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Wei-Sheng Chen Yu-Lun Chang Fu-Chi Hsu Yun-Hwei Shen Fu-Su Yen 《Polymer-Plastics Technology and Engineering》2013,52(6):568-572
In this study, the effects of carboxyl terminated butadiene-acrylonitrile liquid rubber (CTBN) addition on the mechanical and dielectric properties of NiZn ferrite powders-CTBN modified epoxy resin coatings were investigated. It was observed that the occurrence of the small, dispersed spherical CTBN domains in the epoxy resin resulted from the phase separation between epoxy and CTBN could enhance the toughness and dielectric constant at low frequency due to the increase in the phase boundary between ferrite powders and epoxy resin for the samples modified with proper CTBN. The addition of ferrite powders can effectively improve the thermal stability of epoxy resin. 相似文献
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通过钛酸酯偶联剂处理氮化铝(AlN)粉末,采用机械分散和超声波分散相结合的方法,制得环氧树脂/AlN复合材料。实验表明,钛酸酯偶联剂能有效地改善AlN粉末的表面性能,偶联剂质量分数为6%时,改性效果最好;AlN填料质量分数为10% ̄20%时,复合材料的冲击韧性较好。冲击断口形貌分析表明,河流状裂纹越窄,数量和分支越多,扩展路径越长,冲击韧性越好,A l N填料改性效果也越好。 相似文献
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Epoxy resin nanocomposites suspended with nano-glassflakes (NGFs) are studied in the present work. A bi-functional silane, i.e., epoxy propoxy propyl tri-methoxy silane, was used as coupling agent and NGFs’ surface modifier. Fourier transformed infrared spectroscopy and thermogravimetry techniques confirmed the successful surface treatment of the NGFs. Rheological studies of the polymer composites were carried out by measuring complex viscosity and storage and loss modulus values. The rheological results revealed that the presence of silane either as coupling agent or as surface modifier could decrease the nanocomposite viscosity. It is indicated that reduced filler–filler interaction resulted in better dispersion of NGFs. It can be due to soft layer formation on nano-glassflakes by silane groups which prevents the agglomeration of NGFs and subsequently improves their dispersion quality. Storage and loss modulus investigations showed that an inter-connected network structure in the solution might be formed in the presence of silane, probably due to the interaction between the NGFs and the polymer resin phase. Electrochemical impedance spectroscopies were carried out to study the protective performance of epoxy/nano-glassflakes coatings. Although the electrochemical impedance results revealed that the incorporation of silane as coupling agent and surface modifier in the epoxy/NGF coating systems applied on carbon steel substrates could improve the protective performance, the superiority of the epoxy coating formulated with 0.5 wt% of modified NGF was obviously visible during immersion period. 相似文献
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Polypyrrole/SiO2 composite was synthesized by chemical oxidative polymerization of pyrrole using FeCl3. The synthesized polymer composite was loaded in epoxy resin to develop coatings for mild steel substrates using powder coating technique. SEM and TEM images reveal homogenous dispersion of SiO2 particles in polypyrrole matrix. TGA analysis confirms good thermal stability of the polymer composite. Tafel polarization and electrochemical impedance spectroscopy (EIS) results exhibit remarkably high corrosion protection efficiency of epoxy coatings with polymer composite in 3.5% NaCl solution. Corrosion studies of coatings with an artificial defect reveal the passivation of defect by the polymer composite present in the epoxy coatings. Salt spray test results revealed superior corrosion resistance offered by the polymer composite. 相似文献
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Epoxy-polyamide coatings are used to protect metallic substrates in corrosive atmosphere. Thermal stability of the coating can be improved by the addition of inorganic cross-linking agent. Epoxy resin is incorporated with small percentage of silicone resin and cured with two types of hardeners such as polyamide and butyl titanate. The physical properties, heat resistance properties and electrochemical impedance behaviour of these coatings on steel in 0.5 M NaCl solution have been studied. The result implies that the heat resistant character of the titanate-cured coating is increased from 260 to 370 °C. The impedance study has shown that the coating resistance exerted by both the systems is in the range of 105 Ω cm2 after 6 days of immersion in 0.5 M NaCl. FTIR and Raman spectroscopy analysis confirm the presence of titanate linkage in the cured polymer coating. Thermal stability data indicate that the epoxy silicone resin cured with titanate hardener possesses higher thermal stability than that cured by polyamide hardener. 相似文献
