轻骨料性能对界面区微观结构的影响

目的研究不同吸水率轻骨料制备的混凝土中骨料-水泥石界面区的微观形貌、水化产物的钙硅质量比、水泥石的显微硬度以及孔结构等性能参数．方法采用扫描电镜（SEM）、X射线能谱分析（EDXA）、显微硬度以及孔结构等试验手段,并与普通骨料混凝土进行对比分析．结果轻骨料-水泥石界面区各项性能均优于普通骨料,轻骨料吸水率越大、表面越粗糙,界面区水泥石结构越致密,孔结构呈细化趋势,低、中、高吸水率轻骨料-水泥石界面区显微硬度较普通骨料分别提高15．8％、79．6％和96．3％,界面增强层厚度为40～60μm,并且,中、高吸水率陶粒混凝土中,距骨料-水泥石界面-10～0μm范围内具有一个明显的内增强层．结论轻骨料性能对界面区水泥石微观结构具有显著影响,中、高吸水率轻骨料可使界面区结构得以改善．     

轻集料与水泥石界面区元素分布特征研究

研究了高强页岩陶粒与水泥石及其界面区的元素分布特征，探测出界面区宽度约为20～30μm，研究表明界面区Ca^2 向轻集料方向迁移、轻集料内水分向界面区扩散，结果使得界面区的硅钙比较基体小，结构较基体密实，显微硬度较基体大；分析了粉煤灰、矿渣对两相界面组成、结构与性能的影响规律，结果表明随着粉煤灰、矿渣的掺入，界面区硅钙比增大，界面区水泥石的孔隙率和平均孔径显著降低，显微硬度提高，界面得到增强。     

混凝土界面过渡区不均匀特性研究

在新拌混凝土制备过程中,因混凝土内部的微泌水效应和宏观泌水作用会对处于不同位置的骨料周围区域内产生水分的不均匀分布,进而影响界面过渡区的均匀性。利用显微硬度测试技术研究了混凝土界面过渡区的不均匀特性。结果表明,单骨料上、下以及侧面等不同界面处显微硬度值存在较大差别,其中上界面显微硬度值最大。表层骨料周围界面过渡区宽度略大于内部骨料界面过渡区;硅灰的掺加能明显改善混凝土界面过渡区的不均匀性。     

磷酸盐水泥界面过渡区研究

磷酸镁水泥(MPC)是一种新型胶凝材料,常用作快速修补材料,并取得了良好的效果,但关于磷酸镁水泥的界面过渡区的研究目前却十分缺乏。采用XRD、SEM以及EDX等方法对磷酸镁水泥与抛光大理石界面处的物相、微观形貌进行了分析,同时也对界面过渡区的各元素分布进行了测试,对磷酸镁水泥的界面过渡区进行了分析。实验结果表明,磷酸镁水泥在界面处与内部的水化产物晶体生长状况均良好,界面过渡区晶体生长状况与内部差别不大,在加水拌合1h后有大量生长状况良好的水化产物晶体形成,随着龄期的增加,晶体会逐渐增大、增多,晶粒形状也会发生一定变化,结合EDX分析界面过渡区元素变化情况可知,在界面处有大量的Mg及P元素分布,但在距离界面70μm后分布才有一定规律。     

钢筋保护层混凝土细观界面过渡区优化及耐久性

针对传统混凝土结构及构件钢筋保护层混凝土寿命较低,耐久性不良的现状,通过对普通混凝土细观层次上(50～100 μm)的浆-骨界面过渡区进行优化或改善,以耐久性设计为主要目标,设计制备出内部细观界面大幅度优化的高致密保护层混凝土(High-dense concrete cover,简称HDC),并针对其抗渗性、抗钢筋锈蚀、抗酸性气体腐蚀以及抗冻性等耐久性能展开系统的试验研究.结果表明,所制备的HDC抗渗性优良,评价结果为渗透性"非常低";HDC抗钢筋锈蚀性能相比普通混凝土保护层得到大幅度增强;在CO2、SO2加速侵蚀条件下,HDC 90 d中性化深度不足1mm;而HDC冻融后外观形貌、质量损失以及相对动弹性模量等表征抗冻性能的关键指标均明显优于普通混凝土.同时SEM微观试验结果表明,HDC浆-骨界面过渡区尺寸得到有效降低,增加了混凝土微结构密实度.说明HDC特殊的制备技术及其材料本征特性能有效提升了材料的综合性能,从而延长结构的服役寿命.     

