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1.
Ultrathin Hierarchical Porous Carbon Nanosheets for High‐Performance Supercapacitors and Redox Electrolyte Energy Storage
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Kolleboyina Jayaramulu Deepak P. Dubal Bhawna Nagar Vaclav Ranc Ondrej Tomanec Martin Petr Kasibhatta Kumara Ramanatha Datta Radek Zboril Pedro Gómez‐Romero Roland A. Fischer 《Advanced materials (Deerfield Beach, Fla.)》2018,30(15)
The design of advanced high‐energy‐density supercapacitors requires the design of unique materials that combine hierarchical nanoporous structures with high surface area to facilitate ion transport and excellent electrolyte permeability. Here, shape‐controlled 2D nanoporous carbon sheets (NPSs) with graphitic wall structure through the pyrolysis of metal–organic frameworks (MOFs) are developed. As a proof‐of‐concept application, the obtained NPSs are used as the electrode material for a supercapacitor. The carbon‐sheet‐based symmetric cell shows an ultrahigh Brunauer–Emmett–Teller (BET)‐area‐normalized capacitance of 21.4 µF cm?2 (233 F g?1), exceeding other carbon‐based supercapacitors. The addition of potassium iodide as redox‐active species in a sulfuric acid (supporting electrolyte) leads to the ground‐breaking enhancement in the energy density up to 90 Wh kg?1, which is higher than commercial aqueous rechargeable batteries, maintaining its superior power density. Thus, the new material provides a double profits strategy such as battery‐level energy and capacitor‐level power density. 相似文献
2.
Teng Liu Peng Li Na Yao Taige Kong Gongzhen Cheng Shengli Chen Wei Luo 《Advanced materials (Deerfield Beach, Fla.)》2019,31(21)
Direct use of metal–organic frameworks (MOFs) with robust pore structures, large surface areas, and high density of coordinatively unsaturated metal sites as electrochemical active materials is highly desirable (rather than using as templates and/or precursors for high‐temperature calcination), but this is practically hindered by the poor conductivity and low accessibility of active sites in the bulk form. Herein, a universal vapor‐phase method is reported to grow well‐aligned MOFs on conductive carbon cloth (CC) by using metal hydroxyl fluorides with diverse morphologies as self‐sacrificial templates. Specifically, by further partially on‐site generating active Co3S4 species from Co ions in the echinops‐like Co‐based MOF (EC‐MOF) through a controlled vulcanization approach, the resulting Co3S4/EC‐MOF hybrid exhibits much enhanced electrocatalytic performance toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), with overpotentials of 84 and 226 mV required to reach a current density of 10 mA cm?2, respectively. Density functional theory (DFT) calculations and experimental results reveal that the electron transfer between Co3S4 species and EC‐MOF can decrease the electron density of the Co d‐orbital, resulting in more electrocatalytically optimized adsorption properties for Co. This study will open up a new avenue for designing highly ordered MOF‐based surface active materials for various electrochemical energy applications. 相似文献
3.
Chaohai Wang Jeonghun Kim Victor Malgras Jongbeom Na Jianjian Lin Jungmok You Ming Zhang Jiansheng Li Yusuke Yamauchi 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(16)
With the ever‐growing environmental issues, sulfate radical (SO4??)‐based advanced oxidation processes (SR‐AOPs) have been attracting widespread attention due to their high selectivity and oxidative potential in water purification. Among various methods generating SO4??, employing heterogeneous catalysts for activation of peroxymonosulfate or persulfate has been demonstrated as an effective strategy. Therefore, the future advances of SR‐AOPs depend on the development of adequate catalysts with high activity and stability. Metal–organic frameworks (MOFs) with large surface area, ultrahigh porosity, and diversity of material design have been extensively used in heterogeneous catalysts, and more recently, enormous effort has been made to utilize MOFs‐based materials for SR‐AOPs applications. In this work, the state‐of‐the‐art research on pristine MOFs, MOFs composites, and their derivatives, such as oxides, metal/carbon hybrids, and carbon materials for SR‐AOPs, is summarized. The mechanisms, including radical and nonradical pathways, are also detailed in the discussion. This work will hopefully promote the future development of MOFs‐based materials toward SR‐AOPs applications. 相似文献
4.
