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1.
Shuqi Chen Wenwei Liu Zhancheng Li Hua Cheng Jianguo Tian 《Advanced materials (Deerfield Beach, Fla.)》2020,32(3):1805912
Metasurfaces are planar photonic elements composed of subwavelength nanostructures, which can deeply interact with light and exploit new degrees of freedom (DOF) to manipulate optical fields. In the past decade, metasurfaces have drawn great interest from the scientific community due to their profound potential to arbitrarily control light. Here, recent developments of multiplexing and multifunctional metasurfaces, which enable concurrent tasks through a dramatic compact design, are reviewed. The fundamental properties, design strategies, and applications of multiplexing and multifunctional metasurfaces are then discussed. First, recent progress on angular momentum multiplexing, including its behavior under different incident conditions, is considered. Second, a detailed overview of polarization-controlled, wavelength-selective, angle-selective, and reconfigurable multiplexing/multifunctional metasurfaces is provided. Then, the integrated and on-chip design of multifunctional metasurfaces is addressed. Finally, future directions and potential applications are presented. 相似文献
2.
Shuqi Chen Zhancheng Li Wenwei Liu Hua Cheng Jianguo Tian 《Advanced materials (Deerfield Beach, Fla.)》2019,31(16)
Metasurfaces, 2D artificial arrays of subwavelength elements, have attracted great interest from the optical scientific community in recent years because they provide versatile possibilities for the manipulation of optical waves and promise an effective way for miniaturization and integration of optical devices. In the past decade, the main efforts were focused on the realization of single‐dimensional (amplitude, frequency, polarization, or phase) manipulation of optical waves. Compared to the metasurfaces with single‐dimensional manipulation, metasurfaces with multidimensional manipulation of optical waves show significant advantages in many practical application areas, such as optical holograms, sub‐diffraction imaging, and the design of integrated multifunctional optical devices. Nowadays, with the rapid development of nanofabrication techniques, the research of metasurfaces has been inevitably developed from single‐dimensional manipulation toward multidimensional manipulation of optical waves, which greatly boosts the application of metasurfaces and further paves the way for arbitrary design of optical devices. Herein, the recent advances in metasurfaces are briefly reviewed and classified from the viewpoint of different dimensional manipulations of optical waves. Single‐dimensional manipulation and 2D manipulation of optical waves with metasurfaces are discussed systematically. In conclusion, an outlook and perspectives on the challenges and future prospects in these rapidly growing research areas are provided. 相似文献
3.
Optical metasurfaces, as an emerging platform, have been shown to be capable of effectively manipulating the local properties (amplitude, phase, and polarization) of the reflected or transmitted light and have unique strengths in high‐density optical storage, holography, display, etc. The reliability and flexibility of wavefront manipulation makes optical metasurfaces suitable for information encryption by increasing the possibility of encoding combinations of independent channels and the capacity of encryption, and thus the security level. Here, recent progress in metasurface‐based information encoding is reviewed, in which the independent channels for information encoding are built with wavelength and/or polarization in one‐dimensional/two‐dimensional (1D/2D) modes. The way to increase information encoding capacity and security level is proposed, and the opportunities and challenges of information encoding with independent channels based on metasurfaces are discussed. 相似文献
4.
Lei Zhang Xiao Qing Chen Rui Wen Shao Jun Yan Dai Qiang Cheng Giuseppe Castaldi Vincenzo Galdi Tie Jun Cui 《Advanced materials (Deerfield Beach, Fla.)》2019,31(41)
Metasurfaces are artificially engineered ultrathin structures that can finely tailor and control electromagnetic wavefronts. There is currently a strong interest in exploring their capability to lift some fundamental limitations dictated by Lorentz reciprocity, which have strong implications in communication, heat management, and energy harvesting. Time‐varying approaches have emerged as attractive alternatives to conventional schemes relying on magnetic or nonlinear materials, but experimental evidence is currently limited to devices such as circulators and antennas. Here, the recently proposed concept of space‐time‐coding digital metasurfaces is leveraged to break reciprocity. Moreover, it is shown that such nonreciprocal effects can be controlled dynamically. This approach relies on inducing suitable spatiotemporal phase gradients in a programmable way via digital modulation of the metasurface‐elements' phase repsonse, which enable anomalous reflections accompanied by frequency conversions. A prototype operating at microwave frequencies is designed and fabricated for proof‐of‐concept validation. Measured results are in good agreement with theory, hence providing the first experimental evidence of nonreciprocal reflection effects enabled by space‐time‐modulated digital metasurfaces. The proposed concept and platform set the stage for “on‐demand” realization of nonreciprocal effects, in programmable or reconfigurable fashions, which may find several promising applications, including frequency conversion, Doppler frequency illusion, optical isolation, and unidirectional transmission. 相似文献
5.
