Spin transfer effect in magnetic tunnel junction with a nano-current-channel Layer in free layer

The current-induced magnetization switching (spin transfer effect) in a low resistance-area (RA) product magnetic tunnel junction (MTJ) device with critical current density of 1.4/spl times/10/sup 7/ A/cm/sup 2/ was demonstrated. The RA product of the MTJ is 4.2 /spl Omega//spl mu/m/sup 2/ and the magnetoresistance (MR) ratio induced by current is up to 16%. An MTJ structure with a novel nano-current-channel (NCC) layer inserted into the free layer for the current-induced magnetization switching by lower current density was proposed and prototyped. By using the current confined effect, the local current density in the integrated free layer was sufficiently high to switch the magnetization locally. Such local magnetization reversal helped to reverse the magnetic moments around together with the polarized current and spread out the switching of the entire free layer through the superparamagnetic nano-channels. The critical current density was reduced to 4.2/spl times/10/sup 6/ A/cm/sup 2/, which is only one quarter of that for a pure MTJ structure.     

Investigations on the Magnetization Switching Dynamics in Spin Valve Multilayers Under Periodic Applied Magnetic Field

Magnetization switching dynamics in a spin valve nanopillar, induced by spin transfer torque in the presence of a periodic applied field is investigated by solving the Landau–Lifshitz–Gilbert–Slonczewski equation. Under steady state conditions, the switching of magnetization occurs in the system, above a threshold current density value J _c. A general expression for the critical current density is derived and it is shown that this further reduces when there is magnetic interface anisotropy present in the free layer of the spin valve. We also investigated the chaotic behavior of the free layer magnetization vector in a periodically varying applied magnetic field, in the presence of a constant DC magnetic field and spin current. Further, it is found that in the presence of a nonzero interfacial anisotropy, chaotic behavior is observed even at much smaller values of the spin current and DC applied field.     

Electric-field-assisted switching in magnetic tunnel junctions

The advent of spin transfer torque effect accommodates site-specific switching of magnetic nanostructures by current alone without magnetic field. However, the critical current density required for usual spin torque switching remains stubbornly high around 10(6)-10(7) A cm(-2). It would be fundamentally transformative if an electric field through a voltage could assist or accomplish the switching of ferromagnets. Here we report electric-field-assisted reversible switching in CoFeB/MgO/CoFeB magnetic tunnel junctions with interfacial perpendicular magnetic anisotropy, where the coercivity, the magnetic configuration and the tunnelling magnetoresistance can be manipulated by voltage pulses associated with much smaller current densities. These results represent a crucial step towards ultralow energy switching in magnetic tunnel junctions, and open a new avenue for exploring other voltage-controlled spintronic devices.     

Spin transfer torque and tunneling magnetoresistance dependences on finite bias voltages and insulator barrier energy

We investigate the dependence of perpendicular and parallel spin transfer torque (STT) and tunneling magnetoresistance (TMR) on the insulator barrier energy of the magnetic tunnel junction (MTJ). We employed the single orbit tight binding model combined with the Keldysh non-equilibrium Green's function method in order to calculate the perpendicular and parallel STT and the TMR in the MTJ with finite bias voltages. The dependences of the STT and TMR on the insulator barrier energy are calculated for semi-infinite half metallic ferromagnetic electrodes. We find a perfect linear relation between the parallel STT and the tunneling current for a wide range of insulator barrier energy. Furthermore, the TMR also depends on the insulator barrier energy, contradicting Julliere's simple model.     

