Structural performance of ballastless track slabs reinforced with BFRP and SFCB

Because of the inductive impedance caused by steel meshes in traditional reinforced ballastless track slabs, the electrical properties, primarily the rail resistance and inductance, of jointless track circuits are affected by electromagnetic induction between the slabs and the electric current in the rail. This problem results in poor transmission performance throughout the track circuit. Insulating sleeves or cards between the steel meshes have been used to improve the insulation capability of steel meshes in slabs; however, they reduce the bonding performance between the steel bars and concrete. Because of the good insulation properties of fiber-reinforced polymer composite bars (FRPs) and steel-fiber reinforced polymer composite bars (SFCBs), these composite materials have shown potential to overcome this insulation problem. However, the structural performance of the ballastless track slabs reinforced by basalt fiber reinforced polymer composite bars (BFRPs) and SFCBs, which play a key role in the structure and transportation safety, needs to be investigated. In this paper, six ballastless track slabs reinforced with BFRPs, SFCBs, and steel bars were constructed and tested. The following results were obtained. (1) Shear failures were observed for all slabs, both the BFRP and SFCB slabs meet the load level requirements, and SFCBs reinforcements have higher strength utilization compared with BFRPs reinforcements. (2) The bond-quality of SFCBs and BFRPs reinforcements proved slightly poorer than that of the steel bars. Because of the good corrosion resistance of the FRP, the maximum crack width limits can be slightly larger than that of the RC slabs. (3) Bischoff’s equation was initially used to calculate the deflection of partially prestressed concrete slabs under service loads. The results demonstrated a good agreement between the theoretical and experimental analysis. (4) Considering the tensile stiffness, the modified ACI equation was used to calculate the slabs’ crack width and the theoretical and experimental results showed a good agreement.     

Functionally graded carbon nanofiber/phenolic nanocomposites and their mechanical properties

For the first time, functionally graded carbon nanofiber/phenolic nanocomposites were designed and fabricated. The effect of compositional gradients on the flexural properties of functionally graded carbon nanofiber/phenolic composite beams was evaluated. Samples with four compositional gradients as well as a non-graded nanocomposite with the same total carbon nanofiber content and geometry were fabricated using a combination of powder stacking and compression molding techniques. Analytical and finite element models were both performed to investigate the effects of compositional gradients, boundary conditions, and external loadings on flexural properties of nanocomposite beams. Close agreement was observed between analytical solutions, finite element analyses and experiment. The morphology of the fracture surfaces was examined using a scanning electron microscope. The results showed that the flexural properties of carbon nanofiber/phenolic nanocomposites can be greatly improved by controlling the carbon nanofiber content across the thickness of the samples.     

Enhancement of pullout energy in a single-walled carbon nanotube-polyethylene composite system via auxetic effect

Inter-tube bridging of carbon nanotubes (CNTs) is a reliable way to improve the inter-tube stress transfer abilities. The work describes the interfacial interactions provided by a wall-to-wall inter-tube bridging between two single-walled carbon nanotubes (SWCNTs) embedded in a polyethylene (PE) matrix. Molecular dynamics (MD) models of tube pullout phenomena represent by the embedding (10, 10)–(10, 10) SWCNT with interconnections into an amorphous PE matrix. The simulations show that the inter-tube bridging enhances the pullout energies significantly due to the three energy dissipative micro-mechanisms: stress-induced tube deformation with localized auxetic effect, “cutting through” (penetration) between linker and matrix, and the accompanying tube pullout. Moreover, the results also predict that linkers with longer aliphatic chains or aromatic rings provide further increase to the levels of the nanotube pullout energies. These are of potential importance in guiding the design of CNT/polymer composites through inter-tube linkage.     