Novel MOF‐Derived Co@N‐C Bifunctional Catalysts for Highly Efficient Zn–Air Batteries and Water Splitting
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Mingdao Zhang Quanbin Dai Hegen Zheng Mindong Chen Liming Dai 《Advanced materials (Deerfield Beach, Fla.)》2018,30(10)
Metal–organic frameworks (MOFs) and MOF‐derived materials have recently attracted considerable interest as alternatives to noble‐metal electrocatalysts. Herein, the rational design and synthesis of a new class of Co@N‐C materials (C‐MOF‐C2‐T) from a pair of enantiotopic chiral 3D MOFs by pyrolysis at temperature T is reported. The newly developed C‐MOF‐C2‐900 with a unique 3D hierarchical rodlike structure, consisting of homogeneously distributed cobalt nanoparticles encapsulated by partially graphitized N‐doped carbon rings along the rod length, exhibits higher electrocatalytic activities for oxygen reduction and oxygen evolution reactions (ORR and OER) than that of commercial Pt/C and RuO2, respectively. Primary Zn–air batteries based on C‐MOF‐900 for the oxygen reduction reaction (ORR) operated at a discharge potential of 1.30 V with a specific capacity of 741 mA h gZn–1 under 10 mA cm–2. Rechargeable Zn–air batteries based on C‐MOF‐C2‐900 as an ORR and OER bifunctional catalyst exhibit initial charge and discharge potentials at 1.81 and 1.28 V (2 mA cm–2), along with an excellent cycling stability with no increase in polarization even after 120 h – outperform their counterparts based on noble‐metal‐based air electrodes. The resultant rechargeable Zn–air batteries are used to efficiently power electrochemical water‐splitting systems, demonstrating promising potential as integrated green energy systems for practical applications. 相似文献
5.
Yuan Gan Zhi-da Wang Yan Shi Chang-qing Guo Hong-yi Tan Chang-feng Yan 《Journal of Materials Science》2018,53(6):4089-4102
This work offers an effective size-controlled synthesis of platinum nanoparticle (Pt NP) arrays for electrocatalyst through self-assembled nanopatterns of block copolymers on titanium (Ti) wafers. Size, spacing and uniformity of Pt NP with loading of Pt to a minimum were investigated to be controlled and adjusted in order to improve the electrochemically active surface area (ECSA) and ECSA stability, and Pt concentration in copolymer/chloroplatinic acid (H2PtCl6) solution was verified to be one of the most important factors to control the arrays’ structure. In our case, the Pt NPs with predictable size of 5–16.5 nm could be obtained when the Pt concentration is larger than 0.05 mg ml?1, which the dominant diameter is proved to be proportional to one-third power of the Pt concentration according to the linear relation of templates’ Pt/N mass ratio versus Pt concentration, and the Pt NPs remain highly ordered arrays with predictable spacing when the Pt concentration is larger than 0.125 mg ml?1. Decrease in Pt concentration from 2 to 0.125 mg ml?1 is an effective method to improve the ECSA and durability simultaneously. The Pt NP arrays exhibit not only a remarkable initial ECSA value of 106.2 m2 g?1, but also a pseudo-zero particle aggregation possibility during 3000-cycle voltammetry, which is attributed to the high Pt NP dispersion and the ordered arrays that improve the Pt utilization and lower the possibility of aggregation. 相似文献
6.
Botian Liu Songjie Wang Zilong Wang Hang Lei Zhitao Chen Wenjie Mai 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(22)
The recharge ability of zinc metal‐based aqueous batteries is greatly limited by the zinc anode. The poor cycling durability of Zn anodes is attributed to the dendrite growth, shape change and passivation, but this issue has been ignored by using an excessive amount of Zn in the past. Herein, a 3D nanoporous (3D NP) Zn–Cu alloy is fabricated by a sample electrochemical‐assisted annealing thermal method combined, which can be used directly as self‐supported electrodes applied for renewable zinc‐ion devices. The 3D NP architectures electrode offers high electron and ion transport paths and increased material loading per unit substrate area, which can uniformly deposit/strip Zn and improve charge storage ability. Benefiting from the intrinsic materials and architectures features, the 3D NP Zn–Cu alloy anode exhibits high areal capacity and excellent cycling stability. Further, the fabricated high‐voltage double electrolyte aqueous Zn–Br2 battery can deliver maximum areal specific capacity of ≈1.56 mAh cm?2, which is close to the level of typical commercial Li‐ion batteries. The excellent performance makes it an ideal candidate for next‐generation aqueous zinc‐ion batteries. 相似文献
7.
