Exergetic analysis of a double stage LiBr–H2O thermal compressor cooled by air/water and driven by low grade heat

In the present paper, an exergetic analysis of a double stage thermal compressor using the lithium bromide–water solution is performed. The double stage system considered allows obtaining evaporation temperatures equal to 5 °C using solar heat coming from flat plate collectors and other low grade thermal sources. In this study, ambient air and water are alternatively used as cooling fluids without crystallization problems up to condensation–absorption temperatures equal to 50 °C. The results obtained give the entropy generated, the exergy destroyed and the exergetic efficiency of the double stage thermal compressor as a function of the absorption temperature. The conclusions obtained show that the irreversibilities generated by the double stage thermal compressor will tend to increase with the absorption temperature up to 45 °C. The maximum value corresponds to 1.35 kJ kg⁻¹ K⁻¹. The entropy generated and the exergy destroyed by the air cooled system are higher than those by the water cooled one. The difference between the values increases when the absorption temperature increases. For an absorption temperature equal to 50 °C, the air cooled mode generates 14% more entropy and destroys 14% more exergy than the water cooled one. Also, the results are compared with those of previous studies for single and double effect air cooled and water cooled thermal compressors. The conclusions show that the double stage system has about 22% less exergetic efficiency than the single effect one and 32% less exergetic efficiency than the double effect one.     

Entropy generated and exergy destroyed in lithium bromide thermal compressors driven by the exhaust gases of an engine

This work is devoted to the study of the entropy generated and the exergy destroyed in the lithium bromide absorption thermal compressors of single and multiple effects, driven by the heat of the exhaust gases of an engine, when the absorption heat is directly transferred either to water or to air. Air‐cooled systems work with temperature and pressure gradients higher than those cooled by water. The absorption temperature in air‐cooled systems can reach and even exceed 50°C. Under these conditions, boiling temperature within the high desorber of the double and triple effect systems can exceed 200 and 300°C, respectively. Maximum pressures reach values of 1.7 and 15 bar, respectively. The thermal compressor cooled by air generates more entropy and destroys more exergy than the one cooled by water. The triple‐effect thermal compressor destroys less exergy than the one of double effect and the latter destroys less exergy than the one of single effect. The lithium bromide thermal compressor of single effect cooled by air is not feasible when working with absorption temperatures around 50°C. The one of double effect is feasible since the high‐pressure desorber can work at higher temperatures. Under these conditions, the solution cycle described within the high‐pressure desorber remains out of the zone of crystals formation, and offers the possibility of producing more refrigerant than the one of single effect. Also, in the double‐effect compressor less entropy is generated, and therefore less exergy is destroyed than in the single effect. The triple‐effect compressor cooled by air offers the possibility of producing more refrigerant than the one of double effect, but at higher expenses of temperatures and boiling pressures of the solution. This creates corrosion and control problems, which do not have an easy solution yet. Less exergy destruction does not compensate for the increase of these problems. In any case, the compression process of the cooling steam occurs with entropy reduction. Copyright © 2000 John Wiley & Sons, Ltd.     

Theoretical analysis of LiBr/H2O absorption refrigeration systems

A computational model is developed for the parametric investigation of single‐effect and series flow double‐effect LiBr/H₂O absorption refrigeration systems. The effects of generator, absorber, condenser, evaporator and dead state temperatures are examined on the performance of these systems. The parameters computed are coefficient of performance (COP), exergy destruction rates, thermal exergy loss rates, irreversibility and exergetic efficiency. The results indicate that COP and exergetic efficiency of both the systems increase with increase in the generator temperature. There exist different optimum values of generator temperature for maximum COP and maximum exergetic efficiency. The optimum generator temperature is lower corresponding to maximum exergetic efficiency as compared to optimum generator temperature corresponding to maximum COP. The effect of increase in absorber, condenser and evaporator temperatures is to decrease the exergetic efficiency of both the systems. The irreversibility is highest in absorber in both systems. Copyright © 2009 John Wiley & Sons, Ltd.     

