激光熔覆Fe基非晶／纳米晶复合涂层的组织与性能

对以激光熔覆方式在45钢基体上制备的FeNiSiBVRE非晶涂层进行激光晶化,制备非晶／纳米晶复合涂层.利用X射线衍射仪、透射电镜、扫描电镜和磨损试验机研究非晶／纳米晶复合涂层的组织与性能.研究结果表明,涂层存在着分层结构,组成相有晶化相、非晶相和纳米晶相;涂层底部和顶部的显微组织由大量的稀土树枝晶、板条状硼化物和粒状碳化物组成,涂层中部的显微组织是由大量的纳米晶相镶嵌在非晶基体上构成.与没有进行激光晶化的非晶涂层相比,涂层的耐磨损性能下降.其磨损机制以粘着磨损和剥层磨损为主.     

等离子熔覆铁基堆焊合金显微组织与耐磨性

为了提高在严峻工况条件下工作的机械零件的耐磨性,采用等离子熔覆技术,在20g钢表面制备了一系列Fe-15Cr-x-V-0.8C堆焊合金.借助光学显微镜、扫描电镜和x-射线衍射等分析手段研究了合金组织和碳化物形貌.结果表明：堆焊合金显微组织由马氏体、铁素体、少量奥氏体、M₇C₃和VC组成.合金中加入一定数量的V,可诱发基体的马氏体转变,改善合金的耐磨性.随着V的质量分数的增加,VC的数量增加,堆焊合金晶粒显著细化.此外,考察了V的质量分数对堆焊合金硬度及耐磨性的影响.耐磨粒磨损实验结果表明：堆焊合金耐磨性优良,当合金中存在较多数量的硬质相且硬质相分布均匀、晶粒大小适中时,能有效阻止磨粒的显微切削运动,显著提高材料的耐磨性.     

Effect of laser remelting on the microstructure and corrosion resistance of plasma sprayed Fe-based coating

Fe-based amorphous and nanocrystalline coatings were fabricated by air plasma spraying. The coatings were further treated by laser remelting process to improve their microstructure and properties. The corrosion resistance of the as-sprayed and laser-remelted coatings in 3.5wt% NaCl and 1 mol/L HCl solutions was evaluated by electrochemical polarization analysis. It was found that laser-remelted coating appeared much denser than the as-sprayed coating. However, laser-remelted coating contains much more nanocrystalline grains than the as-sprayed coatings, resulting from the lower cooling rate in laser remelting process compared with plasma spraying process. Electrochemical polarization results indicated that the laser-remelted coating has great corrosion resistance than the as-sprayed coating because of its dense structure.     

Abrasive wear behaviors of high velocity arc sprayed iron aluminum composite coatings

The High Velocity Arc Spraying （HVAS） technology was used to prepare Fe-Al composite coatings by the adding of different elements into cored wires to obtain different Fe-Al coatings. The added compounds do great effect on the properties of the composite coatings. The microstructures and abrasive wear performances of the coatings were assessed by transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, and THT07-135 high temperature wear equipment. It was found that the adding of Cr3C2 can greatly increase the room temperature wear behavior, and Fe-Al/WC coatings have adapting periods at the beginning of wear experiment. With the rise of temperature, the wear resistance of Fe-AI/Cr3C2 coatings becomes bad from room temperature to 250℃, and then stable from 250℃ to 550℃; the wear resistance of Fe-Al/WC becomes well with the rise of temperature. The adding of Cr and Ni can also improve wear performances of Fe-Al composite coatings.     

AFM research on Fe-based nanocrystal crystallization mechanism

The cross-section pattern of Fe-based alloy ribbon (Fe_73.5Cu₁Nb₃Si_13.5B₉) annealed at different temperatures was investigated by AFM (atomic force microscope), and the effect mechanism of Nb and Cu in Fe-based alloy ribbon annealing was analyzed with XRD diffraction crystal analysis technique and other research results. New concepts of encapsulated grain, Nb vacancy cluster, Nb-B atom cluster and so on were proposed and used to describe the formation mechanism of α-Fe (Si) nanocrystal. Finally, a three-phase (separation phase, encapsulated phase and nanocrystalline phase) interconnected structure model in Fe-based nanocrystalline alloy was established. Supported by the Natural Science Foundation of Zhejiang Province (Grant No. Y405021), Zhejiang Provincial Science and Technology Key Project (Grant No. 2006C21109) and Key Project of Science and Technology Research of China Ministry of Education (Grant No. 204059)     

