Thermal conductivity of hydrocarbons in the naphthene group under high pressures

The thermal conductivity of hydrocarbons in the naphthene group has been experimentally determined. An equation is now proposed for calculating the thermal conductivity over the given temperature and pressure ranges.Notation thermal conductivity - ₂₀ and ₃₀ values of the thermal conductivity at 20 and 30°C, respectively - t₀,P₀ thermal conductivity at t₀, p₀ - _t p thermal conductivity at temperature t and under pressure P - change in thermal conductivity - P pressure - P_melt melting pressure - P₀ atmospheric pressure - t₀ 20°C temperature - T, t temperature - T_cr critical temperature - temperature coefficient of thermal conductivity - ₂₀ temperature coefficient of density - density - ₂₀ density at 20°C - _cr critical density - M molar mass - =T/T_cr referred temperature - v specific volume - v₀ specific volume at 20°C - v change in specific volume - _{3 0} a coefficient - B (t) a function of the temperature - S a quadratic functional - W_i, weight of the i-th experimental point - _i error of the i-th experimental value of thermal conductivity - B _{y, =0.6} value of B (t) at T = 0.6T_cr - B = B (t)/B_{, =0.6} referred value of coefficient B (t) Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 41, No. 3, pp. 491–499, September, 1981.     

Conditions for existence of exact solutions of the problem of a fusing wedge

A well-defined condition, determining the values of the aperture angles of a fusing wedge, is presented for exact solutions of the single-phase problem of a fusing wedge that were obtained earlier and are written for these values. The critical orientation of the fusing wedge to the axis of fusion when the written solution degenerates is indicated.Notation , , _n , _n , _n A ₁,A ₂,B auxiliary variables - P _n ,Q _n ,S _n ,T _n polynomials - k, m, n, i natural numbers - , _k angles between the normals to the surfaces forming the fusing wedge - z the axis in a Cartesian coordinate system - U temperature at points of the body infinitely remote from the fusing boundary Voronezh Institute of Technology, Voronezh, Russia. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 66, No. 6, pp. 750–753, June, 1994.     

Regularizing algorithm for inverting the Abel equation

The article presents a regularizing algorithm for solving the Abel equation using information on the statistics of the error of measurement of the right-hand side of the equation.Notation (r), f(x) solution and right-hand side of the Abel equation, respectively - f_i value of the right-hand side measured at point x_i - _i uncertainty of the i-th measurement - n number of measurements of the right-hand side - V correlation matrix of the uncertainty of measurement - smoothing parameter - S_n(x) interpolating spline - S_n,(x) smoothing spline - a_i, b_i, c_i, d_i coefficients of the smoothing spline - (r) regularized solution of the Abel equation - e() discrepancy vector - Sp[V] trace of the matrix V Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 2, pp. 270–274, August, 1980.     

Determination of the thermophysical characteristics of alternatively freezing and thawing dispersed media by the method of solving inverse problems of heat conduction

The article explains an algorithm for determining the thermophysical characteristics of dispersed media with phase transitions based on the method of solving inverse problems of heat conduction.Notation r space coordinate - time - T temperature of the specimen - T₀ initial temperature - c_i, c_w, c_sk specific heat of ice, water, and of the organic-mineral skeleton, respectively - c_f, c_m, _f, _m specific heat and thermal conductivity in the frozen and melted zones, respectively - c effective heat capacity - thermal conductivity - p density - ₀, _sb bound and strongly bound moisture, respectively - (T) amount of nonfrozen water - R radius of the cylinder - q() heat flux - I functional - u₁(), U₂() measured temperatures of the specimen at the points r = 0 and r = R, respectively, at the instant - ₁, ₂ degree of confidence of the supplementary information - final instant of time - a, b, k, _s positive constants - L specific heat of melting - N number of grid nodes over space - n number of grid nodes over time - h grid step over space - grid step over time - solution of the conjugate system - s number of iteration Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 2, pp. 292–297, August, 1980.     

