Improving interlaminar fracture toughness of carbon fibre/epoxy laminates by incorporation of nano-particles

Double-cantilever-beam tests were applied to investigate the mode I interlaminar fracture toughness of carbon fibre/epoxy laminates, in which the epoxy matrices were incorporated with rubber and silica nano-particles, either singly or jointly. It is shown that the toughness is improved owing to the presence of these nano-particles although nano-rubber is more effective than nano-silica. Further, by keeping the total particle weight percentage constant in epoxies (e.g., at 8 and 12 wt.%) filled with equal amount of nano-silica and nano-rubber, the interlaminar toughness values of the hybrid laminates are always higher than those with nano-silica filled epoxies but lower than those with nano-rubber filled matrices. Scanning electron microscopy examination of the delaminated surfaces of composite laminates filled with nano-particles revealed that cavitation of nano-rubber particles/void growth and debonding of nano-silica from epoxy matrix are responsible for the improved interlaminar toughness observed. It is also shown that the bulk toughness of nano-particle filled epoxies cannot be fully transferred to the interlaminar toughness of composite laminates, being limited by the constraint effect imposed by the carbon fibres. Finally, the role of fibre-bridging on the delaminated crack and hence delamination toughness is discussed.     

Mechanisms for rate effects on interlaminar fracture toughness of carbon/epoxy and carbon/PEEK composites

The objective of this study was to investigate strain-rate dependent energy absorption mechanisms during interlaminar fracture of thermosetting (epoxy) and thermoplastic (PEEK) uni directional carbon fibre (CF) composites. A simple model addressing the translation of matrix toughness to mode I and mode II interlaminar toughness of the composite is presented, in conjunction with a fractographic examination of the fracture surfaces and the fracture process. The observed rate dependency of composite fracture toughness is attributed to the rate dependent toughness of the viscoelastic matrix and the size of the process zone around the crack tip. Other important factors identified are the roughness of the fracture surface and fibre bridging.     

Rate sensitivity of mode II interlaminar fracture toughness in graphite/epoxy and graphite/PEEK composite materials

This paper presents results from an experimental study of the effect of rate on the Mode II interlaminar fracture toughness, G_IIC, in graphite/PEEK (APC-2) and graphite/epoxy (AS4/3501-6) laminates. The end notched flexure test geometry was employed for Mode II experiments which were performed at room temperature over a range of crosshead speeds from 4·2 × 10⁻⁶ to 9¢2 × 10⁻² mc⁻¹. The APC-2 material exhibited ductile crack growth at low rates and brittle crack growth at high rates. The change in fracture mechanism resulted in a decrease in G_IIC from 1·0 to 0·40 kJ m⁻² at the upper range of test rates. The AS4/3501-6 material exhibited brittle crack growth at all rates. The G_IIC values also decreased at higher test rates from 0·46 to 0·06 kJ m⁻².     

聚酰亚胺颗粒层间增韧碳纤维/邻苯二甲腈树脂复合材料

邻苯二甲腈树脂是一种新型的高性能热固性树脂,具有优良的力学性能和耐高温性能,而邻苯二甲腈树脂本身的脆性限制了其用作结构材料方面的应用.本文采用热塑性聚酰亚胺(PI)颗粒对邻苯二甲腈树脂复合材料进行层间增韧改性,研究改性前后复合材料的耐热性能和力学性能.研究发现,使用PI对邻苯二甲腈复合材料进行改性时,随着掺入量的增加,...     

Improved fracture toughness of carbon fibre/epoxy composite laminates using dissolvable thermoplastic fibres

This paper reports on a novel toughening concept based on dissolvable phenoxy fibres, which are added at the interlaminar region in a carbon fibre/epoxy composite. The composites were prepared by resin infusion of carbon fibre fabric with the phenoxy introduced as a chopped fibre interleaf between the carbon fibre plies. The thermoplastic phenoxy fibre dissolved in the epoxy during curing at elevated temperatures and a phase separated morphology with phenoxy-rich secondary phase was formed upon curing. It was found that the average Mode-I fracture toughness value, G_1c increased tenfold with only 10 wt.% (with regard to the total matrix content) phenoxy fibre added. Other properties such as Young’s modulus, tensile strength and thermal stability were not adversely affected. The mechanical and thermal properties of the neat epoxy–phenoxy blends were also studied for comparison.     