Dapeng Wang Yongsop Hwang Yanmeng Dai Guangyuan Si Shibiao Wei Duk‐Yong Choi Daniel E. Gmez Arnan Mitchell Jiao Lin Xiaocong Yuan 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(20)
Simultaneous broadband and high efficiency merits of designer metasurfaces are currently attracting widespread attention in the field of nanophotonics. However, contemporary metasurfaces rarely achieve both advantages simultaneously. For the category of transmissive metadevices, plasmonic or conventional dielectric metasurfaces are viable for either broadband operation with relatively low efficiency or high efficiency at only a selection of wavelengths. To overcome this limitation, dielectric nanoarcs are proposed as a means to accomplish two advantages. Continuous nanoarcs support different electromagnetic resonant modes at localized areas for generating phase retardation. Meanwhile, the geometric nature of nanoarc curvature endows the nanoarcs with full phase coverage of 0–2π due to the Pancharatnam–Berry phase principle. Experimentally incorporated with the chiral‐detour phase principle, a few compelling functionalities are demonstrated, such as chiral beamsplitting, broadband holography, and helicity‐selective holography. The continuous nanoarc metasurfaces prevail over plasmonic or dielectric discretized building block strategies and the findings lead to novel designs of spin‐controllable metadevices. 相似文献
6.
Song Han Longqing Cong Yogesh Kumar Srivastava Bo Qiang Mikhail V. Rybin Abhishek Kumar Ravikumar Jain Wen Xiang Lim Venu Gopal Achanta Shriganesh S. Prabhu Qi Jie Wang Yuri S. Kivshar Ranjan Singh 《Advanced materials (Deerfield Beach, Fla.)》2019,31(37)
The remarkable emergence of all‐dielectric meta‐photonics governed by the physics of high‐index dielectric materials offers a low‐loss platform for efficient manipulation and subwavelength control of electromagnetic waves from microwaves to visible frequencies. Dielectric metasurfaces can focus electromagnetic waves, generate structured beams and vortices, enhance local fields for advanced sensing, and provide novel functionalities for classical and quantum technologies. Recent advances in meta‐photonics are associated with the exploration of exotic electromagnetic modes called the bound states in the continuum (BICs), which offer a simple interference mechanism to achieve large quality factors (Q) through excitation of supercavity modes in dielectric nanostructures and resonant metasurfaces. Here, a BIC‐driven terahertz metasurface with dynamic control of high‐Q silicon supercavities that are reconfigurable at a nanosecond timescale is experimentally demonstrated. It is revealed that such supercavities enable low‐power, optically induced terahertz switching and modulation of sharp resonances for potential applications in lasing, mode multiplexing, and biosensing. 相似文献
7.
Libin Yan Weiming Zhu Muhammad Faeyz Karim Hong Cai Alex Yuandong Gu Zhongxiang Shen Peter Han Joo Chong Dim‐Lee Kwong Cheng‐Wei Qiu Ai Qun Liu 《Advanced materials (Deerfield Beach, Fla.)》2018,30(39)
The metasurface concept is employed to planarize retroflectors by stacking two metasurfaces with separation that is two orders larger than the wavelength. Here, a retroreflective metasurface using subwavelength‐thick reconfigurable C‐shaped resonators (RCRs) is reported, which reduces the overall thickness from the previous record of 590 λ0 down to only 0.2 λ0. The geometry of RCRs could be in situ controlled to realize equal amplitude and phase modulation onto transverse magnetic (TM)‐polarized and transverse electric (TE)‐polarized incidences. With the phase gradient being engineered, an in‐plane momentum could be imparted to the incident wave, guaranteeing the spin state of the retro‐reflected wave identical to that of the incident light. Such spin‐locked metasurface is natively adaptive toward different incident angles to realize retroreflection by mechanically altering the geometry of RCRs. As a proof of concept, an ultrathin retroreflective metasurface is validated at 15 GHz, under various illumination angles at 10°, 12°, 15°, and 20°. Such adaptive spin‐locked metasurface could find promising applications in spin‐based optical devices, communication systems, remote sensing, RCS enhancement, and so on. 相似文献
8.
