共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
Summary The possibility of group transfer polymerization of methyl methacrylate-terminated polystyrene macromer (MA-PSt) was explored by using 1-methoxy-1-(trimethylsiloxy)-2-methyl-1-propene and tris(dimethylamino)sulfonium difluorotrimethylsilicate as initiator and catalyst, respectively. The results obtained at the polymerization temperature of 0°C were undesirable. However, the oligomerization at -78°C gave almost quantitatively oligo(MA-PSt) of which the degree of polymerization was in good agreement with the mole ratio of macromer to initiator. The GPC curve of oligo(MA-PSt) was sharp and symmetrical. In addition, it was shown by the copolymerization with methyl methacrylate that the polymerizability of the macromer was markedly enhanced in the presence of methyl methacrylate comonomer. 相似文献
3.
4.
Summary The following limit (ceiling) temperatures of polymerization were extrapolated from kinetic data for the anionic polymerization of 2-pyrrolidone initiated with potassium salt of 2-pyrrolidone and the initiation systems of optimum compositions: 66°C for the nonactivated polymerization, 68°C and 73°C for the polymerization accelerated with 1-(1-pyr-rolin-2-yl)-2-pyrrolidone and carbon dioxide, respectively, 73°C and 76°C for the polymerization activated with N-benzoyl-2-pyrrolidone and N-acetyl-2-pyrrolidone,respectively. 相似文献
5.
6.
Plasma polymerization of methane in a magnetically enhanced capacitively coupled bell jar reactor operating at a frequency of 10 kHz is reported. Dependence of polymer deposition rate on monomer feed rate (F), composite power parameter (W/FM), electrode temperature, and electrode cleanliness have been examined. Such functional properties as wettability, adhesion, and thermal stability of the polymer are found to depend on the composite power parameter (W/FM) of the plasma. The permeability studies indicate highly crosslinked nature of the polymer. ESCA studies reveal codeposition of electrode material with the polymer under high W/FM conditions, potential applications of plasma polymer of methane are suggested. 相似文献
7.
8.
9.
Lyudmila Semenycheva Alexander Artemov Natalia Valetova Julia Matkivskaja Alexei Moykin 《Journal of Inorganic and Organometallic Polymers and Materials》2016,26(5):921-931
The article is devoted to the systematization of investigations of arenetricarbonylchromium complexes in radical polymerization transformation at the initiation of vinyl polymerization. The presented data are shown that these compounds are promising and interesting model systems for the study of the phenomenon of the metal atom action on the reactivity of the monomer π-bond. The correlation between the structure of metal-containing monomers and polymerization parameters, as well as the molecular mass properties of the resulting polymers, are discussed. 相似文献
10.
Summary The ring-opening polymerization of 2-phenyl aziridine was studied with several catalyst systems: boron trifluoride etherate, chlorhydric acid, perchloric acid, dimethyl sulfate and methyl triflate. The corresponding polyamine was obtained as a pale yellow solid with a number average molecular weight around 2,000–3,000.A kinetic study is discussed in the case of perchloric acid and methyl triflate. 相似文献
11.
12.
八甲基环四硅氧烷聚合动力学 总被引:10,自引:0,他引:10
以四甲基氢氧化铵为催化剂,用蒸汽压法研究了八甲基环四硅氧烷的聚合动力学,获得了77~110℃间的聚合速率常数,并计算出反应活化能为1030kJ/mol。 相似文献
13.
Summary 3-Vinylbenzenethiol (4) was synthesized and its polymerization yielded poly-(thio-1,3-phenylenethylene), which could be oxidized giving poly-(sulfonyl-1,3-phenylenethylene). 相似文献
14.
15.
16.
This review concerns the polymerization of substituted aldehydes. Two groups of aldehydes have been subjected to systematic study: (1) higher aliphatic aldehydes containing linear chains with up to 12 carbon atoms; (2) branched hydrocarbon chains, including acetaldehyde; and haloaldehydes, derivatives of acetaldehyde substituted with fluorine, chlorine or bromine in the methyl group. The methods of preparation, purification and characterization of the monomers, the mechanisms of polymerization, their thermodynamics and stereochemistry, and the properties of the resulting polymers are all discussed. In addition it is pointed out that several properties exhibited by the polymers may lend themselves to practical applications in the future. 相似文献
17.
研究了对苯二胺与对苯二酰氯在N-甲基吡咯烷酮/氯化钙体系中加入3,4’-二氨基二苯醚为第三单体的三元共聚反应。考察反应时间、反应温度、第三单体用量、单体浓度和CaCl_2用量对共聚物对数粘度的影响。结果表明,在N-甲基吡咯烷酮/氯化钙溶剂体系中,单体浓度为(0. 35~0. 40) mol·L^(-1),单体物质的量分数为25%,首先将温度设定为(-10~-5)℃,待溶液黏稠时将温度升高到(75~80)℃,时间(60~80) min,CaCl_2与-2NH_2物质的量比0. 4~0. 6时,可获得高比浓对数粘度的聚合物。 相似文献
18.
Summary The present paper describes the anionic ring-opening polymerization of anhydro-O-carboxysalicylic acid. At 0°C, the polymerization took place with base catalysts, e.g., sodium phenoxide and pyridine, to give poly-o-benzoate, whose molecular weight was of an order of several thousands. A polymer sample melts at 142–150°C and begins to decompose at 260°C. The molecular weight distribution of the polymer was very sharp, especially when the polymerization was carried out at 0°C. 相似文献
19.
Summary Structure of copolymers obtained by ring opening cationic polymerization from 7-oxabicyclo[ 2.2.1] heptane and ethylene oxide has been recently reported. This study about the spin lattice relaxation times and Nuclear Overhauser enhancement factor in the carbon-13 NMR spectra was performed and the results interpreted in terms of different internal mobility of the units in the copolymer chain.Previous papers in this series are: G. CECCARELLI, F.ANDRUZZI, Makromol. Chem. 180, 1371(1979); F.ANDRUZZI, G.CECCARELLI, M.PACI Polymer 21, 1180(1980); and ref (M.PACI et al. 1981). 相似文献
20.