钢渣矿渣复合掺合料对水泥浆体性能的影响

主要研究单掺钢渣以及钢渣与矿渣复合后对水泥浆体各项物理力学性能的影响.结果表明,钢渣掺入水泥中可以改善水泥浆体的流动性.钢渣与矿渣复合的比例约在2:3,总掺量为50%时,水泥硬化浆体各龄期抗压强度均有较大幅度的提高.说明钢渣与矿渣复掺,能起到相互激发、相互活化的作用.     

兰新铁路第二双线混凝土矿物掺合料掺量优化试验研究

通过对不同混凝土的坍落度、坍落扩展度、不同龄期强度和电通量等指标的测定,研究了粉煤灰和磨细矿渣粉的掺量对兰新铁路第二双线新疆段混凝土的工作性、强度和耐久性的影响.研究结果表明:粉煤灰的掺入可提高混凝土的流动性,抑制水泥早期水化反应速度,而磨细矿渣粉的掺入可提高混凝土的粘聚性和保水性,对流动性不利;两者均能有效降低混凝土电通量.粉煤灰和磨细矿渣粉按适当比例复合掺入对混凝土性能的改善具有更好的效果,对于C30混凝土,粉煤灰掺量为15%,磨细矿渣粉掺量为15%,对于C40混凝土,粉煤灰掺量为15%,磨细矿渣粉掺量为20%,对于C50混凝土,粉煤灰掺量为10%,磨细矿渣粉掺量为30%时,混凝土的工作性、强度和耐久性最好.     

花岗岩石粉与矿物掺合料对胶浆氯离子结合性能的影响

以外掺花岗岩石粉的方式,研究机制砂引入的石粉对胶凝材料浆体氯离子结合性能的影响规律,对比研究矿物掺合料(粉煤灰、矿渣粉分别单掺、复掺取代一定量水泥)对浆体氯离子结合性能的影响.通过改变石粉掺量以及矿物掺和料的掺量,研究掺量对浆体氯离子结合性能的影响.结果表明,对于纯水泥胶浆或者复掺粉煤灰和矿粉的胶浆,掺入一定量的花岗岩石粉后,胶浆的氯离子结合总量、化学结合量和物理吸附量均高于未掺石粉的基准样,且复掺粉煤灰和矿渣粉的胶凝材料浆体的氯离子结合性能优于纯水泥浆体.单掺入30%~50%的粉煤灰或矿渣粉均能改善胶浆的氯离子结合性能,且矿渣粉对胶浆氯离子结合性能的改善作用优于粉煤灰.     

固硫灰-钛矿渣复合掺合料与萘系减水剂的相容性研究

通过考察固硫灰-钛矿渣掺入水泥-减水剂体系后,浆体的Marsh时间、经时损失及减水剂饱和掺量,研究了固硫灰-钛矿渣对水泥与减水剂相容性的影响。结果表明:随着原状固硫灰/钛矿渣的增加,减水剂饱和点掺量和浆体5min的Marsh时间均增加,但60min饱和掺量点处浆体的Marsh时间经时损失变化不明显;磨细固硫灰替代原状固硫灰,可有效改善粉料体系与减水剂的相容性,这主要得益于磨细固硫灰颗粒孔结构的改善。     

石材废粉砂浆的流动性研究

为了探索掺入石材废粉置换等体积细骨料对砂浆性能的影响,研究测量了20组不同水灰比、不同石材废粉体积下砂浆的流动性、黏聚性和抗压强度,量化了各配比的填充密度和平均液层厚度,揭示了石材废粉砂浆流动性能的主要控制因素。结果表明,掺入石材废粉降低了流速和扩展度,最大降幅分别为71.7%和12.0%;提高了黏聚性和抗压强度,最大增幅分别为69.3%和70.8%。回归分析揭示了流速、扩展度和黏聚性受平均液层厚度和石材废粉体积的协同影响,拟合公式相关系数R2值分别为0.92、0.85和0.84。     

无机矿粉对碱激发碳酸盐胶凝材料性能的影响

研究了矿渣、粉煤灰和偏高岭土时碱激发碳酸盐胶凝材料的强度、抗渗性能以及凝胶时间的影响，探讨了该材料浆体的流变特性。研究表明：1)矿渣可大幅度提高该材料的强度和抗渗性能，但会显著缩短凝胶时间；偏高岭土有利于强度的提高，但时抗渗性能和凝胶时间的影响不显著；粉煤灰时这些性能的影响均不显著；2)无机矿粉复合后，可使材料28d的抗压强度达43MPa以上，抗渗压力达1.5MPa以上；3)该胶凝材料的浆体为宾汉型流体；4)该胶凝材料中掺加粉煤灰，其浆体的流动性优于掺加矿渣和偏高岭土的浆体流动性。     