合成C-S-H凝胶对水泥石-集料界面区的影响

研究了利用硅质材料和钙质材料经常温常压下水热反应制得的合成C-S-H疑胶对水泥石-集料界面区结构和性能的影响,发现这种合成凝胶对界面区的结构和性能有独特的改善作用。本文还探讨了合成C-S-H凝胶对界面区的作用机理。     

Investigation of the Interfacial Transition Zone between Aggregate-Cement Paste by AC Impedance Spectroscopy

Three different types and sizes of coarse aggregate were chosen,and the alternating current(AC) impedance of cement paste samples with and without aggregate was measured at different curing ages.Based on Song's equivalent circuit model,the electrical properties from the AC impedance results were obtained,and the resistance of connected pores RCCP was used to characterize the microstructure of the interfacial transition zone(ITZ).The results show that the RCCP of concrete sample with aggregate is lower than that of cement paste sample,which indicates that the introduction of aggregate in cement paste makes the ITZ porous.Furthermore,for the same type of aggregate,an increase in particle size leads to a more porous ITZ,which accounts for the "water effect" and a larger aggregate would accumulate a thicker water film around it.In addition,for the same size of aggregate,the physical interaction between aggregate and cement paste is dominant in early age,and the microstructure of the ITZ around limestone aggregate is denser,which mainly depends on its rough surface and high water absorption.However,the microstructures of the ITZ around granite and basalt aggregates are denser in later age,which may be due to their higher chemical activity,and the chemical interaction between them and cement paste resulting in the generation of more hydrates.AC impedance spectroscopy thus proves to be powerful for evaluation of the microstructure of the ITZ.     

Nanoindentation Characteristics of Cement Paste and Interfacial Transition Zone in Mortar with Rice Husk Ash

The nanostructure of cementitious materials has important effects on concrete properties. The effects of rice husk ash(RHA) on cement hydration product phases and interfacial transition zone(ITZ) in mortar were investigated from the nano-scale structure perspective. The experimental results indicate that, with the increase of RHA dosages of samples, the volume fraction of high-density calcium-silicate-hydrate(HD C-S-H) in porosity and hydration product phases increases. The volume fractions of HD C-S-H in C-S-H of samples show an increasing trend with the increase of RHA dosages. RHA decreases the thickness of ITZ and increases the matrix elastic moduli of samples, however, the RHA dosoges hardly affect the thickness and elastic moduli.     

再生混凝土ITZ结构与性质的研究

采取降低水灰比 ,掺入适量粉煤灰、高效减水剂和对再生集料表面进行处理等措施 ,通过 SEM研究了再生混凝土界面过渡区 (ITZ)的结构与性质。试验结果显示 :降低水胶比 ,掺入 2 0 %的粉煤灰和 2 .5 %高效减水剂 (对水泥 ) ,可使再生混凝土 ITZ结合更加紧密 ,抗压强度得以提高。在同样条件下 ,采用 1% PVA溶液处理过的再生集料 ,有利于提高新拌再生混凝土的流动性 ,同时 ,硬化混凝土的强度也有所提高     

老混凝土中骨料-水泥界面过渡区(ITZ)(Ⅱ)——元素在界面区的分布特征

利用电子探针（EPXM）对骨科颗粒和水泥浆体界面过渡区（ITZ）进行了研究，研究的重点是化学元素在ITZ附近的分布情况，试验结果表明：Ca、K和Fe有不同程度地集中于界面过渡区的趋势，而Si的浓度在界面处相对比较低，但随着远离界面其浓度逐渐升高。Mg、Al等元素在ITZ的局部出现，且有不连续分布的特点。通过对老混凝土中ITZ元素分布的分析，可以部分地了解混凝土内部所发生的离子和物质迁移，骨科和水泥浆体之间发生的化学反应，从而为评估混凝土的化学稳定性乃至其耐久性提供依据。     

Quantitative Analysis and Affecting Factors of the Overlapping Degree of Interfacial Transition Zone between Neighboring Aggregates in Concrete

Based on the nearest surface function formula, a quantitative formula to measure the overlapping degree between the interfacial transition zone (ITZ) of neighboring aggregate particles was put forward. The formula was further deduced to quantitatively analyze the influence of the volume fraction of aggregate, ITZ thickness and the maximum aggregate diameter on the overlapping degree between neighboring ITZ. The volume of ITZ was quantitatively calculated in actual concrete by comparing the nearest surface f...     

基于XPDL的建模技术在软件开发过程的应用

XPDL是工作流管理联盟推出的需由开发商共同遵守的一个统一的过程定义语言规范,由它定义的接口能在开发和运行环境之间提供形式上的分离.此外,用建模工具产生的过程定义可以用于多个工作流产品.分析了软件开发过程模型和工作流基本过程定义元模型,提出了通过XPDL来描述和实现软件开发过程的工作流建模.     

