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为了进一步提高黄铜的耐蚀性,在其钝化液中加入镧盐和苯并三氮唑(BTAH)进行钝化。通过扫描电镜及X射线衍射分析了钝化膜的表面形貌、成分及结构;利用硝酸点滴及中性盐雾试验测试其耐蚀性,利用电化学极化曲线研究镧盐、BTAH单独及共同使用时对黄铜的缓蚀性能。结果表明:BTAH和镧盐具有良好的协同作用,钝化液中同时加入镧盐及BTAH所得复合钝化膜的耐硝酸点滴时间达21 s,耐中性盐雾12 h表面无明显变化;钝化液中镧盐及BTAH协同作用,使黄铜阳极腐蚀电流减小,腐蚀速度降低,使黄铜的耐蚀性能显著增强。 相似文献
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为进一步提高三价铬彩色钝化膜的性能,在无机钝化液中加入有机硅树脂,制备了一种新型高耐蚀性能三价铬彩色钝化液。该钝化液可以在镀锌板表面形成有机-无机复合钝化膜,通过红外光谱仪分析钝化膜结构,采用扫描电镜观察钝化膜微观形貌,用能谱仪分析钝化膜的微观组成,采用电化学试验、中性盐雾试验对钝化膜耐蚀性能进行表征。以正交试验对三价铬彩色钝化液组分进行了优选,以单因素试验研究了钝化温度、钝化液pH值、钝化时间等钝化条件对钝化膜耐腐蚀性能的影响。结果表明:最佳钝化液成分为硫酸铬10.00 g/L,硅树脂12.50 g/L,硝酸钠4.00 g/L,硝酸镍1.25 g/L,氯化钠2.00 g/L;最佳钝化条件为温度30℃,时间150 s,pH值1.8;以最优条件制得的钝化膜色彩鲜艳,耐蚀性能突出,耐中性盐雾腐蚀时间达196 h。 相似文献
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为了提高H62黄铜合金的表面性能,通过正交试验获得了最佳锅、钵双稀土处理液配方。利用硝酸点滴、中性盐雾试验评价了H62黄铜合金钝化膜的耐蚀性能,通过电子探针(EPMA)观测了其表面形态结构及元素分布,利用电化学方法表征了 H62黄铜表面钝化膜在3.5%NaCl溶液中的缓蚀行为,采用XRD对H62黄铜表面钝化膜的成分进行了检测。结果表明:H62黄铜合金由镉、钵双稀土处理液钝化成膜的主要成分为Cu2O,CeO2,La(OH)3,Ce(OH)4;致密的钝化膜耐硝酸点滴时间达到21.98s,在3.5%NaCl溶液自腐蚀电位增加,腐蚀电流降低,腐蚀速度明显降低,耐蚀性能增加,耐中性盐雾性能明显优于鋪单一稀土处理液。 相似文献
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为了提高镀锌板的耐蚀性,以有机硫化物为发黑剂,研制了一种性能稳定的三价铬黑色钝化液,并用该钝化液在常温下对镀锌板进行钝化处理.通过扫描电镜(SEM)观察、醋酸铅点滴试验、Tafel极化曲线和交流阻抗谱测试等方法分析了钝化膜的外观形貌、元素组成及耐蚀性能.结果表明:钝化膜主要含有Zn,Cr,O等元素;钝化膜封闭后乌黑油亮,具有良好的装饰性能,且附着力合格;镀锌板经钝化后,耐醋酸铅点滴时间约为71 s,能有效地阻滞腐蚀的阳极过程,使自腐蚀电位由-1.283 V升高到-1.054 V,正移了近230 mV;自腐蚀电流密度由12.240μA/cm2减小到了2.866 μA/cm2,显著提高了镀锌板的耐蚀性. 相似文献
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一种耐蚀性能较好的锡青铜钝化工艺 总被引:1,自引:1,他引:0
为提高锡青铜钝化膜层的耐蚀性,在传统铜合金钝化液体系的基础上,利用正交试验法对钝化液组分进行了优化,并研究了工艺参数对钝化膜外观和耐蚀性的影响.所得最佳工艺条件为:150 g/L重铬酸钾,15 mL/L硫酸,1 g/L氯化钠,室温,时间10~15 s.结果表明,采用该工艺能获得外观艳丽、光亮,颜色均匀,附着力好的膜层,其点滴试验耐蚀性大于30 s. 相似文献
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一种增强镀锌黑色钝化膜附着力的改良工艺 总被引:1,自引:0,他引:1
度针对镀锌层黑色钝化膜干燥之前柔软易脱落等问题,提出了一种基于硫酸盐-磷酸盐型的银盐黑色钝化工艺,采用单因素试验对黑色钝化溶液组成,操作条件进行了优化,并用SEM、NSS等方法评价了黑色钝化膜的性能,研究结果表明,改良后的黑色钝化工艺完全能够满足镀锌件(特别是滚镀件)黑色钝化的实际生产需要。 相似文献
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The present work examines how passivating oxide film affects the corrosive wear rate of Al-7%Si alloy in H2SO4 solution at room temperature. As the applied potential (relative to a saturated calomel electrode (SCE)) increases to 1.08 VSCE on an Al-7%Si alloy specimen, the corrosive wear rate increases and then decreases for polarization to higher anodic potentials. The corrosive wear rate Wcw consists of three factors, namely pure mechanical wear loss Wmech, weight loss Wdiss caused by the corrosion reaction, and an acceleratory-deceleratory contribution Wacc due to the presence of passivating oxide film. The acceleratory and deceleratory contributions Wacc arising from compositional change of the passivating oxide film indicate the microcutting and microploughing mechanisms respectively of abrasive wear. The increased Wacc by application of 1.08 VSCE is discussed from the viewpoints of hydration and severe abrading wear action of the passivating oxide film on the Al-7%Si alloy specimen. 相似文献