改性温轮胶微丸对水泥浆体性能的影响及其作用机理研究

研制开发出了一种新型的改性温轮胶微丸,旨在改善温轮胶与聚羧酸减水剂之间的竞争吸附问题,即解决原状温轮胶和聚羧酸减水剂共同使用时,原状温轮胶虽然改善浆体的离析泌水,但会大幅降低浆体流动性的问题。对掺入该类型温轮胶微丸后水泥浆体的1h静置泌水率、流变性能、水泥砂浆流动性和胶砂强度的变化进行了研究。结果表明:改性温轮胶微丸能够有效地降低水泥浆体的触变性,当改性温轮胶微丸掺入水泥浆体中时,水泥浆体1h静置泌水率和原状温轮胶一样,能很好地解决浆体的离析泌水问题,同时能够改善水泥砂浆的工作性能并能在一定程度上增进水泥胶砂的强度。其原因是改性温轮胶一方面会形成三维空间网状结构,具有与原状温轮胶相同的增稠、抗离析泌水和剪切稀化的特性;另一方面,衣膜材料与聚羧酸减水剂不存在竞争吸附问题,当其溶解后温轮胶才得到释放,而后释放的温轮胶在浆体中起到增进稳定性的作用,对流动性影响小。     

低需水的新拌水泥浆体流变性研究

在对水泥浆体流变模型和流变性能影响因素分析的基础上，研究了外加剂掺量、SO3含量、矿渣掺量等对新拌水泥浆流变性能的影响。用旋转粘度计对新拌水泥浆进行了动态检测，低需水量水泥的新拌水泥浆具有良好的流变性能，同时它的流变模型符合宾汉姆流变模型。     

新型放射性废物固化胶凝材料浆体对锶铯的吸附研究

研究了富铝碱矿渣粘土矿物复合胶凝材料、碱矿渣水泥、矿渣硅酸水泥浆体对＾９０Ｓｒ、＾１３７Ｃｓ的吸附作用。研究表明：富铝碱矿渣粘土矿物复合胶凝材料中的粘土矿物材料的种类、掺量对吸附比有较大的影响,该材料浆体对＾９０Ｓｒ、＾１３７Ｃｓ的吸附性能优于碱矿渣水泥,硅酸盐水泥以及矿渣硅酸盐水泥。     

大流动性轻集料混凝土研究

研究了粉煤灰、矿渣、硅灰掺合料对大流动性轻集料混凝土性能的影响。试验结果表明，掺合料单掺效果不及复掺；用堆积密度为503kg/m^3，筒压强度为3．08MPa的页岩陶粒，复合掺入20％的磨细粉煤灰和20％的磨细矿渣，可配制出塌落度267mm、扩展度650mm,28d强度为28．8MPa，表观密度为1804kg/m^3的免振捣大流动性轻集料混凝土；轻集料的物理力学对大流动性轻集料混凝土的性能有重要影响。     

石材废渣粉对纤维砂浆新拌性能控制因素的影响研究

掺入石材废渣粉可以改善纤维砂浆或纤维混凝土的力学性能,但同时显著降低其新拌性能.为探索掺入石材废渣粉置换等体积标准砂的聚丙烯纤维砂浆新拌性能的控制因素,测量了20组不同水灰比、不同石材废渣粉置换量下纤维砂浆的流速、扩展度、粘聚性、粘附性和填充密度,计算出平均液层厚度和平均泥浆层厚度.结果显示平均液层厚度和平均泥浆层厚度...     

矿渣粉的活性和流动度研究

对6个细度水平的矿渣粉活性和流动度研究，矿渣粉的抗折活性指数比抗压活性指数高．它在28d内是龄期和细度的单调增函数．矿渣粉的抗压活性指数在7d内是龄期和细度的单调增函数．28d的抗压活性指数采用不同品质的硅酸盐水泥表现存在差异．矿渣粉比表面积在350-650m^2／kg范围内．流动度比都大于110．而矿渣水泥的标准稠度用水量却比硅酸盐水泥高．采用不同细度硅酸盐水泥作为对比样时，矿渣粉流动度比偏差在14％以内．     

Mechanical Properties and Flowability of High Strength Concrete Incorporating Ground Granulated Blast-furnace Slag

The high strength concrete (HSC) was produced by partially replacing the normal portland cement with special ground granulated blast-furnace slag ( GGBS) ranging up to 60% . The effects of the GGBS on the flowabilityand mechanical properties of HSC were studied. The hydration process and microstructure characteristics were investigated by X-ray diffraction ( XRD) and scanning electron microscopy ( SEM), respectively. The test results indicate that the GGBS has especially supplementary effect on water reducing and excellent property of better control of lump loss. The concrete flowability increases remarkably with the increase of GGBS fineness and the replacement level in the range of 20% to 50% . The compressiae and splitting tensile strengths of HSC containing GGBS are higher than the corresponding strength of the control concrete at all ages .     

