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富马酸二甲酯的催化合成 总被引:1,自引:0,他引:1
在反应的第一阶段,以阳离子树脂为催化剂,用马来酸酐和无水甲醇进行酯化反应得到马来酸二甲酯,反应混合物经分离去掉催化剂并干燥除水;在反应的第二阶段,向第一阶段的反应混合物中加入溴的四氯化碳溶液,经光照异构化得到富马酸二甲酯。研究表明,反应第一阶段的较佳条件是:马来酸酐14.7 g,无水甲醇20 mL,阳离子树脂1.5 g,70℃下回流反应5 h;反应第二阶段的较佳条件是:B r2/CC l4和λ=350 nm光照射,产率可达92.5%;实验证明,阳离子树脂催化剂具有良好的重复使用性能。 相似文献
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A novel polyurethane/acrylate (PUA) porous gel electrolyte was prepared by a new method, emulsion polymerization. Compared with the traditional phase inversion method, the new method can eliminate the pollution from solvent and decrease the cost of production. The swelling properties and morphology of the porous polymer membranes were characterized. The porous membranes, made by emulsion polymerization, could absorb large quantities of electrolyte solution to form porous gel electrolytes. The gel electrolytes have good solvent retention ability and high ionic conductivity. Copyright © 2004 Society of Chemical Industry 相似文献
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富马酸二甲酯合成研究进展 总被引:12,自引:0,他引:12
富马酸二甲酯是当前对黄曲霉菌抑制作用最佳的新型食品和饲料防霉、防腐剂。其使用安全 ,生产成本低。本文对近年来富马酸二甲酯的合成方法进行了评述。建议对近年开发的有应用前景的催化剂扩大试验与筛选。 相似文献
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壳聚糖硫酸盐催化合成富马酸二甲酯 总被引:4,自引:0,他引:4
以壳聚糖硫酸盐为催化剂 ,用富马酸与甲醇反应合成了富马酸二甲酯 (DMF) ,用正交实验确定了反应条件对DMF收率的影响。最佳工艺条件为 :反应时间为 6h ,甲醇与富马酸的摩尔比为 6∶1 ,催化剂用量为1 0 g ,DMF的最高收率可达 86 0 %。催化剂重复使用实验表明 ,该催化剂对DMF的合成具有较好的催化活性及重复使用性 相似文献
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富马酸二甲酯的合成新工艺研究 总被引:4,自引:0,他引:4
研究了以糠醛为原料,以KClO3为氧化剂,V2O5为催化剂制备富马酸,在固载杂多酸PW12/C催化下,富马酸和甲醇经过酯化反应合成富马酸二甲酯。考察了催化剂用量、氧化剂用量、反应时间和醇酸比对反应的影响,确定了最佳工艺条件。m(KClO3)∶m(糠醛)=1.8∶1,反应温度105℃,催化剂用量为0.2g时,反应时间4h,富马酸产率为80.7%;酯化反应中n(甲醇)∶n(富马酸)=7∶1,m(PW12/C)∶m(富马酸)=6∶100,回流反应6h,富马酸二甲酯产率达88.1%。 相似文献
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以异佛尔酮二异氰酸酯(IPDI)、聚对苯二甲酸-3-甲基-1,5-戊二醇酯二醇(TPA-1000)、聚乙二醇(PEG-2000)、一缩二乙二醇(DEG)为主要原料合成了一系列热塑型聚氨酯弹性体,然后加入20%的锂盐(LiTFSI)制备不同的全固态电解质(SPE)。结果表明,随着TPA-1000含量的减少和PEG-2000含量的增加,SPE的耐热性增加,玻璃化转变温度减小,拉伸强度减小,断裂伸长率增加。SPE的离子电导率与温度的关系基本符合Arrhenius方程,在80℃,SPE(除纯PEG-2000的电解质外)的电化学窗口均达到4.0V以上,其中质量比TPA-1000:PEG-2000=1:2(SPE4)综合性能最佳,力学为1.87Mpa、电导率为2.15?10-4 S cm-1、窗口为4.3V。以SPE4组装的全固态电池在80℃、0.2C下放电比容量为150 mAh/g。 相似文献
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Alternating current (AC) impedance, Fourier transform (FT)–Raman, and Fourier transform infrared (FTIR) have been conducted on solutions of poly(ethylene oxide)(MW=1000)–urethane electrolytes commingled with LiCF3SO3 as the function of temperature and salt concentration. From the analysis of the Vs(SO3) vibration, the ionic concentration of salt in various chemical environments can be calculated approximately. The spectroscopic evidence was found for the redissociated ion pairs, and ionic congeries increased with increasing temperature. AC impedance measurements is used to calculate the ionic diffusion coefficient (Di). Investigated the various concentrations (from O/Li = 4 ~ 20) at the different temperature (40 ~ 120°C), We found that the calculated values (Di) with the Nernst–Einstein equation are higher than the direct measurement. The discrepancy increases with the increase of temperature. A good correlation between the conductivity and the ionic redissociation is determined from the Vs(SO3) vibration band. The fraction of the “free” ion significantly corresponds to the revised Nernst–Einstein equation by using the Nernst–Einstein relation and compared with those direct measurement. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 785–790, 2002 相似文献
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Bing Yang Lai‐Xiang Zeng Lei Wang Xiao‐Zhen Tang Guo‐Hua Tian Bin Zhang 《应用聚合物科学杂志》2001,80(13):2502-2510
