Effect of fibre/matrix adhesion on residual strength of notched composite laminates

Effects of fibre/matrix adhesion and residual strength of notched polymer matrix composite laminates (PMCLs) and fibre reinforced metal laminates (FRMLs) were investigated. Two different levels of adhesion between fibre and matrix were achieved by using the same carbon fibres with or without surface treatments. After conducting short-beam shear and transverse tension tests for fibre/matrix interface characterisation, residual strength tests were performed for PMCLs and FRMLs containing a circular hole/sharp notch for the two composite systems. It was found that laminates with poor interfacial adhesion between fibre and matrix exhibit higher residual strength than those with strong fibre/matrix adhesion. Major failure mechanisms and modes in two composite systems were studied using SEM fractography. The effective crack growth model (ECGM) was also applied to simulate the residual strength and damage growth of notched composite laminates with different fibre/matrix adhesion. Predictions from the ECGM were well correlated with experimental data.     

Effects of fibre/matrix adhesion on carbon-fibre-reinforced metal laminates—I.: Residual strength

The role of interfacial adhesion between fibre and matrix on the residual strength behaviour of carbon-fibre-reinforced metal laminates (FRMLs) has been investigated. Differences in fibre/matrix adhesion were achieved by using treated and untreated carbon fibres in an epoxy resin system. Mechanical characterisation tests were conducted on bulk composite specimens to determine various properties such as interlaminar shear strength (ILSS) and transverse tension strength which clearly illustrate the difference in fibre/matrix interfacial adhesion. Scanning electron microscopy confirmed the difference in fracture surfaces, the untreated fibre composites showing interfacial failure while the treated fibre composites showed matrix failure. No clear differences were found for the mechanical properties such as tensile strength and Young's modulus of the FRMLs despite the differences in the bulk composite properties. A reduction of 7·5% in the apparent value of the ILSS was identified for the untreated fibre laminates by both three-point and five-point bend tests. Residual strength and blunt notch tests showed remarkable increases in strength for the untreated fibre specimens over the treated ones. Increases of up to 20% and 14% were found for specimens with a circular hole and saw cut, respectively. The increase in strength is attributed to the promotion of fibre/matrix splitting and large delamination zones in the untreated fibre specimens owing to the weak fibre/matrix interface.     

复合材料层合板低速冲击损伤容限的改进方法和影响因素

依据笔者在这方面的研究和前人的工作，以及现有各种改进炭纤维增强树脂基复合材料冲击性能的方法，分析和总结了复合材料层合结构冲击损伤以及损伤容限，其中主要是冲击后压缩强度的重要影响因素，并且讨论了这些因素的作用。     

Impact resistance and tolerance of interleaved tape laminates

This paper presents and discusses the results of low-velocity impact and compression-after-impact (CAI) tests conducted on interleaved and non-interleaved carbon/epoxy tape laminates. Olefin film interleaves provided a strong interface bond, resulting in a reduction in projected damage area. These interleaves changed the stress distribution under impact and restricted delamination formation at the ply interface. An investigation into the compression behaviour of these laminates revealed a reduction in undamaged strength using olefin interleaves. This was attributed to the lack of lateral support for fibres at the fibre/interleaf interface, allowing fibre microbuckling to occur at a low load. Low modulus copolyamide web interleaves resulted in an increase in damage area and minor changes to CAI strength. Examination of laminate cross-sections revealed that this was due to both the open structure of the interleaf and poor resin/interleaf adhesion. High shear modulus polyethylene interleaves resulted in a significant decrease in damage area at various impact energies, with CAI strength improved compared to the non-interleaved laminates.     

