Compression creep rupture behavior of a glass/vinyl ester composite subject to isothermal and one-sided heat flux conditions

Given the expanding applications of polymer matrix composites to civil infrastructure, the marine industry, and the military, we examine the compression creep rupture behavior of a glass/vinyl ester composite subject to combined load and one sided heating simulating fire exposure. We focus on reversible non-linear viscoelastic effects which dominate delayed failure at lower temperatures in the vicinity of the glass transition temperature. A compression strength model which predicts local compression failure due to micro-buckling is extended to include viscoelasticity. Times to failure under combined mechanical load and one sided heating are estimated to within an order of magnitude.     

The response of a multi-directional composite laminate to through-thickness loading

The through-thickness mechanical response of a carbon fibre/epoxy laminated composite of lay-up [0/45/−45]_ns is measured at low rates of strain. Uniaxial tension and compression experiments are carried out on dogbone specimens cut from a thick laminate along different directions, and failure mechanisms are observed via optical and electron microscopy. The effect of direct and shear stresses at the ply interfaces on the onset of failure is measured, and a failure envelope is constructed. The compressive response of specimens of different shape is investigated. Composite beams of different volume and aspect ratios are tested to failure in three-point bending and these tests reveal a strong dependence of the apparent out-of-plane tensile strength of the composite on the beam volume; this effect is modelled by Weibull theory.     

Viscoelasticity, viscoplasticity, and creep failure of polypropylene/clay nanocomposites

Observations are reported on polypropylene/clay nanocomposites in tensile tests with various strain rates, relaxation tests at various strains, and creep tests with various stresses at room temperature. New constitutive equations are derived in viscoelasticity and viscoplasticity of nanocomposites. Adjustable parameters are found by fitting the experimental data. The stress–strain relations are applied to the analysis of creep rupture. It is demonstrated that reinforcement of polypropylene with 1 wt.% of nanoclay induces an increase in time to failure by an order of magnitude.     

Short-term creep behavior of a biodegradable polymer reinforced with wood-fibers

The short-time creep behavior at tensile and single cantilever mode of deformation for a series of biodegradable composites was thoroughly studied. The composites were based on a biodegradable polymer matrix consisted a blend of poly(butylene adipate-terephthalate) (PBAT) copolyester, produced by non-renewable resources, and Polylactic acid (PLA). The matrix was reinforced with three different wood fiber types, at 20 and 30 wt%. The experimental data were analyzed in terms of Findley's and Burger's viscoelastic models. The effect of stress and temperature and wood fiber type on the material's creep response was analytically studied, while the Burger's model parameters were related to the composites morphology. In all cases, the wood fibers improved the creep resistance of the composites.     

The tensile fatigue behaviour of a silica nanoparticle-modified glass fibre reinforced epoxy composite

An anhydride-cured thermosetting epoxy polymer was modified by incorporating 10 wt.% of well-dispersed silica nanoparticles. The stress-controlled tensile fatigue behaviour at a stress ratio of R = 0.1 was investigated for bulk specimens of the neat and the nanoparticle-modified epoxy. The addition of the silica nanoparticles increased the fatigue life by about three to four times. The neat and the nanoparticle-modified epoxy resins were used to fabricate glass fibre reinforced plastic (GFRP) composite laminates by resin infusion under flexible tooling (RIFT) technique. Tensile fatigue tests were performed on these composites, during which the matrix cracking and stiffness degradation was monitored. The fatigue life of the GFRP composite was increased by about three to four times due to the silica nanoparticles. Suppressed matrix cracking and reduced crack propagation rate in the nanoparticle-modified matrix were observed to contribute towards the enhanced fatigue life of the GFRP composite employing silica nanoparticle-modified epoxy matrix.     

