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1.
In the form of a succinct overview the structure and symmetry requirements of magnetic ferroelectrics are discussed. Boracites are the best-studied examples and have phases being simultaneously ferroelectric, ferromagnetic and ferroelastic. One of the salient features of such materials is the obligatory occurrence of the linear and bilinear magnetoelectric effects. They represent an invaluable auxiliary information for magnetic symmetry determination by neutron diffraction. Owing to the complexity of property combinations, work with single crystals and polarized light microscopy is obligatory. Key references of the field are given.  相似文献   

2.
Ferroelectrics undergo one or more crystallographic phase transitions, which involve lattice distortions. The direction of spontaneous polarization in ferroelectrics can be reoriented by an applied electric field (or mechanical stress). There is a spontaneous strain accompanying spontaneous polarization. Phase transitions and domain reorientations thus result in microdeformations. Many devices such as actuators and transducers are based on this behaviour. The origin of microdeformations in ferroelectrics and their consequences are discussed here.  相似文献   

3.
周洪庆  杨春霞  王宇光  宋昊  刘敏 《功能材料》2007,38(12):2093-2096
采用固相反应法制备了未掺杂和La2O3掺杂(0.5%、1%、2%(摩尔分数))的Ba0.55Sr0.45TiO3/MgO复合陶瓷材料,并研究了它们的显微结构和各种介电性能.研究结果表明,La2O3除一部分会进入BST晶格獭代Ba或Sr的位置外,还会有一部分与MgO等形成无定形态物质滞留在晶界,起到抑制BST晶粒生长的作用.BST/MgO复合陶瓷的居里温度随La2O3掺杂量的增大而降低,居里温度的降低导致了介电常数的减小.适量的La2O3掺杂提高了复合陶瓷的调谐性,而且La2O3掺杂明显降低了复合陶瓷的微波介电损耗.0.5%(摩尔分数)La2O3掺杂的BST/MgO复合陶瓷具有最佳的综合介电性能,其在10kHz下的调谐性为6.9%(2kV/mm),3.99GHz时的介电常数和介电损耗分别为87.5和3.35×10-3,基本可以满足铁电移相器的使用要求.  相似文献   

4.
The absorption tunability of 100 nm thickness of ferroelectric Barium Strontium Titanate (Ba0.5Sr0.5TiO3) thin films with different densities of pumped optical field is measured by terahertz time-domain spectroscopy in the range of 0.2 THz – 1.2 THz at 19 °C. Experimental results show that the absorption coefficient of BST film is approximately at 5000 cm−1–20000 cm−1 in the range of 0.2 THz – 1.2 THz and the absorption coefficient reached up to 16% when we applied the optical field up to 600 mW. The theoretical calculations reveal that increasing photoexcitation fluences is responsible for the increasing of transmission change in the conduction current density cause the absorption coefficient varied.  相似文献   

5.
    
Hybrid perovskite materials are famous for their great application potential in photovoltaics and optoelectronics. Among them, lead‐iodide‐based perovskites receive great attention because of their good optical absorption ability and excellent electrical transport properties. Although many believe the ferroelectric photovoltaic effect (FEPV) plays a crucial role for the high conversion efficiency, the ferroelectricity in CH3NH3PbI3 is still under debate, and obtaining ferroelectric lead iodide perovskites is still challenging. In order to avoid the randomness and blindness in the conventional method of searching for perovskite ferroelectrics, a design strategy of fluorine modification is developed. As a demonstration, a nonpolar lead iodide perovskite is modified and a new 2D fluorinated layered hybrid perovskite material of (4,4‐difluorocyclohexylammonium)2PbI4, 1 , is obtained, which possesses clear ferroelectricity with controllable spontaneous polarization. The direct bandgap of 2.38 eV with strong photoluminescence also guarantees the direct observation of polarization‐induced FEPV. More importantly, the 2D structure and fluorination are also expected to achieve both good stability and charge transport properties. 1 is not only a 2D fluorinated lead iodide perovskite with confirmed ferroelectricity, but also a great platform for studying the effect of ferroelectricity and FEPV in the context of lead halide perovskite solar cells and other optoelectronic applications.  相似文献   

6.
温馨  丁一  林国龙 《工业工程》2015,18(2):121-126
为了优化班轮公司航线网络,降低运营成本,针对始发地或目的地位于内陆,且内陆与港口间存在转运OD流的班轮航线进行网络设计。基于Logit和整数线性规划等方法,将内陆OD流转化为港到港需求,建立集装箱班轮航运网络评估模型。模型以总成本最小为目标,同时满足货运需求、装卸港转运时间以及合理安排运力等约束,利用IOLG CPLEX优化软件进行求解。将模型用于某班轮公司航线网络设计,与现有结构相比优化结果显示:在保持总运量大致持平的基础上,可将原有船队规模从81条航线、289只船舶有效缩减到77条航线和269只船舶。表明该模型能够有效降低班轮航线运营成本,具有较大的实践意义。  相似文献   

7.
    
