邢钢铝镇静钢工艺优化

介绍了铝镇静钢的生产工艺及主要设备,并对现有工艺进行了分析。针对铝镇静钢夹杂物数量不能满足市场需要,对铝镇静钢的生产工艺进行优化。实践证明,优化后产品质量满足了市场需要。     

提高低碳铝镇静钢力学性能的研究

对罩式炉生产低碳铝镇静钢产生性能不合的因素进行了定性研究。指出了影响低碳铝镇静钢常规力学性能的主要因素，同时提出提高低碳铝镇静钢力学性能的措施。     

低碳铝镇静钢夹杂物控制技术研究

镀锡用产品采用铝镇静钢生产，要求钢质洁净。低碳铝镇静钢钢中主要夹杂物为三氧化二铝，通过对低碳铝镇静钢夹杂物控制理论的研究，并在梅钢进行工艺实践，检测数据分析表明，梅钢镀锡产品钢中夹杂物控制水平达到了宝钢同类产品先进水平。     

低碳铝镇静钢LF精炼工艺的研究

钢包精炼炉(LF)作为一种实用且高效的炼钢设备,在当前炼钢工艺中发挥着越发重要的作用.文章围绕低碳铝镇静钢,就其在LF精炼工艺存在的一些突出问题(如易堵水口、脱硫率低等),提出了具体的优化对策,以此促进铝镇静钢LF脱氧、去夹杂及脱硫率方面能力的提升,将LF在低碳铝镇静钢精炼生产中的作用最大化发挥出来.     

低碳铝镇静钢LF精炼工艺优化

针对武钢条材总厂一炼钢分厂生产低碳铝镇静钢LF精炼工艺存在的脱硫率低、易堵水口等问题,为兼顾脱硫和去除夹杂物,选取了LF精炼终渣。通过采取LF迅速造白渣及控制熔渣成分、温度、节奏、钙处理等优化工艺,提高了铝镇静钢LF脱氧、脱硫率及去夹杂能力。同时加强过程温度控制,更好地发挥LF在生产低碳铝镇静钢精炼过程中的作用。     

转炉——RH——连铸工艺过程中低碳铝镇静钢的清洁度

针对宝山钢铁（集团）公司炼钢厂ＬＤ—ＲＨ—ＣＣ生产低碳铝镇静钢连铸板坯的工艺，对钢包、中间包、结晶器中钢水和铸坯的清洁度进行了较为系统的研究，并对进一步改善低碳铝镇静钢连铸坯清洁度的措施进行了讨论。     

铝镇静钢中的非金属夹杂物

液态铝镇静钢中的非金属夹杂物主要是铝的氧化物。如果不除去将影响连铸钢产品的质量。此外 ,还会扰乱连铸过程。在钢包冶炼过程短期间隔内从中碳铝镇静钢、低碳硅—铝镇静钢和低碳铝镇静钢炉次取钢样。从钢基体中提取非金属夹杂物 ,并采用扫描电镜和能量弥散光谱进行研究。识别出了 6种形态的夹杂物 :球状、多面体、板状、树枝状、串状以及聚积体。对于每一个试样都测量了总氧含量。观察了大型夹杂物尺寸的变化。在加入铝后的前 10min ,有串状夹杂物存在。 15min后 ,聚集体和大的多面体上升 ,并且尺寸连续增加。聚集体的形成及其随后的增长…     

低碳铝镇静钢铝锰铁脱氧合金化试验

介绍了攀钢用铝锰铁脱氧合金化生产高级别冷轧薄板用钢的可行性和脱氧合金化生产低碳铝镇静钢的工艺路线。采用铝锰铁脱氧合金化后,低碳铝镇静钢优率从现工艺的８５％提高到９９％以上,并且冷轧薄板的表面质量有了大幅度的提高。     

低碳铝镇静钢表面缺陷控制

介绍了低碳铝镇静钢轧后容易出现的几种主要钢质缺陷,并对缺陷的产生原因进行了初步分析,通过改进钢水的化学成份,降低钢水氧化性,适当延长钢水炉外处理时间和降低浇铸时中间包水口吹氩量,可有效减少低碳铝镇静钢的轧后缺陷率.     

微铌处理对低碳铝镇静钢薄钢板组织和性能的影响

以低碳铝镇静钢为研究对象,通过分析不同卷取温度时热轧态和冷轧退火态的显微组织和力学性能以及退火再结晶行为,研究了微铌(0.017%)处理对组织和性能的影响.研究结果表明,低温卷取时,低碳铝镇静钢的显微组织趋于非等轴化,但卷取温度对低碳铝镇静钢热轧态的性能影响较小;低碳铝镇静钢冷轧退火态的晶粒尺寸较热轧态细,因此,低温退火后,强度比热轧态高,此外,低温卷取时,强度较高.微铌处理后,热轧态晶粒得到明显细化,强度得到明显提高,退火再结晶受到明显延迟,当退火温度较低时,强度与热轧态相当,当退火温度较高时,因铌析出相粗化以及晶粒尺寸增加,强度接近于更低温度退火的低碳铝镇静钢.     