Performance assessment of an internal combustion engine at varying dead (reference) state temperatures

This study deals with investigating the effect of varying dead state temperatures on exergy efficiency of a high-oleic methyl ester (HOME) fueled internal combustion engine (ICE). This engine is a 4.5L, four-stroke, four-cylinder, turbocharged, 66.5 kW maximum power capacity John Deere 4045T diesel engine run with HOME, which is genetically modified with a high-oleic soybean oil methyl ester. The test speed is 1400 min⁻¹ at a full load. In the analysis, actual operational data obtained from a study conducted by one of the co-authors at Iowa State University, USA are used. Exergy efficiency values at various dead state temperatures are calculated for comparison purposes since these types of engines may be operated under different outdoor air conditions. The results obtained are discussed from the exergetic point of view. It was found that exergetic efficiency increased as dead state temperature decreased. As a result, exergy efficiency values ranged from 29.78% to 34.93% based on dead state temperatures between −5 °C and 30 °C.     

Crystallization as a limit to develop solar air-cooled LiBr–H2O absorption systems using low-grade heat

In the present work the use of low-temperature solar heat is studied to produce cooling at 5°C, using a double-stage LiBr–H₂O air-cooled absorption cycle. A solar plant, consisting of flat plate collectors feeding the generators of the absorption machine, has been modeled. Operating conditions of the double-stage absorption machine, integrated in the solar plant without crystallization problems for condensation temperatures up to 53°C, are obtained. Results show that about 80°C of generation temperature are required in the absorption machine when condensation temperature reach 50°C, obtaining a COP equal to 0.38 in the theoretical cycle.A comparative study respect to single-stage absorption cycles is performed. Efficiency gain of the double-stage solar absorption system, over the single-stage one, will increase with higher condensation temperatures and lower solar radiation values. Single-stage cycles cannot operate for condensation temperatures higher than 40°C using heat from flat plate collectors. For higher condensation temperatures (45°C) the generation temperatures required (105°C) are very high and crystallization occurs. Condensation temperatures able to use in double-stage cycles may be increased until 53°C using heat from flat plate collectors without reaching crystallization.     

Finite time thermodynamics study and exergetic analysis of ammonia–water absorption systems

This paper presents an optimization study of a single stage absorption machine operating with an ammonia–water mixture under steady state conditions. The power in the evaporator, the temperatures of the external fluids entering the four external heat exchangers as well as the effectiveness of these heat exchangers and the efficiency of the pump are assumed fixed. The results include the minimum value of the total thermal conductance UA_tot as well as the corresponding mean internal temperatures, overall irreversibility and exergetic efficiency for a range of values of the coefficient of performance (COP). They show the existence of three optimum values of the COP: the first minimises UA_tot, the second minimises the overall irreversibility and the third maximises the exergetic efficiency. They also show that these three COP values are lower than the maximum COP which corresponds to the convergence of the internal and external temperatures towards a common value. The influence of various parameters on the minimum thermal conductance of the heat exchangers and on the corresponding exergy efficiency has also been evaluated. From an exergetic viewpoint it is interesting to reduce the temperature at the desorber and at the evaporator and to raise the values of that parameter at the condenser and the absorber. However these changes must be accompanied by an important increase in the total UA if it is desired to conserve a constant COP. The internal heat exchangers between the working fluid and the solution improve both the overall exergy efficiency and the coefficient of performance of the absorption apparatus.     

Effect of irreversibilities on performance of an absorption heat transformer used to increase solar pond’s temperature

Absorption thermal systems are attractive for using waste heat energy from industrial processes and renewable energy such as geothermal energy, solar energy, etc. The Absorption Heat Transformer (AHT) is a promising system for recovering low-level waste heat. The thermal processes in the absorption system release a large amount of heat to the environment. This heat is evolved considerably at temperature, the ambient temperature results in a major irreversible loss in the absorption system components. Exergy analysis emphasises that both losses and irreversibility have an impact on system performance. Therefore, evaluating of the AHT in exergy basis is a much more suitable approach. In this study, a mathematical model of AHTs operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds. A heat source at temperatures not higher than 100 °C was used to simulate the heat input to an AHT from a solar pond. In this paper, exergy analysis of the AHT were performed and effects of exergy losses of the system components on performance of the AHT used to increase solar pond’s temperature were investigated. The maximum upgrading of solar pond’s temperature by the AHT, is obtained at 51.5 °C and gross temperature lift at 93.5 °C with coefficients of performance of about 0.4. The maximum temperature of the useful heat produced by the AHT was ˜150 °C. As a result, determining of exergy losses for the system components show that the absorber and the generator need to be improved thermally. If the exergy losses are reduced, use of the AHT to increase the temperature of the heat used from solar ponds will be more feasable.     