Topographical patterns endow material surfaces with unique and intriguing physical and chemical properties. Spontaneously formed wrinkling has been harnessed to generate surface topography for various functionalities. Despite promising applications in biomedical devices and robot engineering, the friction behavior of wrinkling on curved surfaces remains unclear. Herein, wrinkled surfaces are induced by sputtering metals on soft polymer microspheres. The wrinkle morphologies and length scales can be controlled precisely by tailoring the microsphere radius (substrate curvature) and film thickness. The wrinkled surfaces exhibit controlled friction property, depending on the wrinkling patterns and length scales. An increase in friction force with increasing surface roughness is generally found for dimple patterns and labyrinth patterns. The dimple patterns show the lowest friction due to strong curvature constraint. The herringbone patterns exhibit apparent friction anisotropy with respect to topographic orientation. These results will guide future design of wrinkled surfaces for friction by harnessing substrate curvature.  相似文献   

8.
采用传统的固相反应合成法制备了0.9(K0.5Na0.5)NbO3-0.1LiSbO3(KNN-LS)无铅压电陶瓷,研究了它在不同直流偏置电场下的介电常数的频谱,并分析了直流偏置电场诱导下的相对介电常数变化值Δrε和调谐率K.随着偏置电场的增大,Δrε和K都变大,这与传统的钛酸锶钡陶瓷类的材料结果相反.同时,随着频率的增加,Δrε和K都减小.Δrε随偏置电压的增加而增大,意味着在高的电压下,样品的色散效应增大,其原因可以用空间电荷的极化理论来解释.另外,在外加偏置电压不高的情况下(3 kV/cm),就可以获得相对较大的调谐率1.17%.  相似文献   

9.
    
Printed electronics, which fabricate electrical components and circuits on various substrates by leveraging functional inks and advanced printing technologies, have recently attracted tremendous attention due to their capability of large-scale, high-speed, and cost-effective manufacturing and also their great potential in flexible and wearable devices. To further achieve multifunctional, practical, and commercial applications, various printing technologies toward smarter pattern-design, higher resolution, greater production flexibility, and novel ink formulations toward multi-functionalities and high quality have been insensitively investigated. 2D materials, possessing atomically thin thickness, unique properties and excellent solution-processable ability, hold great potential for high-quality inks. Besides, the great variety of 2D materials ranging from metals, semiconductors to insulators offers great freedom to formulate versatile inks to construct various printed electronics. Here, a detailed review of the progress on 2D material inks formulation and its printed applications has been provided, specifically with an emphasis on emerging printed memristors. Finally, the challenges facing the field and prospects of 2D material inks and printed electronics are discussed.  相似文献   

10.
Abstract

We describe some unsolved problems of current interest; these involve quantum critical points in ferroelectrics and problems which are not amenable to the usual density functional theory, nor to classical Landau free energy approaches (they are kinetically limited), nor even to the Landau–Kittel relationship for domain size (they do not satisfy the assumption of infinite lateral diameter) because they are dominated by finite aperiodic boundary conditions.  相似文献   

11.
    
While acoustic metamaterials provide extraordinary control to manipulate sound waves, their physical realization and applicability are severely impeded by the limited tunability, narrow operational frequency range, and non-compact designs. Integrating liquids with active actuation mechanism in the metamaterials provides broader material and design scope. Active microfluidic techniques for liquid actuation, never used in metamaterials before, will enable active tunability for liquid-embedded metamaterial designs, leading toward a novel class of “microfluidic acoustic metamaterials (MAM).” This work demonstrates deep-subwavelength ultra-compact tunable MAM, consisting of a slit aperture which is tuned by electrically moving a liquid droplet over it using electrowetting-on-dielectric. The proposed design makes MAM inherently multi-stable, and the ability to tune the acoustic field by moving the emission source point provides widescale efficient precision and multiple degrees of freedom. MAM realizes active acoustic switching and amplitude modulation of more than 20 dB and phase modulation from 0 to 2π with greater than 80% transmission efficiency analyzed analytically, experimentally, and numerically. MAM also delivers broadband operations ranging from 35 to 45 kHz. This design strategy opens state-of-the-art pathways for automating, tuning, and miniaturizing metamaterials by using microelectromechanical (MEMS) and microfluidic concepts.  相似文献   

12.
We describe some unsolved problems of current interest; these involve quantum critical points in ferroelectrics and problems which are not amenable to the usual density functional theory, nor to classical Landau free energy approaches (they are kinetically limited), nor even to the Landau–Kittel relationship for domain size (they do not satisfy the assumption of infinite lateral diameter) because they are dominated by finite aperiodic boundary conditions.  相似文献   

