La_(0.5)Sm_(0.2)Sr_(0.3)MnO_3/Ag_x二相复合体的结构及磁电阻

用固相反应法制备La0.5Sm0.2Sr0.3MnO3/(Ag2O)x/2(x=0.00,0.04,0.08,0.25,0.30)样品,通过X射线衍射谱线(XRD),扫描电子显微镜(SEM)照片及SEM能谱(EDS),ρ-T曲线,研究样品的输运行为及磁电阻效应。结果表明:少量掺杂时Ag全部挥发。掺杂量较多时,挥发后多余的Ag主要以金属态包覆在母体颗粒的表面,使体系形成两相复合体。掺Ag为30%摩尔比时,样品的电阻率较低掺杂样品的电阻率降低一个数量级,在300K、0.5T磁场下,磁电阻明显增强,达到9.4%,这与颗粒母体界面结构的改善有关,也与材料电阻率的降低有关。     

La_(0.67)Sr_(0.33)MnO_3/La_(0.75)MnO_(0.67)Sr_(0.33)MnO_3庞磁电阻三层膜的制备及结构形貌和性能

用磁控溅射法在 (0 0 1)取向的LaAlO3单晶基片上制备了La0 .6 7Sr0 .33MnO3/La0 .75MnO3/La0 .6 7Sr0 .33MnO3外延三层膜。结果表明 ,与La0 .6 7Sr0 .33MnO3单层膜相比较 ,外延三层膜的X射线衍射图上出现 3级衍射峰 ,每级衍射峰由 3个峰组成 :其中强度最高的衍射峰代表衬底的衍射 ;次强的代表上下两层La0 .6 7Sr0 .33MnO3膜 ;最弱的代表中间La0 .75MnO3层。三层膜的二维原子力表面形貌为均匀的小颗粒状 ,表明其三维形貌为外延岛状柱状晶。这种三层膜的巨磁电阻效应与中间层La0 .75MnO3的厚度有关 ,当中间层厚度为 70nm时 ,其最大磁电阻值可达到 3 2 % ,这个结果优于La0 .6 7Sr0 .33MnO3单层膜的巨磁电阻效应。其可能的原因是电子在界面上的散射、层间的交互作用 ,以及点阵错配导致的内应力的综合结果。     

(1-x)La0.6Dy0.1Sr0.3MnO3/0.5x(Sb2O3)复合体系的电输运性质及低场磁电阻效应

用固相反应法制备了(1 -x)La0.6Dy0.1Sr0.3MnO3/0.5x( Sb2 O3)系列样品,通过电阻率-温度(ρ-T)曲线以及ρ-T拟合曲线,研究了样品的电输运性质,电输运机制及低场磁电阻效应.结果表明:所有样品在高温区表现为绝缘体导电,在低温区表现为金属导电,产生绝缘体-金属相变;在金属导电区主要是单磁子散射起作用,可以用公式ρ=ρ0+AT拟合;所有样品在整个温区随温度降低MR持续增大,表现出低场磁电阻特征,复合样品的磁电阻(MR)与纯的La0.6Dy0.1Sr0.3 MnO3的MR相比,在低温区减小,在高温区增大,对x=0.15的样品在高温区的MR大幅度提高,当B=0.2 T,T=300 K时,MR达7.79％,比纯La0.6Dy0.1 Sr0.3 MnO3的MR增大2.6倍,有利于MR的实际应用.     

La_(0.7-x)Dy_xSr_(0.3)CoO_3体系磁电性质研究

用固相反应法制备La0.7-xDyxSr0.3CoO3(x=0.05,0.10,0.15,0.20,0.25)样品,通过M-T曲线,ρ-T曲线,-ρT拟合曲线,研究样品的磁性质、输运行为、输运机制。结果表明:在La0.7-xDyxSr0.3CoO3中的许多三价Co离子处于低自旋态(LS:t2g6eg0,S=0)、中自旋态(IS:t2g5eg1,S=1),Dy格子与Co格子之间耦合相当弱。在50 K以上时,短程的铁磁(FM)Co3+-O-Co4+不能造成Dy3+磁矩的平行排列,Dy次格子保持顺磁态。体系的宏观磁性则是由FM的Co次格子磁矩加上Dy次格子的顺磁矩的贡献。在50 K以下时,Dy3+之间的耦合使得它们的磁矩逐渐趋于铁磁有序排列,必然会在Co格点处产生很强的局域磁场。低自旋的Co3+离子在强内磁场作用下,变为高自旋态,磁矩变大。磁化强度曲线在50 K以下随温度降低表现出快速上升的行为。50 K对x≥0.15的高掺杂样品,绝缘体导电的磁背景是铁磁团簇。这种铁磁绝缘体输运行为可能是在La0.7-xDyxSr0.3CoO3体系中,不仅有Co3+-O-Co4+双交换作用,还有Co3+-O-Co3+,Co4+-O-Co4+超交换作用。并且Dy3+离子无规分布的磁势和库伦势,以及颗粒边界效应,对输运行为也有影响。     