Crossover from Kondo-assisted suppression to co-tunneling enhancement of tunneling magnetoresistance via ferromagnetic nanodots in MgO tunnel barriers

The dependence of the tunneling magnetoresistance (TMR) of planar magnetic tunnel junctions on the size of magnetic nanodots incorporated within MgO tunnel barriers is explored. At low temperatures, in the Coulomb blockade (CB) regime, for smaller nanodots the conductance of the junction is increased at low bias consistent with Kondo-assisted tunneling and the TMR is suppressed. For slightly larger nanodots but within the CB regime, the TMR is enhanced at low bias, consistent with co-tunneling. Magnetic tunnel junctions (MTJ) exhibit giant magnetoresistance in small magnetic fields that arises from the flow of spin-polarized current through an ultrathin tunnel barrier separating two magnetic electrodes. The current through an MTJ device depends on the magnetic orientation of the electrodes and is typically higher when the electrode moments are parallel than when they are antiparallel. It has recently been demonstrated that the spin polarization of the tunneling current can be greatly enhanced by using crystalline tunnel barriers formed from MgO as compared with conventional amorphous barriers formed from alumina, due to spin filtering across the MgO layer. The magneto-transport properties of magnetic granular alloys and magnetic tunnel junction devices with magnetic nanodots embedded in amorphous dielectric matrices, and tunnel barriers, respectively, have been studied by several groups, but no systematic studies of the dependence on these properties on the nanodot size have been made.     

Spin filtering effects in monocristalline Fe/MgO/Fe magnetic tunnel junctions

Single-crystal magnetic tunnel junctions employing bcc (1 0 0) Fe electrodes and MgO(1 0 0) insulating barrier are elaborated by molecular beam epitaxy. Two extreme regimes have been investigated. First, for extremely thin MgO thickness we show that the equilibrium tunnel transport in Fe/MgO/Fe systems leads to antiferromagnetic interactions, mediated by the tunneling of the minority spin interfacial resonance state. Second, for large MgO barrier thickness, the tunnel transport validates specific spin filtering effect in terms of symmetry of the electronic Bloch function and symmetry-dependent wave function attenuation in the single-crystal barrier. Within this framework, we present giant tunnel magnetoresistive effects at room temperature (125–150%). Moreover, we illustrate that the interfacial chemical and electronic structure plays a crucial role in the filtering. We show that the insertion of carbon impurities at the Fe/MgO interface changes radically the voltage response of the tunnel magnetoresistance. Moreover, we provide experimental evidence for the electronic interfacial resonance states contribution to the spin polarized tunnel transport.     

Pulse-Width Dependence in Current-Driven Magnetization Reversal Using GaMnAs-Based Double-Barrier Magnetic Tunnel Junction

We have investigated the current pulse width dependence on current-driven magnetization reversal in double-barrier structures using GaMnAs-based magnetic tunneling junctions (MTJ) in order to clarify the origin of low threshold current density for current-driven magnetization reversal. Comparing with the case of single-barrier MTJ, the pulse-width dependence reveals that threshold current density is reduced by double-barrier MTJ. We confirmed that the threshold current density in the order of 10⁴ A/cm² is estimated considering the effect of current pulse width.     

Nanoscale Magnetic Characterization of Tunneling Magnetoresistance Spin Valve Head by Electron Holography

Nanostructured magnetic materials play an important role in increasing miniaturized devices. For the studies of their magnetic properties and behaviors, nanoscale imaging of magnetic field is indispensible. Here, using electron holography, the magnetization distribution of a TMR spin valve head of commercial design is investigated without and with a magnetic field applied. Characterized is the magnetic flux distribution in complex hetero‐nanostructures by averaging the phase images and separating their component magnetic vectors and electric potentials. The magnetic flux densities of the NiFe (shield and 5 nm‐free layers) and the CoPt (20 nm‐bias layer) are estimated to be 1.0 T and 0.9 T, respectively. The changes in the magnetization distribution of the shield, bias, and free layers are visualized in situ for an applied field of 14 kOe. This study demonstrates the promise of electron holography for characterizing the magnetic properties of hetero‐interfaces, nanostructures, and catalysts.     