作为三维超构材料的衍生物,具有亚波长厚度的人工超构表面结构能够在紧凑的平台上灵活操纵光与物质的相互作用,有利于多功能、超紧凑光子器件的研发,对于微纳光子学和集成光子学具有重要意义。铁电晶体铌酸锂凭借其跨越可见光至中红外波段的宽透明窗口以及较大的非线性光学、电光系数,被认为是最有前途的多功能集成光子平台之一。近年来,基于铌酸锂薄膜(lithium-niobate-on-insulator,LNOI)的集成光子学器件研究也得到了迅猛发展。本文总结了几种有潜力制备高质量铌酸锂超构表面的微纳加工技术,同时介绍了近年来铌酸锂超构表面结构的研究进展,并对其未来的研究方向进行了展望。
相似文献9.
Mohammad Taghinejad Zihao Xu Hua Wang Hossein Taghinejad Kyu‐Tae Lee Sean P. Rodrigues Ali Adibi Xiaofeng Qian Tianquan Lian Wenshan Cai 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(5)
Atomically thin transition metal dichalcogenides (TMDs) in their excited states can serve as exceptionally small building blocks for active optical platforms. In this scheme, optical excitation provides a practical approach to control light‐TMD interactions via the photocarrier generation, in an ultrafast manner. Here, it is demonstrated that via a controlled generation of photocarriers the second‐harmonic generation (SHG) from a monolayer MoS2 crystal can be substantially modulated up to ≈55% within a timeframe of ≈250 fs, a set of performance characteristics that showcases the promise of low‐dimensional materials for all‐optical nonlinear data processing. The combined experimental and theoretical study suggests that the large SHG modulation stems from the correlation between the second‐order dielectric susceptibility χ(2) and the density of photoexcited carriers in MoS2. Indeed, the depopulation of the conduction band electrons, at the vicinity of the high‐symmetry K/K′ points of MoS2, suppresses the contribution of interband electronic transitions in the effective χ(2) of the monolayer crystal, enabling the all‐optical modulation of the SHG signal. The strong dependence of the second‐order optical response on the density of photocarriers reveals the promise of time‐resolved nonlinear characterization as an alternative route to monitoring carrier dynamics in excited states of TMDs. 相似文献
10.
Mohammad Taghinejad Hossein Taghinejad Zihao Xu Yawei Liu Sean P. Rodrigues Kyu‐Tae Lee Tianquan Lian Ali Adibi Wenshan Cai 《Advanced materials (Deerfield Beach, Fla.)》2018,30(9)
The optical Kerr nonlinearity of plasmonic metals provides enticing prospects for developing reconfigurable and ultracompact all‐optical modulators. In nanostructured metals, the coherent coupling of light energy to plasmon resonances creates a nonequilibrium electron distribution at an elevated electron temperature that gives rise to significant Kerr optical nonlinearities. Although enhanced nonlinear responses of metals facilitate the realization of efficient modulation devices, the intrinsically slow relaxation dynamics of the photoexcited carriers, primarily governed by electron–phonon interactions, impedes ultrafast all‐optical modulation. Here, femtosecond (≈190 fs) all‐optical modulation in plasmonic systems via the activation of relaxation pathways for hot electrons at the interface of metals and electron acceptor materials, following an on‐resonance excitation of subradiant lattice plasmon modes, is demonstrated. Both the relaxation kinetics and the optical nonlinearity can be actively tuned by leveraging the spectral response of the plasmonic design in the linear regime. The findings offer an opportunity to exploit hot‐electron‐induced nonlinearities for design of self‐contained, ultrafast, and low‐power all‐optical modulators based on plasmonic platforms. 相似文献
11.
The formation of all‐organic dual spin valves (DSVs) with three organic spin‐selective layers, that is, spin‐injection, spin‐detection, and an additional spin‐filtering layer at the intermediate, is reported. As spin‐selective layers, manganese‐ and cobalt phthalocyanines, which are well‐known single‐molecule magnets, are used in their immobilized forms, so that all‐organic DSVs can be prefabricated for characterization. The three spin‐selective layers have provided four configurations with at most two spin‐flip interfaces enforcing spin‐flipping at the two nonmagnetic organic spacer layers, for which copper phthalocyanine is used. Since a couple of the four configurations have exhibited similar resistivities, the degeneracy in the resistive‐states is broken through asymmetric spin‐injection and spin‐detection layers and also through asymmetric thickness of the nonmagnetic spacer layers. When both the spin‐flip interfaces are made operative independently, a 2‐bit logic with four distinct resistive states can be achieved. 相似文献
12.