缝合复合材料层板低速冲击及冲击后压缩实验研究

通过对缝合复合材料层板进行低速冲击和冲击后压缩实验, 研究了不同类型的缝合复合材料层板的冲击损伤特性及冲击后压缩的剩余强度。实验研究表明: 基体损伤和分层是缝合层板与未缝合层板低速冲击的主要损伤模式, 缝合层板具有更好的抗冲击性能, 更高的冲击后压缩强度。缝合密度越大的层板其抗冲击性能越好, 冲击后压缩强度越高。缝合方向为0°的缝合层板较缝合方向为90°的缝合层板具有更好的抗冲击性能和更高的冲击后压缩强度。增加0°方向铺层, 减少45°、-45°方向铺层, 可以提高缝合层板的抗冲击性能和冲击后压缩强度。     

不同形状弹体高速冲击下复合材料层板损伤分析

根据纤维增强复合材料宏细观结构,基于纤维的线弹性假设和基体的粘弹性假设,推导了单向复合材料粘弹性损伤本构关系。在此基础上,结合Hashin失效准则进行单层板面内损伤识别,通过界面单元模拟层间分层损伤,采用非线性有限元方法,建立了复合材料层板高速冲击损伤有限元分析模型。利用该模型,深入研究了不同形状弹体高速冲击下复合材料层板的弹道性能和损伤特性,探讨了相关参数对冲击损伤的影响规律,获得了一些有价值的结论。     

Low-velocity impact response of non-woven hemp fibre reinforced unsaturated polyester composites: Influence of impactor geometry and impact velocity

In this study, the influence of varying impactor geometries on the impact damage characteristics of hemp fibre reinforced unsaturated polyester composites were subjected to a low-velocity impact loading using an instrumented falling weight impact test setup. The three varying tup geometries: hemispherical, 30° and 90°, at four different impact velocity levels: 2.52 m/s, 2.71 m/s, 2.89 m/s and 2.97 m/s were assessed. The experimental results to investigate the influence of impactor geometry suggest that HFRUP composites were able to withstand higher loads when tested with hemispherical impactor and also absorbed more energy than that for 90° and 30° shaped tup geometry. The post impact damage patterns and failure mechanisms of impacted samples were further characterised by ultrasonic (UT) inspection. Impact induced damage characterised by scanning electron microscope (SEM) suggests that damage induced by the impact included a typical failure mechanisms showing matrix cracking, fibre breakage and fibre pullout. As the impact velocity increases the damage to back face of the laminate increased for laminates tested with a hemispherical impactor while it decreased to certain extent for laminates tested with 90° and 30° impactor geometries.     

Failure mechanisms on composite specimens subjected to compression after impact

Composite panels are widely used in aeronautic and aerospace structures due to their high strength/weight ratio. The stiffness and the strength in the thickness direction of laminated composite panels is poor since no fibres are present in that direction and out-of-plane impact loading is considered potentially dangerous, mainly because the damage may be left undetected. Impact loading in composite panels leads to damage with matrix cracking, inter-laminar failure and eventually fibre breakage for higher impact energies. Even when no visible impact damage is observed at the surface on the point of impact, matrix cracking and inter-laminar failure can occur, and the carrying load of the composite laminates is considerably reduced. The greatest reduction in loading is observed in compression due to laminae buckling in the delaminated areas. The objective of this study is to determine the mechanisms of the damage growth of impacted composite laminates when subjected to compression after impact loading. For this purpose a series of impact and compression after impact tests were carried out on composite laminates made of carbon fibre reinforced epoxy resin matrix. An instrumented drop-weight-testing machine and modified compression after impact testing equipment were used together with a C-scan ultrasonic device for the damage identification. Four stacking sequences of two different epoxy resins in carbon fibres representative of four different elastic behaviours and with a different number of interfaces were used. Results showed that the delaminated area due to impact loading depends on the number of interfaces between plies. Two buckling failure mechanisms were identified during compression after impact, which are influenced more by the delamination area than by the stacking sequence.     

Post-Impact Mechanical Characterisation of Glass and Basalt Woven Fabric Laminates

Two woven fabric laminates, one based on basalt fibres, the other on E-glass fibres, as a reinforcement for vinylester matrix, were compared in terms of their post-impact performance. With this aim, first the non-impacted specimens were subjected to interlaminar shear stress and flexural tests, then flexural tests were repeated on laminates impacted using a falling weight tower at three impact energies (7.5, 15 and 22.5J). Tests were monitored using acoustic emission analysis of signal distribution with load and with distance from the impact point. The results show that the materials have a similar damage tolerance to impact and also their post-impact residual properties after impact do not differ much, with a slight superiority for basalt fibre reinforced laminates. The principal difference is represented by the presence of a more extended delamination area on E-glass fibre reinforced laminates than on basalt fibre reinforced ones.     

