共查询到20条相似文献,搜索用时 15 毫秒
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JOHN V. FLORIO 《Journal of the American Ceramic Society》1960,43(5):262-267
The dielectric constant and dissipation factor of both single-crystal and polycrystalline alumina were measured in air over the frequency range lo2 to 3 × 105 cycles per second, in the temperature interval 900° to 1300° C. The three-electrode guard-ring method was used. The observed dielectric losses were due predominately to free-electron conduction mechanisms. The volume conductivity of single-crystal and polycrystalline alumina was calculated from the high-frequency data. The temperature dependences of the volume conductivity for two single crystals of different thicknesses were similar. The large thermal activation energy indicated intrinsic conductivity; the energy band gap of alumina was calculated to be approximately 7.3 electron volts. The bulk conductivities of the polycrystalline alumina were considerably higher than the single-crystal values, presumably because of impurities in the polycrystalline material. The results were compared with values previously reported in the literature. 相似文献
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平行板谐振法测量高介电材料微波特性 总被引:2,自引:1,他引:1
讨论高介电材料介电常数、损耗角正切的测量技术、测量基本原理及相关参数的计算方法。介绍平行板谐振法的测量方法、测量装置和测量系统,阐述该方法的软硬件构成。给出实际测量中模式的判别方法及测量误差分析,并给出部分测量结果。介电常数ε,的测量相对误差小于0.26%,损耗角正切tanδ的测量相对误差小于7.5%。通过不同的方法对所选取的新型高介电材料微波特性进行测量,对比测量结果,验证该测量方法的正确性。 相似文献
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Hanna Kähäri Merja Teirikangas Jari Juuti Heli Jantunen 《Journal of the American Ceramic Society》2014,97(11):3378-3379
Lithium molybdate disks were fabricated by moistening water‐soluble Li2MoO4 powder with deionized water and compressing it under a pressure of 130 MPa. Disks were postprocessed at room temperature, at 120°C, and at 540°C, which is a common sintering temperature for Li2MoO4. Regardless of the postprocessing temperature, densities as high as 87%–93% of the theoretical value were achieved. The X‐ray diffraction patterns of processed disks were all the same with no signs of hydrates or constitutional water. The samples also exhibited very similar microstructures and microwave dielectric properties with a relative permittivity of 4.6–5.2 and a Q × f value of 10 200–18 500 at 9.6 GHz, depending on the postprocessing temperature. 相似文献
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Ang Hu Yonghan Fang J. Francis Young Young-Jei Oh 《Journal of the American Ceramic Society》1999,82(7):1741-1747
The relationship between humidity and dielectric constant for cement densified with small particles (DSP) has been studied in the relative humidity range 0%-93% and the frequency range 1 MHz to 1 GHz. The calculated dielectric constant appears to increase with increasing humidity as a linear relation at fixed frequency. According to experimental data and basic principles for dielectrics, two experimental expressions are suggested for heterogeneous dielectric materials to describe the observed behavior of the dielectric constant. The expressions fit the experimental data well in the frequency range studied. Apparent dielectric constant decreases with increasing frequency. Polarization of DSP cement is also discussed. 相似文献
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研究高温下不同炭黑用量的氢化丁腈橡胶(HNBR)的回弹值、邵尔A型硬度、拉伸强度、拉伸应力松弛性能和动态力学性能等,分析温度对橡胶分子链段和物理交联网络等微观运动和微观结构的影响。结果表明:随着温度从25℃升高至150℃,不同炭黑用量的HNBR硫化胶的邵尔A型硬度和拉伸强度逐渐减小,回弹值先增大后减小,应力松弛速率增大,应变扫描前后储能模量之差减小;炭黑用量越大,高温下HNBR硫化胶的拉伸强度保持率越大,应力松弛的平衡应力占比越小;温度升高会破坏炭黑补强HNBR硫化胶的填料网络结构,导致结合胶含量减少,HNBR硫化胶高温下的力学性能下降。 相似文献
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Satbaev B. N. Nurumgaliev A. Kh. Shishkin Yu. I. Aimbetova É. O. Shalabaev N. T. Satbaev A. B. 《Refractories and Industrial Ceramics》2020,61(1):86-89
Refractories and Industrial Ceramics - Results are provided for studies of self-sintering refractory mix preparation. New technology is proposed for their manufacture. The basis of the mixes... 相似文献
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通过反应共混技术制备了聚苯乙烯(PS)/苯乙烯-丁二烯-苯乙烯共聚物(SBS)改性沥青,研究了 PS 用量、反应剂硫磺(sulfur)对沥青高温贮存稳定性、黏度-温度特性和动态力学性能的影响。结果表明:通过反应共混改性所得到的改性沥青在高温贮存时,当 PS/SBS 不大于1/1时贮存样品上下层软化点差值小于2.5℃,贮存稳定性能得到了明显改善。对于沥青/PS/SBS/Sulfur 为100/3/3/0.15的体系,沥青的黏流活化能(Eη)从65kJ/mol 降低到了52.8kJ/mol;同时显著提高了沥青的高温复数模量和弹性,损耗角正切值(tanδ)在30~100℃范围内的变化小于10。 相似文献
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中温烧结PSBN系统铁电陶瓷结构和性能的研究 总被引:1,自引:1,他引:1
本文研究了中温烧结PbO-SrO-BaO-Nb2O5(PSBN)系统铁电陶瓷介电性能.通过XRD分析确定了主晶相为具有钨青铜结构的Pb0.7Ba0.3Nb2O6(PBN)、Ba0.27Sr0.75Nb2O5.78(BSN);分析了添加剂MnCO3、TiO2、Fe2O3、(MgCO3)4.Mg(OH)2.5H2O对PSBN系统铁电陶瓷介电性能的影响.由于这些添加剂的作用使该系统铁电陶瓷介电系数提高,居里区拓宽并向低温方向移动,绝缘电阻提高,损耗降低,制得高介(ε=4300±200)X7R瓷料. 相似文献
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Vasundhara Katari Sadequa J. Patwe Srungarpu N. Achary Avesh K. Tyagi 《Journal of the American Ceramic Society》2013,96(1):166-173
Orthorhombic InVO4 was prepared by solid‐state reaction method and characterized by powder X‐ray diffraction and scanning electron microscopy. The frequency‐dependent dielectric and conductivity properties were studied from 300 to 973 K by impedance spectroscopy. A significantly enhanced conductivity was observed at higher temperature whereas almost no conduction was observed below 723 K. Appreciable grain boundary conductivity was observed at higher temperature. The activation energies for grain and grain boundary conductivities are 0.87 and 1.28 eV, respectively. The relative permittivity of ~35 was observed in a wider range of frequencies and temperatures. The frequency dispersion dielectric studies indicated thermally activated hopping conduction process. The high temperature structural studies revealed no significant change in structural parameters except a gradual increasing trend in the unit cell parameters and amplitude of isotropic thermal parameters with increasing temperature. 相似文献
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ABSTRACT During the falling rate period of drying the heat requirements for drying hygroscopic materials may be increased substantially ahove the normal latent heat by the heat of desorption of water. In various new high intensity drying processes which are of increasing interest industrially, the drying material may reach quite high temperatures for periods of time sufficiently short that there is no degradation of the properties of the dried material. However the limited stability of many materials at high temperatures precludes determination of heals of desorption by direct measurements because of the long experimental times required for thermodynamic techniques. The present study develops a thermodymically valid method whereby heats of desorption determined at low lemperatures may be extrapolated reliably to the high temperatures where such information is needed but cannot be measured. A relation between isosteric heat of desorption and latent heat of water is derived in order to compare the new 相似文献
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