Tackling Energy Loss for High‐Efficiency Organic Solar Cells with Integrated Multiple Strategies
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Lijian Zuo Xueliang Shi Sae Byeok Jo Yun Liu Fracis Lin Alex K.‐Y. Jen 《Advanced materials (Deerfield Beach, Fla.)》2018,30(16)
Limited by the various inherent energy losses from multiple channels, organic solar cells show inferior device performance compared to traditional inorganic photovoltaic techniques, such as silicon and CuInGaSe. To alleviate these fundamental limitations, an integrated multiple strategy is implemented including molecular design, interfacial engineering, optical manipulation, and tandem device construction into one cell. Considering the close correlation among these loss channels, a sophisticated quantification of energy‐loss reduction is tracked along with each strategy in a perspective to reach rational overall optimum. A novel nonfullerene acceptor, 6TBA, is synthesized to resolve the thermalization and VOC loss, and another small bandgap nonfullerene acceptor, 4TIC, is used in the back sub‐cell to alleviate transmission loss. Tandem architecture design significantly reduces the light absorption loss, and compensates carrier dynamics and thermalization loss. Interfacial engineering further reduces energy loss from carrier dynamics in the tandem architecture. As a result of this concerted effort, a very high power conversion efficiency (13.20%) is obtained. A detailed quantitative analysis on the energy losses confirms that the improved device performance stems from these multiple strategies. The results provide a rational way to explore the ultimate device performance through molecular design and device engineering. 相似文献
13.
Wenpei Fan Wei Tang Joseph Lau Zheyu Shen Jin Xie Jianlin Shi Xiaoyuan Chen 《Advanced materials (Deerfield Beach, Fla.)》2019,31(12)
The advancements in nanotechnology have created multifunctional nanomaterials aimed at enhancing diagnostic accuracy and treatment efficacy for cancer. However, the ability to target deep‐seated tumors remains one of the most critical challenges for certain nanomedicine applications. To this end, X‐ray‐excited theranostic techniques provide a means of overcoming the limits of light penetration and tissue attenuation. Herein, a comprehensive overview of the recent advances in nanotechnology‐enhanced X‐ray‐excited imaging and therapeutic methodologies is presented, with an emphasis on the design of multifunctional nanomaterials for contrast‐enhanced computed tomography (CT) imaging, X‐ray‐excited optical luminescence (XEOL) imaging, and X‐ray‐excited multimodal synchronous/synergistic therapy. The latter is based on the concurrent use of radiotherapy with chemotherapy, gas therapy, photodynamic therapy, or immunotherapy. Moreover, the featured biomedical applications of X‐ray‐excited deep theranostics are discussed to highlight the advantages of X‐ray in high‐sensitivity detection and efficient elimination of malignant tumors. Finally, key issues and technical challenges associated with this deep theranostic technology are identified, with the intention of advancing its translation into the clinic. 相似文献
14.
A long‐standing goal of DNA nanotechnology has been to assemble 3D crystals to be used as molecular scaffolds. The DNA 13‐mer, BET66, self‐assembles via Crick–Watson and noncanonical base pairs to form crystals. The crystals contain solvent channels that run through them in multiple directions, allowing them to accommodate tethered guest molecules. Here, the first example of biomacromolecular core–shell crystal growth is described, by showing that these crystals can be assembled with two or more discrete layers. This approach leads to structurally identical layers on the DNA level, but with each layer differentiated based on the presence or absence of conjugated guest molecules. The crystal solvent channels also allow layer‐specific postcrystallization covalent attachment of guest molecules. Through controlling the guest‐molecule identity, concentration, and layer thickness, this study opens up a new method for using DNA to create multifunctional periodic biomaterials with tunable optical, chemical, and physical properties. 相似文献
15.