Creep behavior of polyurethane nanocomposites with carbon nanotubes

The polyurethane (PU) nanocomposites containing carbon nanotubes (CNTs) were prepared through in situ polymerization for the creep study. The results show that the presence of CNTs leads to a significant improvement of creep resistance of PU. However, this creep resistance does not increase monotonously with increase of CNT contents because it is highly dependent on the dispersion of CNTs. Several theoretical models were then used to establish the relations between CNT dispersion and final creep and creep–recovery behaviors of nanocomposites. The as-obtained viscoelastic and viscoplastic parameters of PU matrix and structural parameters of CNTs further confirmed the retardation effect by CNTs during creep of the nanocomposite systems. Besides, the time–temperature superposition (TTS) principle was also employed in this work to make a further evaluation on the creep of PU/CNT nanocomposites with long-term time scale.     

Electrical properties of polyvinylidene fluoride (PVDF)/multi-walled carbon nanotube (MWCNT) semi-transparent composites: Modelling of DC conductivity

Transparent conductive composites can be achieved from PVDF–MWCNT at very low concentration of MWCNT. These composites show different degree of UV–Visible radiation absorption depending on MWCNT concentration in composites. The composition dependent dielectric properties and AC conductivity were also measured for these composites. Properties like AC conductivity, dielectric constant and loss are increasing with filler concentration. The variations of DC conductivity against composition and temperature are also reported. The electrical hysteresis and electrical set are observed for PVDF–MWCNT composites when subjected to heating–cooling cycle. The validity of different theoretical models depicting percolation threshold with respect to DC conductivity was tested for these composites.     

Tensile and thermomechanical properties of short carbon fiber reinforced polyamide 6 composites

In this study, carbon fiber (CF) reinforced polyamide 6 (PA6) composites were prepared by using melt mixing method. Effects of fiber length and content, on the mechanical, thermal and morphological properties of CF reinforced PA6 composites were investigated. Fiber length distributions of composites were also determined by using an image analyzing program. It was seen that the maximum number of fibers were observed in the range of 0–50 μm. Mechanical test results showed that, increasing CF content increased the tensile strength, modulus and hardness values but decreased strain at break values of composites. DSC results showed that T_g and T_m values of composites were not changed significantly with increasing CF content and length. However, heat of fusion and the relative degree of crystallinity values of composites decreased with ascending CF content. DMA results revealed that storage modulus and loss modulus values of composites increased with increasing CF content.     

The influence of nano/micro hybrid structure on the mechanical and self-sensing properties of carbon nanotube-microparticle reinforced epoxy matrix composite

Nano/micrometer hybrids are prepared by chemical vapor deposition growth of carbon nanotubes (CNTs) on SiC, Al₂O₃ and graphene nanoplatelet (GNP). The mechanical and self-sensing behaviors of the hybrids reinforced epoxy composites are found to be highly dependent on CNT aspect ratio (AR), organization and substrates. The CNT–GNP hybrids exhibit the most significant reinforcing effectiveness, among the three hybrids with AR1200. During tensile loading, the in situ electrical resistance of the CNT–GNP/epoxy and the CNT–SiC/epoxy composites gradually increases to a maximum value and then decreases, which is remarkably different from the monotonic increase in the CNT–Al₂O₃/epoxy composites. However, the CNT–Al₂O₃ with increased AR ⩾ 2000 endows the similar resistance change as the other two hybrids. Besides, when AR < 3200, the tensile modulus and strength of the CNT–Al₂O₃/epoxy composites gradually increase with AR. The interrelationship between the hybrid structure and the mechanical and self-sensing behaviors of the composites are analyzed.     

Significantly improving infrared light-induced shape recovery behavior of shape memory polymeric nanocomposite via a synergistic effect of carbon nanotube and boron nitride

The present work studies the thermomechanical properties and infrared light-induced shape memory effect (SME) in shape memory polymer (SMP) nanocomposite incorporated with carbon nanotube (CNT) and boron nitride. The combination of CNT and boron nitride results in higher glass transition temperature, mechanical strength and thermomechanical strength. While CNTs are employed to improve the absorption of infrared light and thermally conductive property of SMP, boron nitrides facilitate heat transfer from CNTs to the polymer matrix and thus to enable fast response. A unique synergistic effect of CNT and boron nitride was explored to facilitate the heat transfer and accelerate the infrared light-induced shape recovery behavior of the shape memory polymeric nanocomposite.     

