共查询到17条相似文献,搜索用时 109 毫秒
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对ISO 10634-1995“水质———水介质中用于难溶有机物生物降解性能评价水溶液的制备与处理指南”推荐的方法进行逐一筛选,以期建立油溶性表面活性剂生物降解度测定的标准方法。实验结果表明,将油溶性表面活性剂超声乳化后,制备成粒径200 nm~300 nm乳液后,立即分散于水体系中进行降解,结果重复性较好,并且不影响油溶性表面活性剂生物降解度。用该方法对常见的油溶性表面活性剂的生物降解度进行了测定,结果表明大部分油溶性表面活性剂具有很好的生物降解性能;其降解规律与水溶性表面活性剂类似,疏水链长决定油溶性表面活性剂的生物降解性能,而亲水基团影响其生物降解速度。 相似文献
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《中国洗涤用品工业》2017,(8)
简述了表面活性剂对环境的影响及研究进展。着重讨论了表面活性剂的研究方法及表征,各种生物降解过程、降解机理和影响表面活性剂生物降解的因素。并对表面活性剂的安全性及毒性、温和性及对皮肤和黏膜的刺激性进行了简要介绍。 相似文献
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可生物降解——表面活性剂发展的瓶颈与机遇 总被引:2,自引:0,他引:2
介绍了表面活性剂生物降解的定义、分类及其重要性.详述了表面活性剂生物降解的实验方法、表面活性剂结构与生物降解之间的关系和国内外有关表面活性剂生物降解标准与法规的现状及发展趋势.分析了表面活性剂行业面临的问题,提出了促进可持续发展的建议. 相似文献
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Qingbin Dong Yonghong Zhao Guangliang Zhang Yingjie Ren 《Journal of surfactants and detergents》2016,19(6):1327-1332
This investigation was performed to determine the anaerobic biodegradation of alkyl ethoxy glucoside (AEG) nonionic surfactants using the OECD 311 method. The influence of different initial concentrations of AEG on the primary biodegradation rate was investigated using the anthrone analysis method. The results show that different initial concentrations have similar good biodegradability and the biodegradation rate can reach more than 90 % even at the highest initial concentration of 100 mg/l. Alkyl polyglucoside (APG) surfactants have previously been confirmed as readily biodegradable. The profile of concentration changes over the incubation time of AEG and APG had similar trends. Therefore, AEG are also considered as readily biodegradable. The gas chromatograph‐mass spectrometer analytical method was used to identify the metabolites. The content of alcohol ethoxylate (AEO) increased with decrease in the number of AEG at the initial stage of degradation. It was found that AEO with longer EO chains disappeared first. Accordingly, a degradation pathway that accounts for the experiment results was proposed. 相似文献
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Mao Z Zheng XF Zhang YQ Tao XX Li Y Wang W 《International journal of molecular sciences》2012,13(1):491-505
Nonylphenol (NP) is an ultimate degradation product of nonylphenol polyethoxylates (NPE) that is primarily used in cleaning and industrial processes. Its widespread use has led to the wide existence of NP in various environmental matrices, such as water, sediment, air and soil. NP can be decreased by biodegradation through the action of microorganisms under aerobic or anaerobic conditions. Half-lives of biodegradation ranged from a few days to almost one hundred days. The degradation rate for NP was influenced by temperature, pH and additions of yeast extracts, surfactants, aluminum sulfate, acetate, pyruvate, lactate, manganese dioxide, ferric chloride, sodium chloride, hydrogen peroxide, heavy metals, and phthalic acid esters. Although NP is present at low concentrations in the environment, as an endocrine disruptor the risks of long-term exposure to low concentrations remain largely unknown. This paper reviews the occurrence of NP in the environment and its aerobic and anaerobic biodegradation in natural environments and sewage treatment plants, which is essential for assessing the potential risk associated with low level exposure to NP and other endocrine disruptors. 相似文献
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Juan Carlos Quintero Maria Teresa Moreira Gumersindo Feijoo Juan M Lema 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(9):1005-1015
The extensive utilization of hydrophobic organic compounds (HOCs) such as pesticides generates high environmental pollution levels. Due to their hydrophobicity, this type of compound tends to accumulate in soil organic matter and, thus, soil desorption limits their availability for microbial degradation. The use of surfactants may increase the pollutant's desorption from the soil. One of the pesticides with strong sorption characteristics is hexachlorocyclohexane (HCH), a mixture of isomers: α‐, β‐, γ‐ and δ‐HCH. In this work, we evaluated the use of three surfactants, Triton X100, Tween 80 and sodium dodecyl sulfate (SDS), on the HCH desorption from a sandy loam soil. The effects of the addition of these surfactants on anaerobic biodegradation were studied. To attain this purpose, different assays were performed to evaluate both effects. Triton X100 exerted the best desorption of HCH isomers, followed by Tween 80, whereas SDS caused no significant desorption of the isomers. Triton had a strong inhibitory effect on the HCH biodegradation, while Tween 80 did not decrease the degradation rates of the different isomers. Moreover, the degradation rates of β‐ and δ‐HCH were significantly enhanced (around 10%). On the other hand, detrimental effects on the biodegradation rates and yields were due to the ageing of the soil, depending on the period of exposure of the soil to the pollutant. Copyright © 2005 Society of Chemical Industry 相似文献
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Manuela Lechuga Alejandro Fernández-Arteaga Mercedes Fernández-Serrano Encarnación Jurado Alejandro Burgos Francisco Ríos 《Journal of surfactants and detergents》2014,17(2):363-370
This study investigated the extent of primary and final biodegradation of anionic and non-ionic surfactants to evaluate the combined use of ozonation and biodegradation in surfactant removal. The surfactants used were alkylpolyglucosides and linear alkyl benzene sulfonates. The anionic surfactant containing a benzene ring on its structure was oxidized faster than was the non-ionic surfactant. Both surfactants showed poor mineralization due to ozonation indicating an ozone attack primarily on carbon bonds. The results indicate that the removal of surfactants and of the total organic carbon is increased by the consecutive use of ozonation and biodegradation. 相似文献
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L. Kravetz 《Journal of the American Oil Chemists' Society》1981,58(1):58A-65A
The biodegradation of alcohol ethoxylates (AE) and alkylphenol ethoxylates (APE) is reviewed. Biodegradation test methods,
ranging from laboratory tests to full-scale waste treatment plant studies are described for these surfactants. A comparison
is made between primary and ultimate biodegradability criteria and the limitations of the various analytical methods used
in these determinations are discussed. The most recently published data suggest sewage bacteria degrade AE by a mechanism
which is different from that by which APE degrades. The use of radiolabeled surfactants to elicit more detailed information
about the biodegradation mechanisms of AE is described. The role of biodegradation on the impact of surfactants released to
the environment is assessed, and future environmental concerns for nonionics are considered. 相似文献