共查询到19条相似文献,搜索用时 109 毫秒
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在合成原料浓度较高的情况下,利用水热合成的方式制备得到了α-Fe2O3纳米棒,有效提高了水热合成纳米粉末的产量,利用超声处理的方式将团聚的α-Fe2O3纳米棒进行了有效分离,利用X射线衍射(XRD)、傅里叶红外光谱(FTIR)和场发射扫描电镜(SEM)对样品进行了物相分析和形貌观察,测试这种纳米材料在不同温度下对丙酮的气敏性能,通过这种方法制备得到的气敏材料对丙酮具有良好的响应特性,具有工作温度低、检测极限低、选择性和稳定性良好等优势。 相似文献
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分析了微波烧结的原理和特点,并将其引入气敏元件的制备工艺中,研究微波烧结工艺对纯纳米ZnO厚膜阵列元件的气敏性和稳定性的影响.实验表明:微波烧结ZnO厚膜时间越长,厚膜电导和敏感性越小.在20,40,60 min 3种烧结对比中,20 min烧结的元件具有最好的敏感性和最低的最佳敏感温度,60min烧结的元件具有最好的稳定性.可见微波烧结可以有效调控气敏元件的敏感性和稳定性,是一种值得推广的新的气敏元件的制备技术. 相似文献
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采用Zn(CH3COO)2·2H2O和Fe(NO3)3·9H2O分别作为水热反应的锌源和铁源制备得到了ZnFe2O4纳米片状中空球。利用硼氢化钠和氯铂酸作为原料在常温下将不同质量分数的Pt混合到ZnFe2O4纳米粉末中。利用X射线衍射(XRD)、透射电镜(TEM)和场发射扫描电镜(SEM)对样品进行了物相分析和形貌观察。分析了不同Pt质量分数的Pt-ZnFe2O4气敏层在不同温度下对丙酮的气敏性能,通过Pt激活的ZnFe2O4纳米粉末较未激活时对丙酮的气敏性能有了显著提高,具有工作温度低、选择性好和湿度稳定性好等优势。 相似文献
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将4种质量分数(5%,10%,20%,30%)的Co(CH3COO)24H2O混合到四针状纳米ZnO原料里,采用超声化学浸泡法制备出表面改性四针状纳米ZnO颗粒。通过XRD和TEM分析了表面改性四针状纳米ZnO结构的物相和形貌特征。随着Co(CH3COO)24H2O质量分数增大,Co3O4相明显出现,Co3O4相沉积在ZnO表面上。研究表明:以表面改性四针状纳米ZnO粉末为原料制备的厚膜气敏元件,与纯ZnO气敏元件相比,Co(CH3COO)24H2O质量分数为5%的气敏元件对酒精和甲醇有较高的灵敏度,并讨论了表面改性对气敏性能的影响。 相似文献
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本文采用溶剂热法制备了双金属Zn-Fe金属有机框架结构(Zn-Fe MOF),利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射仪(XRD)对其微观形貌和晶相进行表征分析。结果表明:制备的双金属Zn-Fe MOF为纳米球结构,其直径约为150 nm。同时,制备了基于双金属Zn-Fe MOF材料的气体传感器件,研究了其对丙酮的气敏特性。测试结果表明:基于双金属Zn-Fe MOF的气体传感器对丙酮的最佳工作温度为210 ℃。在最佳工作温度下,对浓度为1×10-6的丙酮气体响应可达到2,响应/恢复时间分别为6 s / 13 s,且具有较好的重复性和长期稳定性。最后,对基于双金属Zn-Fe MOF气体传感器的气敏机理进行了讨论。 相似文献
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Li LiuAuthor Vitae Shouchun LiAuthor VitaeJuan ZhuangAuthor Vitae Lianyuan WangAuthor VitaeJinbao ZhangAuthor Vitae Haiying LiAuthor VitaeZhen LiuAuthor Vitae Yu HanAuthor VitaeXiaoxue JiangAuthor Vitae Peng ZhangAuthor Vitae 《Sensors and actuators. B, Chemical》2011,155(2):782-788
Pure and Co-doped (0.3 wt%, 0.5 wt%, and 1 wt%) ZnO nanofibers are synthesized by an electrospinning method and followed by calcination. The as-synthesized nanofibers are characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy dispersive X-ray (EDX) spectroscopy. Comparing with pure ZnO nanofibers, Co-doped nanofibers exhibit improved acetone sensing properties at 360 °C. The response of 0.5 wt% Co-doped ZnO nanofibers to 100 ppm acetone is about 16, which is 3.5 times larger than that of pure nanofibers (about 4.4). The response and recovery times of 0.5 wt% Co-doped ZnO nanofibers to 100 ppm acetone are about 6 and 4 s, respectively. Moreover, Co-doped ZnO nanofibers can successfully distinguish acetone and ethanol/methanol, even in a complicated ambience. The high response and quick response/recovery are based on the one-dimensional nanostructure of ZnO nanofibers combining with the Co-doping effect. The selectivity is explained by the different optimized operating temperatures of Co-doped ZnO nanofibers to different gases. 相似文献