锆处理低碳低合金高强度钢的杂质控制

针对传统工艺技术生产的高强度低合金钢(HSLA)中杂质较高、性能不稳定等缺陷,改进了冶炼及连铸过程中一些工艺,形成了一套自主操作技术.生产的锆处理HSLA钢杂质含量显著降低,加入合金元素锆经改进工艺生产的钢板中夹杂物的大小、形态及分布均得到了明显改善,形成颗粒细小、圆形或近圆形、呈弥散分布的夹杂物.经电子探针和能谱分析表明,夹杂物一般是由Ti2O3、Al2O3、ZrO2及MnS组成的复合夹杂物,Ti2O3、Al2O3、ZrO2位于复合夹杂物的中心部位,MnS位于外层.锆处理和新工艺联合应用有效地改善了钢中夹杂物的特性,生产的HSLA钢板质量大幅度提高,具有良好的力学性能.     

Experimental and DFT study on cerium inclusions in clean steels

To provide insights into deforming Ce-O-S-Al inclusions in steels and improving the mechanical properties,the evolution process of such harmful inclusions in clean steels was investigated by thermodynamic calculation,metallographic examination and first-principles calculation in this paper.For the tested IF steel,the thermodynamic analysis results are consistent with the calculated formation enthalpy.After Ce addition,the inclusions are transformed from Al₂O₃and TiN-Al₂TiO₅-Al₂O₃to Ce2O₃,Ce₂O₂S,CeAlO₃,TiN-Al₂TiO₅-Ce₂O₃and TiN-Al₂TiO₅-Ce₂O₂S composite inclusions,which can be confirmed by metallographic examination.The elastic constants were calculated,and the bulk modulus,Young's modulus,shear modulus and Poisson's ratio were evaluated by the Voigt-Reuss-Hill(VRH)approximation.All inclusions except Ce₂O₃show apparent brittleness.TiN,Al₂O₃,Al₂TiO₅and CeAlO₃present much higher hardness than iron matrix,while the hardness of Ce2O₃or Ce₂O₂S is close to that of iron matrix.The thermal expansion coefficients of Ce₂O₃and CeAlO₃are close to that of iron matrix,whereas,Ce₂O₂S inclusion has largely different thermal expansion coefficient from iron matrix and may deteriorate the steel performance at higher temperatures.The relatively small differences between Ce inclusions and iron matrix in terms of hardness,toughness,brittleness,and thermal expansion coefficient can explain the improvement of the mechanical properties of the tested steel.     

Enhancing mechanical properties and air permeability of corundum porous materials by in situ formation of LaAl_(11)O_(18) in bonding phase

Corundum porous materials of particle-packing type with different contents of in situ formed LaAl_(11)O_(18)were prepared using tabular corundum,reactive alumina and La_2O_3 powder as raw materials.The effects of the introduction of LaAl_(11)O_(18) on the microstructure.phase composition and properties of the porous materials were investigated.The specimens were characterized by scanning electron microscopy.X-ray diffraction and mercury porosimetry.Results show that platelet-like LaAl_(11)O_(18) is formed in situ by the reactions of La_2O_3 and Al_2O_3.With a certain amount of La_2O_3 added.the cold crushing strength,cold modulus of rupture and hot modulus of rupture(1400 x 0.5 h) of the specimens are increased,and the air permeability is improved simultaneously.However.upon further increasing the amount of La_2O_3 added,the mechanical properties and air permeability of the porous materials then decrease gradually owing to the increased numbers of pores and cracks in the bonding phase.The enhanced mechanical properties of the specimens with La_2O_3 added are attributed to the strengthening effects of plate-like LaAl_(11)O_(18) in the bonding phase and to the activated sintering of both Al_2O_3 powder and corundum coarse aggregate for the diffusion of La~(3+)in Al_2O_3 lattice.In addition,the improved air permeability of the specimens should be related to the decreased content of pores in the bonding phase and the reduced number of interfacial cracks.     