Formation of N‐Doped Carbon‐Coated ZnO/ZnCo2O4/CuCo2O4 Derived from a Polymetallic Metal–Organic Framework: Toward High‐Rate and Long‐Cycle‐Life Lithium Storage
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Ji‐Liang Niu Cheng‐Hui Zeng Hai‐Jun Peng Xiao‐Ming Lin Palanivel Sathishkumar Yue‐Peng Cai 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(47)
Metal–organic frameworks (MOFs) are very promising self‐sacrificing templates for the large‐scale fabrication of new functional materials owing to their versatile functionalities and tunable porosities. Most conventional metal oxide electrodes derived from MOFs are limited by the low abundance of incorporated metal elements. This study reports a new strategy for the synthesis of multicomponent active metal oxides by the pyrolysis of polymetallic MOF precursors. A hollow N‐doped carbon‐coated ZnO/ZnCo2O4/CuCo2O4 nanohybrid is prepared by the thermal annealing of a polymetallic MOF with ammonium bicarbonate as a pore‐forming agent. This is the first report on the rational design and preparation of a hybrid composed of three active metal oxide components originating from MOF precursors. Interestingly, as a lithium‐ion battery anode, the developed electrode delivers a reversible capacity of 1742 mAh g?1 after 500 cycles at a current density of 0.3 mA g?1. Furthermore, the material shows large storage capacities (1009 and 667 mAh g?1), even at high current flow (3 and 10 A g?1). The remarkable high‐rate capability and outstanding long‐life cycling stability of the multidoped metal oxide benefits from the carbon‐coated integrated nanostructure with a hollow interior and the three active metal oxide components. 相似文献
8.
Multishelled NixCo3–xO4 Hollow Microspheres Derived from Bimetal–Organic Frameworks as Anode Materials for High‐Performance Lithium‐Ion Batteries
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Lan‐Lan Wu Zhuo Wang Yan Long Jian Li Yu Liu Qi‐Shun Wang Xiao Wang Shu‐Yan Song Xiaogang Liu Hong‐Jie Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(17)
Metal–organic frameworks (MOFs) featuring versatile topological architectures are considered to be efficient self‐sacrificial templates to achieve mesoporous nanostructured materials. A facile and cost‐efficient strategy is developed to scalably fabricate binary metal oxides with complex hollow interior structures and tunable compositions. Bimetal–organic frameworks of Ni‐Co‐BTC solid microspheres with diverse Ni/Co ratios are readily prepared by solvothermal method to induce the Ni x Co3? x O4 multishelled hollow microspheres through a morphology‐inherited annealing treatment. The obtained mixed metal oxides are demonstrated to be composed of nanometer‐sized subunits in the shells and large void spaces left between adjacent shells. When evaluated as anode materials for lithium‐ion batteries, Ni x Co3? x O4‐0.1 multishelled hollow microspheres deliver a high reversible capacity of 1109.8 mAh g?1 after 100 cycles at a current density of 100 mA g?1 with an excellent high‐rate capability. Appropriate capacities of 832 and 673 mAh g?1 could also be retained after 300 cycles at large currents of 1 and 2 A g?1, respectively. These prominent electrochemical properties raise a concept of synthesizing MOFs‐derived mixed metal oxides with multishelled hollow structures for progressive lithium‐ion batteries. 相似文献
9.
Sampath Prabhakaran Jayaraman Balamurugan Nam Hoon Kim Joong Hee Lee 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(19)
The development of hierarchical nanostructures with highly active and durable multifunctional catalysts has a new significance in the context of new energy technologies of water splitting and metal–air batteries. Herein, a strategy is demonstrated to construct a 3D hierarchical oxygenated cobalt molybdenum selenide (O‐Co1?xMoxSe2) series with attractive nanoarchitectures, which are fabricated by a simple and cost‐effective hydrothermal process followed by an exclusive ion‐exchange process. Owing to its highly electroactive sites with numerous nanoporous networks and plentiful oxygen vacancies, the optimal O‐Co0.5Mo0.5Se2 could catalyze the hydrogen evolution reaction and oxygen evolution reaction effectively with a low overpotential of ≈102 and 189 mV, at a current density of 10 mA cm?2, respectively, and exceptional durability. Most importantly, the O‐Co0.5Mo0.5Se2||O‐Co0.5Mo0.5Se2 water splitting device only entails a voltage of ≈1.53 V at a current density of 10 mA cm?2, which is much better than benchmark Pt/C||RuO2 (≈1.56 V). Furthermore, O‐Co0.5Mo0.5Se2 air cathode‐based zinc–air batteries exhibit an excellent power density of 120.28 mW cm?2 and exceptional cycling stability for 60 h, superior to those of state‐of‐art Pt/C+RuO2 pair‐based zinc–air batteries. The present study provides a strategy to design hierarchical 3D oxygenated bimetallic selenide‐based multifunctional catalysts for energy conversion and storage systems. 相似文献
10.