Spin dependent tunneling

During the past four years, researchers made significant advances in fabricating magnetic tunnel junctions with reproducible magnetic and magnetotransport properties. Important developments include optimization of oxidation processes, discovery of new class of magnetic tunnel junctions, combination of spin dependent tunneling with the Coulomb blockade effect, and a better theoretical understanding of the I–V characteristics of magnetic tunnel junctions. These developments make them promising candidates for magnetic random access memories.     

Reversible electrical switching of spin polarization in multiferroic tunnel junctions

Spin-polarized transport in ferromagnetic tunnel junctions, characterized by tunnel magnetoresistance, has already been proven to have great potential for application in the field of spintronics and in magnetic random access memories. Until recently, in such a junction the insulating barrier played only a passive role, namely to facilitate electron tunnelling between the ferromagnetic electrodes. However, new possibilities emerged when ferroelectric materials were used for the insulating barrier, as these possess a permanent dielectric polarization switchable between two stable states. Adding to the two different magnetization alignments of the electrode, four non-volatile states are therefore possible in such multiferroic tunnel junctions. Here, we show that owing to the coupling between magnetization and ferroelectric polarization at the interface between the electrode and barrier of a multiferroic tunnel junction, the spin polarization of the tunnelling electrons can be reversibly and remanently inverted by switching the ferroelectric polarization of the barrier. Selecting the spin direction of the tunnelling electrons by short electric pulses in the nanosecond range rather than by an applied magnetic field enables new possibilities for spin control in spintronic devices.     

Bulk Spin Torque-Driven Perpendicular Magnetization Switching in L10 FePt Single Layer

Due to its inherent superior perpendicular magnetocrystalline anisotropy, the FePt in L1₀ phase enables magnetic storage and memory devices with ultrahigh capacity. However, reversing the FePt magnetic state, and therefore encoding information, has proven to be extremely difficult. Here, it is demonstrated that an electric current can exert a large spin torque on an L1₀ FePt magnet, ultimately leading to reversible magnetization switching. The spin torque monotonically increases with increasing FePt thickness, exhibiting a bulk characteristic. Meanwhile, the spin torque effective fields and switching efficiency increase as the FePt approaches higher chemical ordering with stronger spin–orbit coupling. The symmetry breaking that generates spin torque within L1₀ FePt is shown to arise from an inherent structural gradient along the film normal direction. By artificially reversing the structural gradient, an opposite spin torque effect in L1₀ FePt is demonstrated. At last, the role of the disorder gradient in generating a substantial torque in a single ferromagnet is supported by theoretical calculations. These results will push forward the frontier of material systems for generating spin torques and will have a transformative impact on magnetic storage and spin memory devices with simple architecture, ultrahigh density, and readily application.     

A link between the coercivity and microstructure of high moment Fe films and their use in magnetic tunnel junctions

Magnetron sputtered single Fe films have been “softened” magnetically by controlled N-doping during the sputter deposition. This technique allows a reduction in grain size and coercivity of the Fe films, without decreasing the saturation magnetization and without the formation of any crystalline FeN phases. We describe this effect through a modification of the random magnetocrystalline anisotropy model, by taking the film thickness into account. The coercivities calculated in this way are in good agreement with those obtained experimentally.It is demonstrated that N-doping can be applied beneficially to control the switching field of the ‘free’ layer in magnetic trilayer films of the MTJ type. It is thus possible to construct an all Fe-electrode magnetic tunnel junction (MTJ) that displays the tunneling magnetoresistance (TMR) effect by altering the switching field of one Fe layer using N-doping. The ability to control the magnetic softness of high magnetic moment materials is important in regard to their incorporation into TMR devices.     

Magneto-Memristive Switching in a 2D Layer Antiferromagnet

Memristive devices whose resistance can be hysteretically switched by electric field or current are intensely pursued both for fundamental interest as well as potential applications in neuromorphic computing and phase-change memory. When the underlying material exhibits additional charge or spin order, the resistive states can be directly coupled, further allowing electrical control of the collective phases. The observation of abrupt, memristive switching of tunneling current in nanoscale junctions of ultrathin CrI₃, a natural layer antiferromagnet, is reported here. The coupling to spin order enables both tuning of the resistance hysteresis by magnetic field and electric-field switching of magnetization even in multilayer samples.     