Yang Deng Xi Wang Zilun Gong Kaichen Dong Shuai Lou Nicolas Pégard Kyle B. Tom Fuyi Yang Zheng You Laura Waller Jie Yao 《Advanced materials (Deerfield Beach, Fla.)》2018,30(38)
Featuring high photon energy and short wavelength, ultraviolet (UV) light enables numerous applications such as high‐resolution imaging, photolithography, and sensing. In order to manipulate UV light, bulky optics are usually required, and hence do not meet the fast‐growing requirements of integration in compact systems. Recently, metasurfaces have shown unprecedented control of light, enabling substantial miniaturization of photonic devices from terahertz to visible regions. However, material challenges have hampered the realization of such functionalities at shorter wavelengths. Herein, it is experimentally demonstrated that all‐silicon (Si) metasurfaces with thicknesses of only one‐tenth of the working wavelength can be designed and fabricated to manipulate broadband UV light with efficiencies comparable to plasmonic metasurface performance in infrared (IR). Also, for the first time, photolithography enabled by metasurface‐generated UV holograms is shown. Such performance enhancement is attributed to increased scattering cross sections of Si antennas in the UV range, which is adequately modeled via a circuit. The new platform introduced here will deepen the understanding of light–matter interactions and introduce even more material options to broadband metaphotonic applications, including those in integrated photonics and holographic lithography technologies. 相似文献
16.
Three‐Layered Hollow Nanospheres Based Coatings with Ultrahigh‐Performance of Energy‐Saving,Antireflection, and Self‐Cleaning for Smart Windows
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Lin Yao Zhe Qu Zili Pang Jing Li Siyao Tang Junhui He Lili Feng 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(34)
In this study, a well‐controlled interfacial engineering method for the synthesis of SiO2/TiO2/VO2 three‐layered hollow nanospheres (TLHNs) and TLHNs‐based multifunctional coatings is reported. The as‐prepared coatings allow for an outstanding integration of thermochromism from the outer VO2(M) layer, photocatalytic self‐cleaning capability from the middle TiO2(A) layer, and antireflective property from internal SiO2 HNs. The TLHNs coatings exhibit excellent optical performance with ultrahigh luminous transmittance (Tlum‐l = 74%) and an improved solar modulation ability (ΔTsol = 12%). To the best knowledge, this integrated optical performance is the highest ever reported for TiO2/VO2‐based thermochromic coatings. An ingenious computation model is proposed, which allows the neff of nanostructured coatings to be rapidly obtained. The experimental and calculated results reveal that the unique three‐layered structure significantly reduces the refractive index (from 2.25 to 1.33 at 600 nm) and reflectance (Rave, from 22.3 to 5.3%) in the visible region as compared with dense coatings. Infrared thermal imaging characterization and self‐cleaning tests provide valid evidence of SiO2/TiO2/VO2 TLHNs coatings' potential for energy‐saving and self‐cleaning smart windows. The exciting inexpensive and universal fabrication process for well‐defined structures may inspire various developments in processable and multifunctional devices. 相似文献
17.
Christian Martella Carlo Mennucci Alessio Lamperti Emmanuele Cappelluti Francesco Buatier de Mongeot Alessandro Molle 《Advanced materials (Deerfield Beach, Fla.)》2018,30(9)
MoS2 and generally speaking, the wide family of transition‐metal dichalcogenides represents a solid nanotechnology platform on which to engineer a wealth of new and outperforming applications involving 2D materials. An even richer flexibility can be gained by extrinsically inducing an in‐plane shape anisotropy of the nanosheets. Here, the synthesis of anisotropic MoS2 nanosheets is proposed as a prototypical example in this respect starting from a highly conformal chemical vapor deposition on prepatterend substrates and aiming at the more general purpose of tailoring anisotropy of 2D nanosheets by design. This is envisioned to be a suitable configuration for strain engineering as far as strain can be spatially redistributed in morphologically different regions. With a similar approach, both the optical and electronic properties of the 2D transition‐metal dichalcogenides can be tailored over macroscopic sample areas in a self‐organized fashion, thus paving the way for new applications in the field of optical metasurfaces, light harvesting, and catalysis. 相似文献
18.
