Analysis of the potential production and the development of bioenergy in the province of Mendoza – Bio-fuels and biomass – Using geographic information systems

In this work, the partial results of the potential production of energy, starting from the biomass and the development of the crops, directed to the production of bio-fuels (Colza and Topinamur) in the North irrigation oasis of Mendoza, Argentina within the National Program of Bio-energy developed by INTA is presented.     

Scenarios for biofuel demands,biomass production and land use – The case of Denmark

The land potential for producing biomass for bioenergy purposes has been highly debated in recent years. The present paper analyses the possibilities and consequences for land use and agricultural production of biofuel production in Denmark based on domestic wheat and rape under specific scenario conditions for the period 2010–2030. The potential is assessed for a situation where policy targets for renewable energy carriers in the transport sector is reached using biofuels, and where second generation ethanol increasingly substitutes first generation ethanol.Three scenarios are developed and evaluated: a baseline, an alternative scenario allowing continuous growth in the now dominant livestock branch and a biofuel scenario assuming that efforts to achieve self-sufficiency in biofuel displaces part of the domestic production of fodder.Results show that the biofuel demand could be met in 2020; but only if current rape oil production is used to satisfy local bio-diesel demand. It would also imply that the Danish bio-diesel export currently supplying a minor part of the German fuel market would seize. In 2030, however, only about 60 percent of the biofuel demand would be covered by self-sufficiency. If biofuels were to displace animal production to make up for this, a reduction of the pig production between 10 and 20 percent would result. Efficiency increases across production branches would allow the animal production to continue un-affected if about half of the rape oil produced for other purposes is utilized.     

Characterization and performance evaluation of Pt–Ru electrocatalysts supported on different carbon materials for direct methanol fuel cells

The paper addresses the effect of the carbon support on the microstructure and performance of Pt–Ru-based anodes for direct methanol fuel cells (DMFC), based on the study of four electrodes with a carbon black functionalized with HNO₃, a mesoporous carbon (CMK-3), a physical mixture of TiO₂ and carbon black and a reference carbon thermally treated in helium atmosphere (HeTT). It is shown that CMK-3 hinders the growth of the electrocatalyst nanoparticles (2.7 nm) and improves their distribution on the support surface, whereas the oxidized surfaces of HNO₃ carbon and TiO₂+carbon lead to larger (4–4.5 nm), agglomerated particles, and the lowest electrochemical active areas (54 and 26 m² g⁻¹, in contrast with 90 m² g⁻¹ for CMK-3), as determined from CO stripping experiments. However, HNO₃ and TiO₂ are characterized by the lowest CO oxidation potential (0.4 V vs. RHE), thus suggesting higher CO tolerance for the se electrodes. Tests in DMFC configuration show that the three modified electrodes have clearly better performance than the reference HeTT. The highest power density attained with electrodes supported on carbon treated with HNO₃ (65 mW cm⁻²/300 mA cm⁻² at 90 °C) and the equally interesting performance of the TiO₂-based electrodes (53 mW cm⁻²/300 mA cm⁻²), is a strong indication of the positive effect of the presence of oxygenated groups on the methanol oxidation reaction. The results are interpreted in order to identify separate microstructural (electrocatalyst particle size, porosity) and compositional (oxygenated surface groups, presence of oxide phase) effects on the electrode performance.     

Application of a multicriteria methodology for evaluation of energy alternatives for hydrogen production for the automotive sector – Case study

This paper presents a case study focusing on fourteen most used energy alternatives in Brazil, possible to feed large scale hydrogen production plants for the automotive sector. The evaluations are made using a Decision Making Support Method, MACBETH - Measuring Attractiveness by a Categorical Based Evaluation Technique, with the computational code M-MACBETH 3.2.0, using criteria that include economic and financial, technological, environmental and social aspects. The selected criteria that were used in the assessment, for each of the energy alternatives are capital to be invested in a plant, leveled cost of electric energy produced, CO₂ emissions, mortality rate due to the technology use and energy efficiency of technology. The main results obtained showed that photovoltaics off grid electric energy is the most attractive alternative, followed by the photovoltaic on grid alternative, for an eventual automotive hydrogen program in Brazil.     