Solid poly(ethylene oxide)–urethane electrolytes were prepared from blends of polyurethane and NaClO4. The samples were characterized by FTIR, DSC, atomic force microscopy, and complex impedance analysis. The effect of the concentration of NaClO4 on the poly(ethylene oxide)–urethane/NaClO4 complex were studied. The results showed that the concentration of NaClO4 had an important effect on the ion–polymer interaction, ion–ion interaction, glass‐transition temperature, morphologic structure, and ionic conductivity of the complex. We also prepared a model compound of hard segments and found that the conductivity of the complex decreased when the model compound was blended into the complex. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 2502–2510, 2001 相似文献
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Low crosslinked copolymer of linear and hyperbranched polyurethane (CHPU) was prepared, and the ionic conductivities and thermal properties of the composite polymer electrolytes composed of CHPU and LiClO4 were investigated. The FTIR and Raman spectra analysis indicated that the polyurethane copolymer could dissolve more lithium salt than the corresponding polymer electrolytes of the non crosslinked hyperbranched polyurethane, and showed higher conductivities. At salt concentration EO/Li = 4, the electrolyte CHPU30‐LiClO4 reached its maximum conductivity, 1.51 × 10?5 S cm?1 at 25°C. DSC measurement was also used for the analysis of the thermal properties of polymer electrolytes. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 3607–3613, 2007 相似文献
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Hybrid solid polymer electrolytes (HSPE) of high ionic conductivity were prepared using polyethylene oxide (PEO), polyacrylonitrile (PAN), propylene carbonate (PrC), ethylene carbonate (EC), and LiClO4. These electrolyte films were dry, free standing, and dimensionally stable. The HSPE films were characterized by constructing symmetrical cells containing nonblocking lithium electrodes as well as blocking stainless steel electrodes. Studies were made on ionic conductivity, electrochemical reaction, interfacial stability, and morphology of the films using alternating current impedance spectroscopy, infrared spectroscopy, and scanning electron microscopy. The properties of HSPE were compared with the films prepared using (i) PEO, PrC, and LiClO4; and (ii) PAN, PrC, EC, and LiClO4. The specific conductivity of the HSPE films was marginally less. Nevertheless, the dimensional stability was much superior. The interfacial stability of lithium was similar in the three electrolyte films. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 65: 2191–2199, 1997 相似文献
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Sulfonated multiblock copolynaphthalimides (co-SPIs) with block length of 5-20 were prepared by a two-pot polymerization method from 1,4,5,8-naphthalenetetracarboxylic dianhydride, sulfonated diamines of 2,2′-bis(4-sulfophenoxy)benzidine (BSPOB) and 4,4′-bis(4-aminophenoxy)biphenyl-3,3′-disulfonic acid (BAPBDS) and nonsulfonated diamines. The scanning transmission electron microscopy showed that the BSPOB-based multiblock co-SPI membranes had well-defined microphase-separated structure where the hydrophilic and hydrophobic layer-like domains were oriented in the plane direction of membrane. On the other hand, the BAPBDS-based multiblock co-SPIs and all the random co-SPIs showed the homogeneous morphology. The water uptake, anisotropic membrane swelling, anisotropic proton conductivity and polymer electrolyte fuel cell (PEFC) performance were investigated for the multiblock and random co-SPIs. The results demonstrated strong effects of the membrane morphology on these properties. The BSPOB-based multiblock co-SPI membranes exhibited the larger through-plane swelling and the lower through-plane conductivity than the random ones, and as a result exhibited the lower PEFC performances. This study gives good understanding of the morphology-property relationship in novel block architectures' design. 相似文献