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难浸砷金精矿的碱性常温常压预氧化 总被引:7,自引:0,他引:7
本文提供了1种难浸金精矿的湿法预氧化新工艺,它包括细磨、强化碱浸预氧化、氰化和炭吸附。在螺旋搅拌式塔式磨浸机中,先将目的难浸金精矿细磨至98%<37μm,然后在40%的矿浆质量浓度、11℃的环境温度和0.1MPa的环境压力下强化碱浸24h,NaOH的消耗量为88kg/t矿,仅为相同氧化率条件下将砷硫氧化成砷酸盐和硫酸盐所需理论碱耗量的30%。预氧化完成后经36h的氰化浸出和炭吸附,金的浸出率从预氧化前的24.6%提高到95.4%,金的吸附率99.2%,NaCN的消耗4kg/t矿。整个提金工艺的成本约300元/t矿。 相似文献
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用石硫合剂(LSSS)法从高铅金精矿浸出金 总被引:3,自引:1,他引:2
石硫合剂法是最新的无氰提金技术。石硫合剂法浸金机理是:电化学──催化机理。本文对石硫合剂法浸出高铅顽固金精矿样的工艺研究表明:石硫合剂法对顽固金精矿的适应性良好,采取二段浸出工艺,金浸出率可达99%,为国内外大量顽固金矿的开发利用提供了条件和可能途径。 相似文献
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采用HClO4预氧化、FeCl3进一步氧化络合方法联合浸出品位低、成分杂的卡林型金矿中的金。机理分析认为,在浸出前期加入HClO4将金属硫化物中的硫以高价态硫酸根离子、硫酸氢根离子等形式进入溶液而脱除,减少单质硫形成钝化膜包裹从而阻碍金属硫化物的解离,同时保证体系中一定初始浓度的[Fe3+]、[Cl-],有利于后续FeCl3浸金。正交试验研究表明,选定的4个因素对金浸出率的影响顺序为HClO4体积分数>FeCl3浓度>浸出温度>HClO4预氧化时间,得到的较优浸出条件为HClO4体积分数6%、预氧化时间1 h、FeCl3浓度1.8 mol/L、40℃浸出5 h,在该条件下卡林型金矿金的浸出率为71.02%。 相似文献
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对金品位为2.02 g/t的某低品位氧化微细粒金矿开展了全泥浸出提取金的试验研究。优选出非氰浸出剂CC-1,确定了相应工艺参数,在此基础上开展了3个粒级柱浸试验,对柱浸含金溶液进行了活性炭吸附试验,研究表明该矿石适宜于利用非氰浸出剂CC-1堆浸回收金。矿石磨至-200目占80%、矿浆液固比2:1、石灰用量3000 g/t原矿、CC-1浓度0.10%、浸出时间30 h条件下金浸出率92.75%;在石灰用量3000 g/t、CC-1浓度0.10%、浸出时间10 d时-10 mm矿样Au浸出率92.46%,浸出时间15 d时-20 mm及-30 mm矿样Au浸出率分别为91.49%、89.24%。采用CC-1作为浸出剂的含Au溶液活性炭吸附率为95.72%~97.11%。 相似文献
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1 INTRODUCTIONCyanidationprocess ,characterizedbyeffectivenessandlowoperatingcost,asaconventionaltechnologyforgoldextractionfromores ,hasbeenusedinindustryforover 10 0years .Howeverthecyanideisahighlytoxicchemical,andcommercialcyanidationprocessislimitedint… 相似文献
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O. CELEP I. ALP H. DEVECI M. VICIL 《中国有色金属学会会刊》2009,19(3):707-713
The amenability of a refractory ore to the extraction of gold and silver by cyanide leaching was investigated. Diagnostic leaching tests were also performed to shed light on the refractory characteristics of ore. The leaching tests show that the extraction of gold and silver is consistently low, i.e. ≤47% and ≤19.2%, respectively, over a leaching period of 24 h. Even fine grinding (e.g. <38 μm) does not improve the recovery of gold and silver. Diagnostic leaching approach provides information into the cause of the refractoriness of the ore. The findings suggest that the refractoriness is induced by the dissemination and encapsulation of the very fine gold and silver particles largely in the carbonates, oxides and sulfides and, to a small extent, with silicates present in the ore matrix. These findings highlight the practical importance of diagnostic leaching for the understanding of the refractory characteristic of such an ore and for the identification of possible pretreatment options to overcome its refractoriness prior to cyanide leaching. 相似文献
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孟宇群 《中国有色金属学会会刊》2005,15(5):1178-1184
A new hydrometallurgical process for a carbonaceous refractory gold concentrate at ambient temperature and pressure was presented, including grinding-leaching, intensified alkaline leaching(IAL), thiosulfate leaching and cementation by zinc powder. The experimental results show that the grinding-leaching and intensified alkaline leaching process result in the selective oxidation of arsenopyrite and pyrite. The oxidation ratio of As is 96.6%, and 46.7 % for S. The total consumption of NaOH in alkaline leaching is only 28 % of that theoretically calculated under the conditions of full oxidization for the same amount of arsenopyrite and pyrite transforming into arsenates and sulfates, and 83.6% of gold is synchro-dissoluted by thiosulfate self-generated during pretreatment. Since the carbonaceous matter in concentrate possesses a strong capability of preg robbing, the cyanidation process is not suitable for the extraction of gold after pretreatment. However, the gold leaching rate by thiosulfate leaching for 24 h is increased to 91.7% from 0 - 3.2% by ultra-fine grinding without the pretreatment. The recovery of gold by zinc cementation gets to 99.6%. Due to the thiosulfate self-generated during alkaline leaching, the reagent addition in thiosulfate leaching afterwards is lower than the normal one. 相似文献
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研究了微波焙烧预处理对微细浸染型难处理金矿浸出的影响。正交试验表明,各因素对浸出率影响程度大小依次为:微波焙烧温度、焙烧时间、浸出时间、浸出剂TY-3用量和氢氧化钠用量。在微波焙烧温度550℃,焙烧时间40 min,浸出剂TY-3用量14 kg/t,氢氧化钠用量8 kg/t,浸出10 h的优化条件下,浸出率达94.8%。XRD分析结果表明,经微波加热焙烧后,原矿中黄铁矿转化为赤铁矿。与马弗炉焙烧对比,微波焙烧可能具有选择性加热作用,更有利于矿石中包裹金的暴露。 相似文献
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《中国有色金属学会会刊》2020,30(4):1111-1123
A novel process based on chlorination roasting was proposed to simultaneously recover gold and zinc from refractory carbonaceous gold ore by using NaCl as chlorination agent. The effects of roasting temperature, roasting time and NaCl content on the volatilization rates of gold and zinc were investigated. The reaction mechanism and the phase transition process were also analyzed by means of SEM, EDS and XRD. The results demonstrated that under the optimal conditions of NaCl content of 10%, roasting temperature of 800 °C, roasting time of 4 h and gas flow rate of 1 L/min, the rates of gold and zinc were 92% and 92.56%, respectively. During low-temperature chlorination roasting stage, a certain content of sulfur was beneficial to the chlorination reactions of gold and zinc; and during high-temperature chlorination roasting stage, the crystal structure of vanadium-bearing mica was destroyed, and the vanadium-containing oxides were beneficial to the chlorinating volatilization of gold and zinc. Eventually, the chlorinated volatiles of gold and zinc could be recovered by alkaline solution. 相似文献