Transient safety evaluation of the heat pipe microreactor – Potential energy source for hydrogen production

Recently, microreactor designs have been receiving significant attention in the nuclear industry due to their potential advantages in certain applications. These nuclear reactor designs have been considered to provide reliable and sustainable power for on-site installation and operation. Microreactors may be utilized to provide heat and power to hydrogen production, remote communities, and industrial facilities such as military installations, disaster relief zones, and are being considered for underwater and deep space operation as well. However, these designs and concepts remain largely untested and unproven in the commercial industry. Further research and development are still required to prove microreactor designs are safe and reliable for commercial use. Different cooling technologies have been taken into consideration for microreactor concepts since the 1960s, mainly for federal space reactor projects such as LEGOLRCS, HOMER, and KRUSTY. This work provides thermal hydraulics and analysis for the Idaho National Laboratory's MAGNET (Micro-reactor Agile Non-nuclear Experimental Testbed) facility. The MAGNET facility is currently being developed to duplicate a microreactor design using heat pipe cooling technology. Our main goal is to examine the response of the test facility under steady-state and transient operation conditions. We constructed our own estimated model of the MAGNET geometry using a software coupling method made up of MOOSE/SAM software systems. The steady state results of this work have been published in a former article. The new results mainly focus on the transient states. By communicating with the Idaho National Laboratories, we upgraded the geometry of MAGNET heat pipes. This not only verifies the design of the facility under such conditions but also benchmarks the modeling capability of the MOOSE/SAM code system that can be potentially used to model other microreactor concepts in the future.     

Multi-scale complexities of solid acid catalysts in the catalytic fast pyrolysis of biomass for bio-oil production – A review

Despite remarkable progress in catalytic fast pyrolysis, bio-oil production is far from commercialization because of multi-scale challenges, and major constraints lie with catalysts. This review aims to introduce major constraints of acid catalysts and simultaneously to find out possible solutions for the production of fuel-grade bio-oil in biomass catalytic fast pyrolysis. The catalytic activities of several materials which act as acid catalysts and the impacts of Bronsted and Lewis acid site on the formation of aromatic hydrocarbons are discussed. Considering the complexity of catalytic fast pyrolysis of biomass with acid catalysts, in-depth understandings of cracking, deoxygenation, carbon-carbon coupling, and aromatization for both in-situ and ex-situ configurations are emphasized. The limitation of diffusion along with coke formation, active site poisoning, thermal/hydrothermal deactivation, sintering, and low aromatics in bio-oil are process complexities with solid acid catalysts. The economic viability of large-scale bio-oil production demands progress in catalyst modification or/and developing new catalysts. The potential of different catalyst modification strategies for an adequate amount of acid sites and pore size confinement is discussed. By critically evaluating the challenges and potential of catalyst modification techniques, multi-functional catalysts may be an effective approach for selective conversion of biomass to bio-oil and chemicals through catalytic fast pyrolysis. This review offers a scientific reference for the research and development of catalytic fast pyrolysis of biomass.     

Influence of the structural and surface characteristics of activated carbon on the catalytic decomposition of hydrogen iodide in the sulfur–iodine cycle for hydrogen production

Coal-based activated carbon (AC-COAL) catalysts subjected to acid treatment were tested to evaluate their performance on hydrogen-iodide (HI) decomposition for hydrogen production in sulfur-iodine (SI or IS) cycle. The effects of acid treatment on catalysts and the relations between sample properties and catalytic activities were discussed. The AC-COAL obtained by non-oxidative acid treatments had the best catalytic activity. However, the catalytic activity of AC-COAL decreased after the treatment of nitric acid. Higher surface area, higher carbon contents, lower ash contents and fewer surface oxidation groups contributed to the catalytic activity of ACs. HI decomposition on the AC surface itself may be due to high densities of unpaired electrons associated with structural defects and edge plane sites with similar structural ordering. Moreover, the oxygen-containing groups reduced the electron transfer capability associated with the basal plane sites.     