Nonstationary process of heat transfer in a tube with longitudinal fins

An analytical solution to the problem of nonstationary thermal interaction of a flow of a heat-transfer agent and a thin-walled tube with longitudinal fins is constructed for variable parameters of heat transfer.Notation u, temperatures of the fins - ,w temperatures of the tube walls - temperature of the flow of the heat-transfer agent - _i ,i= coefficients of heat transfer from the ambient medium to the fins and the tube walls, respectively - _i ,i= temperature distributions for the ambient medium - coefficients of heat transfer from the flow of the heat-transfer agent to the tube walls - q _i density of the heat flux to the corresponding portions of the tube - heat capacity, thermal conductivity, density, and thickness of the fin and tube material - c _p , ,G, F heat capacity, density, and flow rate of the heat-transfer agent, cross-sectional area of the tube - dimensions of the tube Bauman Moscow State Technical University. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 66, No. 6, pp. 673–680, June, 1994.     

Viscosity of steam in the critical region

The shear viscosity of fluids exhibits an anomalous enhancement in the close vicinity of the critical point. A detailed experimental study of the viscosity of steam in the critical region has been reported by Rivkin and collaborators. A reanalysis of the experimental data indicates that the behavior of the viscosity of steam near the critical point is similar to that observed for other fluids near the critical point. An interpolating equation for the viscosity of water and steam is presented that incorporates the critical viscosity enhancement.Nomenclature a critical region equation of state parameter - a _k coefficients in equation for ₀ - a _ij coefficients in equation for ¯ - b critical region equation of state parameter - c _p specific heat at constant pressure - c _v specific heat at constant volume - k critical region equation of state parameter - k _B Boltzmann constant - P pressure - P _r 22.115 MPa - P ^* P/P _r - P _c critical pressure - P _i coefficients in critical region equation of state - R~P (P-P _c )/P _c - q parameter in equation for critical viscosity enhancement - r parametric variable in critical region equation of state - T temperature in K (IPTS-48) - T _r 647.27 K - T ^* T/T _r - T _c critical temperature - T (T–T _c )/T _c - V volume - critical exponent of specific heat - critical exponent of coexistence curve - critical exponent of compressibility - critical exponent of chemical potential at T=T _c - dynamic viscosity - ₀ lim ₀ - ¯ normal viscosity - critical viscosity enhancement - ¯ thermal conductivity - normal thermal conductivity - critical thermal conductivity enhancement - parametric variable in critical region equation of state - correlation length - ₀ correlation length amplitude above T _c at = _c - critical exponent of correlation length - density - _r 317.763 kg/m³ - ^* / _r - _c critical density - (– _c )/ _c - _p estimated error of pressure - _T estimated error of temperature - estimated error of viscosity - exponent of critical viscosity enhancement - _t (/P) _T symmetrized compressibility - _T ^* _T P _r / _r ² - _{t t} P _c / _c ²     

Nonlinear asymptotic theory of hypersonic flow past a circular cone

Summary The hypersonic small-disturbance theory is reexamined in this study. A systematic and rigorous approach is proposed to obtain the nonlinear asymptotic equation from the Taylor-Maccoll equation for hypersonic flow past a circular cone. Using this approach, consideration is made of a general asymptotic expansion of the unified supersonic-hypersonic similarity parameter together with the stretched coordinate. Moreover, the successive approximate solutions of the nonlinear hypersonic smalldisturbance equation are solved by iteration. Both of these approximations provide a closed-form solution, which is suitable for the analysis of various related flow problems. Besides the velocity components, the shock location and other thermodynamic properties are presented. Comparisons are also made of the zeroth-order with first-order approximations for shock location and pressure coefficient on the cone surface, respectively. The latter (including the nonlinear effects) demonstrates better correlation with exact solution than the zeroth-order approximation. This approach offers further insight into the fundamental features of hypersonic small-disturbance theory.Notation a speed of sound - H unified supersonic-hypersonic similarity parameter, - K hypersonic similarity parameter, M - M freestream Mach number - P pressure - T temperature - S entropy - u, v radial, polar velocities - V freestream velocity - shock angle - cone angle - density - density ratio, /() - ratio of specific heats - polar angle - stretched polar angle, / - (), (), () gage functions     

Dielectric Properties of Melt-Grown Cd1 – xZnxTe Crystals

The real (") and imaginary (") parts of the complex dielectric permittivity of Cd_{1 – x} Zn _x Te (x= 0.1–0.2) crystals are measured as a function of temperature and frequency. The "-vs.-temperature data show a maximum, and " rises rapidly at about the same temperature. This behavior is interpreted in terms of compositional fluctuations, structural defects, and the associated internal electric fields.     