等离子喷涂梯度涂层的显微组织结构和性能

针对低散热发动机主要部件铝活塞顶部制备热障涂层的需要，用等离子喷涂法在铝基体上制备出梯度涂层，对其性能与显微组织结构进行了研究．抗热震实验结果表明，梯度涂层具有较高的结合强度．金相显微观测结果表明，梯度热障层结构致密，由基体至涂层表面。形成5种无宏观结合界面的成分呈梯度变化的组织结构．     

低纯度材料制备块体铁基非晶合金

采用工业用原材料在铜模铸造条件下制备了Fe₄₈Cr₁₅Mo₁₄C₁₅B₆Y₂和Fe_46-xNi₂Cr₁₅Mo₁₄C₁₅B₆Y₂Nb_x(x=1,2,3)块体非晶合金,研究了y(Ni)=2%和y(Nb)=1%～3%元素对合金非晶形成能力与力学性能等方面的作用.采用x射线(XRD)仪、差分扫描量热计(DSC)、万能材料力学实验机和扫描电镜(SEM)对铸态样品的相组成、非晶合金的热稳定性、合金的断裂强度及其断口形貌进行了研究.实验结果表明：Fe₄₅Ni₂Cr₁₅Mo₁₄C₁₅B₆Y₂Nb₁可以形成直径超过5 mm的大块非晶合金,与Fe₄₈Cr₁₅Mo₁₄C₁₅B₆Y₂相比,非晶形成能力获得了较大的提高.并且Fe₄₈Cr₁₅Mo₁₄C₁₅B₆Y₂和Fe_46-xNi₂Cr₁₅Mo₁₄C₁₅B₆Y₂Nb_x(x=1,2)非晶合金的约化玻璃转化温度和过冷液相区的大小与合金的非晶形成能力有良好的对应关系,但合金的力学性能有所降低.合金断口均表现为典型的脆性断裂特征.     

等离子喷涂复合陶瓷涂层及其耐磨性能

用等离子喷涂技术制取了ＭＯ＋Ａｌ２Ｏ３－ＴｉＯ２、ＭＯＳ２＋Ａｌ２Ｏ３、ＴｉＯ２＋Ｃｒ３Ｃ２ＮｉＣｒ和ＭｏＳ２＋Ｃｒ３Ｃ２－ＮｉＣｒ复合涂层．利用ＳＥＭ、ＸＲＤ、和ＸＰＳ等技术．观察和分析了涂层的显微结构和喷涂过程中的物相变化及添加成分对涂层耐磨性能的影响．在ＭＭ－２００型磨损试验机上测定了涂层的滑动摩擦系数和磨损率．结果表明；Ｍｏ、ＭｏＳ２与Ａｌ２Ｏ３－ＴｉＯ２的结合性能较好，ＴｉＯ２、ＭｏＳ２在Ｃｒ３Ｃ２－ＮｉＣｒ涂层的气孔和裂纹处偏聚；添加ＭｏＳ２对Ａｌ２Ｏ３－ＴｉＯ２涂层的物相组成有明显的影响；适量的ＭＯ、ＭＯＳ２加入Ａｌ２Ｏ３－ＴｉＯ２中，可以降低涂层的摩擦系数和磨损率；而ＴｉＯ２、ＭｏＳ２加入Ｃｒ３Ｃ２－ＮｉＣｒ中，对涂层的摩擦磨损性能影响不大     

Effects of sintering temperature on the microstructural evolution and wear behavior of WCp reinforced Ni-based coatings

This article focuses on the microstructural evolution and wear behavior of 50wt%WC reinforced Ni-based composites prepared onto 304 stainless steel substrates by vacuum sintering at different sintering temperatures. The microstructure and chemical composition of the coatings were investigated by X-ray diffraction （XRD）, differential thermal analysis （DTA）, scanning and transmission electron microscopy （SEM and TEM） equipped with energy-dispersive X-ray spectroscopy （EDS）. The wear resistance of the coatings was tested by thrust washer testing. The mechanisms of the decomposition, dissolution, and precipitation of primary carbides, and their influences on the wear resistance have been discussed. The results indicate that the coating sintered at 1175℃ is composed of fine WC particles, coarse M6C （M=Ni, Fe, Co, etc.） carbides, and discrete borides dispersed in solid solution. Upon increasing the sintering temperature to 1225℃, the microstructure reveals few incompletely dissolved WC particles trapped in larger M6C, Cr-rich lamellar M23C6, and M3C2 in the austenite matrix. M23C6 and M3C2 precipitates are formed in both the γ/M6C grain boundary and the matrix. These large-sized and lamellar brittle phases tend to weaken the wear resistance of the composite coatings. The wear behavior is controlled simultaneously by both abrasive wear and adhesive wear. Among them, abrasive wear plays a major role in the wear process of the coating sintered at 1175℃, while the effect of adhesive wear is predominant in the coating sintered at 1225℃.     

