The dose-response of Harshaw TLD-700H

Harshaw TLD-700H (7LiF:Mg,Cu,P) was previously characterised for low- to high-dose ranges from 1 microGy to 20 Gy. This paper describes the studies and results of dose-response and linearity at much higher doses. TLD-700H is a near perfect dosimetric material with near tissue equivalence, flat energy response, and the ability to measure beta, gamma and X rays. These new results extend the applicability of Harshaw TLD-700H into more dosimetric measurement environments. The simple glow curve structure provides insignificant fade, eliminating special oven preparation methods experienced by other materials. The work presented in this paper quantifies the performance of Harshaw TLD-700H in extended ranges.     

Development of LiF:Mg,Cu,Si TL material (new KLT-300) with a low-residual signal and high-thermal stability

LiF-based thermoluminescence (TL) materials have been widely used for radiation dosimetry due to their attractive features. LiF:Mg,Cu,P is one of the most sensitive tissue-equivalent TL materials, approximately 40 times more sensitive than LiF:Mg,Ti (TLD-100), but it has two main drawbacks: a thermal loss of the TL sensitivity when annealed at temperatures >240 degrees C, and a relatively high-residual signal. Recently, LiF:Mg,Cu,Na,Si TL material was developed to overcome these drawbacks at the Korea Atomic Energy Research Institute, but it provided only marginal improvements in reducing the residual signal. The newly developed LiF:Mg,Cu,Si TL material has a significantly lower residual signal and a better stability to thermal treatments. In this article, the preparation method and some dosimetric properties (sensitivity and residual signal) of the new LiF:Mg,Cu,Si TL material are presented. At the end of the preparation procedures, a dual-step annealing method is introduced and this has proved as a very efficient method to reduce the high-temperature peak and is the cause of residual signal. Therefore, the high-temperature peak in the glow curve was significantly reduced. The sensitivity is approximately 20 times higher than that of TLD-100 and the residual signal was estimated to be approximately 0.04%.     

Performance of Harshaw TLD-100H two-element Dosemeter

One of the advantages of LiF based thermoluminescent (TL) materials is its tissue-equivalent property. The Harshaw TLD-100H (LiF:Mg,Cu,P) material has demonstrated that it has a near-flat photon energy response and high sensitivity. With the optimized dosemeter filters built into the holder, the Harshaw TLD-100H two-element dosemeter can be used as a whole body personnel dosemeter for gamma, X ray and beta monitoring without the use of an algorithm or correction factor. This paper presents the dose performance of the Harshaw TLD-100H two-element dosemeter against the ANSI N13.11-2001 standard and the results of tests that are required in IEC 1066 International Standard.     

The application of computerised analysis of glow curves to personal dosimetry in LiF:Mg,Cu,P

In personnel monitoring services, it is important to omit the high-temperature annealing process so that large numbers of TL detectors can be produced economically. There are two efficient ways of reducing the residual signal of LiF:Mg,Cu,P. One is by increasing the maximum readout temperature and the other is by improving the preparation procedure (increasing the Cu concentration and the sintering temperature) but both reduce the TL sensitivity. In personal dosimetry the real dosimetric signals are separated from the residual signals by computerised analysis of glow curves. The adverse influence of the high residual signals of LiF:Mg.Cu.P TL material has been effectively eliminated and the sensitivity remains stable. A good dosimetric result using only reader measurement without pre-irradiation oven annealing is attained in a dose range of 50-80,000 microGy.     

A comparative study on the susceptibility of LiF:Mg,Ti (TLD-100) and LiF:Mg,Cu,P (TLD-100H) to spurious signals in thermoluminescence dosimetry

It is well known that spurious signals can occur in thermoluminescence dosimetry (TLD) whenever contaminants (i.e. dirt, oil, dust) are present on the surface of the TLD card or crystal during the read-out process. For TLD cards, the Teflon material can also contribute to the background noise and this contribution has been found to depend on the material's light absorption. These non-radiation-induced signals contribute to the total light output during TLD read-out and can lead to incorrect dosimetry especially for low-dose measurements such as personal dosimetry. However, these spurious signals are generally in the low-temperature channels and are mostly accompanied by abnormal glow curves. Most of the published reports dealing with this type of spurious TL signal are on the LiF:Mg,Ti (TLD-100) material. The relatively new TLD material, LiF:Mg,Cu,P, is more sensitive and has higher signal-to-noise ratio than the traditional LiF:Mg,Ti. In this study, the effects of disturbing signals to the LiF:Mg,Cu,P (TLD-100H) cards used in personal dosimetry are investigated and compared with those of LiF:Mg,Ti (TLD-100).     