A mechanism-based multi-scale model for predicting thermo-oxidative degradation in high temperature polymer matrix composites

This paper describes a mechanism-based multi-scale model for life prediction of high temperature polymer matrix composites (HTPMC) under thermo-oxidative aging conditions. The multi-scale model incorporates molecular level damage such as inter-crosslink chain scission in a thermoset polymer due to thermo-oxidative aging of the polymer resin. The degradation of inter-laminar stress depends on remaining inter-crosslink density of thermo-set polymer in fiber/matrix interface region subjected to thermo-oxidative aging environment. The degradation of inter-laminar shear stress of thermo-oxidatively aged unidirectional IM-7/PETI-5 composite specimens at 300 °C was modeled using an in-house test-bed FEA code (NOVA-3D). A micromechanics based viscoelastic cohesive layer model was used to model delamination. The model is fully rate dependent and does not require a pre-assigned traction-separation law. Viscoelastic regularization of the constitutive equations of the cohesive layer used in this model not only mitigates numerical instability, but also enables the analysis to follow load-deflection behavior beyond peak failure load. The model was able to successfully simulate delamination failure in thermo-oxidatively aged unidirectional IM-7/PETI-5 composite, and the model predictions were verified using test data.     

Evaluation of the mechanical behavior of epoxy composite reinforced with Kevlar plain fabric and glass/Kevlar hybrid fabric

In this study, composite plates were manufactured by hand lay-up process with epoxy matrix (DGEBA) reinforced with Kevlar fiber plain fabric and Kevlar/glass hybrid fabric, using to an innovative architecture. Results of the mechanical properties of composites were obtained by tensile, bending and impact tests. These tests were performed in the parallel direction or fill directions of the warp and in a 90° direction. FTIR was used in order to verify the minimum curing time of the resin to perform the mechanical tests, and scanning electron microscopy was used to observe reinforcement and matrix fractures. Composites with Kevlar/glass hybrid structure in the reinforcing fabric showed the better results with respect to specific mechanical strength, as well as bending and impact energy.     

Fatigue crack growth behavior of silica particulate reinforced epoxy resin composite

In the present work, fatigue crack growth tests of epoxy resin composite reinforced with silica particle under various R-ratios were carried out to investigate the effect of R-ratio on crack growth behavior and to discuss fatigue crack growth mechanism. Crack growth curves arranged by ΔK showed clear R-ratio dependence even under no crack closure, where the values of ΔK_th were 0.82 and 0.33 MPa √m for R = 0.1 and 0.7 respectively. However, crack growth curves arranged by K_max merged into almost one curve regardless of R-ratio, which indicated that crack growth behavior of the present composite was time-dependent. The value of K_max,th were in the range from 0.78 to 1.12 MPa √m. In situ crack growth observation revealed the crack growth mechanism: micro-cracking near the interface between silica particle and resin matrix occurs ahead of a main crack and then micro-cracks coalesce with a main crack to grow. The crack path was in the epoxy matrix, which was consistent with the time-dependent crack growth.     

Creep behavior of polyurethane nanocomposites with carbon nanotubes

The polyurethane (PU) nanocomposites containing carbon nanotubes (CNTs) were prepared through in situ polymerization for the creep study. The results show that the presence of CNTs leads to a significant improvement of creep resistance of PU. However, this creep resistance does not increase monotonously with increase of CNT contents because it is highly dependent on the dispersion of CNTs. Several theoretical models were then used to establish the relations between CNT dispersion and final creep and creep–recovery behaviors of nanocomposites. The as-obtained viscoelastic and viscoplastic parameters of PU matrix and structural parameters of CNTs further confirmed the retardation effect by CNTs during creep of the nanocomposite systems. Besides, the time–temperature superposition (TTS) principle was also employed in this work to make a further evaluation on the creep of PU/CNT nanocomposites with long-term time scale.     