Corrosion and irradiation behavior of Fe-based amorphous coating in lead-bismuth eutectic liquids

Lead-bismuth eutectics (LBE) have considerable potential as a candidate material for accelerator-driven sub-critical systems (ADS). However, LBE corrosion and irradiation damage are two urgent challenges remaining to be solved for impellers of primary pumps. In this study, we have explored the possibility of using Fe-based amorphous coatings to overcome LBE corrosion and concurrently to sustain irradiation damage. Specifically, the Fe₅₄Cr₁₈Mo₂Zr₈B₁₈ amorphous coating was prepared by high-velocity oxygen-fuel (HVOF) spraying on 316L steel and exposed to saturated oxygen static LBE for 500 h at 400°C. The coating with high thermal stability (T_g=615°C and T_x=660°C) effectively prevented the substrate steel from being corroded by LBE owing to its unique long-range disordered atomic packing. The coating also exhibited strong irradiation resistance when being subjected to 45 dpa (displacement per atom) Au ion irradiation at room temperature, with no sign of crystallization even at the maximum implantation depth of 300 nm. Consequently, the hardness of the coatings before and after irradiation increased slightly. The current findings shed new insights into understanding corrosion mechanism and irradiation behavior of amorphous solids in LBE and expand the application range of amorphous materials.

     

Effect of hydrogen on the friction and wear of Ni-P coatings

The effects of charging and outgassing on the friction and wear of Ni-P amorphous and nanocrystalline coatings were studied under ambient humidity and temperature.The results indicate that hydrogen charging can greatly decrease the volume loss during friction and increase the wear durability.However,the wear durability can be restored after outgassing.There are many cracks on the brittle nanocrystalline before charging,and no crack appears after charging,but there are only a few cracks on the outgassed s...     

铁基纳米非晶丝脉冲电流退火的最佳电流密度研究

Fe基纳米非晶丝通过脉冲电流获得Fe基纳米晶丝,可以改善其巨磁阻抗效应.通过在不同的准电流密度下对非晶丝进行退火,并分析退火后Fe基纳米晶丝的巨磁阻抗效应,得出当准电流密度为8.0 V时,可获得最佳的巨磁阻抗效应,其巨磁阻抗效应达到16.911%,退火效果为6.791%.     

Characterization of functionally graded ZrO_2 thermal barrier coatings sprayed by supersonic plasma spray with dual powder feed ports

1INTRODUCTION Thermalbarriercoatings(TBCs)arewidelyusedintheaerospaceandautomotiveindustriesfor increasedoperationtemperatureofimportantther malcomponentsofsystemssuchastheturbineen gineanddieselengineinordertoachieveanin creaseintheefficiency,performance…     

Dry wear behaviors of wear resistant composite coatings produced by laser cladding

Using different proportional mixtures of Ni-coated MoS2, TiC and pure Ni powders, new typical wear resistant and selflubricant coatings were formed on low carbon steel by laser cladding process. The microstructures and phase composition of the composite coatings were studied by SEM and XRD. The typical microstructure of the composite coating is composed of multisulfide phases including binary element sulfide and ternary element sulfide, γ-Ni, TiC and Mo2C. Wear tests were carried out using an FALEX-6 type pin-on-disc machine. The friction coefficient and mass loss of three kinds of MoS2/TiC/Ni laser clad coatings are lower than those of quenched 45 steel, and the worn surfaces of the laser cladding coatings are very smooth. Because of high hardness combined with low friction, the laser cladding composite coating with a mixture of 70% Ni-coated MoS2, 20%TiC and 10% pure Ni powder presents better wear behaviors than the composite coating with other powder blends. The composition analysis of the worn surface of GCr15 bearing steel shows that the transferred film from the laser cladding coating to the opposite surface of GCr15 bearing steel contains an amount of sulfide, which can change the micro-friction mechanism and lead to a reduced friction coefficient.     

速凝剂和钢纤维对喷射混凝土性能的影响

速凝剂作为一种外加剂,能够有效地减少水泥的凝结时间,降低喷射混凝土的回弹率.通过试验比较,速凝剂能够提高混凝土早期的强度,1 d试验结果表明,加入速凝剂的试件比未加速凝剂的抗压强度、抗折和抗拉强度分别提高了6.8%,19.4%和71.1%;但速凝剂会使得混凝土终期强度降低,影响其使用,28 d试验结果显示,加入速凝剂的试件比未加入速凝剂的抗压强度、抗折强度和抗拉强度分别降低了15.4%,3.8%和20.2%.试件中掺入钢纤维,则可以很好地提高混凝土的强度,28d试验结果显示,掺速凝剂混凝土试件中加入钢纤维后,其抗压、抗折和抗拉强度分别提高了10.3%,9.6%和33.5%.故加入钢纤维不但可以降低速凝剂对混凝土的影响,而且还可以增强混凝土的抗渗性.     