Thermoluminescence dosimetry of a thermal neutron field and comparison with Monte Carlo calculations

The characteristics of thermoluminescence dosemeters (TLDs) regarding the determination of photon and neutron absorbed doses were investigated in a thermal neutron beam. Harshaw TLD-100 (LiF:Mg,Ti) and TLD-700 (7LiF:Mg,Ti) were compared with similar materials from Solid Dosimetric Detector and Method Laboratory (People's Republic of China). Harshaw TLD-700H (7LiF:Mg,Cu,P) and aluminium oxide (Al2O3:Mg,Y) from Hungary were also considered for photon dose measurement. The neutron sensitivity of the investigated materials was measured and found to be consistent with values reported by other authors. A comparison was made between the TL dose measurements and results obtained via conventional methods. An agreement within 20% was obtained, which demonstrates the ability of TLD for measuring neutron and photon doses in a mixed field, using careful calibration procedures and determining the neutron sensitivity for the usage conditions.     

Pre-irradiation and post-irradiation fading of the Harshaw 8841 TLD in different environmental conditions

The pre-irradiation and post-irradiation fading of a commercially available LiF:Mg,Cu,P thermoluminescent detector (TLD)-the Harshaw 8841 TLD-have been assessed. The Harshaw 8841 TLD comprises three TLD-700H chips (99.7% 7LiF and 0.03% 6LiF by weight) and one TLD-600H chip (4.4% 7LiF and 95.6% 6LiF by weight). Pre-irradiation and post-irradiation fading were measured for storage times up to 164 d and three different storage temperatures (-8, 25 and 50 degrees C). Dosemeters were irradiated in a mixed photon-neutron field so that the fading behaviour of the photon and neutron signals could be studied. The TLD-700H and TLD-600H chips exhibited complex changes in sensitivity and signal that depended on storage time, storage temperature and the type of radiation to which the chips had been exposed. However, the magnitudes of these changes in sensitivity and signal were relatively small. TLD-600H and TLD-700H, therefore, exhibit good stability of sensitivity and signal.     

Reproducibility of TL measurements in a mixed field of thermal neutrons and photons

The reproducibility of measurements performed with GR-100 (LiF:Mg,Ti) from the Solid Dosimetric Detector and Method Laboratory (DML) China, GR-107 (7LiF:Mg,Ti, DML), TLD-700H (7LiF:Mg.Cu,P, Harshaw) and Al2O3:Mg,Y (Hungary) in photon and mixed photon-neutron fields was investigated. Mixed-field irradiations were performed in a thermal neutron field generated at a nuclear reactor. GR-100 sensitivity decreased after mixed-field irradiations, while no significant change was found for the other materials. Using GR-100 for the dosimetry of mixed and high-intensity fields requires careful procedures.     

UV-induced bleaching of deep traps in Harshaw TLD LiF:Mg,Cu,P and LiF:Mg,Ti

The effects of UV-induced bleaching of deep traps on Harshaw thermoluminescent (TL) LiF:Mg,Cu,P and LiF:Mg,Ti materials were investigated. During a normal heating cycle, LiF:Mg,Cu,P is limited to a maximum temperature of 240 °C. LiF:Mg,Ti can be read to higher temperatures; however, encapsulation in polytetrafluoroethylene limits the maximum readout temperature to 300 °C. Generally, for both materials, these respective temperatures are sufficient for emptying traps corresponding to the main dosemetric peaks. However, when the dosemeters are subjected to a high dose level, such as 1 Gy (much higher than individual monitoring dose levels), higher temperature traps are filled that cannot be emptied without exceeding the above-mentioned maximum temperatures. These high temperature traps tend to be unstable during normal readout and can significantly increase the residual TL signal. The purpose of this study was to investigate the applicability of a UV-induced bleaching technique for emptying higher temperature traps following high-dose applications. In addition, in the case of LiF:Mg,Cu,P, where the maximum readout temperature is significantly lower, we investigated the possibility of reducing the residual signal using the application of repeated readout cycles. The optical bleaching approach was found to be effective in the case of LiF:Mg,Ti; however, for LiF:Mg,Cu,P, no reduction in the residual signal was observed. For this latter material, the application of repeatable readout cycles is very effective and residual signals equivalent to dose levels as low as 0.01 mGy were observed following an initial dose of 5 Gy. To the best of our knowledge, this work is the first attempt to apply an 'optical annealing' technique to the Harshaw thermoluminescent dosemeter (TLD) materials.     

Type testing the Model 6600 plus automatic TLD reader

The Harshaw Model 6600 Plus is a reader with a capacity for 200 TLD cards or 800 extremity cards. The new unit integrates more functionality, and significantly automates the QC and calibration process compared to the Model 6600. The Model 6600 Plus was tested against the IEC 61066 (1991-2012) procedures using Harshaw TLD-700H and TLD-600H, LiF:Mg,Cu,P based TLD Cards. An overview of the type testing procedures is presented. These include batch homogeneity, detection threshold, reproducibility, linearity, self-irradiation, residue, light effects on dosemeter, light leakage to reader, voltage and frequency, dropping and reader stability. The new TLD reader was found to meet all the IEC criteria by large margins and appears well suited for whole body, extremity and environmental dosimetry applications, with a high degree of dosimetric performance.     