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The aim of this work is to prevent back transfer of electrons due to direct contact between the electrolyte and the FTO glass substrate using a TiO2 passivating layer. The TiO2 passivating layer was deposited on FTO glass by e-beam evaporation. The TiO2 film was prepared with different deposition rates. The specific surface area was reduced with increasing deposition rate. The nanoporous TiO2 upper layer was coated by screen-printing on the TiO2 passivating layer prepared by e-beam evaporation. The optical transmittance and absorbance of the TiO2 films depend on the morphology of the TiO2 passivating layer. The dye-sensitized solar cells influenced the surface morphology of the TiO2 passivating layer. The dye-sensitized solar cell using the TiO2 passivating layer recorded a maximum conversion efficiency of 4.93% due to effective prevention of the electron recombination to the electrolyte. 相似文献
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S.C. Tjong 《Materials Research Bulletin》1982,17(10):1297-1304
Passive films were formed on nickel in borate buffer solution (pH 8.4) at various anodic potentials. XPS and SIMS techniques were used to determine the passivating species present on the surface film. It is shown that the film formed at low passivating potentials consists of Ni (OH)2 and NiO, and the film formed preceding oxygen evolution consists mainly of Ni2O3. 相似文献
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为了进一步提高热浸镀锌层钝化膜的耐蚀性能,针对目前无铬钝化多为独立体系的有机物钝化或无机物钝化的情况,运用有机物与无机物进行复合钝化。通过正交试验法确立了热浸镀锌层无色钝化工艺,采用单因素变量法、点滴试验、中性盐雾腐蚀试验及电化学测试技术,研究了复合钝化工艺参数对钝化膜外观和耐蚀性的影响。结果表明:最佳复合钝化工艺为40 g/L丙烯酸树脂,20 g/L硝酸钠,40 g/L硅酸钠,15 m L/L过氧化氢;p H值11,钝化时间30 s,温度30℃,恒温烘干;钝化膜的耐蚀性能接近于三价铬钝化。 相似文献
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首次利用1,3-二氧五环(DOL)对金属锂电极进行预处理,以使该电极钝化,提高其界面稳定性.电化学阻抗谱(EIS)分析表明,当金属锂电极长时间浸泡在电解液中时,经过DOL预处理的锂电极与未经处理的锂电极相比,具有更低、更稳定界面阻抗.同时,扫描电子显微镜(SEM)观察也证明,在长时间浸泡后,经过预处理的锂电极表面要比未经处理的锂电极表面,更加平整,并有更少的锂枝晶出现.显然,DOL预处理对锂电极具有很好的钝化作用.进而,由于预处理在锂电极表面生成稳定的界面膜所具有的钝化作用,经过该处理的锂电极在连续的充放电循环中,显示出更高的循环效率. 相似文献
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The recombination properties of silicon passivated with films of rare-earth oxides were investigated. The films were obtained
by thermal resistive sputtering of a rare-earth metal followed by thermal oxidation of the obtained layer in air at 400 °C.
It was established that the effective nonequilibrium charge-carrier lifetime measured by photoconductivity relaxation is 2–3
times higher after deposition of the rare-earth oxide film. Surface recombination rates at the silicon-rare-earth oxide interface
were determined to be 290–730 cm/s for different rare-earth oxides. The combination of high optical transmittance of the experimental
materials and low recombination losses in silicon coated with a rare-earth oxide film makes it possible to recommend rare-earth
oxide films as optical antireflection and passivating coatings for silicon photoelectric devices.
Pis’ma Zh. Tekh. Fiz. 24, 16–21 (April 12, 1998) 相似文献