Porous Gold Nanoshells on Functional NH2‐MOFs: Facile Synthesis and Designable Platforms for Cancer Multiple Therapy
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Chuang Liu Lijia Luo Leyong Zeng Jie Xing Yuanzhi Xia Shan Sun Luyun Zhang Zhe Yu Junlie Yao Zhangsen Yu Ozioma Udochukwu Akakuru Madiha Saeed Aiguo Wu 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(35)
AuroShell nanoparticles (sealed gold nanoshell on silica) are the only inorganic materials that are approved for clinical trial for photothermal ablation of solid tumors. Based on that, porous gold nanoshell structures are thus critical for cancer multiple theranostics in the future owing to their inherent cargo‐loading ability. Nevertheless, adjusting the diverse experimental parameters of the reported procedures to obtain porous gold nanoshell structures is challenging. Herein, a series of amino‐functionalized porous metal–organic frameworks (NH2‐MOFs) nanoparticles are uncovered as superior templates for porous gold nanoshell deposition (NH2‐MOFs@Aushell) by means of a more facile and general one‐step method, which combines the enriched functionalities of NH2‐MOFs with those of porous gold nanoshells. Moreover, in order to illustrate the promising applications of this method in biomedicine, platinum nanozymes‐encapsulated NH2‐MOFs are further designed with porous gold nanoshell coating and photosensitizer chlorin e6 (Ce6)‐loaded nanoparticles with continuous O2‐evolving ability (Pt@UiO‐66‐NH2@Aushell‐Ce6). The combination of photodynamic and photothermal therapy is then carried out both in vitro and in vivo, achieving excellent synergistic therapeutic outcomes. Therefore, this work not only presents a facile strategy to fabricate functionalized porous gold nanoshell structures, but also illustrates an excellent synergistic tumor therapy strategy. 相似文献
11.
Runming Tao Guang Yang Ethan C. Self Jiyuan Liang John R. Dunlap Shuang Men Chi‐Linh Do‐Thanh Jixing Liu Yiman Zhang Sheng Zhao Hailong Lyu Alexei P. Sokolov Jagjit Nanda Xiao‐Guang Sun Sheng Dai 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(29)
Nanoporous TiNb2O7 (NPTNO) material is synthesized by a sol–gel method with an ionic liquid (IL) as the nanoporous structure directing template. NPTNO exhibits a high reversible capacity of 210 mAh g–1 even at the charging rate of 50 C and an excellent cyclability of half‐cell capacity retention of 74% for 1000 cycles at 5 C and LiNi0.5Mn1.5O4‐coupled full‐cell capacity retentions of 81% and 87% for 1000 cycles at 1 C and 2 C, respectively. The studies of the 1000 cycled NPTNO electrode illustrate that the IL‐directed mesoporous structure can enhance the cyclability of NPTNO cells due to the alleviation of repetitive mechanical stress and volume fluctuation induced by the repetitive Li+ insertion‐extraction processes. The measured Li+ diffusion coefficients from the galvanostatic intermittent titration technique suggest that the IL‐templating strategy indeed ensures the fast rechargeability of NPTNO cells based on the fast Li+ diffusion kinetics. Benefitting from the nanoporous structure, NPTNO with unhindered Li+ diffusion pathways achieves a superior rate capability in the titanium‐based oxide materials and the best full‐cell cyclability in the TNO materials. Therefore, the templating potential of IL is demonstrated, and the superb electrochemical performance establishes the IL‐directed NPTNO as a promising anode candidate for fast‐rechargeable LIBs. 相似文献
12.