Combined effects of fiber/matrix interface and water absorption on the tribological behaviors of water-lubricated polytetrafluoroethylene-based composites reinforced with carbon and basalt fibers

Tribological behaviors of two PTFE-based composites reinforced with carbon fibers and basalt fibers sliding against stainless steel under water lubrication were investigated and compared with those of pure PTFE. Results showed that carbon fibers were well bonded with PTFE matrix by dendritic PTFE nano-ribbons in a Boston ivy-like manner, but the basalt fibers were poorly bonded with the matrix. Due to the great accelerating effect of poor fiber/matrix interfacial adhesion on water absorption, BF/PTFE with the highest crystallinity unexpectedly showed the highest water absorption, resulting in serious matrix plasticization and degradation of fiber/matrix interfacial adhesion. As a result, as the reinforcement failure of basalt fibers occurred, BF/PTFE exhibited the highest wear rate. Instead, because good fiber/matrix interfacial adhesion was favor of the resistance to water intrusion, CF/PTFE composite was not dominated by remarkable matrix plasticization and fiber/matrix interface degradation, and showed the lowest wear rate.     

Preparation of continuous carbon nanotube networks in carbon fiber/epoxy composite

In order to optimize carbon nanotube (CNT) dispersion state in fiber/epoxy composite, a novel kind of CNT organization form of continuous networks was designed. The present work mainly discussed the feasibility of preparing continuous CNT networks in composite: Fiber fabric was immersed into CNT aqueous solution (containing dispersant) followed by freeze drying and pyrolysis process, prior to epoxy infusion. The morphologies of fabric with CNTs were observed by Scanning Electron Microscope. The relationship between CNT networks and flowing epoxy resin was studied. Properties of composite, including out-of-plane electrical conductivity and interlaminar shear strength (ILSS), were measured. The results demonstrated that continuous and porous CNT networks formed by entangled CNTs could be assembled in fiber fabric. Most part of them were preserved in composite due to the robustness of network structures. The preserved CNT networks significantly improved out-of-plane electrical conductivity, and also have an effect on ILSS value.     

Fire structural resistance of basalt fibre composite

Basalt fibres are emerging as a replacement to E-glass fibres in polymer matrix composites for selected applications. In this study, the fire structural resistance of a basalt fibre composite is determined experimentally and analytically, and it is compared against an equivalent laminate reinforced with E-glass fibres. When exposed to the same radiant heat flux, the basalt fibre composite heated up more rapidly and reached higher temperatures than the glass fibre laminate due to its higher thermal emissivity. The tensile structural survivability of the basalt fibre composite was inferior to the glass fibre laminate when exposed to the same radiant heat flux. Tensile softening of both materials occurred by thermal softening and decomposition of the polymer matrix and weakening of the fibre reinforcement, which occur at similar rates. The inferior fire resistance of the basalt fibre composite is due mainly to higher emissivity, which causes it to become hotter in fire.     

Fracture mechanic modeling of fiber reinforced polymer shear-strengthened reinforced concrete beam

A numerical method is developed to model shear-strengthening of reinforced concrete beam by using fiber reinforced polymer (FRP) composites. Tensile crack is simulated by a non-linear spring element with softening behavior ahead of the crack tip to model the cohesive zone in concrete. A truss element is used, parallel to the spring element, to simulate the energy dissipation rate by the FRP. The strain energy release rate is calculated directly by using a virtual crack closure technique. It is observed that the length of the fracture process zone (FPZ) increases with the application of FRP shear-strengthening. The present model shows that the main diagonal crack is formed at the support in the control beam while it appears through the shear span in the shear-strengthened beam. Another important observation is that the load capacity increases with the number of CFRP sheets in the shear span.     