Impact damage characterisation of carbon fibre/epoxy composites with multi-layer reinforcement

Low-velocity impact tests were performed to investigate the impact behaviour of carbon fibre/epoxy composite laminates reinforced by short fibres and other interleaving materials. Characterisation techniques, such as cross-sectional fractography and scanning acoustic microscopy, were employed quantitatively to assess the internal damage of some composite laminates at the sub-surface under impact. Scanning electron microscopy was used to observe impact fractures and damage modes at the fracture surfaces of the laminate specimens. The results show that composite laminates experience various types of fracture; delamination, intra-ply cracking, matrix cracking, fibre breakage and damage depending on the interlayer materials. The trade-off between impact resistance and residual strength is minimised for composites reinforced by Zylon fibres, while that for composites interleaved by poly(ethylene-co-acrylic acid) (PEEA) film is substantial because of deteriorating residual strength, even though the damaged area is significantly reduced. Damages produced on the front and back surfaces of impact were also observed and compared for some laminates.     

低速冲击下复合材料层板压缩许用值

为评估航空结构中常用的T300级和T800级2种碳纤维/环氧树脂复合材料层压板的冲击后压缩许用值,对2种材料体系下具有不同厚度及铺层的层板进行了低速冲击和冲击后压缩试验;讨论了冲击能量、凹坑深度、损伤面积及冲击后剩余压缩强度等之间的关系,以及厚度、铺层、表面防护等因素对其造成的影响;重点关注了2种材料体系下各组层板的目视勉强可见冲击损伤(BVID)形成条件以及含BVID层板的剩余强度.结果表明:厚度及铺层对层板的凹坑深度-冲击能量关系影响较大,而对冲击后压缩强度-凹坑深度及冲击后压缩破坏应变-凹坑深度关系影响较小,且在相同铺层比例下,BVID对应的冲击能量随厚度近似呈线性增长.X850层板的损伤阻抗性能明显优于CCF300/5228层板的,但二者损伤容限性能相当.加铜网、涂漆等表面处理显著提高了层板的损伤阻抗,但对损伤容限性能影响不大;在损伤不超过BVID时,所有CCF300/5228试件的压缩破坏应变均大于4 000 με,而X850材料体系下压缩破坏应变均在3 000 με之上.     

An experimental study of low velocity impact response in 2/2 twill weave composite laminates manufactured by a novel fabrication process

A novel fabrication process for advanced composite components—the Quicktep^TM process was described. 2/2 twill weave MTM56/CF0300 carbon epoxy composite laminates were manufactured by the Quickstep and the autoclave processes. The response of these laminates to drop-weight low velocity impact at energy levels ranging from 5 to 30 J was investigated. It was found that the laminates fabricated by the Quickstep had better impact damage tolerance than those fabricated by the autoclave. Optical microscopy revealed extensive matrix fracture in the center of the backside of the autoclave laminates indicating the more brittle property of the epoxy matrix cured by the autoclave process. Interfacial shear strength (IFSS) for two composite systems were measured by micro–debond experiments. The MTM56/CF0300 material cured by the Quickstep showed stronger fibre matrix adhesion. Since the thickness and density of the impact targets produced by two processes were different, finite element analysis (FEA) was performed to study the effect of these factors on the impact response. The simulation results showed that the difference in thickness and density affects the stress distribution under impact loading. Higher thickness and lower density caused by processing lead to less endurance to drop weight impact loading. Therefore the better performance of Quickstep laminates under impact loading was not due to the thickness and density change, but resulted from stronger mechanical properties.     