Opposite effects of self-growth amorphous carbon and carbon nanotubes on the reforming of toluene with Ni/α-Al2O3 for hydrogen production

Ni-based catalysts are prone to be deactivated by carbon deposition. This study aims to investigate the influence mechanism of different types of carbon deposition on the activity of Ni/α-Al₂O₃ catalyst at various steam-to-carbon (S/C) ratios during steam reforming of toluene for hydrogen production. At a low S/C ratio of 1, the catalytic activity of Ni/α-Al₂O₃ was inhibited due to the covering and blocking of Ni active sites by the formation of amorphous carbon on the Ni surface. While at a high S/C ratio of 3, more than 80 wt% of carbon deposition was found to be self-growth carbon nanotubes (CNTs) with an average diameter of around 15 nm. The activity of Ni/α-Al₂O₃ in steam reforming of toluene was unusually promoted, which can be attributed to the tip-growth mechanism of CNTs, whereby the Ni particles migrated to the tip or the surface of CNTs, resulting in the improved active site dispersion.     

The impact of sustainability criteria on the costs and potentials of bioenergy production – Applied for case studies in Brazil and Ukraine

The goal of this paper is to analyse the impact of the implementation of a certification system on the management system (costs) of and the availability of land (quantity) for bioenergy production. Twelve socio-economic areas of concern (food supply, child labour, (minimum) wages, employment, health care and education) and environmental areas of concern (soil erosion, depletion of fresh water resources, nutrient losses and soil nutrient depletion, pollution from chemicals and biodiversity) are included. Since there is no generally accepted definition of sustainability, a loose and strict set of criteria are defined. Short rotation coppice (SRC) production systems in Ukraine and South East Brazil in 2015 are taken as case studies. The results indicate that it seems feasible to produce biomass for energy purposes at reasonable cost levels and meeting strict sustainability criteria at the same time. The loose set of criteria has no impact on the costs of energy crop production, which are calculated to be 1.7 € GJ^?1 in Brazil and 2.1 € GJ^?1 in Ukraine. The strict set of criteria results in an increase of the costs of energy crop production by 42 % in Brazil and 14 % in Ukraine. In general, compliance with strict socio-economic criteria has a limited impact on the costs, because SRC is relatively labour extensive. Strict environmental criteria likely have a larger impact.     

Metallic and carbonaceous –based catalysts performance in the solar catalytic decomposition of methane for hydrogen and carbon production

Solar catalytic decomposition of methane (SCDM) was investigated in a solar furnace facility with different catalysts. The aim of this exploratory study was to investigate the potential of the catalytic methane decomposition approach providing the reaction heat via solar energy at different experimental conditions. All experiments conducted pointed out to the simultaneous production of a gas phase composed only by hydrogen and un-reacted methane with a solid product deposited into the catalyst particles varying upon the catalysts used: nanostructured carbons either in form of carbon nanofibers (CNF) or multi-walled carbon nanotubes (MWCNT) were obtained with the metallic catalyst whereas amorphous carbon was produced using a carbonaceous catalyst. The use of catalysts in the solar assisted methane decomposition present some advantages as compared to the high temperature non-catalytic solar methane decomposition route, mainly derived from the use of lower temperatures (600–950 °C): SCDM yields higher reaction rates, provides an enhancement in process efficiency, avoids the formation of other hydrocarbons (100% selectivity to H₂) and increases the quality of the carbonaceous product obtained, when compared to the non-catalytic route.     

