物和银组成的高温固体润滑PS304镀层。本文主要分析了组份、热处理和基体材料对PS304性能的影响：PS304复合镀层在较大温度范围内适用于不同材料的基体,在空气中经过高温短时间或中温长时间的热处理后,减少了镀层粒子间的残余热应力,提高了镀层的内聚强度和镀层与基体的结合强度。     

Ni-W-Co/SiC微粒复合材料的磨损规律和机理

研究了Ni-W-Co/SiC微粒复合镀层在润滑渐污条件下的滑动磨损特性,分析了载荷、滑动速度及SiC微粒质量分数对复合镀层磨损机制的影响。试验结果表明：在污染条件下,Ni-W-Co合金的磨损机制主要为显微切削和犁沟;SiC微粒复合相的主要流失形式为撞击脱落。     

Ni-W-P/PTFE电刷镀多元复合材料工艺及性能研究

用电刷镀技术使基体材料形成一层具有弥散硬质相及自润滑减摩组分的PTFE复合镀层。研究了Ni－W－P／PTFE电刷镀的工艺、刷镀液组成、热处理条件对Ni－W－P／PTFE复合镀层的硬度及磨损率的影响。确定了热处理温度378℃，复合镀层PTFE含量20％－30％时复合镀层的摩擦性能最好；当复合镀层中添加PTFE后能显著降低损率，大大提高镀层的耐磨性。     

高速数控机床主轴轴承的油—气润滑技术

阐述了超高速切削机床主轴轴承润滑的重要性，在分析轴承摩擦与润滑的基础上，着重分析了油－气润滑系统的结构原理及其工作过程，并用试验曲线证实了油－气润滑优越的润滑性能。     

电刷镀镍/碳纳米管复合纳米镀层的结构与磨损性能

用含碳纳米管的快速镍电刷镀液制备了镍/碳纳米管复合纳米镀层,研究了热处理温度和镀液中碳纳米管含量对镀层平均晶粒尺寸、结构、力学性能及耐磨性能的影响。结果表明,镀层的晶粒大小随热处理温度的升高是先降低而后增大的;同样碳纳米管的加入对镍刷镀层的平均晶粒尺寸和微结构有显著的影响。镀层的硬度和耐磨性与镀层的平均晶粒尺寸有非常好的对应关系。热处理和碳纳米管的强化作用可导致镀层晶粒细化和结构致密化,从而有效地改善了镀层的力学性能和耐磨性能。     

Effect of carbon nanotube addition on the tribological behavior of carbon/carbon composites

Carbon nanotube composite coatings were applied onto carbon/carbon composites to improve wear properties. Carbon nanotubes have been prepared by catalytic pyrolysis of hydrocarbons. The nanotube slurry was prepared by addition of phenolic resin and solvent to infiltrate into C/C composites. The nanotube added composites were then carbonized in a nitrogen atmosphere. Ball-on-disc type wear tests were performed to evaluate the tribological properties of the carbon nanotube added carbon composites. The result showed that addition of nanotube has the potential to increase the wear resistance of carbon composites. Changes in Raman spectra, morphology and surface damage were studied to explain observed wear behavior.     

Dry friction and wear characteristics of nickel/carbon nanotube electroless composite deposits

Ni/carbon nanotube (Ni/CNTs) composite coatings were deposited on carbon steel plate by electroless deposition. The friction and wear properties were examined under dry sliding conditions using the ball-on-disk configuration. For reference, carbon steel plate was coated with Ni, Ni/SiC and Ni/graphite. The results show that the Ni/CNT coating has a microhardness value of 865 Hv, greater than for SiC reinforced composite deposits. The Ni/CNTs composite coating possesses not only a higher wear resistance but also a lower friction coefficient, resulting from their improved mechanical characteristics and the unique topological structure of the hollow nanotubes.     