Damage in carbon fibre composites due to repetitive low-velocity impact loads

The effect of repetitive impacting with increasing impact energy on unsupported thermoset matrix and thermoplastic matrix carbon fibre laminates was studied. In the case of the thermoset laminates, there were two abrupt losses in stiffness, the first corresponding to through-the-thickness damage and the second to the damage extending to the specimen edges. The thermoplastic matrix laminates exhibited a continuous decline in stiffness but again the damage sequence was through-the-thickness followed by extension to the specimen edges. Static bend testing of these composites resulted in the same type and extent of damage as was observed for impact loading. The effect of increasing the unsupported area and laminate thickness were investigated. Impacting with increasing impact energy was compared to repetitive impacting at a constant impact energy.     

压缩预应力对复合材料层板抗冲击损伤性能的影响

为确定压缩预应力对复合材料层板抗冲击损伤性能的影响,首先对不同压缩预应力下的碳纤维/双马树脂CCF300/5428层板进行了低速冲击和准静态压痕试验,然后通过热揭层和冲击后压缩试验分别得到了层板分层面积和剩余强度。结果表明:压缩预应力会大幅降低层板的接触刚度和弯曲刚度,从而导致相同冲击能量下层板凹坑深度和背部基体开裂长度增大;对于准静态压痕过程和相同冲击能量下的冲击过程,分层起始载荷和峰值载荷均随压缩预应力的增大而减小;在相同冲击能量下,随着压缩预应力的增大,层板内部分层总面积及冲击能量吸收比不断增大,剩余压缩强度不断降低。因此,压缩预应力会降低复合材料层板的冲击损伤阻抗,对损伤容限性能不利,在对承受压缩载荷结构的试验验证过程中应考虑压缩预应力对抗冲击损伤性能的影响。      

On the impact performance of carbon fibre laminates with epoxy and PEEK matrices

A study was made of the mechanical properties and impact performance of carbon fibre/PEEK (0,90), ($\text{±45}$) and ($\text{±45,0}$) laminates and comparisons were made with similar carbon fibre/epoxy laminatesFibre dominated properties such as plain tensile strength were similar to those of epoxy laminates with similar fibres and volume fractions. Because of the increased toughness of PEEK there was less extensive matrix cracking, even though there was fibre debonding, and this gave increased transverse and shear cracking strains, increased shear strengths but decreased notched tensile strengths. The lower modulus and yield stress of PEEK caused lower compressive strengths, but PEEK absorbed little moisture and at 120°C moisture had little effect on mechanical properties.Dropweight impact produced less extensive damage in carbon fibre/PEEK laminates. Residual tensile strengths were similar but, because of the less extensive damage and greater delamination fracture energy, the residual compressive strengths were significantly greater with a PEEK matrix.Microscopic examination showed less matrix cracking and more fibre buckling in the carbon fibre/PEEK and this is discussed in relation to mechanical properties.     

Response of notched carbon/PEEK and carbon/epoxy laminates subjected to tension fatigue loading

In this study a comparison is made between the tensile static and fatigue behaviours of quasi-isotropic carbon/PEEK and carbon/epoxy notched laminates, selected as separate representatives of both tough and brittle matrix composites. Damage progression was monitored by various non-destructive (ultrasonic scanning and x-radiography) and destructive (deply and microscopic examinations) techniques, and by continuously measuring the change in stiffness, in order to identify the effect of damage on mechanical properties.
The experimental observations indicated that fatigue damage in carbon/epoxy laminates consists of a combination of matrix cracks, longitudinal splitting and delaminations which attenuate the stress concentration and suppress fibre fracture at the notch; as a consequence, fatigue failure can be reached only after very high numbers of cycles while tensile residual strengths continuously increase over the range of lives investigated (10³–10⁶ cycles). Due to the superior matrix toughness and the high fibre-matrix adhesion, the nature of fatigue damage in carbon/PEEK laminates strongly depends on the stress level. At high stresses the absence of early splitting and delaminations promotes the propagation of fibre fracture therefore resulting in poor fatigue performances and significant strength reductions; while at low stress levels damage modes are matrix controlled and this again translates into very long fatigue lives. These results indicate a strong influence of the major damage mechanisms typical of the two material systems on the behaviour of the laminates, with the nature, more than the amount, of damage appearing as the controlling parameter of the material response up to failure.     

