共查询到17条相似文献,搜索用时 125 毫秒
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两亲性超支化聚合物研究进展 总被引:1,自引:0,他引:1
介绍了两亲性超支化聚合物的合成方法,利用长链烷基和聚乙二醇对超支化聚合物端基接枝改性;或者对超支化聚合物改性引入活性位点,再利用其引发乙烯基单体,通过自由基聚合、开环聚合得到两亲性超支化聚合物。阐述了不同结构的两亲性超支化聚合物在溶液中的独特性质,如核壳型单分子胶束以及不同胶束形态的聚集体。详细介绍了两亲性超支化聚合物在药物输送载体、材料改性以及染料分子的封装等领域的应用现状,指出采用新的改性技术、聚合技术制备具有特殊性能的两亲性超支化聚合物以及探索其在生物医药领域的研究为今后的主要发展方向。 相似文献
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超支化聚合物增韧环氧树脂的研究进展 总被引:6,自引:0,他引:6
介绍超支化聚合物的结构及特点,着重综述了超支化聚合物增韧改性环氧树脂的研究进展,指出了超支化聚合物在环氧树脂改性方面的发展方向。 相似文献
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主要介绍了含特殊结构基元的超支化聚合物和超分子超支化聚合物的合成方法,并综述了这些新型超支化聚合物在生物医学材料、光学材料、电学材料方面的应用研究进展。 相似文献
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Summary
A hyperbranched polymer containing azo chromophores on the periphery has been synthesized from transesterification reaction
between a hyperbranched polyester bearing peripheral hydroxyl groups and ethyl 4-{4'-[N, Ndi(hydroxyethyl)aminobutoxy]phenylazo}benzoate. The hyperbranched polyester was obtained by adding the AB2 monomers step by step to a multifunctional core molecule. Narrow molecular weight distribution, with a polydispersity index
as low as 1.1, was achieved by this method. The azobenzene- functionalized hyperbranched polymer as well as the corresponding
azo monomer showed typical photoresponsive behavior of an azobenzene type molecule. The trans azobenzene units of the hyperbranched
polymer could be reversibly switched by UV irradiation to the cis form that recovered slowly to the trans form in the dark.
However, significantly less conversion from the trans isomer to the cis isomer was observed for the azobenzenefunctionalized
hyperbranched polymer at the photostationary states under the irradiation of UV light, which could be attributed to the increased
steric hindrance in the hyperbranched polymer.
Received: 1 April 2002 /Revised version: 10 July 2002/ Accepted: 15 July 2002 相似文献
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Güngör Gündüz Nagehan Keskin Üner Çolak Bora Mavis 《Journal of Coatings Technology and Research》2018,15(4):831-843
In this study, a new hybrid alkyd resin was formulated using melamine-based hyperbranched polymer having 24 hydroxyl groups on its structure and relatively low molecular weight alkyd. The alkyd was synthesized using an oil mixture (40% linseed + 60% sunflower). Melamine was used as the core molecule for the hyperbranched polymer due to its excellent properties such as greater hardness, alkali and solvent resistance, and thermal stability. Melamine was first hydroxylated using formaldehyde and changed into hexamethylol melamine. This product was then twice hydroxylated with dimethylol propionic acid to obtain a hyperbranched polymer with 24 hydroxyl end groups. It was then reacted with low molecular weight alkyd resin at different proportions. The product had a low viscosity and could easily flow like oil. It is a solvent-free and water-free liquid. The ‘hyperbranched polymer/alkyd’ ratio affected physical properties of the liquid polymer and also the mechanical properties of the hardened polymer, which can be used for surface coating. The viscosity of the liquid resin decreases from 148 to 8.84 Pa.s as the hyperbranched-polymer-to-alkyd ratio is decreased from 1:3 to 1:24. On the other hand, the hardness of heat-treated resin decreases from 198 Persoz to 43 Persoz, respectively. That is, the increase in the amount of hyperbranched polymer in the resin increases hardness, whereas the increase in the amount of alkyd decreases it. The mechanical tests of hardened resins showed that all specimens passed conical mandrel bending test, and they all depicted high adhesion, and high abrasion and impact resistance. The specimens also had excellent gloss properties. 相似文献
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Sheng‐Jie Wang Xiao‐Dong Fan Qing‐Fa Si Jie Kong Yu‐Yang Liu Wen‐Qiang Qiao Guo‐Bin Zhang 《应用聚合物科学杂志》2006,102(6):5818-5824
A hyperbranched polyethoxysiloxane was synthesized via hydrolytic polycondensation between methyltriethoxysilane (MTES) and tetraethoxysilane (TEOS), with hydrochloride acid as catalyst. FTIR, 1H NMR, 29Si NMR, and GPC measurements confirmed that the polyethoxysiloxane synthesized was indeed a hyperbranched polymer with a degree of branching of 0.67. It was also found that there were no silanol groups in polymer matrix. This quality can effectively enhance its storage stability. Based on the hyperbranched polyethoxysiloxane, a novel antifouling coating with high curing speed at ambient temperature was developed. The recipe and other technique parameters of the coating were revealed and investigated. Experiments indicate that the coating performs well as an antifouling agent and can be applied to various ceramic products. By using scanning electron microscope (SEM) to inspect the surface of a polished tile applied with the coating, the antifouling mechanism was studied and the results were explained in accordance with the penetrating and crosslinking of the macromolecules of hyperbrached polyethoxysiloxane into the microdefects on the surface of tiles. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5818–5824, 2006 相似文献