Pre- and post-irradiation fading effect for LiF:Mg,Ti and LiF:Mg,Cu,P materials used in routine monitoring

LiF is a well-known thermoluminescent (TL) material used in individual monitoring, and its fading characteristics have been studied for years. In the present study, the fading characteristics (for a period of 150 d) of various commercial LiF materials with different dopants have been evaluated. The materials used in the study are those used in routine procedures by the Personal Dosimetry Department of Greek Atomic Energy Commission and in particular, LiF:Mg,Ti (MTS-N, TL Poland), LiF:Mg,Cu,P (MCP-N, TL Poland), LiF:Mg,Cu,P (MCP-Ns, thin active layer detector, TL Poland) and LiF:Mg,Cu,P (TLD100H, Harshaw). The study showed that there is a sensitivity loss in signal of up to 20 % for the MTS-N material for a 150-d period in the pre-irradiation fading phase. The MCP-N has a stable behaviour in the pre-irradiation fading phase, but this also depends on the readout system. As far as the post-irradiation fading effect is concerned, a decrease of up to 20 % for the MTS-N material is observed for the same time period. On the other hand, the LiF:Mg,Cu,P material presents a stable behaviour within ± 5 %. These results show that the fading effect is different for each material and should be taken into account when estimating doses from dosemeters that are in use for >2 months.     

Combined effects of high doses and temperature on radiation-induced radicals and their relative contributions to EPR signal in gamma-irradiated alanine

The glow curve shape of LiF:Mg,Cu,P (MCP) material is studied in this research. The study is focused on the effects of the heating rate on the dosimetric peaks. Different configurations of dosemeters (chips, cards and powder) are studied. The shifting of the dominant dosimetric peak is observed and analysed. The curves are deconvoluted using the new Harshaw Glow Curve Analyser (GCA) program. Results of the study are presented, as well as possible explanations as to the observed effects.     

Comparison of time effects, decision limit and residual signal in Harshaw LiF:Mg,Ti and LiF:Mg,Cu,P

The personal dosimetry service of the UK Health Protection Agency-formerly of the National Radiological Protection Board (NRPB)-is currently commissioning a body thermoluminescence dosemeter (TLD) system based on the use of Harshaw(TM) 8800 readers and two-element cards. As part of the process, studies have been carried out into the long-term time dependence of response, the limit of detection and the magnitude of the signal remaining after recommended processing. TLD cards containing both conventional lithium fluoride (LiF:Mg,Ti) and the high-sensitivity material LiF:Mg,Cu,P were available, thus allowing a comparison between the two types of material.     

Main dosimetric characteristics of some tissue-equivalent TL detectors

The aim of this work was to determine important dosimetric characteristics of several types of the most interesting tissue-equivalent thermoluminescent detectors (TLDs). Special attention was given to the determination of energy dependence for medium and low energy X rays. The following types of TLDs were investigated: (a) two new types based on lithium borate: Li2B4O7:Cu,In and Li,B4O7:Cu,In,Ag; (b) two types of the recently developed highly sensitive LiF:Mg,Cu,P material: TLD-700H and GR 200A and (c) two well known types of LiF:Mg,Ti detectors: TLD-100 and TLD-700. In order to determine their photon energy response characteristics, TLDs previously calibrated with 137Cs gamma rays were simultaneously irradiated with X ray beams in the range of effective energies between 33 and 116 keV. Measured energy responses (relative to air), normalised to those to 137Cs photons were compared with calculated data. Although the deviations of the measured data from the 'theoretical' predictions are different for all the investigated TLDs, there is no large difference in 'tissue-equivalency' between them.     

The MCNP-4C2 design of a two element photon/electron dosemeter that uses magnesium/copper/phosphorus doped lithium fluoride

The Health Protection Agency is changing from using detectors made from 7LiF:Mg,Ti in its photon/electron personal dosemeters, to 7LiF:Mg,Cu,P. Specifically, the Harshaw TLD-700H card is to be adopted. As a consequence of this change, the dosemeter holder is also being modified not only to accommodate the shape of the new card, but also to optimize the photon and electron response characteristics of the device. This redesign process was achieved using MCNP-4C2 and the kerma approximation, electron range/energy tables with additional electron transport calculations, and experimental validation, with different potential filters compared; the optimum filter studied was a polytetrafluoroethylene disc of diameter 18 mm and thickness 4.3 mm. Calculated relative response characteristics at different angles of incidence and energies between 16 and 6174 keV are presented for this new dosemeter configuration and compared with measured type-test results. A new estimate for the energy-dependent relative light conversion efficiency appropriate to the 7LiF:Mg,Cu,P was also derived for determining the correct dosemeter response.     