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Minggang ZhaoAuthor VitaeXinchang WangAuthor Vitae Lingling NingAuthor VitaeJianfeng JiaAuthor Vitae Xinjian LiAuthor VitaeLiangliang CaoAuthor Vitae 《Sensors and actuators. B, Chemical》2011,156(2):588-592
Pure and Cu-doped ZnO nanofibers were synthesized via electrospinning technology. The morphology and structure of the as-synthesized nanofibers were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and Raman spectroscopy. The effects of Cu doping on H2S sensing properties at low concentration (1-10 ppm) were investigated at 230 °C. The results show that the H2S sensing properties of ZnO nanofibers are effectively improved by Cu doping: 6 at% Cu-doped ZnO nanofibers show a maximum sensitivity to H2S gas, and the response to 10 ppm H2S is one order of magnitude higher than the one of pure ZnO nanofibers. 相似文献
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通过离子交换技术对衬底表面改性,然后喷墨打印掩膜图形,在聚酰亚胺衬底两面分别制备了银叉指电极和加热电阻.通过调节电阻加热器两端的直流偏压,实现25 ℃~280 ℃的控温加热.集成的加热器具有双重功能:纳米ZnO敏感薄膜原位沉积和高温检测.结果表明,该传感器对丙酮气体的灵敏度随温度单调增加(<150 ℃).此外,加热器促进了ZnO敏感薄膜表面丙酮气体分子的解吸,缩短了传感器响应和恢复时间,并减小了初始电阻的漂移.此外,在丙酮检测中,加热器能有效地减少湿度干扰. 相似文献
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研究以贵金属Pd作为掺杂剂的ZnO纳米线敏感元件的乙醇气敏性能。采用水热法在叉指电极上直接制备出具有c轴取向的ZnO多晶纳米线。用SEM,XRD和EDS分析手段观测了材料的微观结构,并对其乙醇气敏性能进行了测试。实验结果表明:对于体积分数为200×10-6的乙醇气体,Pd掺杂的ZnO纳米线在灵敏度(8.17)、工作温度(325℃)和响应恢复时间(15,8s)上优于纯的ZnO纳米线。最后,对Pd掺杂的气敏机理进行了讨论。 相似文献
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提出了一种环保、高效、低成本的传感器制作方法.应用等离子体射流喷枪沉积ZnO半导体材料,其中等离子体射流喷枪的气源为N2,电源采用输出频率为20 kHz的高频高压电源.使用Zn(NO3)2的水溶液作为前驱物,经过雾化装置形成气溶胶,气溶胶在等离子体的氛围中成功在衬底上沉积出一层ZnO半导体材料,通过XRD、SEM、UV-Vis等对其进行表征分析.并对基于该方法制备的ZnO湿度传感器性能进行表征.ZnO沉积时间为5 min时的灵敏度最高,低湿和高湿下分别为0.435 pF/% RH和19.634 pF/% RH,同时该样品的迟滞、响应时间与恢复时间亦是最优. 相似文献
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Kewei LiuAuthor Vitae Makoto SakuraiAuthor Vitae Masakazu AonoAuthor Vitae 《Sensors and actuators. B, Chemical》2011,157(1):98-102
Pinecone-shaped ZnO nanostructures have been fabricated on Si substrate by pulsed laser deposition. The scanning electron microscope images showed that pinecone-shaped ZnO nanostructure was 6-fold symmetry and has the rough surface on one end. X-ray diffraction, Raman spectra and X-ray photoelectron spectroscopy indicated that the ZnO nanostructures have high crystal quality and a large amount of surface states. Compared with ZnO nanowires and nanobelts, the oxygen gas sensor based on pinecone-shaped ZnO nanostructures has excellent selectivity, fast response and recover, and lower operating temperature. Meanwhile, the response properties are very stable over several circles. 相似文献