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建筑用耐火钢的研究现状及发展趋势 总被引:1,自引:0,他引:1
耐火钢是建筑钢结构的首选绿色钢铁材料。国外钢铁生产企业通过不同的成分设计思路相继开发了不同级别的耐火钢,并已大量应用于高层建筑。国内也进行了研究开发,且性能达到与国外耐火钢相当的水平,但是应用业绩较少,其原因是传统耐火钢Mo含量高,合金成本远高于普通建筑用钢。耐火钢必须通过一定量的贝氏体以保证良好的高温性能,而贝氏体属中温转变组织,对轧制及冷却工艺要求高,是耐火钢开发的难点。开发低Mo含量的低成本、高强度、高韧性耐火钢,并逐渐取代普通建筑钢+耐火涂层,是现代建筑钢结构的发展趋势之一。 相似文献
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建筑结构用新型抗震耐火钢Q420FRE的开发 总被引:1,自引:0,他引:1
新型耐火钢除了要求具有等同或优于普通建筑钢的室温力学性能和良好焊接性能,还需要保证耐火性能和良好抗震性能,并拥有比传统耐火钢成本更低的特点。南钢基于实验室试验的结果,设计了低Mo新型耐火钢的化学成分和轧制工艺,试制了不同厚度规格的Q420FRE耐火钢,其各项性能均优于标准对同级别耐火钢的要求。600℃高温强度达到室温强度的70%,280 MPa恒载荷下的耐火极限温度约为700℃,模拟二次火灾高温强度仍超过280 MPa,屈强比0.83,具有良好的耐火及抗震性能。 相似文献
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《钢铁钒钛》2021,42(4):138-143
设计了两种不同Cr含量460 MPa级抗震耐火建筑用钢,并进行了室温和高温机械性能检测,0.4%Cr和0.8%Cr试验钢的性能均满足抗震钢屈强比≤0.83,并且耐火钢600℃保温3 h后屈服强度≥307 MPa的标准。JMatPro热力学软件对460 MPa级抗震耐火建筑用钢的析出相进行计算,采用光学显微镜和透射电子显微镜方法对钢中的析出相进行了分析。结果表明,试验钢随Cr含量的升高,室温抗拉强度升高,屈强比降低,具有更好的抗震性能。Cr的增加,减少了高温稳定性较差的析出相的析出,降低了析出相中Mo的含量,促使Mo更多地溶入基体中,从而提高了抗震钢的高温固溶强化作用和耐火性能。 相似文献
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设计了一系列Mo质量分数从0.1%到0.8%的Fe-Mo-C三元模型钢.采用两种不同热处理工艺制度得到不同的组织,研究了Mo元素对耐火钢高温强度的两种强化形式:固溶强化和贝氏体相变强化.Mo可以显著提高耐火钢的高温强度,它在耐火钢中的主要高温强化机理是固溶强化.Mo质量分数不高于0.5%时,其高温固溶强化效果明显,每添加0.1%的Mo,600℃的屈服强度增量为13.71 MPa;但当Mo质量分数大于0.5%后,高温强度增幅逐渐减小.此外,贝氏体相变强化对耐火钢的高温强度也有重要影响.当贝氏体体积分数达到20%时,耐火钢的高温强度显著增加. 相似文献
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为了推动耐火钢的市场应用,采用低碳、低钼(约0.2%)及铌、钒、钛的复合微合金化成分设计,成功开发出低成本Q345耐火钢。采用Formastor-Digital全自动相变测试仪测定了试验钢的连续冷却转变(CCT)曲线,利用Gleeble-1500热模拟试验机研究了变形后不同冷却工艺对试验钢组织及硬度的影响,并采用SEM、EBSD、TEM和物理化学相分析等手段对热轧及600 ℃高温拉伸试样基体组织及纳米第二相进行了详细表征,定量分析了试验钢室温及高温下的强度机制。结果表明,轧后760~780 ℃开始层流冷却、终冷温度为400~600 ℃,试验钢获得铁素体+贝氏体组织。经600 ℃高温拉伸后,试验钢中MC相的质量分数及处于18 nm以下的粒子质量百分比相对于热轧态试样分别提高了16.4%、9.8%,这些新析出的纳米级粒子在高温下起到了良好的沉淀强化作用,一定程度弥补了高温下因剪切模量下降和细晶强化失效导致的高温屈服强度的损失;固溶、沉淀强化为Q345耐火钢主要的高温强化方式。 相似文献
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对铝含量为2%、4%(质量分数,下同)的310S耐热钢板材采用手工氩弧焊(TIG)的焊接方法进行焊接,利用光学显微镜对焊缝的显微组织进行分析,利用电子探针(EMPA)分析焊接母材的元素分布,并对焊接接头进行室温和高温(800℃)力学性能测试。结果表明:不同铝含量的310S耐热钢板材焊接后的组织均良好,都没有宏观裂纹及夹杂等缺陷;铝元素的加入,抑制了焊接热影响区晶粒的异常长大,细化了晶粒;高铝310S的焊接板材与母材一样具有优良的室温力学性能和高温力学性能,加铝310S耐热钢具有良好的焊接性能。 相似文献
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《钢铁研究学报(英文版)》2015,(11)
Two cold rolled hot-dip galvanizing dual phase(DP) 450 steels with different amounts of chromium were designed and the effects of the chromium concentration and galvanizing processes on the microstructure and mechanical properties were also investigated. The results show that the experimental steels exhibit typical dual phase microstructure character. However, the ferrite phase of steel with higher chromium is more regular and its boundaries are clearer. Meanwhile, martensite austenite(MA) island in steel No. 2 is diffused and no longer distributes along the grain boundary as net or chain shape. More MA islands enriched with Cr element can be found in the ferrite grains, and the increment of Cr element improves the stablity of the austenite so that the austenite has been reserved in MA islands. In addition, the experimental steel with higher chromium exhibits better elongation, lower yield ratio and better formability. The mean hole expanding ratio of steels No. 1 and No. 2 is 161.70% and 192.70%, respectively. 相似文献
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《钢铁研究学报(英文版)》2011,(Z1):625-628