Imaging microstructure and stress fields within a cross-ply composite laminate

Microfocus X-ray diffraction can be used in a scanning acquisition mode to image a fibre reinforced composite material in terms of a range of different parameters. This includes microstructural information, as well as detail of emerging stress fields around open hole geometries. In this study, the in situ deformation of a cross-ply laminate specimen is investigated. The results show a number of interesting phenomena related to stress transfer in such systems. This includes stress concentrations in fibres adjacent to the open hole and local shear forces acting upon fibres perpendicular to the deformation axis. In addition to imaging the sample, the technique also allows a number of mechanical parameters to be estimated. This includes transverse strain and longitudinal stiffness. Using isotropic elasticity theory, the stress concentration tangential to the open hole can be determined analytically.     

Compressive response of Z-pinned woven glass fiber textile composite laminates: Experiments

In the first of this two part sequel, experimental results pertaining to the compressive response and failure of Z-pinned S-Glass fiber, plain-weave laminated composites are presented. These experiments are motivated by a need to understand the effect of Z-pinning on the strength and stiffness of these composites. A series of experiments are performed based upon density of the Z-pins and the diameter of the Z-pins. It is concluded that the damage zone around a Z-pin plays an important role in influencing the stiffness and strength of the Z-pin composite. In part 2 of this sequel, a 3D finite element (FE) based numerical model (based upon the composite microstructure acquired from scanning electron micrograph-SEM images) are used to capture details of the observed failure mechanisms and to provide predictions of the stiffness and strength of the composite.     

Dynamic response of full-scale sandwich composite structures subject to air-blast loading

Glass-fibre reinforced polymer (GFRP) sandwich structures (1.6 m × 1.3 m) were subject to 30 kg charges of C4 explosive at stand-off distances 8–14 m. Experiments provide detailed data for sandwich panel response, which are often used in civil and military structures, where air-blast loading represents a serious threat. High-speed photography, with digital image correlation (DIC), was employed to monitor the deformation of these structures during the blasts. Failure mechanisms were revealed in the DIC data, confirmed in post-test sectioning. The experimental data provides for the development of analytical and computational models. Moreover, it underlines the importance of support boundary conditions with regards to blast mitigation. These findings were analysed further in finite element simulations, where boundary stiffness was, as expected, shown to strongly influence the panel deformation. In-depth parametric studies are ongoing to establish the hierarchy of the various factors that influence the blast response of sandwich composite structures.     

A generic approach to constitutive modelling of composite delamination under mixed-mode loading conditions

A generic approach to constitutive modelling of composite delamination under mixed mode loading conditions is developed. The proposed approach is thermodynamically consistent and takes into account two major dissipative mechanisms in composite delamination: debonding (creation of new surfaces) and plastic/frictional deformation (plastic deformation of resin and/or friction between crack surfaces). The coupling between these two mechanisms, experimentally observed at the macro scales through the stiffness reduction and permanent crack openings, is usually not considered in depth in many cohesive models in the literature. All model parameters are shown to be identifiable and measurable from experiments. The model prediction of mixed-mode delamination is in good agreement with benchmarked mixed-mode bending experiments. It is further shown that accounting for all major dissipative mechanisms in the modelling of delamination is the key to the accurate prediction of both resistance and damage of the interface.     

Fractographic observations on delamination growth and the subsequent migration through the laminate

This paper describes fractographic observations from the detailed examination of delamination fracture surfaces and offers an interpretation of the key growth mechanisms. Firstly, the relationship between toughness, delamination failure criteria and fracture morphology is presented and the influence of cusp formation and deformation on toughness is discussed. Observations regarding delaminations migrating through the lamina at multidirectional ply interfaces are then discussed. It is demonstrated how this migration process can be avoided in fracture toughness coupons and consequently the toughness of multidirectional ply interfaces can be characterised. The influence of migration on delamination growth from embedded defects in laminates under compression is presented, and these results are extended to demonstrate how migration influences damage growth in structures. The paper concludes by making recommendations for realistic modelling of migration, and suggests how it can be exploited in damage tolerant structural design.     