Spin control by application of electric current and voltage in FeCo-MgO junctions

Efficient control and detection of spins are the most important tasks in spintronics. The current and voltage applied to a magnetic tunnel junction may exert a torque on the magnetic thin layer in the junction and cause its reversal or continuous precession. The discovery of the giant tunnelling magnetoresistance effect in ferromagnetic tunnelling junctions using an MgO barrier enabled us to obtain a large signal output from the magnetization reversal and precession. Also, the interplay of large spin configuration-electric conduction coupling provides highly nonlinear effects like the spin-torque diode effect. The negative resistance effect and amplification using it are predicted. A new discovery about a voltage-induced magnetic anisotropy change in Fe ultrathin films is also discussed.     

Spin transport in spin filtering magnetic tunneling junctions

Taking into account spin-orbit coupling and s-d interaction, we investigate spin transport properties of the magnetic tunneling junctions with spin filtering barrier using Landauer-Büttiker formalism implemented with the recursive algorithm to calculate the real-space Green function. We predict completely different bias dependence of negative tunnel magnetoresistance (TMR) between the systems composed of nonmagnetic electrode (NM)/ferromagnetic barrier (FB)/ferromagnet (FM) and NM/FB/FM/NM spin filtering tunnel junctions (SFTJs). Analyses of the results provide us possible ways of designing the systems which modulate the TMR in the negative magnetoresistance regime.     

Ionic Liquid Gating Control of Spin Reorientation Transition and Switching of Perpendicular Magnetic Anisotropy

Electric field (E‐field) modulation of perpendicular magnetic anisotropy (PMA) switching, in an energy‐efficient manner, is of great potential to realize magnetoelectric (ME) memories and other ME devices. Voltage control of the spin‐reorientation transition (SRT) that allows the magnetic moment rotating between the out‐of‐plane and the in‐plane direction is thereby crucial. In this work, a remarkable magnetic anisotropy field change up to 1572 Oe is achieved under a small operation voltage of 4 V through ionic liquid (IL) gating control of SRT in Au/[DEME]⁺[TFSI]^?/Pt/(Co/Pt)₂/Ta capacitor heterostructures at room temperature, corresponding to a large ME coefficient of 378 Oe V^?1. As revealed by both ferromagnetic resonance measurements and magnetic domain evolution observation, the magnetization can be switched stably and reversibly between the out‐of‐plane and in‐plane directions via IL gating. The key mechanism, revealed by the first‐principles calculation, is that the IL gating process influences the interfacial spin–orbital coupling as well as net Rashba magnetic field between the Co and Pt layers, resulting in the modulation of the SRT and in‐plane/out‐of‐plane magnetization switching. This work demonstrates a unique IL‐gated PMA with large ME tunability and paves a way toward IL gating spintronic/electronic devices such as voltage tunable PMA memories.     

Spin-transfer switching current distribution and reduction in magnetic tunneling junction-based structures