Evaluating two extremity dosemeters based on LiF:Mg,Ti or LiF:Mg,Cu,P

Evaluation of a new extremity dosemeter is presented. The dosemeter is a passive device that is easy to wear and features a permanent individual numerical ID with barcode, a watertight case, an automatic TLD reader and database management software. Two dosemeters were studied: the first consists of a 100 mg x cm(-2) 7LiF:Mg,Ti (TLD-700) chip and a 42 mg x cm(-2) cap, the other consists of a 7 mg x cm(-2) layer of 7LiF:Mg,Cu,P (TLD-700H) powder and a 5 mg x cm(-2) cap. Sensitivity, repeatability, lower limit detection, angular responses and energy responses for these dosemeters are studied and presented. The dose calculation algorithm is developed and its dosimetric performance accuracy is compared with the standard ANSI N13.32-1995, Performance Testing of Extremity Dosemeters.     

The implementation in routine of the ENEA new personal photon dosemeter

The ENEA photon dosemeter, introduced in 1995, consisting of two differently filtrated LiF(Mg,Cu,P) detectors, has been modified recently. The ABS (acrylonitrile butadiene styrene) plastic support has been replaced by a new aluminium card supporting the same two detectors (LiF(Mg,Cu,P) GR200). The new card, fully developed at the ENEA-Radiation Protection Institute (which is going to be patented), can now be processed through a Harshaw Model 6600 Automated TLD Reader, a hot gas reader. This paper reports the results of the individual calibration of approximately 60,000 LiF(Mg,Cu,P) GR200 detectors inserted on the new aluminium cards. Before the implementation in routine of the new cards, the reader has been characterised. Steps and tests to be made to use the card in routine (i.e. reader stability, linearity, reproducibility, etc.) are reported. The whole dosimetric system now combines the very good performances of the Harshaw Model 6600 reader and that of LiF(Mg,Cu,P) thermoluminescent material.     

Energy dependence of new thermoluminescent detectors in terms of HP(10) values

The aim of this work was to determine energy dependence characteristics in terms of values of the personal dose equivalent, HP(10). The following types of thermoluminescent detectors (TLDs) were investigated: (a) two new types based on lithium borate, Li2B4O7:Cu,In and Li2B4O7:Cu,In,Ag; (b) two types based on the highly sensitive material LiF:Mg,Cu,P, TLD-700H and GR 200A; (c) two well-known types of LiF:Mg,Ti detector, TLD-100 and TLD-700 and (d) highly sensitive Al2O3:C detectors. TLDs previously calibrated with 137Cs gamma rays were simultaneously irradiated with X ray beams in the range of mean energies between 33 and 116 keV. The irradiations were performed with detectors in polymethyl methacrylate (PMMA) holders placed on a 30 cm x 30 cm x 15 cm water phantom with PMMA walls (ISO phantom). Measured energy responses were compared with calculated data for HP(10) values. The results confirmed the satisfactory tissue equivalent characteristics of all investigated TLDs except Al2O3:C, which (due to its large energy dependence) is suitable for personal dosimetry only with an appropriate filter.     

Comparison of the effects of exposure to light in Harshaw LiF:Mg,Ti and LiF:Mg,Cu,P

The response of thermoluminescence dosemeters (TLDs) to light, in various conditions, has been studied. TLD cards containing both conventional lithium fluoride (LiF:Mg,Ti) and the high-sensitivity material LiF:Mg,Cu,P were available, so permitting a comparison between the two types. Also available for the tests were Harshaw(TM) extremity EXT-RAD (LiF:Mg,Cu,P) dosemeters. The LiF:Mg,Ti body TLD cards and the EXT-RAD extremity dosemeters both showed some response to fluorescent light, while the LiF:Mg,Cu,P cards showed no significant response. It is therefore concluded that LiF:Mg,Cu,P body cards need no special precautions to protect them from the effects of light. For LiF:Mg,Ti cards and extremity dosemeters, effects are small, but steps to avoid excessive light exposure should be considered.     

Type testing of an extremity finger stall dosemeter based on Harshaw TLD EXTRAD technology

A new type of extremity dosemeter, which incorporates the Harshaw TLD EXTRAD dosemeter element into a PVC finger stall, has been developed. The dosemeter uses high-sensitivity lithium fluoride, (7)LiF:Mg,Cu,P (TLD-700H) in a thin 7 mg cm(-2) layer, with alternative coverings of PVC at 10 mg cm(-2) and aluminised polyester at 3.2 mg cm(-2). Results are presented of the type testing of both versions of the finger stall dosemeter against published standards.