Assessing the impact of renewable energy sources on the electricity price level and variability – A quantile regression approach

The literature on renewable energy sources indicates that an increase of the intermittent wind and solar generation affects significantly the distribution of electricity prices. In this article, the influence of two types of renewable energy sources (wind and solar photo voltaic) on the level and variability of German electricity spot prices is analyzed. The quantile regression models are built to estimate the merit order effect for different quantiles of electricity prices. The results indicate that both types of renewable generations have a similar, negative impact on the price level, approximated by the price median. When the price volatility, measured by the inter-quantile range (IQR), is considered, the outcomes show that wind and solar influence prices differently. Conditional on the level of the total demand, the wind generation would either increase (when the demand is low) or decrease (when the demand is high) the IQR. Meanwhile, the increase of solar power stabilizes the price variance for moderate demand level. Thus, policy supporting the development and integration of RES should search for a balance between the wind and solar power.     

Investigation of the effect of carbon post- vs pre-coated metallic bipolar plates for PEMFCs – start-up and shut-down

In this work, the influence of increased potentials during the start-up/shut-down process on metallic bipolar plates (316L) with the coating system Cr/a-C based on graphite-like carbon is investigated. In comparison to commonly applied post-coated bipolar plates, a new low-cost manufacturing process based on pre-coated metal sheets for bipolar plates was evaluated. By developing a vehicle near start-up/shut-down cycle, a relative humidity of 140% and anode residence time of 0.94 s show the greatest damage potential of the cycle variations. After 2000 start-up/shut-down cycles, pre-coated metallic bipolar plates show no increased voltage loss compared to conventional coatings. Nevertheless, the resistances increase for Cr/a-C post- and pre-coating at the H₂ outlet. This correlates with an increased surface roughness of the bipolar plate but otherwise only minor surface changes can be observed. The coating variation has no effect on the extent of catalyst coated membrane thinning or increased content of metal ions.     

Directly growth of highly uniform MnS–MoS2 on carbon cloth for advanced H2 evolution electrocatalyst in different pH electrolytes

The activation energy barrier of the H–O bond of water molecules is high, and thus the rate of H₂ evolution reaction (HER) via water splitting is very slow. Hence, chemists are committed to finding high-performance, cheap and stable catalysts for realizing efficient H₂ production. The molybdenum disulfide (MoS₂)-based bimetallic sulfide electrocatalysts are favored by researchers because of their particular structures and properties. Herein, the Waugh type polyoxometalate (POM) is used as raw materials. A series of MnS–MoS₂ electrocatalysts are in-situ coupled on carbon cloth (CC) substrate by a hydrothermal sulfidation method. The catalyst MnS-MoS₂-CC possesses high catalytic activity for HER in a alkaline electrolyte, showing a low overpotential of 54 mV at a current density of 10 mA cm^?2, which is very close to 35 mV of the 20% Pt/C electrode. Meanwhile, under a current density of over 50 mA cm^?2, the overpotential of MnS-MoS₂-CC is less than that of the 20% Pt/C electrode. Moreover, the electrocatalysts show overpotentials of 141 mV and 201 mV at a current density of 10 mA cm^?2 in 0.5 M H₂SO₄ and 1.0 M phosphate buffer solution (PBS), respectively. Besides the high catalytic activity, the MnS-MoS₂-CC electrode shows long-term durability in a wide pH range, which is confirmed by several methods including the tests of linear sweep voltammetry (LSV) curve, current density vs. time (I-t) curve, and scanning electron microscopy (SEM). This work provides a feasible route for the preparation of HER electrocatalysts applied in broad pH conditions, especially for alkaline solutions.     