Spin transfer switching current distribution within a cell and switching current reduction were studied at room temperature for magnetic tunnel junction-based structures with resistance area product (RA) ranged from 10 to 30 /spl Omega/-/spl mu/m/sup 2/ and TMR of 15%-30%. These were patterned into current perpendicular to plane configured nanopillars having elliptical cross sections of area /spl sim/0.02 /spl mu/m/sup 2/. The width of the critical current distribution (sigma/average of distribution), measured using 30 ms current pulse, was found to be 3% for cells with thermal factor (KuV/k/sub B/T) of 65. An analytical expression for probability density function p(I/I/sub c0/) was derived considering a thermally activated spin transfer model, which supports the experimental observation that the thermal factor is the most significant parameter in determining the within-cell critical current distribution. Spin-transfer switching current reduction was investigated through enhancing effective spin polarization factor /spl eta//sub eff/ in magnetic tunnel junction-based dual spin filter (DSF) structures. The intrinsic switching current density (J/sub c0/) was estimated by extrapolating experimental data of critical current density (J/sub c/) versus pulse width (/spl tau/), to a pulse width of 1 ns. A reduction in intrinsic switching current density for a dual spin filter (DSF: Ta/PtMn/CoFe/Ru/CoFeB/Al2O3/CoFeB/spacer/CoFe/PtMn/Ta) was observed compared to single magnetic tunnel junctions (MTJ: Ta/PtMn/CoFe/Ru/CoFeB/Al2O3/CoFeB/Ta). J/sub c/ at /spl tau/ of 1 ns (/spl sim/J/sub c0/) for the MTJ and DSF samples were 7/spl times/10/sup 6/ and 2.2/spl times/10/sup 6/ A/cm/sup 2/, respectively, for identical free layers. Thus, a significant enhancement of the spin transfer switching efficiency is seen for DSF structure compared to the single MTJ case.     

Deterministic Magnetization Switching Using Lateral Spin–Orbit Torque

Current-induced magnetization switching by spin–orbit torque (SOT) holds considerable promise for next generation ultralow-power memory and logic applications. In most cases, generation of spin–orbit torques has relied on an external injection of out-of-plane spin currents into the magnetic layer, while an external magnetic field along the electric current direction is generally required for realizing deterministic switching by SOT. Here, deterministic current-induced SOT full magnetization switching by lateral spin–orbit torque in zero external magnetic field is reported. The Pt/Co/Pt magnetic structure is locally annealed by a laser track along the in-plane current direction, resulting in a lateral Pt gradient within the ferromagnetic layer, as confirmed by microstructure and chemical composition analysis. In zero magnetic field, the direction of the deterministic current-induced magnetization switching depends on the location of the laser track, but shows no dependence on the net polarization of external out-of-plane spin currents. From the behavior under external magnetic fields, two independent mechanisms giving rise to SOT are identified, i.e., the lateral Pt–Co asymmetry as well as out-of-plane injected spin currents, where the polarization and the magnitude of the SOT in the former case depends on the relative location and the laser power of the annealing track.     

Field‐Free Programmable Spin Logics via Chirality‐Reversible Spin–Orbit Torque Switching

Spin–orbit torque (SOT)‐induced magnetization switching exhibits chirality (clockwise or counterclockwise), which offers the prospect of programmable spin‐logic devices integrating nonvolatile spintronic memory cells with logic functions. Chirality is usually fixed by an applied or effective magnetic field in reported studies. Herein, utilizing an in‐plane magnetic layer that is also switchable by SOT, the chirality of a perpendicular magnetic layer that is exchange‐coupled with the in‐plane layer can be reversed in a purely electrical way. In a single Hall bar device designed from this multilayer structure, three logic gates including AND, NAND, and NOT are reconfigured, which opens a gateway toward practical programmable spin‐logic devices.     

Characterization of Domain Switching Behavior of MTJ Cells Using Magnetic Force Microscopy (MFM) and R–H Loop Analysis

Correlation between electrical and magnetic properties of magnetic tunnel junctions (MTJ) for magnetic random access memory (MRAM) was studied. The MTJ (Ta/NiFeCr/ PtMn/CoFe/Ru/CoFe/Al₂O₃/CoFe/NiFe/Ta) was analyzed by utilizing R-H loops and MFM images. We verified that a kink in an R-H loop comes from a vortex domain of free layer. In addition, we also observed a close relationship between a domain switching behavior and an irregular R-H curve. These results would be useful for the characterization of the MTJ cell, thereby optimizing the process to realize an ultrahigh density MRAM.