Bounding-surface plasticity: Stress space versus strain space

Summary A bounding-surface plasticity model is formulated in stress space in a general enough manner to accommodate a considerable range of hardening mechanisms. Conditions are then established under which this formulation can be made equivalent to its strain-space analogue. Special cases of the hardening law are discussed next, followed by a new criterion to ensure nesting. Finally, correlations with experimental data are investigated.Notation (a) centre of the stress-space (strain-space) loading surface; i.e., backstress (backstrain) - ^* (a ^*) centre of the stress-space (strain-space) bounding surface - (a ) target toward which the centre of the stress-space (strain-space) loading surface moves under purely image-point hardening - (b) parameter to describe how close the loading surface is to nesting with the bounding surface in stress (strain) space; see (H10) - (c) elastic compliance (stiffness) tensor - (d) parameter to describe how close the stress (strain) lies to its image point on the bounding surface; see (H10) - (D) generalised plastic modulus (plastic compliance); see (1) - function expressing the dependence of the generalised plastic modulus on (plastic complianceD ond) - ^* (D ^*) analogue to (D) for the bounding surface - function expressing the dependence of ^* on (D ^* ond) - () strain (stress) - ' (') deviatoric strain (stress) - ^P ( ^R ) plastic strain (stress relaxation); see Fig. 1 - () image point on the bounding surface corresponding to the current strain (stress) - _iso (f _iso) at the point of invoking consistency, the fraction of local loading-surface motion arising from a change of radius; i.e., fraction of isotropic hardening in the stress-space theory - _kin (f _kin) at the point of invoking consistency, the fraction of local loading-surface motion arising from a change in the backstress (backstrain); i.e., fraction of kinematic hardening in the stress-space theory - _nor (f _nor) at the point of invoking consistency, the fraction of backstress (backstrain) motion directed toward the image stress (strain); i.e., the image-point fraction of the kinematic hardening in the stress-space theory - _ima (f _ima) at the point of invoking consistency, the fraction of backstress (backstrain) motion directed toward the image stress (strain); i.e., the image-point fraction of the kinematic hardening in the stress-space theory - function relating _iso to , , and (f _iso tob,d, andl) - function relating _kin to , , and (f _kin onb,d, andl) - function relating _nor to , , and (f _nor onb,d, andl) - function relating _ima to , , and (f _ima onb,d, andl) - the fraction of outwardly normal bounding-surface motion at the Mróz image point which arises from a change of radius - the fraction of outwardly normal bounding-surface motion at the Mróz image point which arises from a change in the centre - function relating _iso ^* to (f _iso ^* tod) - function relating _kin ^* to (f _kin ^* tod) - (l) parameter to describe the full extent of plastic loading up to the present, giving the arc length of plastic strain (stress relaxation) trajectory; see (H10) - function relating the direction for image-point translation of the loading surface to various other tensorial directions associated with the current state; see (H5). With 6 Figures     

Inhomogeneous shear flows of linear polymers

Solutions of a system of equations of nonlinear viscoelastic fluid motion describing inhomogeneous shear flows of linear polymers are indicated.Notation _ij stress tensor - p pressure - F_i mass force vector - _ij Kronecker delta - coefficient of shear viscosity - relaxation time - _ij inner parameter - _ij=vi/x_j velocity gradient tensor - ₀ initial value of the shear viscosity coefficient - ₀ initial value of the relaxation time - D dimensionless first invariant of the additional stress tensor - A, B, C constants of integration - f(D) universal function characterizing the material - r, , z cylindrical coordinates - u=v_z axial component of the velocity vector - v=v circumferential component of the velocity vector - ₁, ₂ first and second differences of the normal stress - Q volume mass flow rate - R radius of a circular tube - R₁, R₂ radii of the inner and outer cylinders, respectively - M moment per unit length Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 41, No. 3, pp. 449–456, September, 1981.     