钙钛矿锰氧化物(La_(1-x)Gd_x)_(0.5)Sr_(0.5)MnO_3的电磁特性

通过磁化强度和电阻的测量对多晶样品(La1-xGdx)0.5Sr0.5MnO3(x=0,0.1,0.2,0.3,0.4)的电磁特性进行了系统的实验研究。当x≤0.2时,样品显示出铁磁金属态(FMM)到顺磁绝缘态(PM I)的转变;当0.3≤x≤0.4时,金属-绝缘体转变温度Tp消失,样品显示出反铁磁绝缘态(AFM I)到顺磁绝缘态(PM I)的转变。同时随着x的增加所有样品的居里温度Tc和金属-绝缘体转变温度Tp都降低,并且在居里温度附近观测到了磁电阻效应。     

La_(0.4)Ca_(0.6)Mn_(1-x)Ga_xO_3体系的电荷有序相

用固相反应法制备La0.4Ca0.6Mn1-xGaxO3(x=0,0.08,0.10,0.12,0.15)系列多晶样品。通过X射线衍射(XRD)图谱、电阻率-温度(ρ-T)曲线、磁化强度-温度(M-T)曲线和电子自旋共振(ESR)图谱,研究Ga3+替代Mn3+对La0.4Ca0.6Mn1-xGaxO3体系电荷有序相的影响。结果表明,当Ga掺杂量高达15%时电荷有序相仍然没有被破坏。这是因为Ga3+是非磁性离子,而La0.4Ca0.6MnO3是CE型反铁磁电荷有序相结构,Ga3+替代Mn3+只是仅仅起到把体系中的长程自旋序破坏为短程自旋序的作用,同时随Ga替代量增大,Mn3+与Mn4+的比远离双交换的最佳摩尔配比(Mn3+∶Mn4+=2∶1),不利于双交换,因而非磁性的Ga3+替代Mn3+难以破坏La0.4Ca0.6MnO3的电荷有序相。     

(1-x)La0.7Ca0.3MnO3/xAg磁电阻的温度稳定性

用固相反应法将Ag引入La0.7Ca0.3MnO3颗粒表面,形成(1-x)La0.7Ca0.3MnO3/xAg(x=0.00,0.10,0.20,0.25,0.30,0.35)。通过XRD谱、扫描电子显微镜(SEM)照片及SEM能谱(EDS)、ρ-T曲线、ρ-T拟合曲线、MR-T曲线,研究电输运性质及MR温度稳定性。结果表明:随复Ag量增大,电阻率急剧下降,高复Ag(x≥0.3)的电阻率比低复Ag(x≤0.10)的电阻率下降2个数量级;发现x=0.00,0.10用ρ-T2公式拟合比较合理,是单磁子散射作用;x=0.20,0.25用ρ-T2.5公式拟合比较合理,是自旋波散射作用;x=0.30,0.35,分别在97,93 K以上用ρ-T4.5公式拟合比较合理,说明是电子-磁子散射作用;所有复Ag样品,在250～20 K温区MR表现出很好的温度稳性,特别是x=0.10的样品,在220～150 K温区MR保持(13.8±0.2)%。提出磁电阻稳定性的机制:Ag与钙钛矿颗粒形成电输运二元通道,钙钛矿颗粒通道产生的低场磁电阻与Ag通道产生的正常磁电阻共同作用,产生MR温度稳定性。     