13.
14.
Using Green's matrix method and resonance capacity concept, surface plasmon resonances of metallic nanostrips are investigated. We first show how the resonance wavelength is determined by the geometric parameters. Then, resonances from visible to near-infrared, depending on the strip size, are obtained. For a specific nanostrip-type, a linear tunability of resonance wavelength is demonstrated from λR = 900 nm to λR = 1800 nm by merely changing the dimensions and keeping the aspect ratio fixed. It is also found that the near field is more enhanced around the thin and long nanostrip. These results can act as a guide in practical design work.  相似文献   

15.
16.
用化学络合的方法制得含弱荧光稀土离子镨Pr(Ⅲ)和铒Er(Ⅲ)的单体,并经自由基聚合方法制得含Pr(Ⅲ)和Er(Ⅲ)的聚丙烯酸酯聚合物.通过对聚合物薄膜的荧光分析发现,敏化离子La(Ⅲ)、Y(Ⅲ)、Yb(Ⅲ)的引入,使含弱荧光稀土离子镨Pr(Ⅲ)和铒Er(Ⅲ)的聚丙烯酸酯表现出了明显的荧光发射特性,且通过引入这些敏化离子,可实现对上述聚合物的特征荧光发射光谱的调控作用;同时发现敏化离子Yb(Ⅲ)对上述两种聚合物的荧光调控作用都较为明显.  相似文献   

17.
Sol-Gel制备Ba1-x Srx TiO3系铁电薄膜的介电、调谐性能*   总被引:12,自引:0,他引:12  
丁文  丁永平  孟中岩 《功能材料》2001,32(4):388-390
用sol-gel工艺制备Ba1-xSrxTiO3系铁电薄膜(1-x=0.3,0.5-0.9)。实验证实,在制备溶胶过程中,提高加热温度能有效增加BST薄膜的介电调谐百分率。室温下,100kHz,各组分薄膜的介电常数(ε)和介电调谐百分率(Tunability%)均呈现较高的值。其中,Ba0.8Sr0.2TiO3的介电常数和调谐百分率达到最大分别为:678和39%,比国际上同类文献报道的数据高。BST的ε-E曲线呈良好的单值函数关系。介电温谱出现明显宽化,调谐曲线峰值点对应的温度较居里温度低20-30℃,本文并对上述现象作出解释。  相似文献   

18.
G Guekos  D Syvridis 《Sadhana》1992,17(3-4):373-383
The paper reviews recent results obtained with diode lasers used in external hybrid cavities with frequency selective feedback. Such cavities attract continuing interest for several reasons. They generate a tunable single laser mode with very low linewidths (usually a few tens of kilohertz). Very wide discrete tunable ranges over 100 nm for Fabry-Perot type and over 200 nm for quantum well lasers are achieved. They can be made to oscillate in a tunable mode having the desired polarization state,TE orTM and, in some cases, simultaneously atTE andTM. This is done by designing a cavity that increases strongly theTM/TE intensity ratio and by using coatings on one laser facet that greatly lower bothTE andTM reflectivities. High-speed polarization switching in the gigahertz range is possible by inserting passive or active polarization selecting elements in the cavity. For all these reasons hybrid external cavities are attractive for applications in optical metrology, spectroscopy and optical communications. Moreover, the external cavity configuration allows the study of physical mechanisms in the laser diode by inducing on purpose phenomena that would have been otherwise impossible to achieve with free-running lasers.  相似文献   

19.
    
The biomimetic characteristics of the memristor as an electronic synapse and neuron have inspired the advent of new information technology in the neuromorphic computing. The application of the memristors can be extended to the artificial nerves on condition of the presence of electronic receptors which can transfer the external stimuli to the internal nerve system. In this work, nociceptor behaviors are demonstrated from the Pt/HfO2/TiN memristor for the electronic receptors. The device shows four specific nociceptive behaviors; threshold, relaxation, allodynia, and hyperalgesia, according to the strength, duration, and repetition rate of the external stimuli. Such nociceptive behaviors are attributed to the electron trapping/detrapping to/from the traps in the HfO2 layer, where the depth of trap energy level is ≈0.7 eV. Also, the built‐in potential by the work function mismatch between the Pt and TiN electrodes induces time‐dependent relaxation of trapped electrons, providing the appropriate relaxation behavior. The relaxation time can take from several milliseconds to tens of seconds, which corresponds to the time span of the decay of biosignal. The material‐wise evaluation of the electronic nociceptor in comparison with other material, which did not show the desired functionality, Pt/Ti/HfO2/TiN, reveals the importance of careful material design and fabrication.  相似文献   

20.
李伟  陈明  杨恒 《计测技术》2006,26(3):55-58
介绍了基于SRAM LUT结构的FPGA的几种在线配置方式,同时给出了在嵌入式系统中利用ARM7TDMI微处理器产生FPGA配置时序的方法;给出了最小系统应用电路;结合程序,分析如何产生FPGA的配置时序;本方案的实用性在本文得到充分说明.  相似文献   

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