Studies of compressor pressure ratio effect on GAXAC (generator–absorber–exchange absorption compression) cooler

This paper presents simulation studies conducted on a GAXAC cycle of capacity 3.514 kW using ammonia–water as working fluid for cooling applications. The low side pressure ratio of (compressor pressure ratio) of the cycle has been optimized for optimum COP. The effects of temperatures of the generator, condenser, absorber and evaporator on the COP of the cycle as a function of low side pressure ratio have been studied. The effect of the low side pressure ratio on the heat duties (kW) of the cycle has also been studied. It is found that for a given value of desorber and approach temperatures, the optimum COP corresponding to the optimum pressure ratio is independent of the temperatures of condenser, absorber and evaporator. The optimum COP for the desorber temperatures 110 °C, 130 °C, 150 °C and approach temperature 14 °C at all optimum pressure ratios are found to be 1.00, 0.97 and 0.94, respectively. Comparison of GAXAC and standard GAX cycle was carried out and found that GAXAC cycle has 26% higher value of COP than the standard GAX cycle.     

Exergy analysis of a compression–absorption system for heating and cooling applications

An exergy analysis of a single‐stage compression–absorption system with R22‐E181 as the working fluid pair is carried out. Theoretical results obtained have been compared with those obtained from the experiment. Results show that the heat of mixing of the refrigerant vapour and solution at absorber and desorber contributes a significant amount to the internal entropy generation rates. A significant part of internal entropy generation rate is also due to non‐isentropic compression of refrigerant vapour at higher absorber pressure. The exergetic efficiency of the system increases with the increase in absorber pressure due to reduction in internal irreversibilities. Higher value of weak solution concentration along with the increase in solution concentration difference results in higher exergetic efficiency of the system. Thus, a compression–absorption system performs better when operated at higher absorber pressure, and an improved system performance can also be achieved with higher value of weak solution concentration with higher possible solution concentration difference. Copyright © 2008 John Wiley & Sons, Ltd.     

Exergy analysis of multi-effect water–LiBr absorption systems: From half to triple effect

An exergy analysis, which only considers the unavoidable exergy destruction, is conducted for single, double, triple and half effect Water–Lithium bromide absorption cycles. Thus, the obtained performances represent the maximum achievable performance under the given operation conditions.The coefficient of performance (COP), the exergetic efficiencies and the exergy destruction rates are determined and the effect of the heat source temperature is evaluated. As expected, the COP increases significantly from double lift to triple effect cycles. The exergetic efficiency varies less among the different configurations. In all cycles the effect of the heat source temperature on the exergy destruction rates is similar for the same type of components, while the quantitative contributions depend on cycle type and flow configuration. Largest exergy destruction occurs in the absorbers and generators, especially at higher heat source temperatures.     

Exergoeconomic assessment of a geothermal assisted high temperature steam electrolysis system

Exergoeconomic formulations and procedure including exergy flows and cost formation and allocation within a high temperature steam electrolysis (HTSE) system are developed, and applied at three environmental temperatures. The cost accounting procedure is based on the specific exergy costing (SPECO) methodology. Exergy based cost-balance equations are obtained by fuel and product approach. Cost allocations in the system are obtained and effect of the second-law efficiency on exergetic cost parameters is investigated. The capital investment cost, the operating and maintenance costs and the total cost of the system are determined to be 422.2, 2.04, and 424.3 €/kWh, respectively. The specific unit exergetic costs of the power input to the system are 0.0895, 0.0702, and 0.0645 €/kWh at the environmental temperatures of 25 °C, 11 °C, and −1 °C, respectively. The exergetic costs of steam are 0.000509, 0.000544, and 0.000574 €/kWh at the same environmental temperatures, respectively. The amount of energy consumption for the production of one kg hydrogen is obtained as 133 kWh (112.5 kWh power + 20.5 kWh steam), and this corresponds to a hydrogen cost of 1.6 €/kg H₂.     