Biochar and plant growth promoting rhizobacteria effects on switchgrass (Panicum virgatum cv. Cave-in-Rock) for biomass production in southern Québec depend on soil type and location

Switchgrass (Panicum virgatum L.) is a fast growing native C₄ perennial and a lignocellulosic biomass crop for North America. In combination with biochar, an active plant growth promoting rhizobacterial (PGPR) community can contribute to the long-term sequestration of carbon in soil, fix nitrogen, and enhance the availability of other nutrients to plants. Biochar and PGPR have the potential to improve grass biomass production, but they have not been tested together under high-latitude temperate zone field conditions. Therefore, the objective of this three-year field study was to determine whether there were effects on biomass yield and yield components of switchgrass (cv. Cave-in-Rock) due to a rhizobacterium that was able to mobilize soil phosphorus (Pseudomonas rhodesiae), a bacterial consortium that was able to supply nitrogen (Paenibacillus polymyxa, Rahnella sp., and Serrati sp.), and pine wood chip biochar applied as a soil amendment at 20 Mg ha⁻¹. The incorporation of biochar, or inoculation with the N-fixing consortium, and the combined inoculation of the experimental bacteria had positive effects on switchgrass height. At a loam soil site in Sainte-Anne-de-Bellevue, Québec, when nitrogen fertilizer was not applied, the addition of biochar had a positive effect on stand count (tillers m⁻¹ row). On the sandy soil in Sainte-Anne-de-Bellevue, when biochar was applied with 100 kg N ha⁻¹, biomass yield increased over the control but did not provide additional benefits over plots receiving only 50 kg N ha⁻¹. It remains unclear whether or not the increased C sequestration of this management system justifies increased N fertilizer usage.     

Analysis on the feasibility of biomass power plants adding to the electric power system – Economic,regulatory and market aspects – State of Pará, Brazil

This paper presents an analysis of the feasibility of implementing biomass power plants, through thermoelectric power generation, and adding such plants to the electric system of the local electric utility by means of independent power production. Economic, regulatory, and market issues are also addressed.The biomass being considered is produced by the lumber sector, since that is one of the industrial sectors generating the largest amount of residues in a concentrated manner in the region under study, and also considering the fact that the disposal of such residues is currently difficult for the lumber companies.The locations with the largest production of residues, as well as the size of potential plants, are identified, the generation costs of the plants calculated, and the feasibility for implementing the plants is evaluated considering the market and the regulation of the Brazilian electric power sector.     

Macro-economic impact of large-scale deployment of biomass resources for energy and materials on a national level—A combined approach for the Netherlands

Biomass is considered one of the most important options in the transition to a sustainable energy system with reduced greenhouse gas (GHG) emissions and increased security of enegry supply. In order to facilitate this transition with targeted policies and implementation strategies, it is of vital importance to understand the economic benefits, uncertainties and risks of this transition. This article presents a quantification of the economic impacts on value added, employment shares and the trade balance as well as required biomass and avoided primary energy and greenhouse gases related to large scale biomass deployment on a country level (the Netherlands) for different future scenarios to 2030. This is done by using the macro-economic computable general equilibrium (CGE) model LEITAP, capable of quantifying direct and indirect effects of a bio-based economy combined with a spread sheet tool to address underlying technological details. Although the combined approach has limitations, the results of the projections show that substitution of fossil energy carriers by biomass, could have positive economic effects, as well as reducing GHG emissions and fossil energy requirement. Key factors to achieve these targets are enhanced technological development and the import of sustainable biomass resources to the Netherlands.     

Can the environmental benefits of biomass support agriculture?—The case of cereals for electricity and bioethanol production in Northern Spain

Recent policy documents, such as the EC Communication on an Energy Policy for Europe (January 2007) make emphasis on the opportunities that energy applications can offer certain agricultural commodities, especially in the framework of a progressive dismantling of the Common Agricultural Policy. This paper analyses whether this can be true for wheat and barley farmers, using the real example of a straw-based power plant in Northern Spain and a theoretical factory for bioethanol production fed with cereal grain. The outcomes of such an exercise, in which their relative environmental benefits vis-à-vis fossil fuel alternatives are worked out with the aid of a simplified life-cycle approach, show that the characteristics of the electricity and biomass markets, the baseline scenario and the fuel prices are crucial for the future of the sector.     