Infrared stress measurements of thermal damage to laser-processed carbon fiber reinforced plastics

Recently, the laser processing of carbon fiber reinforced plastics (CFRPs) has attracted attention owing to the high processing speed and less tool wear. A problem in the laser processing of CFRPs is the lower strength than that of CFRPs processed by machines. This is considered to be due to the heat-affected zone (HAZ) generated during laser processing. In this study, the stress distributions of CFRPs processed by a laser obtained was evaluated by using infrared thermography. X-ray CT images were also obtained, which enabled us to discuss the stress distribution in terms of the HAZ. The stress distribution showed that the area with reduced stress generated in the HAZ which was introduced by laser processing. The region of low stress in the HAZ was visualized by infrared thermography. It is shown that the regions with reduced stress induce the conventionally reported decrease in strength of laser-processed CFRPs.     

The tensile fatigue behaviour of a silica nanoparticle-modified glass fibre reinforced epoxy composite

An anhydride-cured thermosetting epoxy polymer was modified by incorporating 10 wt.% of well-dispersed silica nanoparticles. The stress-controlled tensile fatigue behaviour at a stress ratio of R = 0.1 was investigated for bulk specimens of the neat and the nanoparticle-modified epoxy. The addition of the silica nanoparticles increased the fatigue life by about three to four times. The neat and the nanoparticle-modified epoxy resins were used to fabricate glass fibre reinforced plastic (GFRP) composite laminates by resin infusion under flexible tooling (RIFT) technique. Tensile fatigue tests were performed on these composites, during which the matrix cracking and stiffness degradation was monitored. The fatigue life of the GFRP composite was increased by about three to four times due to the silica nanoparticles. Suppressed matrix cracking and reduced crack propagation rate in the nanoparticle-modified matrix were observed to contribute towards the enhanced fatigue life of the GFRP composite employing silica nanoparticle-modified epoxy matrix.     

Hybrid carbon fiber composite lattice truss structures

Carbon fiber reinforced polymer (CFRP) composite sandwich panels with hybrid foam filled CFRP pyramidal lattice cores have been assembled from linear carbon fiber braids and Divinycell H250 polymer foam trapezoids. These have been stitched to 3D woven carbon fiber face sheets and infused with an epoxy resin using a vacuum assisted resin transfer molding process. Sandwich panels with carbon fiber composite truss volumes of 1.5–17.5% of the core volume have been fabricated, and the through-thickness compressive strength and modulus measured, and compared with micromechanical models that establish the relationships between the mechanical properties of the core, its topology and the mechanical properties of the truss and foam. The through thickness modulus and strength of the hybrid cores is found to increase with increasing truss core volume fraction. However, the lattice strength saturates at high CFRP truss volume fraction as the proportion of the truss material contained in the nodes increases. The use of linear carbon fiber braids is shown to facilitate the simpler fabrication of hybrid CFRP structures compared to previously described approaches. Their specific strength, moduli and energy absorption is found to be comparable to those made by alternative approaches.     

An investigation on shape memory behaviours of hydro-epoxy/glass fibre composites

Shape-memory polymers (SMPs) have the capacity to return large strains by external stimuli. Among various SMPs, shape-memory epoxy has received considerable attention because of its superior mechanical and thermal properties as well as excellent shape-memory performance. In this study, short glass fibre-reinforced shape-memory hydro-epoxy composites are developed to improve further the mechanical property of shape-memory epoxy resin. The thermomechanical and shape-memory properties of the developed composite materials are investigated by dynamic mechanical analysis, bend test and shape recovery test. The results indicate that the glass modulus and bend strength of the developed composite materials initially increase and then slightly decrease with increasing short glass fibre content. The glass transition temperature of the developed composite materials does not change with increasing short glass fibre. When the short glass fibre content is less than 4.5 wt.%, full recovery can be observed after only several minutes at different temperatures. The shape-memory property of the composite materials is not affected greatly. However, when the short glass fibre content is more than 4.5 wt.%, the material would be destroyed after deformation.     