Co9S8 Nanoparticles‐Embedded N/S‐Codoped Carbon Nanofibers Derived from Metal–Organic Framework‐Wrapped CdS Nanowires for Efficient Oxygen Evolution Reaction
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Lan‐Lan Wu Qi‐Shun Wang Jian Li Yan Long Yu Liu Shu‐Yan Song Hong‐Jie Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(20)
Metal–organic frameworks (MOFs) with tunable compositions and morphologies are recognized as efficient self‐sacrificial templates to achieve function‐oriented nanostructured materials. Moreover, it is urgently needed to develop highly efficient noble metal‐free oxygen evolution reaction (OER) electrocatalysts to accelerate the development of overall water splitting green energy conversion systems. Herein, a facile and cost‐efficient strategy to synthesize Co9S8 nanoparticles‐embedded N/S‐codoped carbon nanofibers (Co9S8/NSCNFs) as highly active OER catalyst is developed. The hybrid precursor of core–shell ZIF‐wrapped CdS nanowires is first prepared and then leads to the formation of uniformly dispersed Co9S8/N, S‐codoped carbon nanocomposites through a one‐step calcination reaction. The optimal Co9S8/NSCNFs‐850 is demonstrated to possess excellent electrocatalytic performance for OER in 1.0 m KOH solution, affording a low overpotential of 302 mV to reach the current density of 10 mA cm?2, a small Tafel slope of 54 mV dec?1, and superior long‐term stability for 1000 cyclic voltammetry cycles. The favorable results raise a concept of exploring more MOF‐based nanohybrids as precursors to induce the synthesis of novel porous nanomaterials as non‐noble‐metal electrocatalysts for sustainable energy conversion. 相似文献
13.
Kaipeng Cheng Frantisek Svec Yongqin Lv Tianwei Tan 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(44)
Encapsulation of enzymes in metal–organic frameworks (MOFs) is often obstructed by the small size of the orifices typical of most reported MOFs, which prevent the passage of larger‐size enzymes. Here, the preparation of hierarchical micro‐ and mesoporous Zn‐based MOFs via the templated emulsification method using hydrogels as a template is presented. Zinc‐based hydrogels featuring a 3D interconnecting network are first produced via the formation of hydrogen bonds between melamine and salicylic acid in which zinc ions are well distributed. Further coordination with organic linkers followed by the removal of the hydrogel template produces hierarchical Zn‐based MOFs containing both micropores and mesopores. These new MOFs are used for the encapsulation of glucose oxidase and horseradish peroxidase to prove the concept. The immobilized enzymes exhibit a remarkably enhanced increased operational stability and enzymatic activity with a kcat/km value of 85.68 mm s–1. This value is 7.7‐fold higher compared to that found for the free enzymes in solution, and 2.7‐fold higher than enzymes adsorbed on conventional microporous MOFs. The much higher catalytic activity of the mesoporous conjugate for Knoevenagel reactions is demonstrated, since the large pores enable easier access to the active sites, and compared with that observed for catalysis using microporous MOFs. 相似文献
14.
Acid and Base Resistant Zirconium Polyphenolate‐Metalloporphyrin Scaffolds for Efficient CO2 Photoreduction
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Er‐Xia Chen Mei Qiu Yong‐Fan Zhang Yong‐Sheng Zhu Li‐Yang Liu Ya‐Yong Sun Xianhui Bu Jian Zhang Qipu Lin 《Advanced materials (Deerfield Beach, Fla.)》2018,30(2)
A series of zirconium polyphenolate‐decorated‐(metallo)porphyrin metal–organic frameworks (MOFs), ZrPP‐n (n = 1, 2), featuring infinite ZrIV‐oxo chains linked via polyphenolate groups on four peripheries of eclipse‐arranged porphyrin macrocycles, are successfully constructed through a top–down process from simulation to synthesis. These are the unusual examples of Zr‐MOFs (or MOFs in general) based on phenolic porphyrins, instead of commonly known carboxylate‐based types. Representative ZrPP‐1 not only exhibits strong acid resistance (pH = 1, HCl) but also remains intact even when immersed in saturated NaOH solution (≈20 m ), an exceptionally large range of pH resistance among MOFs. The metallation at the porphyrin core gives rise to materials with enhanced sorption and catalytic properties. In particular, ZrPP‐1‐Co, with precise and uniform distribution of active centers, exhibits not only high CO2 trapping capability (≈90 cm3 g?1 at 1 atm, 273 K, among the highest in Zr‐MOFs) but also high photocatalytic activity for reduction of CO2 into CO (≈14 mmol g?1 h?1) and high selectivity over CH4 (>96.4%) without any cocatalyst under visible‐light irradiation (λ > 420 nm). Given the strong chemical resistance under extreme alkali conditions, these catalysts can be recycled without appreciable loss of activity. The possible mechanism for photocatalytic reduction of CO2‐to‐CO over ZrPP‐1‐Co is also proposed. 相似文献
15.