Characterization of interlaminar shear failures of graphite/epoxy composite materials

Research undertaken to develop a more fundamental understanding of interlaminar shear failure in laminated graphite/epoxy composites is described. A test method capable of producing a state of pure interlaminar shear stress within a specified region of a composite test specimen was devised. The test method consisted of the four-point flexural testing of a unique test sample constructed of a coupon of Hercules AS4/3501-6, unidirectional, graphite/epoxy material bonded between two strips of steel using a room-temperature-curing epoxy adhesive. The major advantage of the test method is that the interlaminar shear failure of the composite coupon results from an induced state of pure shear stress, rather than from damage resulting from a complex stress state affecting the region of loading as typically occurs in the case of conventional flexural-type shear tests. The resulting shear failures were characterized with respect to fracture surface appearance, mode of failure, and stress state on the failure plane. A specially designed crack detection device was used to determine the site of fracture initiation and the direction of crack propagation.     

Mode I interlaminar fracture toughness of commingled carbon fibre/PEEK composites

Carbon fibre/poly (ether-ether-ketone) (PEEK) composites were fabricated from plain weave cloth using the commingled yarn of carbon fibres with PEEK filaments. The undirectional specimen was made from the warp of commingled yarn and the weft of PEEK yarn, while the two-dimensional specimen was made from commingled yarns both of the warp and the weft. During the hot-pressing process, PEEK filaments melt to form the matrix of the composite. The interlaminar fracture toughness of the commingled composite was measured and compared with that of the prepreg composite. The critical strain energy release rates,/'G _Ics, obtained for the commingled composites were higher than the prepreg composite. In particular, the two-dimensional composite exhibited higherG _Ic than the unidirectional commingled composite. Factors increasing the fracture toughness of commingled composites have also been investigated by SEM observation of the fractured surface.     

Analysis of stitched laminated ENF specimens for interlaminar mode II fracture toughness

Two simple micromechanics based models are proposed to predict the effect of through-thickness reinforcement (stitching) on the improvement of delamination crack growth resistance in end-notched flexure (ENF) specimens. In the first model, it is assumed that stitches stretch elastically and then rupture when the load carried approaches the failure load. In the second model, it is assumed that stitches are discontinuous and that the stitch thread-matrix interface is completely frictional. Approximate closed form solutions for energy release rates are obtained, and the effects of stitch density, matrix-stitch thread interfacial shear stress, stitch thread diameter, volume fraction of stitches, critical energy release rate and Young's modulus are then examined. A simple design study for sizing the ENF specimen to minimise geometric nonlinear response is presented. The influences of interlaminar shear deformation and friction between the crack surfaces on the strain energy release rate are examined.     

Effects of carbon nanotubes on the interlaminar shear strength and fracture toughness of carbon fiber composite laminates: a review

Journal of Materials Science - The interlaminar mechanical properties of composites are important parameters for the application of laminates, and many scholars have applied carbon nanotubes (CNTs)...     

Effect of the loading rate on mode I interlaminar fracture toughness of laminated composites

The objective of the present study is to determine the influence of the loading rate on the critical energy release rate G_Ic of fibre-reinforced epoxy laminates. In order to perform pure mode I loading at higher opening velocities, a new test device is developed. The approach is based on a symmetrical opening displacement applied to a DCB specimen. In the data reduction, the influence of the kinetic energy has to be taken into account. The results obtained on the unidirectional carbon-epoxy laminate T300/914 at crack opening rates up to 1.6 m/s show a slight effect of the loading rate on G_Ic.     