煅烧煤矸石用作水泥高活性混合材的研究

将经煅烧等过程进行活化处理的煤矸石细粉与磨至一定比表面积的水泥熟料及天然生石膏混合均匀,制成了活化煤矸石粉掺量比例不同的多组混合水泥,并对其胶砂强度性能、标准稠度用水量、胶砂流动度进行了实验检测.同时,还应用SEM对混合水泥硬化浆体的微观结构进行了观察.结果表明,掺入经活化处理的煤矸石粉配制的混合水泥具有较好的强度性能;随掺量增加,水泥浆体的流变性能变差,但对凝结时间并无明显影响.     

Mechanical Properties and Flowability of High Strength Concrete

The high strength concrete (HSC) was produced by partiallyreplacing the normal portland cement with special ground granulated blast-furnace slag (GGBS) ranging up to 60%. The effects of the GGBS on the flowabilityand mechanical properties of HSC were studied. The hydration process and microstructure characteristics were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively.The test results indicate that the GGBS has especially supplementary effect on water reducing and excellent property of better control of lump loss. The concrete flowability increases remarkably with the increase of GGBS fineness and the replacement level in the range of 20% to 50%. The compressive and splitting tensile strengths of HSC containing GGBS are higher than the corresponding strength of the control concrete at all ages.     

纤维混杂对超高性能纤维增强水泥基复合材料力学性能的影响

采用最紧密堆积理论对UHPFRC进行配合比设计，并通过应用Excel Solver Tool进行编程求解，实现了UHPFRCC符合体系的理论设计，利用石灰石粉改善流动性的作用得到最终配合比。基于基准配合比，研究了钢纤维与合成纤维混杂对UHPFRCC的力学性能的影响。试验结果表明：基于Dinger-Funk模型可实现自密实UHPFRCC的配合比设计；混杂纤维可增强UHPFRCC的抗压强度，但抗折强度有所降低；相比于单掺2%钢纤维的UHPFRCC，合成纤维的取代掺入均降低了UHPFRCC的抗压强度和抗折强度。     

Adsorption mechanism of polycarboxylate-based superplasticizer in CFBC ash-Portland cement paste

Circulating fluidized bed combustion （CFBC） ash exhibits the desirable pozzolanic activity which makes it a potential supplementary cementitious material to replace cement for concrete production. However, the high unburnt carbon content and porous surface structure of CFBC ash may adsorb water reducer and thereby significantly reduce the efficiency of water-reducing agents. The adsorption mechanism of polycarboxylate superplasticizer in CFBC ash-Portland cement paste was investigated by ultraviolet-visible spectrophotometer, and the conception of ＂invalid adsorption site＂ of CFBC ash was presented. The results show that the adsorption behavior of polycarboxylate superplasticizer in coal ash-Portland cement paste can be described by Langmuir isothermal adsorption equation. The adsorption capacity of CFBC ash-Portland cement paste is higher than that of pulverized coal combustion （PCC） fly ash-Portland cement paste. Moreover, the adsorption amount of polycarboxylate superplasticizer increases with the ratio of ash-to-cement in the paste. At last, the fluidity of CFBC ash-Portland cement paste is lower than that of the PCC fly ash paste. This work suggests that when CFBC ash is used as concrete admixture, the poor flowability of the cementitious system due to the high adsorption of water and water-reducing agent should be taken into consideration.     

Effect of curing conditions on the hydration and performance of CFBC ash cementitious system

Circulating fluidized bed combustion （CFBC） ash can be used as supplementary cementitious material for concrete production for its high pozzolanic activity. We investigated the effect of curing conditions on the hydration and performance of CFBC ash-Portland cement system （30： 70, by mass） including hydration products, paste microstructure, linear expansion ratio, chemically combined water content and compressive strength. The results show that tobermorite rather than ettringite is generated under the condition of autoclaved curing. The expansion and mortar strength of the system cured in water is higher than those cured in air at a given age, and the strength and bulk volume may retract under the condition of air curing. In addition, autoclaved curing facilitates the increase of strength gain at early curing ages （the increase rate lowers down in the following ages） and the improvement of system volume stability. It is suggested that sufficient water is necessary for the curing of CFBC ash cementitious system, and autoclaved curing may be considered where volume stability is a primary concern.     

碱-矿渣-锰合金渣胶凝材料的研制

锰合金渣是生产锰系合金排放的工业废弃物,近年来锰矿资源的开采和利用发展迅速,产生的大量锰渣造成了严重的环境污染。将锰合金渣与矿渣复合,制备了碱-矿渣-锰合金渣胶凝材料,测试了所制备胶结材的抗压和抗折强度,利用扫描电镜分析了其微观结构。研究结果表明,随着锰渣掺量增加,碱-矿渣-锰渣胶凝材料的强度总体呈降低趋势;提高锰渣细度,所制备的胶凝材料强度亦随之增加;碱激发下磨细锰合金渣具有一定的水化硬化活性,其活性低于磨细矿渣。