Rui Li Xiongjun Liu Ruoyu Wu Jing Wang Zhibin Li K. C. Chan Hui Wang Yuan Wu Zhaoping Lu 《Advanced materials (Deerfield Beach, Fla.)》2019,31(49)
Hydrogen evolution reaction (HER) in alkaline media urgently requires electrocatalysts concurrently possessing excellent activity, flexible free‐standing capability, and low cost. A honeycombed nanoporous/glassy sandwich structure fabricated through dealloying metallic glass (MG) is reported. This free‐standing hybrid shows outstanding HER performance with a very small overpotential of 37 mV at 10 mA cm?2 and a low Tafel slope of 30 mV dec?1 in alkaline media, outperforming commercial Pt/C. By alloying 3 at% Pt into the MG precursor, a honeycombed Pt75Ni25 solid solution nanoporous structure, with fertile active sites and large contact areas for efficient HER, is created on the dealloyed MG surface. Meanwhile, the surface compressive lattice‐strain effect is also introduced by substituting the Pt lattice sites with the smaller Ni atoms, which can effectively reduce the hydrogen adsorption energy and thus improve the hydrogen evolution. Moreover, the outstanding stability and flexibility stemming from the ductile MG matrix also make the hybrid suitable for practical electrode application. This work not only offers a reliable strategy to develop cost‐effective and flexible multicomponent catalysts with low Pt usage for efficient HER, but also sheds light on understanding the alloying effects of the catalytic process. 相似文献
16.
Sujeong Lee Gihyun Lee Moonhyun Oh 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(36):2370285
The structures of metal–organic frameworks (MOFs) are typically determined by the building blocks that compose them and the conditions under which they are formed. MOFs tend to adopt a thermodynamically and/or kinetically stable structure (naturally preferred form). Thus, constructing MOFs with naturally nonpreferred structures is a challenging task, as it requires avoiding the easier pathway toward a naturally preferred MOF. Herein, an approach to construct naturally nonpreferred dicarboxylate-linked MOFs employing reaction templates is reported. This strategy relies on the registry between the surface of the template and the cell lattice of a target MOF, which reduces the effort required to form naturally nonpreferred MOFs. Reactions of p-block trivalent metal ions (Ga3+ and In3+) with dicarboxylic acids typically produce preferred MIL-53 or MIL-68. However, the surface of UiO-67 (and UiO-66) template exhibits the well-defined hexagonal lattice, which induce the selective formation of a naturally nonpreferred MIL-88 structure. Inductively grown MIL-88s are purely isolated from the template via provoking a post-mismatch in their lattices and weakening the interfacial interaction between product and template. It is also discovered that an appropriate template for effective induced production of naturally nonpreferred MOFs shall be properly selected based on the cell lattice of a target MOF. 相似文献
17.
Xue Chang Xian‐Feng Yang Yang Qiao Shuo Wang Ming‐Hui Zhang Jun Xu Dan‐Hong Wang Xian‐He Bu 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(14)
The Keggin‐type polyoxometalates (POMs) are effective catalysts for oxidative desulfurization (ODS) and confining these POMs in metal–organic frameworks (MOFs) is a promising strategy to improve their performances. Herein, postsynthetic modification of POMs confined in MOFs by adding thiourea creates more unsaturated metal sites as defects, promoting ODS catalytic activity. Additional modification by confining 1‐butyl‐3‐methyl imidazolium POMs in MOFs is performed to obtain higher ODS activity, owing to the affinity between electron‐rich thiophene‐based compounds and electrophilic imidazolium compounds. The ODS catalytic activities of four Zr‐MOF‐based composites (bottle around ship) including phosphomolybdate acid (PMA)/UiO‐66, [Bmim]3PMo12O40/UiO‐66, PMA/Thiourea/UiO‐66, and [Bmim]3PMo12O40/Thiourea/UiO‐66 are therefore investigated in detail. In order to explore the catalytic mechanism of these MOF composites, their microstructures and electronic structures are probed by various techniques such as X‐ray diffraction, thermogravimetric analysis, Fourier transform infrared, Raman, scanning electron microscope, transmission electron microscope, BET, X‐ray photoelectron spectroscopy, EPR, UV–vis, NMR spectra, and H2‐temperature‐programmed reduction. The results reveal that phosphomolybdate blues and imidazolium phosphomolybdate blues with different Mo5+/Mo6+ ratios with the Keggin structure are confined in defected UiO‐66 for all four composites. This approach can be applied to design and synthesize other POMs/MOFs composites as efficient catalysts. 相似文献
18.