有机黏土对碳纤维/聚醚砜-环氧复合材料层间断裂韧性的影响

采用溶剂法和热熔法制备了不同有机黏土质量分数的有机黏土/聚醚砜（PES）-环氧复合材料,通过对其微观形态和力学性能的研究,揭示了复合材料的增韧机制。在有机黏土/PES-环氧复合材料中添加T800H（12K）碳纤维,制备了T800H-有机黏土/PES-环氧复合材料预浸料单向带,采用热压罐工艺制备了复合材料单向板,对其I型、II型层间断裂韧性进行了研究。结果表明:T800H-有机黏土/PES-环氧复合材料的层间断裂韧性随有机黏土质量分数变化趋势与有机黏土/PES-环氧复合材料的断裂韧性趋势一致,证明了增韧机制的正确性。      

Effect of fibre content on the interlaminar fracture toughness of unidirectional glass-fibre/polyamide composite

In this paper, the effects of fibre content on the interlaminar fracture in continuous glass-fibre/polyamide 12 composite have been investigated under model I (DCB) loading condition. The specimens were fabricated with different fibre volume contents (21%, 26%, 34% and 39%) by using a powder impregnation method. It was observed that the values of G_IC(NL) and G_IC(PROP) of this material have a dropping tendency with increasing fibre volume content in the range of 21%–39%, while no general trends in G_IC(5%) and G_IC(VIS). Results show that the glass-fibre/polyamide 12 composites possess high mode I fracture toughness, which is mainly attributed to the high ductility of the polyamide 12 matrix, and the increased fibre bridging caused by the increasing of the fibre volume content can not change the decrease tendency of G_IC(PROP). The fracture surfaces of the specimens were observed by scanning electron microscopy, and the fracture mechanism was analysed.     

Mode III interlaminar fracture of carbon/epoxy laminates using a four-point bending plate test

A new four-point bending plate (4PBP) test was used for characterising the mode III interlaminar fracture of carbon/epoxy laminates. The specimen has a cross-ply lay-up and two edge delaminations whose propagation becomes visible at the edges. Although the test setup is very simple, determination of the mode III critical strain energy release rate G_IIIc requires finite element analyses (FEA). The virtual crack closure technique with an assumed initiation region was first proposed for computing G_IIIc. This scheme was subsequently validated by crack growth simulations with a cohesive zone model. The results showed an average G_IIIc = 1550 J/m², which is significantly higher than the G_IIIc = 850–1100 J/m² and G_IIc = 800 J/m² measured in previous studies.     

CF/EP composite laminates with carbon black and copper chloride for improved electrical conductivity and interlaminar fracture toughness

An experimental study was conducted to improve the electrical conductivity of continuous carbon fibre/epoxy (CF/EP) composite laminate, with simultaneous improvement in mechanical performance, by incorporating nano-scale carbon black (CB) particles and copper chloride (CC) electrolyte into the epoxy matrix. CF/EP laminates of 65 vol.% of carbon fibres were manufactured using a vacuum-assisted resin infusion (VARI) technique. The effects of CB and the synergy of CB/CC on electrical resistivity, tensile strength and elastic modulus and fracture toughness (K_IC) of the epoxy matrix were experimentally characterised, as well as the transverse tensile modulus and strength, Mode I and Mode II interlaminar fracture toughness of the CF/EP laminates. The results showed that the addition of up to 3.0 wt.% CB in the epoxy matrix, with the assistance of CC, noticeably improved the electrical conductivity of the epoxy and the CF/EP laminates, with mechanical performance also enhanced to a certain extent.     

Mixed-mode I + III interlaminar fracture of carbon/epoxy laminates

A new test was developed for measuring the mixed-mode I + III interlaminar fracture toughness. The specimen adopted was an 8-point bending plate (8PBP) with a cross-ply lay-up and a mid-thickness edge pre-delamination at the standard 0/0 interface. Finite element analyses (FEA) showed that a wide range of mode mix ratios can be achieved by varying the load point displacements imposed. However, the need of FEA based experimental data reduction and of a relatively complicated fixture are important drawbacks of test developed. Nevertheless, results for carbon/epoxy laminates showed a realistic evolution of initiation G_c values with the G_III/G mode mix ratio.     