Exergy analysis of double effect vapor absorption refrigeration system

Energy and exergy analyses previously performed by the authors for a single effect absorption refrigeration system have been extended to double effect vapor absorption refrigeration system with the expectation of reducing energy supply as well as an interest in the diversification of the motive power employed by HVAC technologies. The total exergy destruction in the system as a percentage of the exergy input from a generator heating water over a range of operating temperatures is examined for a system operating on LiBr–H₂O solution. The exergy destruction in each component, the coefficient of performance (COP) and the exergetic COP of the system are determined. It is shown that exergy destructions occur significantly in generators, absorbers, evaporator2 and heat exchangers while the exergy destructions in condenser1, evaporator1, throttling valves, and expansion valves are relatively smaller within the range of 1–5%. The results further indicate that with an increase in the generator1 temperature the COP and ECOP increase, but there is a significant reduction in total exergy destruction of the system for the same. On the other hand, the COP and ECOP decrease with an increase in the absorber1 temperature while the total exergy destruction of the system increases significantly with a small increase in the absorber1 temperature. The results show that the exergy method can be used as an effective criterion in designing an irreversible double effect absorption refrigeration system and may be a good tool for the determination of the optimum working conditions of such systems. Copyright © 2007 John Wiley & Sons, Ltd.     

二类热泵在利用余热供热中的热力分析

对单级二类吸收式热泵进行热力分析,建立了热泵系统各部分质量守恒、能量平衡和火用分析数学模型。根据火用平衡方程计算了各个部分的火用损失和热泵系统的火用效率。分析了溶液换热器稀溶液温差、热源温差、余热源温度和冷却水温度对火用损失、循环倍率和COP等的影响。对热泵系统进行了火用能质量评定,确定了火用能的薄弱环节。     

Solar thermal power cycle with integration of methanol decomposition and middle-temperature solar thermal energy

In this paper, we have proposed a new solar thermal power cycle which integrates methanol decomposition and middle-temperature solar thermal energy, and investigated its features based on the principle of the cascade utilization of chemical exergy. Also, the methanol decomposition with a catalyst was experimentally studied at temperatures of 150–300 °C and under atmospheric pressure. The chemical energy released by methanol fuel in this cycle consisted of two successive processes: solar energy drives the thermal decomposition of methanol in a solar receiver-reactor, and the syngas of resulting products is combusted with air, namely, indirect combustion after methanol decomposition. As a result, the net solar-to-electric efficiency of the proposed cycle could be 35% at the collector temperature of 220 °C and the turbine inlet temperature of 1300 °C, and the exergy loss in the indirect combustion of methanol was about 7% points lower than that in the direct combustion of methanol. The promising results obtained in this study indicated that this new solar thermal power cycle could make significant improvements both in the efficient use of the chemical energy of clean synthetic fuel and in the middle-temperature solar thermal energy in a power system.     

Performance improvement of absorption heat transformer

In this study, a mathematical model of absorption heat transformer (AHT) operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds and used a special ejector located at the absorber inlet. By the use of the ejector, the obtained absorber pressure becomes higher than the evaporator pressure and thus the system works with triple-pressure-level. The ejector has two functions: (i) aids pressure recovery from the evaporator and (ii) upgrades the mixing process and the pre-absorption by the weak solution of the ammonia coming from the evaporator. The other advantage of the system with ejector is increased absorber temperature. Therefore, pressure recovery and pre-absorption in the ejector improves the efficiency of the AHT. Under the same circumstances, when compared to an AHT with and without an ejector, the system's COP and exergetic coefficient of performance (ECOP) were improved by 14% and 30%, respectively and the circulation ratio (f) was reduced by 57% at the maximum efficiency condition. Due to the reduced circulation ratio, the system dimensions can be reduced; consequently, this decreases overall cost. The maximum upgrading of the solar pond's temperature by the AHT was obtained at 57.5 °C and gross temperature lift at 97.5 °C with coefficients of performance of about 0.5. The maximum temperature of the useful heat produced by the AHT was 150 °C. In addition, exergy losses for each component in the system were calculated at different working temperatures and the results of both systems with and without an ejector were compared. Exergy analysis emphasised that both the losses and irreversibilities have an impact on the system performance and exergy analysis can be used to identify the less efficient components of the system. Exergy analyses also showed that the exergy loss of the absorber of AHT with ejector was higher than those of other components.     