Effects of damage thresholds on stresses in composite laminates under transverse impact

Studies on stresses and damage in fiber reinforced polymeric matrix composite laminates subjected to transverse impact are conducted by a 3D finite element analysis. The stress analysis is carried out by developing a constitutive equation including damage variables, therefore, effects of damage and damage thresholds on the stresses in the laminates can be investigated. Effects of damage threshold of matrix materials on stresses suggest suitable matrix materials for composite laminates, which could improve damage tolerance of the composite laminates, and resistance of the composite laminates to impact could be improved significantly by increasing the damage threshold.     

Influence of Matrix Ductility and Fibre Architecture on the Repeated Impact Response of Glass-Fibre-Reinforced Laminated Composites

This paper describes the results of falling weight impact tests on glass-fibre-reinforced laminates. The test program consisted of (i) falling weight impact tests for the determination of the penetration energy and the influence of laminate construction on damage development and (ii) repeated falling weight impact tests for the determination of the impact fatigue lifetime and damage development under repeated impact conditions at sub-penetration energy levels. The objective of this work is to compare the impact behaviour of cross-ply laminates based on a brittle unsaturated polyester resin and a more ductile vinyl ester resin system and two types of glass reinforcement, i.e. woven- and multiaxial non-crimp fabric. The penetration energy of the various composite laminates appeared to be mainly influenced by the type of reinforcement, whereas damage development during (repeated) impact is strongly influenced by both fibre architecture and resin. No significant effect of the different material parameters investigated on the number of impacts to penetration (impact fatigue lifetime) is observed. Especially when the repeated impact energy is normalised with respect to the penetration energy, all laminates showed similar behaviour.     

Post-impact compressive strength of curved GFRP laminates

Low velocity impacts to fibre reinforced plastic composites cause a pattern of damage consisting in general of delamination, fibre breakage and matrix cracking. Such damage is accidental and may go unnoticed; therefore composite structures must be designed assuming impact damage exists. Previous work on flat composite laminates has resulted in a reasonable understanding of the mechanisms of compressive strength reduction. There are, however, many instances where curved laminates are used in structures where impact is likely. Furthermore, due to the mechanisms of strength reduction, it may be expected that curvature would have a significant effect on the behaviour of the laminates.The work described here consists of experimental measurement of the post-impact compressive strength of curved GFRP laminates. The laminates were of 8 plies of 0.3 mm thick pre-impregnated glass fibre/epoxy tape in a (0, ±45, 0°)_s lay-up. Each laminate was 200 mm in length by 50 mm wide with the plane of curvature normal to the length. Laminates were impacted on the convex surface of the laminate by dropping a steel mass from 1 m vertically above it.Impacted laminates were loaded in compression and the out-of-plane displacements of the top and bottom surfaces were recorded. Final failure was typically due to fibre breakage occurring through the centre of the impacted area of the laminate. Possible differences in the impact response, and measurable differences in the sizes of the impact damage area, were found to arise from these curvatures, and differences were observed in their post-impact buckling behaviour. However, perhaps unexpectedly, the post-impact compressive strength for a curved laminate was found to be similar to that for a flat laminate. The failure loads for the impact damage laminates are shown to be comparable with those for laminates containing artificial delaminations.     

The mechanical properties of oxyfluorinated hybrids of glass fibre and polypropylene fibre

The mechanical properties of a low-cost system comprising orthophthalic polyester resin reinforced with hybrids of glass and polypropylene fibres were investigated. The fibres were oxyfluorinated to overcome the poor surface adhesion properties of polypropylene. Interlaminar shear tests, Izod-type impact tests and tensile tests were considered. It would be expected that increasing polypropylene fibre content corresponds with a decrease in mechanical properties due to the poor properties of polypropylene. Oxyfluorinated laminates containing approximately 25% and 50% polypropylene in the warp direction were, however, found to exhibit significant improvements in interlaminar shear strength, in peak shear stress under impact loading as well as in impact resistance over untreated glass fibre laminates. Scanning electron microscope images show that the reason for this improvement is that the interfacial bond between the polypropylene fibres and the resin is strengthened to such an extent that failure occurs within the polypropylene fibres rather than at the interface.