Interfacial mobility and its effect on interlaminar fracture toughness in glass-fibre-reinforced epoxy laminates

The effects of interfacial treatment of glass fibres in glass/epoxy composites were studied through Mode I delamination fracture toughness tests using a double cantilever beam specimen. The treatment of glass fibres with two similar silane coupling agents has been shown to improve the mechanical properties of the composite as a function of the type of coupling agent, -aminopropyltriethoxysilane (APS) and -aminobutyltriethoxysilane (ABS) have similar chemistry, but differ in mobility (molecular motion) at the coupling agent-epoxy interface. The critical energy release rate, G _1c, for the APS-treated composites (0.59±0.05 kJ m^–2) was shown to be higher than that of the ABS-treated one (0.37±0.01 kJ m^–2) and also the untreated one (0.31±0.02 kJ m^–2). In this case, the bulk structural property appears to be a function of the microscopic interfacial properties including the dynamics of the coupling agent layer. Optical characterization of the fracture surfaces reveal delamination at the epoxy-glass interface for the untreated samples, while the ABS- and APS-treated samples showed less interfacial delamination, respectively.     

孔隙对碳纤维/环氧复合材料层合板层间剪切疲劳性能的影响

研究了孔隙对碳纤维增强环氧树脂基复合材料层合板［(±45)/0₄/(0, 90)/0₂］_S的静态层间剪切强度和层间剪切疲劳性能的影响。采用不同的热压罐压力制备了孔隙率为0.4%~6.6%的试样。采用显微照相法和图像分析技术对孔隙率和孔隙的微观形貌进行了分析。研究结果表明, 随着热压罐压力的降低, 大孔隙(S>7.85×10-3mm2)所占的比例逐渐增加, 平均孔隙率增加。在孔隙率为0.4%~6.6%时, 每增加1%, 复合材料层压板的层间剪切强度下降2.4%。随着孔隙率的增加, 层压板的疲劳寿命降低。与静态试验相比, 孔隙率对层压板疲劳性能的影响比对静态性能的影响大。大孔隙的存在促进了疲劳裂纹的产生和扩展。      

Four-point bend interlaminar shear testing of uni- and multi-directional carbon/epoxy composite systems

Purpose of the paper is to investigate the possibility of extending the interlaminar shear strength (ILSS) results obtained by four-point bend testing of unidirectional laminates to multidirectional laminates, such as cross-ply and quasi-isotropic, the testing of which is a common practice in the industry but has not been previously validated in the literature. An experimental database is gathered through the known modified version of the ASTM D2344 short beam test and the results show a surprising proximity of results for the three different fiber architectures for the same composite system. Various finite element analyses were developed using ANSYS^® software, allowing for better insight on the mechanics of delamination in four-point bending, and showed extremely good agreement with the experimental values. The final and most accurate model partially confirmed observations made by other authors, and includes the ‘skewed’ profile of the shear stress through the thickness and its variation along the length, the distribution of the shear stress across the width, the location of delamination initiation and propagation and maximum ILSS and the shear stress contour.     

A study on interlaminar behavior of carbon/epoxy laminated curved beams by use of acoustic emission

Abstract

The interlaminar tensile strength of carbon/epoxy laminated curved beams with variable thickness and through-the-thickness tufted reinforcement is studied experimentally by means of a four-point-bending test in accordance with ASTM D6415. These tests are monitored by the acoustic emission (AE) technique in order to gain deeper knowledge of the delamination onset and post-failure behavior. The results show that AE technique has proven to perform well when identifying delamination onset and its evolution after failure. In addition to this, AE has demonstrated to be an appropriate tool to assess the manufacturing quality of the carbon/epoxy laminated curved-beam, once the right pattern has previously been established.