Yifan Lin Gen Chen Hao Wan Fashen Chen Xiaohe Liu Renzhi Ma 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(18)
2D metal–organic frameworks (2D MOFs) are promising templates for the fabrication of carbon supported 2D metal/metal sulfide nanocomposites. Herein, controllable synthesis of a newly developed 2D Ni‐based MOF nanoplates in well‐defined rectangle morphology is first realized via a pyridine‐assisted bottom‐up solvothermal treatment of NiSO4 and 4,4′‐bipyridine. The thickness of the MOF nanoplates can be controlled to below 20 nm, while the lateral size can be tuned in a wide range with different amounts of pyridine. Subsequent pyrolysis treatment converts the MOF nanoplates into 2D free‐standing nitrogen‐doped Ni‐Ni3S2@carbon nanoplates. The obtained Ni‐Ni3S2 nanoparticles encapsulated in the N‐doped carbon matrix exhibits high electrocatalytic activity in oxygen evolution reaction. A low overpotential of 284.7 mV at a current density of 10 mA cm?2 is achieved in alkaline solution, which is among the best reported performance of substrate‐free nickel sulfides based nanomaterials. 相似文献
19.
Kuaibing Wang Qingqing Li Zhujuan Ren Chao Li Yang Chu Zikai Wang Mingdao Zhang Hua Wu Qichun Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(30)
Two identical layered metal–organic frameworks (MOFs) (CoFRS and NiFRS) are constructed by using flexible 1,10‐bis(1,2,4‐triazol‐1‐yl)decane as pillars and 1,4‐benzenedicarboxylic acid as rigid linkers. The single‐crystal structure analysis indicates that the as‐synthesized MOFs possess fluctuant 2D networks with large interlayer lattices. Serving as active electrode elements in supercapacitors, both MOFs deliver excellent rate capabilities, high capacities, and longstanding endurances. Moreover, the new intermediates in two electrodes before and after long‐lifespan cycling are also examined, which cannot be identified as metal hydroxides in the peer reports. After assembled into battery‐supercapacitor (BatCap) hybrid devices, the NiFRS//activated carbon (AC) device displays better electrochemical results in terms of gravimetric capacitance and cycling performance than CoFRS//AC devices, and a higher energy‐density value of 28.7 Wh kg?1 compared to other peer references with MOFs‐based electrodes. Furthermore, the possible factors to support the distinct performances are discussed and analyzed. 相似文献
20.
Liaoyong Wen Yan Mi Chengliang Wang Yaoguo Fang Fabian Grote Huaping Zhao Min Zhou Yong Lei 《Small (Weinheim an der Bergstrasse, Germany)》2014,10(15):3162-3168
Due to the unique advantages of Pt, it plays an important role in fuel cells and microelectronics. Considering the fact that Pt is an expensive metal, a major challenging point nowadays is how to realize efficient utilization of Pt. In this paper, a cost‐effective atomic layer deposition (ALD) process with a low N2 filling step is introduced for realizing well‐defined Pt nanotube arrays in anodic alumina nano‐porous templates. Compared to the conventional ALD growth of Pt, much fewer ALD cycles and a shorter precursor pulsing time are required, which originates from the low N2 filling step. To achieve similar Pt nanotubes, about half cycles and 10% Pt precursor pulsing time is needed using our ALD process. Meanwhile, the Pt nanotube array is explored as a current collector for supercapacitors based on core/shell Pt/MnO2 nanotubes. This nanotube‐based electrode exhibits high gravimetric and areal specific capacitance (810 Fg?1 and 75 mF cm?2 at a scan rate of 5 mV s?1) as well as an excellent rate capability (68% capacitance retention from 2 to 100 Ag?1). Additionally, a negligible capacitance loss is observed after 8000 cycles of random charging‐discharging from 2 to 100 Ag?1. 相似文献