论宏观调控下开发区发展模式的转变

在当前政策形势不甚明朗、开发区发展一片茫然之际,通过深入分析宏观调控下开发区内外环境发生的转变,探讨了如何将开发区的生存危机转变成发展契机的几点思路,以供相关决策层参考,谋求化解开发区生存危机之计。     

老混凝土中骨料-水泥界面过渡区(ITZ)(Ⅰ)——元素与化合物在ITZ的富集现象

利用扫描电子显微镜（SEM）、电子探针（EPXM）和电子能谱（EDXA）对骨料颗粒和水泥浆体界面过渡区（ITZ）进行了研究，研究的重点是老混凝土中骨料－水泥界面过渡区的微观结构特征和成份分布，结果表明，老混凝土由于在成熟度高，其ITZ中水化物十分丰富，密实度高。ITZ内部和外部的水化产物组成存在一定的差别，表现在Ca,K和Fe等元素富集于ITZ，而Si元素在此区域的含量相对较低，对于特定的元素或物质在ITZ中的富集现象的研究，有助于提高对混凝土材料稳定性的认识。     

Flexural Stress Homogenization Effects of Interfacial Transition Layers in Modified ZrB_2-Al_2O_3/Epoxy Composites

The effect of interfacial modification on flexural strength of epoxy composites filled with modified ZrB_2-Al_2O_3 composite fillers was investigated in order to explore the stress distribution of modified composites under external load. The mechanical performance of epoxy composites filled with 0 vol%, 1 vol%, 3 vol% and 5 vol% unmodified and modified ZrB_2-Al_2O_3 fillers was characterized by three point bending(TPB) tests. The fracture surfaces of epoxy composites were observed by scanning electronic microscope(SEM). The results showed that the epoxy composite reinforced by 1 vol%modified fillers exhibited the optimal mechanical performance. According to the Von Mises stress contours simulated by finite element models(FEM) and the SEM images, it was shown that the modified ZrB_2-Al_2O_3 multiphase fillers could homogenize the stress in the epoxy composites due to the transition effect resulted from the interfacial modification layers on the surfaces of multiphase fillers. It contributed to the improvement of mechanical performance of epoxy composites further.     

基于UML的软件开发建模方法的研究

开发具有可复用性、可扩展性的高质量软件,必须采用面向对象技术,而统一建模语言是面向对象分析与设计的重要工具,它支持系统开发的全过程。结合面向对象的建模方法,介绍了UML的结构和机制,并且通过实例对UML的建模机制做了系统的概述。     

水泥混凝土浆体 集料界面区结构与性能

混凝土浆体-集料界面区结构与性能影响混凝土的整体性能,是混凝土材料研究的热点之一。针对水泥混凝土浆体-集料界面区结构与性能特点,从混凝土界面区结构、性能、研究手段、改善方法及其对水泥混凝土性能影响等方面,综述了国内外水泥混凝土浆体-集料界面区结构与性能研究进展。总结了界面区结构特征与性能影响因素及微观和宏观两种界面区研究手段,分析界面区结构与性能差异原因及对混凝土整体性能影响程度,概括了矿渣粉和偶联剂等无机和有机两类界面区结构与性能改善方法,最后,提出混凝土界面区结构与性能研究重点和方向。     

Development and Application of Intelligent Prediction Software for Broken Rock Zone Thickness of Drifts

In order to seek the economical, practical and effective method of obtaining the thickness of broken rock zone, an emerging intelligent prediction method with adaptive neuro-fuzzy inference system (ANFIS) was introduced into the thickness prediction. And the software with functions of creating and applying prediction systems was developed on the platform of MATLAB6.5. The software was used to predict the broken rock zone thickness of drifts at Liangbei coal mine, Xinlong Company of Coal Industry in Xuchang city of Henan province. The results show that the predicted values accord well with the in situ measured ones. Thereby the validity of the software is validated and it provides a new approach to obtaining the broken zone thickness.     

集料与硅酸盐水泥石界面区的若干研究

利用XRD层析法和SEM研究了集料与硅酸盐水泥石界面区的组成、CH晶体取向指数等。实验结果表明,界面区中水化产物主要是C-S-H凝胶、CH晶体、AFt、孔隙以及未水化的熟料矿物;界面区中CH晶体发育良好,取向作用较强,界面处它以(001)面平行于集料表面生长;水化龄期增长或水灰比提高时,CH晶体取向作用增强,而且水灰比高时,界面区中孔洞、裂纹增多,降低界面粘结强度;水泥中掺入5.0%wt硅灰后,CH晶体取向作用下降;水泥中掺入5.0wt%FDN减水剂,由于水泥早期水化程度低,对水泥石-集料早期粘结强度不利,但28d后其粘结强度就能赶上并超过其它试样。