APS/HVOF热喷涂WC基金属陶瓷涂层的微观组织与性能

WC基涂层由于具有较高的硬度、优异的耐磨性、较好的抗腐蚀性,广泛应用于石油等工业中提高零件的磨损和腐蚀性能。随着现代化工业中工件服役环境日趋复杂,对制备性能优异的WC基涂层要求越来越高。在热喷涂技术中,热喷涂大气等离子热喷涂(APS) 喷涂温度范围广,可以提高至数万温度,在喷涂难容材料方面具有无与伦比的优势,而超音速火焰喷涂(HVOF)由于具有较高的焰流速度,粒子动能较高,同时由于喷涂过程中N2等冷却喷涂材料,近来在涂层制备中具有广泛的应用。本文利用APS与HVOF两种热喷涂方法在45钢表面制备WC-10Co-4Cr、WC-17Co两种涂层,对不同方式制备的涂层截面硬度、金相组织、与基体结合能力、涂层脱碳情况进行分析。结果表明：HVOF 涂层在喷涂中粒子未充分熔化,但粒子动能较高,表面相比于APS喷涂方式更加平整,与基体的结合性能好于APS制备的涂层。通过HVOF制备的两种涂层的孔隙率均低于APS制备的涂层,其中HVOF 制备的WC-17Co具有最小的孔隙率(0.65%)。此外,HVOF涂层的硬度均高于APS制备的涂层,由于具有较少的粘结相,通过HVOF制备的WC-10Co-4Cr涂层具有最高的截面硬度。相比于HVOF,APS具有较高的喷涂温度和较低的焰流速度导致涂层在喷涂过程中氧化脱碳现象较为严重,出现大量的W2C及少量的Co3W3C、Co6W6C等脆性η相。因此,HVOF更适合于喷涂WC-10Co-4Cr、WC-17Co两种涂层。     

温度控制Fe基合金带纳米微晶生长技术的研究

研究了Fe73.0CuNb1.5V2Si13.5B9非晶带经不同温度（480℃、510℃、540℃、570℃）退火而长成的纳米微晶薄带的软磁特性,发现540℃是其最佳退火温度,经该温度退火可获得最高的巨磁阻抗效应。     

Microstructure and wear resistance of electro-thermal explosion sprayed stellite coating used for remanufacturing

Electro-thermal explosion directional spraying was used to prepare the stellite coating on substrate of the AISI 1045 steel. The morphologies of cross-section and worn scar, porosity, distribution of elements, micro-hardness and wear resistance of the coating were determined by means of SEM, EDAX, micro-hardness tester and sliding wear tester. Because of the compact construction, good bonding and high hardness, the coating is characterized by good wear resistance. The results show that the mainly failure mode of the stellite coating is micro-plowing. Foundation item: Project(2003AA331130) supported by Hi-tech Research and Development Program of China; Project(50235030) supported by the National Natural Science Foundation of China     

铝合金上电沉积Ni-P-CNTs复合镀层及其摩擦性能研究

采用复合电沉积法在铝合金表面上制备了镍 磷 碳纳米管（Ni-P-CNTs）复合镀层,并用X射线衍射（XRD）和扫描电镜（SEM）对其进行了表征,分析了电流密度和镀液中碳纳米管的质量浓度对复合镀层形貌及其摩擦磨损性能的影响.当电流密度为3.0 A/dm2时可以得到表面光亮、平整的复合镀层,复合镀层中碳纳米管体积分数随着镀液中碳纳米管质量浓度的增加而增加.Ni-P-CNTs复合镀层比Ni-P镀层具有更高的硬度、耐磨性能和更低的摩擦系数.随着复合镀层中碳纳米管体积分数的增加,复合镀层的磨损量和摩擦系数逐渐降低.复合镀层摩擦性能的改善是由于碳纳米管具有优异的力学性能和良好的自润滑性能.     

Microstructure and wear resistance of electro-thermal explosion sprayed stellite coating used for remanufacturing

Electro-thermal explosion directional spraying was used to prepare the stellite coating on substrate of the AISI 1045 steel. The morphologies of cross-section and worn scar, porosity, distribution of elements, microhardness and wear resistance of the coating were determined by means of SEM, EDAX, micro-hardness tester and sliding wear tester. Because of the compact construction, good bonding and high hardness, the coating is characterized by good wear resistance. The results show that the mainly failure mode of the stellite coating is microplowing.