La_(0.67)Ca_(0.33-x)Ba_xMnO_3的电输运性质反常及磁电阻温度稳定性

用固相反应法制备La_(0.67)Ca_(0.33-x)Ba_xMn O_3(x=0,0.10,0.15,0.20,0.25)系列样品,烧结温度为1200℃。通过X射线衍射(XRD)图谱,扫描电子显微镜(SEM)照片、零场和加场下的电阻率-温度(ρ-T)曲线,磁电阻-温度(MR-T)曲线,研究Ba~(2+)替代Ca~(2+)的La_(0.67)Ca_(0.33-x)Ba_xMnO_3的电输运性质及磁电阻温度稳定性。结果表明:随Ba~(2+)替代量的改变晶体结构发生变化,x=0的样品为立方结构,x=0.10的样品为正交结构,x=0.15,0.20,0.30的样品为六方结构。x=0.10样品的电输运性质出现反常,它的电阻率不仅比未掺Ba的La_(0.67)Ca_(0.33)Mn O_3高出60倍,也比高掺Ba样品的电阻率高出几倍,随Ba~(2+)替代量的增加电阻率逐渐下降,用掺Ba引起的晶格结构变化及Mn O_6八面体畸变进行解释;高掺Ba样品实现了室温附近磁电阻温度稳定性,x=0.15的样品在187~246 K温区磁电阻为(8.91±0.42)%,x=0.20的样品在230~290 K温区磁电阻为(6.07±0.32)%,x=0.25的样品在320 K以下直至50 K温区磁电阻均大于14%。在0.8 T磁场下在室温附近产生磁电阻的温度稳定性有利于MR效应的实际应用。磁电阻温度稳定性机制是,钙钛矿的磁电阻是体相内双交换作用产生的本征磁电阻与界面自旋相关散射或自旋极化隧穿产生的低场磁电阻的叠加,制备样品时控制烧结温度(1200℃),尽量提高低场磁电阻,两种磁电阻叠加产生磁电阻温度稳定性。     

La2/3(Ca60Ba40)1/3MnO3的磁电阻与磁化强度及其相关性

用固相反应法制备了La2/3(Ca60Ba40)1/3MnO3多晶材料,测量了77K～320K范围内的磁化曲线及在77K～350K范围内0～1.0T外磁场下的电阻率。结果表明低场磁电阻与高场磁电阻随外磁场的变化与磁化强度(M2)的变化存在着一定相关性,采用ρ(M)∝1-M2及低温隧穿磁电阻效应和逾渗模型解释了实验结果。     

在La_(0.67)Sr_(0.33)MnO_3中保持Mn~(3+)∶Mn~(4+)=2∶1的镁掺杂效应

通过测量样品的M T曲线、M H曲线、ESR曲线、红外光谱、拉曼光谱、ρ -T曲线和MR T曲线 ,研究了双掺杂La0 .6 7+ 1 .33xSr0 .33- 1 .33xMn1 -xMgxO3(0.0 0≤x≤ 0 .2 5 )体系的磁电性质和输运行为。对x =0 .10和 0 .15 ,在温度高于TConset时出现相分离 ;对x =0 .2 0和 0 .2 5 ,在低温区出现了反铁磁 (AFM )行为。x =0 .0 5的 ρ-T关系存在金属 绝缘体 (MI)转变 ;x≥ 0 .15的所有样品在测量温区内显示绝缘体行为。这些奇异现象用M H关系、ESR曲线和拉曼光谱给予了很好的解释     

Magnetic Coupling in La0.67 Ca0.33 MnO3／La0.67 Sr0.33 CoO3／La0.67 Ca0.33MnO3 Trilayer Films

The perovskite La0.67 Ca0.33 MnO3/La0.67 Sr0.33 CoO3/La0.67 Ca0.33 MnO3 trilayers were fabricated by a facing-target sputtering technique and their magnetotransport properties were investigated. The magnetoresistance is dependent on spacer thickness and dramatically decreases when La0.67 Sr0.33 CoO3 layer is thick enough because of its short-circuiting effect. Different from La0.67 Ca0.33 MnO3 single layer, trilayer films with thin La0.67 Sr0.33 CoO3 spacer have the enhanced metal-semiconductor transition temperature (TMS) of La0.67 Ca0.33 MnO3 layers. The magnetic coercivity Hc shows a nonmonotonic behavior with changing the spacer layer thickness at 230 K. The waist-like hysteresis indicates that there is an indirect exchange coupling between the top and bottom Lao.67 Ca0.33 MnO3 layers across the spacer La0.67 Sr0.33 CoO3 layer.     

Research of Colossal Magnetoresistance in La0.67Ca0.33Mn1-xCrxO3 (0.00≤x≤0.15)

The extraordinary colossal magnetoresistance (CMR) behavior in was found that the substitution with Cr on Mn sites introduces an additional bump in zero-field resistivity. With increasing Cr content, this additional bump grows up drastically while the original resistivity peak associated with magnetic order transition diminishes gradually. Under the applied magnetic field, both bumps of resistivity are deeply compressed, which leads to the appearance of two peaks in CMR response. As a result, the temperature range of CMR response is significantly broadened, spanned from the lowest to near room temperature. These results suggest that Mn-site element substitution could be a potent way of tuning CMR response.     