Thermodynamics of the quasiequilibrial growth of crazes

By comparing the morphology and physical properties (averaged over the scale of 1 to 10m) of a crazed and uncrazed polymer, it can be concluded that crazing is a new phase development in the initially homogeneous material. The present study is based on recent work on the general thermodynamic explanation of the development of a damaged layer of material. The treatment generalizes the model of a crack-cut in mechanics. The complete system of equations for the quasiequilibrial craze growth follows from the conditions of local and global phase equilibrium, mechanical equilibrium and a kinematic condition. Constitutive equations of craze growth-equations are proposed that are between the geometric characteristics of a craze and generalized forces. It is shown that these forces, conjugated with the geometric characteristics of a craze, can be expressed through the known path independent integrals (J, L, M,). The criterion of craze growth is developed from the condition of global phase equilibrium. F Helmholtz's free energy - G Gibb's free energy (thermodynamic potential) - f density ofF - g density ofG - T absolute temperature - S density of entropy - strain tensor - components of - stress tensor - components of - _y stress along the boundary of an active zone (yield stress) - _b stress along the boundary of an inert zone - applied stress - value of at the moment of craze initiation - K stress intensity factor - C tensor of elastic moduli - C ^–1 tensor of compliance - internal tensorial product - V volume occupied by sample - V ₁ volume occupied by original material - V ₂ volume occupied by crazed material - V boundary ofV - (V) vector-function localized on V - (x) characteristic function of an area - (x) variation of(x) - (x) a finite function - tensor of alternation - components of the boundary displacement vector - l components of the vector of translation - n components of the normal to a boundary - _k components of the vector of rotation - e symmetric tensor of deviatoric deformation of an active zone - expansion of an active zone - J ⁽ⁱ⁾ ,L _k ⁽ⁱ⁾ ,M ⁽ⁱ⁾,N ⁽ⁱ⁾ partial derivatives ofG ⁽ⁱ⁾ with respect tol , _k, ande , respectively - [ ] jump of the parameter inside the brackets - thickness of a craze - 2l length of a craze - 2b length of an active zone - l _c distance between the geometrical centres of the active zone and the craze - ^* craze thickness on the boundary of an active and the inert zone - l ^* craze parameter (length dimension) - A craze parameter (dimensionless) - ^* extension of craze material     

A method of determining liquid water and ice in thermophysical tests on porous materials

A method is described for quantitative determination of liquid water and ice based on the sharp difference between the time characteristics of water and heat transport.Notation dielectric constant - ₀ density of dry material - u moisture content - l thickness - relative error - v_i volume proportion of phase i Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 5, pp. 889–893, May, 1981.     

Transient heat conduction in hollow spheres with a moving inner boundary

The finite integral transform method is used to obtain the solution of unsteady heat conduction problems for a hollow sphere with a moving internal boundary and various boundary conditions at the outer surface. For the solution of the problems of interest integral transform formulas are presented with kernels (16), (20), and (24) and the corresponding inversion formulas (18), (22), (26), (29) and characteristic equations (17), (21), (25), (28), (31), (33).Nomenclature a, thermal diffusivity and conductivity - t temperature of phase transformation - density - heat transfer coefficient - Q total quantity of heat passing through inner boundary - F latent heat of phase transformation - Fo(1,)=a/R ₁ ² , Fo(i,)=/r _i ² , Fo(i, _i)=a _i/r _i ² Fourier numbers - Bi₂=R₂/ Biot number     

Kinetics of the removal of liquid from capillaryporous bodies in a fluidized bed under nonisotherma l conditions

A theory of mass transfer in capillary-porous bodies is proposed which allows for thermogradient transfer of a bound substance in liquid form. The results obtained are used to calculate the process of drying of ceramic articles in a fluidized bed.Notation t, T temperature - a_m coefficient of moisture conductivity - , , density, viscosity, and surface tension of liquid - h thickness of liquid film - n disjoining pressure - A Hamaker constant - coefficient of external mass exchange - ₁ coefficient of heat transfer - coefficient of thermal conductivity - Fo Fourier number - volumetric moisture content of porous body - W_s surface moisture content of body - n=n₁+n₂ porosity - r pore radius in the particles - F= F₁+ F₂ surface area of porous body - R₁, R₂ radii of wide and narrow capillaries - moisture content - x_o, x_oe coordinates of menisci in wide capillaries and at end of first stage, respectively - P_o, P_oe Pressures at surface of body and at end of first stage, respectively Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 11–18, July, 1980.     