Reinforcement and quantitative description of inorganic particulate-filled polymer composites

Understanding the reinforcing mechanisms should be meaningful for preparation of new polymer composites. The reinforcing mechanisms of the inorganic particulate-filled polymer composites were analyzed and discussed in the present paper, and concluded several reinforcing theories on the basis of the previous studies, such as interfacial adhesion reinforcing theory, filler inducing crystallization reinforcing theory, filler frame reinforcing theory, and synergistic reinforcing effect theory. The reinforcing effects should be related closely to the filler shape and size, in addition to the filler concentration and dispersion in the matrix. Consequently, to describe accurately the reinforcing mechanisms of the composites, two or more reinforcing theories should be used for the actual composite system, and one of among them should be usually as the major reinforcing mechanism. Finally, the quantitative characterization of the reinforcement was described.     

Engineering the coefficient of thermal expansion and thermal conductivity of polymers filled with high aspect ratio silica nanofibers

The thermomechanical properties of epoxy filled with two different types of silica nanofillers: spherical nanoparticles and nanofibers were investigated as a function of silica nanofiller aspect ratio and concentration. Results indicated that at room temperature and at 8.74% silica nanofiber concentration (by volume) the thermal conductivity of epoxy increased twofold and coefficient of thermal expansion (CET) decreased by ∼40%. Silica nanofiber filled epoxy showed 1.4 times greater CET and 1.5 times greater thermal conductivity compared to spherical nanoparticle filled epoxy. The significant changes observed in thermomechanical properties of silica nanofiber filled epoxy were attributed to its high aspect ratio by constraining the polymer matrix as well as reducing the phonon scattering due to the formation of a continuous fiber network within the matrix. In addition to being electrically insulating, the improved properties of silica nanofiber filled epoxy make it an extremely attractive material as underfill and encapsulant in advanced electronic packaging industry.     

Estimating mechanical properties of 2D triaxially braided textile composites based on microstructure properties

Textile composites manufactured using Resin Transfer Modeling (RTM) can offer advantages in some automotive applications including reduction in weight, while being relatively simpler to fabricate than standard laminated composites used for aerospace applications. However, one of the challenges that arise with these textile composite materials is that the mechanical properties are inherently dependent on the local and final (in-situ) architecture of the textile itself as a result of the molding and curing processes. While this provides additional latitude in the composite design process it also necessitates the development of analytical models that can estimate the mechanical properties of a textile composite based on the textile architecture and the properties of the manufactured component.In this paper, an analytical model is developed and its estimations are compared against experimental in-plane engineering properties for composites with various textile architectures. Results from the model are also compared against finite element (FE) based computational results. The microstructures of the 2D triaxially braided composite (2DTBC) studied were extensively characterized. The microstructure properties thus measured were used in the analytical model to estimate the mechanical properties. Uniaxial tension and V-notched rail shear tests were conducted on 2DTBC with different textile architectures. Good agreement between the analytical, computational, and experimental results were observed and are reported here. Furthermore, computational estimations of matrix mechanical properties are limited to the linear elastic range of a representative material volume (unit cell) and coupon data. Full mechanical response of larger 2DTBC structures, albeit of prime interest, is beyond the scope of this work and could be the focus of follow up studies.     

Influence of electroless nickel-plating on fracture toughness of pitch-based carbon fibre reinforced composites

Nickel-Pitch-based carbon fibres (Ni-PFs) were prepared by electroless nickel-plating to enhance fracture toughness of Ni-PFs reinforced epoxy matrix composites (Ni-PFs/epoxy). The surface properties of Ni-PFs were determined by scanning electron microscopy (SEM), X-ray photoelectron spectrometry (XPS), and X-ray diffraction (XRD). The fracture toughness of the Ni-PFs/epoxy was assessed by critical stress intensity factor (K_IC) and critical strain energy release rate (G_IC). The fracture toughness of Ni-PFs/epoxy was enhanced compared to those of PFs/epoxy. These results were attributed to the increase of the degree of adhesion at interfaces between Ni-PFs and matrix resins in the composites.