超低碳钢夹杂物控制技术探讨

本文综述了超低碳钢的夹杂物起源,并以日本等先进钢厂的实践经验为基础,对Al2O3夹杂物的产生的工艺过程、影响因素重点进行了讨论,包括渣钢间二次氧化行为、RH处理中夹杂物行为、夹杂物的上浮行为以及铸坯的皮下气泡等.钢包渣改质是控制二次氧化的重要手段,RH加铝前自由氧含量尽可能降低,将浇铸时的氩气量降低均为控制超低碳钢的Al2O3类夹杂物的有效措施.     

不锈钢(304HC)浇铸过程保护渣成分变化及其对渣性能影响

通过不锈钢(304HC)连铸过程中对结晶器内液渣现场取样、分析,探索了结晶器内渣-钢界面化学反应及钢中杂夹的吸收造成渣成分的变化,及其对熔渣性能的影响.研究表明,渣中Al2O3、Cr2O3含量有所增长,F减少,碱度下降,并造成保护渣使用性能发生变化,粘度有波动、凝固温度升高及结晶率下降.研究结果为更合理地设计不锈钢连铸保护渣配方,进一步降低不锈钢铸坯表面缺陷提供了依据.     

高炉渣钾容量的试验研究

为降低碱金属对高炉的危害,提高炉渣的排碱能力,采用气-渣平衡法测定了1 723 K时高炉渣的钾容量.依据广钢实际高炉渣成分,用纯化学试剂配制炉渣,用一定组成K(g)-CO-CO2-Ar混合气体提供一定的氧分压和钾分压.研究表明:试验条件下,w(MgO)和w(A12O3)一定时,钾容量随w(CaO)/w(SiO2)的增大而减小;在w(CaO)/w(SiO2)和w(A12O3)一定时,钾容量随w(MgO)的增大而增大;在w(CaO)/w(SiO2)和w(MgO)一定时,钾容量随w(A12O3)的增大而增大;当[w(CaO) w(MgO)]/w(SiO2)和w(A12O3)固定不变时,增加w(MgO),降低w(CaO),钾容量明显增大.广钢炉渣的合理成分为:w(CaO)/w(SiO2)保持在1.0,w(MgO)保持在12%～15%,w(A12O3)不超过15%.     

Study on non-metallic inclusions in Al killed high strength alloy steel refined by high basicity and high Al_2O_3 content slag

Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al₂O₃ slag.It was found that the steel/slag reaction time largely affected non-metallic inclusions.With the reaction time increased from 30 min to 90 min in laboratory study,MgO-Al₂O₃ spinels were gradually changed into CaO-MgO-Al₂O₃ system inclusions surrounded by softer CaO-Al₂O₃ surface layers.By using high basicity slag which contained as much as 41%Al₂O₃ in the laboratory study,ratio of low melting temperature CaO-MgO-Al₂O₃ system inclusions was remarkably increased to above 80%.In the industrial experiment,during the secondary refining,the inclusions changed in order of "Al₂O₃→MgO-Al₂O₃→CaO-MgO-Al₂O₃".Through the LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al₂O₃ and CaO-MgO-Al₂O₃ system inclusions.     

高铝钢连铸保护渣性能的控制

 高铝钢连铸过程中,钢渣反应将导致连铸保护渣成分和性能发生较大的变化。论文从热力学方面分析了高铝钢钢渣反应特性,计算结果表明为了减少渣中SiO2的还原,应控制渣中的SiO2含量,此外,在连铸保护渣中配加MnO能抑制渣中SiO2的大量还原;同时采用高碱性高玻璃化连铸保护渣理论保证熔渣在钢渣反应和吸收Al2O3夹杂后性能的稳定性。在此基础上,进行了工业性试验,结果表明：高铝钢连铸保护渣吸收夹杂物后熔点和粘度变化不大,铸坯表面和皮下质量良好,完全满足高铝钢浇铸要求。     

高Al_2O_3含量渣系高炉冶炼工艺探讨

针对当前高炉炼铁原料中A l2O3含量不断提高,导致炉渣中A l2O3含量也不断提高的新情况,从分析炉渣的物理化学特性入手,剖析了高A l2O3含量高炉给操作带来的危害,并分析了在高A l2O3含量条件下改变炉渣碱度、成分对高炉冶炼的影响,探讨了高A l2O3含量条件下高炉的冶炼工艺。分析表明,炉渣中A l2O3含量高时,不能通过提高碱度的方法改善炉渣的脱硫能力;适宜地提高炉渣中M gO的含量,将有助于降低炉渣粘度和提高炉渣脱硫能力,渣中适宜的M gO含量应为8%~11%;提出了合理添加M gO的新型工艺。     

无铝脱氧在钢轨钢中的应用

攀钢采用无铝脱氧工艺，使钢轨钢中的Als和A12O3夹杂大幅降低，满足了用户对钢轨钢中Als和A12O3夹杂的要求。