Is energy cropping in Europe compatible with biodiversity? – Opportunities and threats to biodiversity from land-based production of biomass for bioenergy purposes

Based on literature and six country studies (Belgium, Denmark, Finland, Netherlands, Sweden, Slovakia) this paper discusses the compatibility of the EU 2020 targets for renewable energy with conservation of biodiversity.We conclude that increased demand for biomass for bioenergy purposes may lead to a continued conversion of valuable habitats into productive lands and to intensification, which both have negative effects on biodiversity. On the other hand, increased demand for biomass also provides opportunities for biodiversity, both within existing productive lands and in abandoned or degraded lands. Perennial crops may lead to increased diversity in crop patterns, lower input uses, and higher landscape structural diversity which may all have positive effects on biodiversity.In production forest opportunities exist to harvest primary wood residues. Removal of these forest residues under strict sustainability conditions may become economically attractive with increased biomass demand.An additional biomass potential is represented by recreation areas, road-side verges, semi-natural and natural areas and lands which have no other use because they have been abandoned, polluted or degraded.Whether effects of cropping of biomass and/or removal of biomass has positive or negative impact on biodiversity depends strongly on specific regional circumstances, the type of land and land use shifts involved and the associated management practices in general. However, it is clear that in the six countries studied certain types of biomass crops are likely to be more sustainable than others.     

Catalysts based on Co-Birnessite and Co-Todorokite for the efficient production of hydrogen by ethanol steam reforming

Two structured manganese oxides (Birnessite and Todorokite) containing Co have been studied in the steam reforming of ethanol. It has been found that both materials are active in the hydrogen production, exhibiting high values of conversion of ethanol and selectivities to hydrogen (100% and 70%, respectively). The best results have been obtained with the catalyst based on Todorokite material. Characterization by DRX, BET area, TPR and TEM has allowed to find that the excellent performance exhibited by this material could be attributed to the lower size of the Co metallic particles present in this sample (6 nm vs 12 nm in Birnessite). This lower size could be related to the especial microporous structure of Todorokite precursor, which could provide high-quality positions for the stabilization of the Co metal particles during calcination and reduction steps. Catalytic deactivation has also been considered. Deactivation was found higher for Todorokite-based catalyst, which presented the largest amount of deposited carbon (26.2 wt% for Co-TOD vs 10.6 wt% for Co-BIR). On the other hand, the degree of metal sintering was found similar in both catalysts. Therefore, the deactivation of the catalysts has been attributed primarily to the deposition of coke. The results presented here show that it is possible to prepare new catalysts based on manganese oxides with Birnessite and Todorokite structure and promoted with Co with high catalytic performance in the steam reforming of ethanol.     

Performance prediction and evaluation of the scroll-type hydrogen pump for FCVs based on CFD–Taguchi method

To improve hydrogen utilisation and provide superior water management, the recirculation hydrogen pump is one of the key components in a fuel-cell vehicle (FCV). This work focused on the performance estimation of a scroll-type hydrogen pump for FCVs. A series of CFD simulation cases were designed using the Taguchi method and were carried out to determine the optimum conditions for volumetric efficiency, and the effects of four factors, including pressure ratio, rotating speed, axial clearance, and radial clearance. The contributions of these factors on volumetric efficiency and shaft power were quantified by the analysis of variance (ANOVA) method. The results show that axial clearance and rotating speed are the main influencing factors on volumetric efficiency, and their contribution ratios are 45.3% and 39.6%, respectively, in the operational range of the hydrogen pump for FCVs. Pressure ratio and rotating speed should be considered first to reduce shaft power, and their contribution ratios are 40.9% and 55.4%, respectively. At last, the performance maps of the scroll-type hydrogen pump were obtained to reveal the dynamic changes at various working conditions. It is found that volumetric efficiency and shaft power are more sensitive to the change in rotating speed when the pressure ratio deviates from the designed value. The results can be used as guidelines for component matching in the design and operation of PEM fuel cell systems.