Microstructure and wear resistance of nickel–carbon nanotube composite coating from brush plating technique

This paper investigates the microstructure and wear resistance of nickel–carbon nanotube (CNT) composite coating deposited by brush plating technique. The Ni/CNT coating deposited with a pulse current source has less porosity, higher hardness and higher wear resistance than that with a DC source. CNTs greatly improve the coating performance. The wear mechanism is mainly the smearing of the Ni/CNTs coatings, instead of the fracture for the Ni coatings.     

Wear and corrosion behavior of electrodeposited nickel–carbon nanotube composite coatings on Ti–6Al–4V alloy in Hanks′ solution

Carbon nanotubes (CNT) have received considerable interest in many industries, but composite coatings of CNTs have not yet been sufficiently developed for use in biomedical implants. This investigation elucidates the wear and corrosion behavior of electroplated Ni/CNT composite coatings on Ti–6Al–4V alloy in Hanks’ solution. Experimental results indicate that the CNTs in an electroplated Ni/CNT composite coating increase its hardness to 98.5% higher than that of a pure Ni coating. Additionally, an Ni/CNT composite coating can form stable and dense passive film, which significantly improves wear and corrosion in Hanks′ solution.     

镍、硼、碳纳米管复合镀层的性能研究

用化学复合镀的方法,把碳纳米管作为第二相加入到化学镀镍、硼镀液中得到复合镀层;改变还原剂二甲胺硼烷在镀液中的相对浓度,得到各种镀层表面成分;利用摩擦磨损实验机、电化学综合测试仪、X射线光电子能谱（XPS）和扫描电子显微镜等分析复合镀层的摩擦磨损性能、耐腐蚀性能、表面形貌特性。结果表明：通过化学复合镀的方法得到镍、硼和碳纳米管复合镀层,其平均厚度为7~8μm;随着二甲胺硼烷在镀液中的相对浓度增加,镀层的摩擦因数减小,磨损量和腐蚀电流也减小,说明随着二甲胺硼烷在镀液中浓度的增加,其耐磨性和抗腐蚀性逐渐提高;复合镀层中主要含有N i,C,O 3种元素,其中N i以单质的形态出现,B以N i2B化合物的形态出现,元素C以碳纳米管形式沉积在镍硼基体中。     

Tribological Behavior of Carbon-Nanotube-Filled PTFE Composites

Carbon nanotube/polytetrafluoroethylene (CNT/PTFE) composites with different volume fractions were prepared and their friction and wear properties were investigated using a ring-on-block under dry conditions. It was found that CNTs signifi-cantly increased the wear resistance of PTFE composites and decreased their coefficient of friction. PTFE composites with 15–20 vol.% CNTs exhibited very high wear resistance. The significant improvements in the tribological properties of CNT/PTFE composites are attributed to the super-strong mechanical properties and the very high aspect ratio of CNTs. The CNTs greatly reinforce the structure of the PTFE-based composites and thereby greatly reduce the adhesive and plough wear of CNT/PTFE composites. The CNTs are released from the composite during sliding and transferred to the interface of the friction couples. They thus serve as spacers, preventing direct contact between the mating surfaces and thereby reducing both wear rate and friction coefficient.     

包覆镍CNTs/AM60复合材料铸态显微组织与力学性能

采用机械搅拌铸造法制备了包覆镍碳纳米管(CNTs)/AM60复合材料,研究了包覆镍CNTs加入量对铸态复合材料力学性能的影响规律,并用扫描电子显微镜观察了复合材料的拉伸断口形貌以及显微组织。结果表明:复合材料显微组织为等轴晶,包覆镍的CNTs主要分布在-αMg共晶相内和晶界处,不仅起到细化晶粒的作用,而且还起到搭接晶粒和强化晶界的作用;复合材料的力学性能随CNTs加入量的增多呈现先增大后减小的趋势,当其质量分数为1%时,抗拉强度、显微硬度、伸长率同时达到最大,比AM60镁合金分别提高了46.23%,41.82%,74.52%,弹性模量在其质量分数为1.2%时达到最大。