The correlation among finish rolling temperature (FRT),microstructure and mechanical property of the high grade pipeline steel was investigated in this study.The microstructure of the steels with different finish rolling temperatures was observed with scanning electronic microscope (SEM) and transmission electronic microscope (TEM).The martensite/austenite (M/A) islands distribution was fixed by colour metallography,and the mechanical properties of the steels were tested with quasi-static tensile testing machine.The result shows that the fraction of M/A island increased with the finish rolling temperature decreasing,and when the finish rolling temperature is 800℃,the mechanical properties are the best. 相似文献
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Ferritic/martensitic (F/M) steels have been recommended as one of the candidate materials for supercritical water cooled reactor (SCWR) in-core components use for its high thermal conductivity, low thermal expansion coefficient and inherently good dimensional stability under irradiation condition in comparison to austenitic steel. CNS-Ⅱ F/M steel which has good mechanical properties was one of the 9-12Cr F/M steels designed for SCWR in the previous work. In this study a modified CNS-Ⅱ F/M steel was used and it′s ultimate tensile strength was 925 MPa at room temperature and 483 MPa at 600 ℃ after optimizing heat treatment parameter. The ductile to brittle transition temperature of modified CNS-Ⅱ F/M steel is -55 ℃. Those are at the same level or even higher than that of CNS-Ⅱ and some commercial F/M steels nominated for SCWR in-core component use. The transmission electron microscope (TEM) results showed that the mechanical properties of the tempered martensite was closely related to the decomposition stage of the martensite. 相似文献
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Chongmin Kim A. Richard Johnson William F. Hosford 《Metallurgical and Materials Transactions A》1982,13(9):1595-1605
The influence of microstructural variations on the fracture toughness of two tool steels with compositions 6 pct W-5 pct Mo-4
pct Cr-2 pct V-0.8 pct C (AISI M2 high-speed steel) and 2 pct W-2.75 pct Mo-4.5 pct Cr-1 pct V-0.5 pct C (VASCO-MA) was investigated.
In the as-hardened condition, the M2 steel has a higher fracture toughness than the MA steel, although the latter steel is
softer. In the tempered condition, MA is softer and has a higher fracture toughness than M2. When the hardening temperature
is below 1095 °C (2000 °F), tempering of both steels causes embrittlement,i.e., a reduction of fracture toughness as well as hardness. The fracture toughness of both steels was enhanced by increasing
the grain size. The steel samples with intercept grain size of 5 (average grain diameter of 30 microns) or coarser exhibit
2 to 3 MPa√m (2 to 3 ksi√in.) higher fracture toughness than samples with intercept grain size of 10 (average grain diameter
of 15 microns) or finer. Tempering temperature has no effect on the fracture toughness of M2 and MA steels as long as the
final tempered hardness of the steels is constant. Retained austenite has no influence on the fracture toughness of as-hardened
MA steel, but a high content of retained austenite appears to raise the fracture toughness of as-hardened M2 steel. There
is a temperature of austenitization for each tool steel at which the retained austenite content in the as-quenched samples
is a maximum. The above described results were explained through changes in the microstructure and the fracture modes.