Zhi Zhou Li Feng Liang Ming Peng Zhuo Ying Li Shi Xue Dong Wang Liang Sheng Liao 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(19)
Organic semiconductor micro‐/nanocrystals with regular shapes have been demonstrated for many applications, such as organic field‐effect transistors, organic waveguide devices, organic solid‐state lasers, and therefore are inherently ideal building blocks for the key circuits in the next generation of miniaturized optoelectronics. In the study, blue‐emissive organic molecules of 1,4‐bis(2‐methylstyryl)benzene (o‐MSB) can assemble into rectangular microcrystals at a large scale via the room‐temperature solution‐exchange method. Because of the Förster resonance energy transfer, the energy of the absorbed photons by the host matrix organic molecules of o‐MSB can directly transfer to the dopant organic molecules of tetracene or 1,2:8,9‐dibenzopentacene (DBP), which then emit visible photons in different colors from blue to green, and to yellow. More impressively, by modulating the doping molar ratios of DBP to o‐MSB, bright white‐emissive organic microcrystals with well‐preserved rectangular morphology can be successfully achieved with a low doping ratio of 1.5%. These self‐assembled organic semiconductor microcrystals with multicolor emissions can be the white‐light sources for the integrated optical circuits at micro‐/nanoscale. 相似文献
19.
High Performance and Stable All‐Inorganic Metal Halide Perovskite‐Based Photodetectors for Optical Communication Applications
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Chunxiong Bao Jie Yang Sai Bai Weidong Xu Zhibo Yan Qingyu Xu Junming Liu Wenjing Zhang Feng Gao 《Advanced materials (Deerfield Beach, Fla.)》2018,30(38)
Photodetectors are critical parts of an optical communication system for achieving efficient photoelectronic conversion of signals, and the response speed directly determines the bandwidth of the whole system. Metal halide perovskites, an emerging class of low‐cost solution‐processed semiconductors, exhibiting strong optical absorption, low trap states, and high carrier mobility, are widely investigated in photodetection applications. Herein, through optimizing the device engineering and film quality, high‐performance photodetectors based on all‐inorganic cesium lead halide perovskite (CsPbIxBr3–x), which simultaneously possess high sensitivity and fast response, are demonstrated. The optimized devices processed from CsPbIBr2 perovskite show a practically measured detectable limit of about 21.5 pW cm?2 and a fast response time of 20 ns, which are both among the highest reported device performance of perovskite‐based photodetectors. Moreover, the photodetectors exhibit outstanding long‐term environmental stability, with negligible degradation of the photoresponse property after 2000 h under ambient conditions. In addition, the resulting perovskite photodetector is successfully integrated into an optical communication system and its applications as an optical signal receiver on transmitting text and audio signals is demonstrated. The results suggest that all‐inorganic metal halide perovskite‐based photodetectors have great application potential for optical communication. 相似文献
20.
Multifunctional Gadolinium‐Doped Mesoporous TiO2 Nanobeads: Photoluminescence,Enhanced Spin Relaxation,and Reactive Oxygen Species Photogeneration,Beneficial for Cancer Diagnosis and Treatment
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Roghayeh Imani Ralf Dillert Detlef W. Bahnemann Meysam Pazoki Tomaž Apih Veno Kononenko Neža Repar Veronika Kralj‐Iglič Gerrit Boschloo Damjana Drobne Tomas Edvinsson Aleš Iglič 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(20)
Materials with controllable multifunctional abilities for optical imaging (OI) and magnetic resonant imaging (MRI) that also can be used in photodynamic therapy are very interesting for future applications. Mesoporous TiO2 sub‐micrometer particles are doped with gadolinium to improve photoluminescence functionality and spin relaxation for MRI, with the added benefit of enhanced generation of reactive oxygen species (ROS). The Gd‐doped TiO2 exhibits red emission at 637 nm that is beneficial for OI and significantly improves MRI relaxation times, with a beneficial decrease in spin–lattice and spin–spin relaxation times. Density functional theory calculations show that Gd3+ ions introduce impurity energy levels inside the bandgap of anatase TiO2, and also create dipoles that are beneficial for charge separation and decreased electron–hole recombination in the doped lattice. The Gd‐doped TiO2 nanobeads (NBs) show enhanced ability for ROS monitored via ?OH radical photogeneration, in comparison with undoped TiO2 nanobeads and TiO2 P25, for Gd‐doping up to 10%. Cellular internalization and biocompatibility of TiO2@x Gd NBs are tested in vitro on MG‐63 human osteosarcoma cells, showing full biocompatibility. After photoactivation of the particles, anticancer trace by means of ROS photogeneration is observed just after 3 min irradiation. 相似文献