Residual thermal stresses in the pull-out specimen: A finite element calculation

The residual thermal stress field in the pull-out specimen is calculated in the case of a high properties thermoset system (carbon-bismaleimide). The calculation is performed within the framework of the linear theory of elasticity by means of a finite element method. The specimen is modelled as a three-phase composite (holder-fibre-matrix). The meniscus which forms at the fibre entry is taken into account in order to provide a realistic stress concentration. The latter is far higher than the matrix strength. Evidence that fibre debonding propagates from the fibre end during cooling is then produced.Nomenclature T thermal load - L _e embedded length - r _f fibre radius - _c curvature radius of the meniscus (fibre entry) - r _c radial dimension of the finite element mesh - E _m,E _h matrix and holder moduli - E _A,E _T fibre axial and transverse moduli - _m, _h matrix and holder thermal expansion coefficients - _A, _T fibre axial and transverse thermal expansion coefficients - _rr, , _zz, _rz non-zero components of the residual stress field - _rr ⁱ , ^im , _zz ^im , _rz ⁱ stresses at the interface in the matrix (r=r _f + ) - _rr ⁱ , ^if , _zz ^if , _rz ⁱ stresses at the interface in the fibre (r=r _f–) - _p1 maximum principal stress - _zz ^f mean axial stress over the fibre section - _rupt ^m matrix strength - u _r ,u _z non-zero components of the displacement field     

The effect of Ag additions on the microstructure of aluminium–lithium alloys

Minor quantities of Ag have been added to Al–Li–Cu–Mg–Zr alloys. Their microstructure has been studied by means of optical metallography, transmission electron microscopy and X-ray diffraction. In the high Li, low Cu : Mg ratio alloys the main phases found were , , S and T₁, while fewer T₂ and Al₇Cu₂Fe precipitates were also observed. The addition of up to 0.5 wt% Ag diminishes the and T₁ precipitates size. This is attributed to a small increase of Li solubility in the matrix. In the low Li, high Cu : Mg ratio alloy the addition of 0.2 wt % Ag resulted in the precipitation of phase simultaneously with , , S and T₁ phases. Due to the low Li concentration an unusual growth of the / precipitates at the expense of the precipitates was also observed.     

Nonsteady thermocapillary mass transfer in the laser alloying of metals

This article examines convective mass transfer of an impurity in a shallow bath of molten metal with allowance for the motion of the fusion front during the laser alloying of metals.Notation r, z, cylindrical coordinates - t time - T_i temperature of the liquid (i=1) and solid (i=2) phases - q(r) absorbed energy flux - k concentration factor - T_m melting point - L heat of fusion - density - _i, _i thermal conductivity and diffusivity - T₀ initial temperature - , absolute and kinematic viscosities of the melt - v_r, v_z projections of the melt velocity on the coordinate axes r and z - p pressure - surface tension Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 56, No. 5, pp. 799–805, May, 1989.     

Simulation of the Process of Water Freezing in a Round Pipe

The problem of freezing of pure water in a round pipe is treated with due regard for convection under asymmetric thermal boundary conditions in the absence of motion along the pipe. The problem is solved numerically using the control volume approach, SIMPLER algorithm, and the enthalpy method. Results are obtained for three Grashof (Gr) and six Biot (Bi) numbers: Gr = 1.55 × 10⁶, Bi = 0.305 (0 < ), Bi = 0.044 ( < 2); Gr = 1.24 × 10⁷, Bi = 0.610 (0 < ), Bi = 0.087 ( < 2); Gr = 9.89 × 10⁷, Bi = 1.220 (0 < ), Bi = 0.174 ( < 2). The correctness of calculation of the problem disregarding free-convection flows is analyzed.     

Universal simulation of degenerating homogeneous turbulence

The problem of universal simulation of the dynamics of a turbulent velocity field (universal in the sense of arbitrary values of the Reynolds turbulence number) is treated on the basis of the moment model in the second approximation.Notation ¯q² _i ² double the kinetic turbulence energy - _u ² =5v¯q²/_u Taylor turbulence scale squared - _u=v1/x_k)²> kinetic-energy dissipation function - N_Re,=¯q²_u / Reynolds turbulence number Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 42, No. 1, pp. 46–52, January, 1982.     

The fracture energy of a glass fibre composite

The fracture energy of a glass fibre-polyester composite has been measured by work of fracture ( _f) measurements on bending beams, and by linear elastic fracture mechanics analyses ( _i) of the bending beams and edge-notched tensile plates. It was found that for the bend specimens _i< _f. The work of fracture, _f, displayed a strain rate dependence, but there was no such dependence of _i. It is postulated that _i is determined by a debonding mechanism while _f is the sum of a debonding mechanism plus a pull-out contribution. The edge-notched tensile plate experiments showed that _i obtained from thick plates was less than that obtained from side-grooved plates, and that in each case there was a dependence of _i on crack size.