共查询到20条相似文献,搜索用时 62 毫秒
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介绍了聚吡咯、聚噻吩、聚苯胺等导电聚合物在化学修饰电极中的研究与应用情况。导电聚合物的制备条件,包括聚合方法、溶剂性质、支持电解质、温度、掺杂情况等影响聚合物修饰膜的导电性。通过单体的衍生改性、与其它单体共聚、掺杂、或与其它聚合物、纳米粒子等的复合等方法,改进导电聚合物修饰电极的性能,使其具有更好的催化或电学、光学性质。 相似文献
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锌、钯等金属的卤化物或复合物是丙炔醇进行聚合和共聚合反应的有效催化剂。所得的聚合物具有良好的导电性和热稳定性,并可制成涂层。加入第三组份能明显地提高聚合物的热稳定性,掺杂则使聚合物电导率大为提高。 相似文献
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导电高分子材料的研究概况 总被引:5,自引:0,他引:5
戈明亮 《现代塑料加工应用》2002,14(4):43-46
综合介绍了导电聚合物的种类及其合成的方法,列举了导电聚合物在不同领域的应用情况,同时对导电聚合物未来的发展提出了一些看法。 相似文献
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全生物降解高分子材料的发展现状 总被引:11,自引:0,他引:11
生物降解高分子材料因医药、医学、环境等方面的需求而迅速发展起来,在近几十年,世界先进国家非常重视该领域的研究和开发工作,并取得一些重要进展。在简要介绍生物降解高分子材料的降解过程后,着重对全生物降解高分子材料的发展现状作了综述,其中包括化学合成高分子和天然高分子的研究和开发,同时对生物降解高分子材料存在的问题及其将来发展趋势等方面进行了讨论。 相似文献
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Baoxiang Wang Chenjie Liu Yichao Yin Xiaoli Tian Shoushan Yu Kezheng Chen Pengbo Liu Bing Liang 《应用聚合物科学杂志》2013,130(2):1104-1113
A novel polyaniline nanofiber/kaolinite nanoplatelet hybrid nanocomposite was synthesized by means of rapidly mixed in situ polymerization. The resultant polyaniline/kaolinite hybrid nanocomposite was characterized via different techniques, such as X‐ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The results show that 2D clay nanoplatelets are coated by the 1D polyaniline nanofibers. The nanoclay platelets can improve the thermal stability of polyaniline nanofibers. An electrorheological effect is found with the suspension of polyaniline nanofiber/kaolinite nanoplatelet hybrid nanocomposite dispersed in silicone oil. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1104‐1113, 2013 相似文献
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The monolayer characteristics of photochromic azo containing addition and condensationpolymers have been investigated under different conditions of illumination. Possible orientations of the polymers in the monolayers have been proposed. It was found that trans → cis photoisomerization of these materials was not always possible in the Langmuir films and photoinduced changes in monolayer area with time were followed for those polymers which showed uninhibited photoisomerization. 相似文献
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本文介绍了研制的聚硅烷型密封材料的密封防潮,高低温适应性,电气绝缘和化学稳定必胼指出了它的应用前景。 相似文献
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《国际聚合物材料杂志》2012,61(1-4):193-209
Abstract The general affects of diffusion of water in polymers are reviewed and discussed. 相似文献
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《国际聚合物材料杂志》2012,61(1-4):267-276
Abstract Typical systems biodegradable polymer-drugs for the treatment of different diseases are considered and also the dosage forms used therein. Biodegradable polymers are classified as to degradation mechanism, hydrolysis mechanism and solubilization mechanism. Influence of the distribution type of drug in biodegradable polymer is described in relation to release rate. 相似文献
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Liwei Zhang 《Polymer》2006,47(15):5259-5266
Reversible addition-fragmentation chain transfer (RAFT) polymerization of styrene using bisallyl trithiocarbonate as a chain transfer agent (CTA) was studied. The polymerization exhibited first-order kinetics and the molecular weight increased linearly with increase of monomer conversion. Well defined allyl-functionalized telechelic polystyrene (PS), poly(tert-butyl acrylate) (PtBA) and corresponding triblock copolymers, polystyrene-b-poly(n-butyl acrylate)-b-polystyrene (PS-b-PnBA-b-PS) and poly(tert-butyl acrylate)-b-polystyrene-b-poly(tert-butyl acrylate) (PtBA-b-PS-b-PtBA) were prepared as characterized with GPC and NMR analysis. The allyl-end groups of the telechelic PS have been switched to 1,2-dibromopropyl groups quantitatively by bromine addition reaction, further substitution of the bromide with azide was also made. Furthermore, star PS with allyl-end-functionalized arms was synthesized by RAFT polymerization of divinyl benzene using allyl-functionalized PS as a macro-CTA via arm-first approach. Star polymer with a thiol-functionalized core was generated by aminolysis reaction of the star polymer and ethylenediamine. As a result, difunctionalized star polymer with allyl and thiol groups was obtained and was used as a stabilizer for the formation of gold nanoparticles. 相似文献