Estimation of thermal conductivity for polypropylene/hollow glass bead composites

The thermal conductivity of hollow glass bead (HGB)-filled polypropylene (PP) composites was estimated using the thermal conductivity equation of inorganic hollow microsphere-filled polymer composites published in the previous paper. The estimations were compared with the measured data of the PP composites filled with two kinds of HGB with different size (the mean diameter was respectively 35 μm and 70 μm). The results showed that the predictions of the thermal conductivity were in good agreement with the measured data except to individual data points. Furthermore, both the estimated and measured thermal conductivity decreased roughly linearly with increasing the HGB volume fraction when the HGB volume fraction was less than 20%; the influence of the particle diameter on the thermal conductivity was insignificant.     

Cryogenic delamination growth in woven glass/epoxy composite laminates under mixed-mode I/II fatigue loading

This paper investigates the fatigue delamination growth behavior in woven glass fiber reinforced polymer (GFRP) composite laminates under mixed-mode I/II conditions at cryogenic temperatures. Fatigue delamination tests were performed with the mixed-mode bending (MMB) test apparatus at room temperature, liquid nitrogen temperature (77 K) and liquid helium temperature (4 K), in order to obtain the delamination growth rate as a function of the range of the energy release rate, and the dependence of the delamination growth behavior on the temperature and the mixed-mode ratio of mode I and mode II was examined. The energy release rate was evaluated using three-dimensional finite element analysis. The fractographic examinations by scanning electron microscopy (SEM) were also carried out to assess the mixed-mode fatigue delamination growth mechanisms in the woven GFRP laminates at cryogenic temperatures.     

Deformation micromechanics of a model cellulose/glass fibre hybrid composite

Interfacial stress transfer in a model hybrid composite has been investigated. An Sm³⁺ doped glass fibre and a high-modulus regenerated cellulose fibre were embedded in close proximity to each other in an epoxy resin matrix dumbbell-shaped model composite. This model composite was then deformed until the glass fibre fragmented. Shifts of the absolute positions of a Raman band from the cellulose fibre, located at 1095 cm⁻¹, and a luminescence band from a doped glass fibre, located at 648 nm, were recorded simultaneously. A calibration of these shifts, for both fibres deformed in air, was used to determine the point-to-point distribution of strain in the fibres around the breaks in the glass fibre. Each break that occurred in the glass fibre during fragmentation was shown to generate a local stress concentration in the cellulose fibre, which was quantified using Raman spectroscopy. Using theoretical model fits to the data it is shown that the interfacial shear stress between both fibres and the resin can be determined. A stress concentration factor (SCF) was also determined for the regenerated cellulose fibre, showing how the presence of debonding reduces this factor. This study offers a new approach for following the micromechanics of the interfaces within hybrid composite materials, in particular where plant fibres are used to replace glass fibres.     

A progressive failure model for mesh-size-independent FE analysis of composite laminates subject to low-velocity impact damage

An original, ply-level, computationally efficient, three-dimensional (3D) composite damage model is presented in this paper, which is applicable to predicting the low velocity impact response of unidirectional (UD) PMC laminates. The proposed model is implemented into the Finite Element (FE) code ABAQUS/Explicit for one-integration point solid elements and validated against low velocity impact experimental results.     

Dynamic mechanical analysis of fumed silica/cyanate ester nanocomposites

Fumed silica particles with average primary particle diameters of 12 and 40 nm were combined with a low viscosity bisphenol E cyanate ester resin to form composite materials with enhanced storage modulus and reduced damping behavior, as evidenced by dynamic mechanical analysis (DMA). The storage modulus increased with volume fraction of fumed silica in both the glassy and rubbery regions, but the increase was more pronounced in the rubbery region. The maximum increase in storage modulus in the glassy region was 75% for 20.7 vol% of 40 nm fumed silica, while the same composition showed a 231% increase in the rubbery storage modulus. Furthermore, decreases in damping behavior were used to estimate the effective polymer-particle interphase thickness. The glass transition temperature of the nanocomposites was not changed significantly with increasing volume fraction.