Experimental studies on bubble pump operated diffusion absorption machine based on light hydrocarbons for solar cooling

An experimental investigation of an air-cooled diffusion absorption machine operating with a binary light hydrocarbon mixture (C₄H₁₀/C₉H₂₀) as working fluids and helium as pressure equalizing inert gas is presented in this paper. The machine, made of copper an available and very good heat conducting metal, is intended to be solar powered heat from flat plate or common evacuated tube collectors. The cooling capacity is 40–47 W respectively for 9 and 11°C chilled water temperature. Cold is produced at temperatures between −10 and +10 °C for a driving temperature in the range of 120–150 °C.     

Constraints of using thermostatic expansion valves to operate air-cooled chillers at lower condensing temperatures

Thermostatic expansion valves (TXVs) have long been used in air-cooled chillers to implement head pressure control under which the condensing temperature is kept high at around 50 °C by staging condenser fans as few as possible. This paper considers how TXVs prevent the chillers from operating with an increased COP at lower condensing temperatures when the chiller load or outdoor temperature drops. An analysis on an existing air-cooled reciprocating chiller showed that the range of differential pressures across TXVs restricts the maximum heat rejection airflow required to increase the chiller COP, though the set point of condensing temperature is reduced to 22 °C from a high level of 45 °C. It is possible to use electronic expansion valves to meet the differential pressure requirements for maximum chiller COP. There is a maximum of 28.7% increase in the chiller COP when the heat rejection airflow is able to be maximized in various operating conditions. The results of this paper emphasize criteria for lowering the condensing temperature to enhance the performance of air-cooled chillers.     

Exergy analysis: an absorption refrigerator using lithium bromide and water as the working fluids

The thermodynamic processes in the absorption refrigeration system releases a large amount of heat to the environment. This heat is evolved at temperatures considerably above the ambient temperature, which results in a major irreversible loss in the system components. In this paper an exergy analysis is carried out on a single-effect absorption refrigeration cycle with lithium-bromide–water as the working fluid pair. Numerical results for the cycle are tabulated. A design procedure has been applied to a lithium-bromide absorption cycle and an optimisation procedure that consists of determining the enthalpy, entropy, temperature, mass flow rate, heat rate in each component, and coefficient of performance has been performed.     

Single-stage and advanced absorption heat transformers operating with lithium bromide mixtures used to increase solar pond's temperature

Mathematical models of single-stage and advanced absorption heat transformers operating with the water/lithium bromide and water/Carrol™ mixtures were developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds. Plots of coefficients of performance and gross temperature lifts are shown against the temperatures of the heat supplied by the solar pond. The results showed that the single-stage and the double absorption heat transformer are the most promising configuration to be coupled to solar ponds. With single-stage heat transformers it is possible to increase solar pond's temperature until 50°C with coefficients of performance of about 0.48 and with double absorption heat transformers until 100°C with coefficients of performance of 0.33.     

Performance assessment of a geothermally heated building

This study deals with an exergetic performance evaluation of a geothermally heated building. This building used in the analysis has a volume of 1147.03 m³ and a net floor area of 95.59 m², while indoor and exterior air temperatures are 20 and 0 °C, respectively. The geothermal heating system used for the heat production was constructed in the Ozkilcik heating center, Izmir, Turkey. Thermal water has a pressure of 6.8 bar, a temperature of 122 °C and a mass flow rate of 54.73 kg/s, while it is reinjected at 3.2 bar and 72 °C. The system investigated feeds three regions. Among these, the Ozkanlar region has supply/return pressure and temperature values of 4.6/3 bar and 80/60 °C, respectively. Energy and exergy flows are studied to quantify and illustrate exergy destructions in the overall system. Total exergy input rate to the system is found to be 9.92 kW and the largest exergy destruction rate occurs in the primary energy transformation at 3.85 kW.