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采用低粘度环氧树脂、活性稀释剂、流平剂、消泡剂、偶联剂、硅微粉、改性胺固化剂等制得了环氧防腐涂料并应用于甲醇贮罐,考察了环氧树脂固化物的耐腐蚀性能。结果表明:该环氧涂层固化物经甲醇25℃/30d浸泡,质量变化率小,实际应用效果良好。 相似文献
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Xie Guozhi Wang Ping Yuan Liukui Zhang Baoshan Lin Pinghua Lu Huaixian 《应用聚合物科学杂志》2009,114(4):2344-2347
The effects of silane coupling agent doping on the microstructure and microwave properties of melt‐spun Nd‐Fe‐Co alloys were investigated. All as‐milled powders, with or without silane coupling agent treatment, were characterized as flake‐like shape. However, it is found that with the addition of 0.25 mL coupling agent, the as‐milled Nd‐Fe‐Co powders can deagglomerate and become more uniform dispersion with smaller thickness. In contrast, the excessive addition of coupling agent led to somewhat higher thickness of the flakes and much more amount of coupling agent on the surface of powder. The electromagnetic properties show that the Reflection loss will arrive ?27.1 dB at 4.2 GHz, for the addition of 0.25 mL coupling agent powders. The probably reasons for this are discussed on the basis of the morphology of the powders, uniform dispersion and the physical coating between the polymer and coupling agent. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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钛酸钾晶须及硫酸钙晶须改性环氧树脂 总被引:2,自引:0,他引:2
应用硅烷及钛酸酯等偶联剂对钛酸钾晶须及硫酸钙晶须进行表面处理,考察晶须对环氧树脂力学性能、工艺性等的影响。研究表明,钛酸钾晶须经硅烷偶联剂处理后,能很好地改善复合材料的性能,硅烷的表面处理效果较钛酸酯的好。钛酸钾晶须添加到环氧树脂中后,材料的弯曲强度随晶须含量增大逐渐增大,在晶须含量为8%时达到最大值,之后性能稍有下降;材料的弯曲模量随晶须添加量的增加逐渐增大,冲击强度稍有降低。体系中添加硫酸钙晶须后,材料的性能也得到一定程度的提高。硫酸钙晶须对环氧树脂工艺性的影响较钛酸钾晶须小。SEM表明,晶须经合适的偶联剂表面改性后,与树脂基体的界面粘接得到有效改善。 相似文献
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Abdullah M. Asiri Mahmoud A. Hussein Bahaa M. Abu‐Zied Abou‐Elhagag A. Hermas 《Polymer Composites》2015,36(10):1875-1883
Coating properties of new Ni‐La‐ferrites/epoxy resin nanocomposites has been achieved using modified epoxy resin with Ni‐La‐ferrite nanoparticles in the form of NiLaFeO4/epoxy nanocomposites using electrochemical impedance and sorption of water measurements. Simple solution method with ultrasonic assistance was used in the preparation of the new nanocomposites in situ while epoxy resin was prepared. The new materials were characterized by X‐ray diffraction analysis, thermogravimetric analysis, scanning electron microscopy, and electrochemical impedance spectroscopy. The nanocrystalline NiLaFeO4 showed a good distribution and high compatibility forming strong interfacial adhesion within the epoxy matrix. Furthermore, it had ability to facilitate thermal degradation of the epoxy resin nanocomposite due to its catalytic effect. Temperatures at 10, 25, 50% weight loss and the normalized solid residue left at 500°C (NR500) were measured. The presence of nanocrystalline NiLaFeO4 stabilized the char residue obtained at 500°C in the resulting composites. The Ni‐La‐ferrite nanoparticles decreased water sorption (WS) of the epoxy. The 5% and 10%‐ Ni‐La‐ferrites/epoxy nanocomposites showed least amount of WS among the epoxy composites. The 5 and 10% Ni‐La‐ferrite nanoparticles contents enhanced significantly the barrier behavior of the epoxy as coating of stainless steel. POLYM. COMPOS., 36:1875–1883, 2015. © 2014 Society of Plastics Engineers 相似文献
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系统研究了偶联剂和润滑剂等添加剂对注射成型尼龙6铁氧体粘结磁体磁性能的影响。结果表明,用偶联剂对磁粉进行表面处理,能够很好地改善树脂与磁粉的相容性,提高磁粉在树脂中的分散性,其中当偶联剂用量为2%(质量分数,下同)时,磁性能最好,剩磁(Br)、矫顽力(HcB)、内禀矫顽力(HcJ)以及最大磁能积(BHmax)分别达到0.23T,176.3kA/m,283.8kA/m,10.4kJ/m^3;润滑荆的使用能有效改善体系的流动性,降低共混过程中对磁粉结构的破坏,改善磁体的磁性,当润精剂用量为1%时,HcJ增加了9.3%。 相似文献
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以双酚A环氧树脂(E20)为主要成膜物,层片状玻璃鳞片和云母氧化铁为主要填料,辅助以铝粉、氧化铁红颜料,以及各种助剂和溶剂,再分别加入固化剂脂肪族胺加成物、聚酰胺TY-650,制得高固体分厚浆型环氧玻璃鳞片涂料。通过常规的力学性能(涂层的硬度、耐冲击性、柔韧性、附着力等)和耐腐蚀性测试,对比了不同固化剂对环氧玻璃鳞片涂层性能的影响。研究结果表明,脂肪族胺加成物与环氧树脂交联固化的玻璃鳞片涂层的硬度、附着力以及交流阻抗值都较高,具有良好的综合性能,加入铝粉对基体可起到阴极保护作用。 相似文献