CHONGMIN KIM, formerly with Climax Molybdenum Company of Michigan, Ann Arbor, MI. 相似文献
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A study of the structure and mechanical properties of Fe-Cr-Mo-C martensitic steels with and without boron addition has been
carried out. Nonconventional heat treatments have subsequently been designed to improve the mechanical properties of these
steels. Boron has been known to be a very potent element in increasing the hardenability of steel, but its effect on structure
and mechanical properties of quenched and tempered martensitic steels has not been clear. The present results show that the
as-quenched structures of both steels consist mainly of dislocated martensite. In the boron-free steel, there are more lath
boundary retained austenite films. The boron-treated steel shows higher strengths at all tempering temperatures but with lower
Charpy V-notch impact energies. Both steels show tempered martensite embrittlement when tempered at 350 °C for 1 h. The properties
above 500 °C tempering are significantly different in the two steels. While the boron-free steel shows a continuous increase
in toughness when tempered above 500 °C, the boron-treated steel suffers a second drop in toughness at 600 °C tempering. Transmission
electron microscopy studies show that in the 600 °C tempered boron-treated steel large, more or less continuous cementite
films are present at the lath boundaries, which are probably responsible for the embrittlement. The differences in mechanical
properties at tempering temperatures above 500 °C are rationalized in terms of the effect of boron-vacancy interactions on
the recovery and recrystallization behavior of these steels. Although boron seems to impair room temperature impact toughness
at low strength levels, it does not affect this property at high strength levels. By simple nonconventinal heat treatments
of the present alloys, martensitic steels may be produced with quite good strength-toughness properties which are much superior
to those of existing commercial ultra-high strength steels. It is also shown that very good combinations of strength and toughness
can be obtained with as-quenched martensitic steels. 相似文献
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摘要:以在650℃温轧的Fe-24Mn-2Al-1Si-0.05C TWIP钢为研究对象,通过金相显微镜(OM)、扫描电镜(SEM)、透射电镜(TEM)、室温拉伸等实验手段,研究温轧TWIP钢在回复退火、部分再结晶退火、高温短时退火以及高温退火等不同退火工艺下其微观组织及力学性能的演变。结果表明,随着退火工艺的改变,实验钢的微观组织由回复退火时包含高密度位错、形变孪晶等的变形晶粒逐渐向高温退火时的无畸变再结晶晶粒转变;而部分再结晶退火时,实验钢的微观组织由未再结晶区的变形晶粒和细小的再结晶晶粒混合组成。随退火工艺的改变,实验钢拉伸前、后的硬度变化趋势为先下降然后基本不变最后上升;实验钢的变形机制逐渐由位错滑移为主向孪生滑移为主转变。 相似文献
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Effect of Cooling Start Temperature on Microstructure and Mechanical Properties of X80 High Deformability Pipeline Steel 总被引:1,自引:0,他引:1
The effect of cooling (laminar cooling) start temperature on the phase constitution was analyzed by quantitative metallography. The martensite/austenite (M/A) island distribution was fixed by colour metallography. The strength and uniform elongation of the steels were tested with quasi-static tensile testing machine. The in-coordinate deformation of the soft and hard phases was analyzed using FEM. The results indicate that when the cooling start temperature is 690 ℃, the mechanical properties are the best, meeting the requirements of X80 high deformability pipeline steel. 相似文献
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Zheng-yun Zhang Jian-chun Cao Zhong-hua Zhong Xiao-long Zhou Wei Chen Yin-hui Yang 《钢铁研究学报(英文版)》2017,24(1):111-120
To investigate the tensile deformation behavior of high strength anti-seismic steel with multi-phase micro-structure, tensile tests with strains of 0.05, 0.12 and 0.22 were performed at room temperature.Micro-structure of tested steels was observed by means of optical microscopy (OM), transmission electron mi-croscopy (TEM) and scanning electron microscopy (SEM).Tensile mechanical properties of tested steels were obtained, and the influence of bainite content on deformation behavior was also discussed.Mean-while, the deformation mechanism of steel with three kinds of microstructures of bainite, pearlite and fer-rite was analyzed.Results show that tested steel with high volume fraction of bainite exhibits a continuous deformation behavior, and this may be attributed to a higher bainite volume fraction and a lower mobile dislocation density.The morphology of microstructure will influence the mechanical properties of tested steels.An increasing content of bainite can improve the tensile strength, but reduce the plasticity and toughness of the tested steels.In the deformation process of 0.039Nb steel, the ferrite and bainite have priorities to deform, and the deformation exhibits co-deformation of all microstructures in the later stage of deformation.In the deformation process of 0.024Nb-0.032V steel, the ferrite and pearlite have priori-ties to deform, and the deformation exhibits co-deformation of all microstructures in the later stage of de-formation. 相似文献