Magnetic and Magnetoresistance Properties in （La0.67Ca0.33MnO3）x／（ZrO2）1-x Composite System

Inrecentyears,muchattentionhasbeenpaidto therare earthdopedmanganitesduetotheirextraor dinarymagneticandtransportproperties.Onone hand,itisbecausetheirabundantelectronicstructure andmagneticproperties[1];ontheotherhand,they exhibitcolossalmagnetoresistan…     

La0.67Sr0.33MnO3/La0.75MnO3/La0.67Sr0.33MnO3庞磁电阻三层膜的制备及结构形貌和性能

用磁控溅射法在(001)取向的LaAlO3单晶基片上制备了La0.67Sr0.33MnO3/La0.75MnO3/La0.67Sr0.33MnO3外延三层膜.结果表明, 与La0.67Sr0.33MnO3单层膜相比较, 外延三层膜的X射线衍射图上出现3级衍射峰, 每级衍射峰由3个峰组成其中强度最高的衍射峰代表衬底的衍射;次强的代表上下两层La0.67Sr0.33MnO3膜;最弱的代表中间La0.75MnO3层.三层膜的二维原子力表面形貌为均匀的小颗粒状, 表明其三维形貌为外延岛状柱状晶.这种三层膜的巨磁电阻效应与中间层La0.75MnO3的厚度有关, 当中间层厚度为70 nm时, 其最大磁电阻值可达到32%, 这个结果优于La0.67Sr0.33MnO3 单层膜的巨磁电阻效应.其可能的原因是电子在界面上的散射、层间的交互作用, 以及点阵错配导致的内应力的综合结果.     

Electrical Transport and Giant Magnetoresistance in （ 1 - x ） La0.67 Ca0.33 MnO3/x CuO Composites

Samples with nominal composition of （1 - x）La0.67Ca0.33MnO3 （LCMO）/xCuO （x = 0%, 2%, 4% and 20% ） were made using a special experimental method. The temperature dependence of the resistivity （ρ） of the composites was investigated in the temperature range of 10 - 300 K and different magnetic fields of H = 0, 0.1, 0.3, 0.5, 1.0 and 3.0 T. The results showed that CuO percentage x had important effects on metal-insulator transition temperature （Tp）, zero field peak resistivity （ρmax）, and magnetoresistance （MR） properties of the composites. Tp shifted sharply towards low temperature with the increase of x in the range of x ≤4%, but was almost independent of x at high level of CuO content. Composites with x = 4 % and 20 % exhibited similar electrical transmission behavior. Compared with pure LCMO, enhanced magnetoresistance could be clearly observed even in a quite low magnetic field of 0.3 T. For x =4% and 20% samples, the MR value at 0.3 T could reach as high as - 88% and - 90%, respectively. XRD and SEM analysis showed that the substantial enhancement of MR, especially near Tp, was because of local spin disorder between contiguous LCMO ferromagnetic particles caused by the addition of CuO.     

Spin Dependent Hopping in Ti Doped La0.67 Ca0.33 MnO3

A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system.     

Thickness Effect on Electronic Transport in Single Crystal La0.67 Ca0.33 MnO3 Thin Films

Lattice strain in thin films induced by film-sub-strate mismatchis one source for variant magnetic andresistive behaviors especiallyfor the manganite perovs-kites for which the lattice effects are wellestablished[1~5].It has been also reported that low-fi…     

Effect of heat treatment on electroresistance in Nd0.67Sr0.33MnO3 ceramics

A remarkable CER(colossal electroresistance) effect was observed in a series of polycrystalline Nd0.67Sr0.33MnO3 samples synthe-sized by high energy ball milling successive heat treatment.The CER ratio increased with increasing heating time and reached 3580% at a low temperature for the Nd0.67Sr0.33MnO3 ceramic annealed up to 13 h as measuring current was enhanced from 5 to 500 μA.The result showed that the CER effect was strongly dependent on the sample's microstructure,especially on the foreign phases whi...     

La_(0.67)Ca_(0.33)Mn_(1-x)T_xO_3低场下的大磁阻效应

研究了在低磁场 H≤ 0 .8T区间下的材料 L a0 .6 7Ca0 .33Mn1 - x Tx O3( T=Fe或 Ni)中的磁阻效应 ,发现在L a0 .6 7Ca0 .33Mn1 - x Fex O3中用铁替代锰降低了磁阻比 ,但改善了磁阻随磁场变化的线性度。用少量的镍替换锰 ( x=0 .1)时 ,可得到较好的低场高磁阻变化特性