The Microstructure of Graphite Spherulites in Cast Iron

The microstructure of graphite spherulites （G.S.） in Ce addition ductile cast iron was carried out using transmission electron microscopy （TEM） techniques. The structral characterization of the graphites is as following: there are platelets growing along the periphery as well as fan-like structure formed from platelet aggregates in the diameter section of spherulite, in which most of the platelets are with sizes ranging from several to tens nm in radial; the [001] direction of the platelets would have a tend to parallel to radial of the G. S. and meanwhile, they also a small misorientation deviated from the radial among the platelets each other. It shows that the anisotropy of graphites has been restrained by adding Ce element in cast iron and the structural characterization of the G. S. is consistent with the Double’ s model of the conical helixes formed in helical growing and branching.     

Role of Sulfur on the Transition from Graphite to Cementite Eutectic in Cast Iron

In the current study, an analytic solution is considered to explain the influence of sulfur on the transition from graphite to cementite eutectic in cast iron. The outcome from the current study indicates that this transition can be related to (a) the graphite nucleation potential (directly characterized by the cell count and indirectly by the nucleation coefficients; (b) the eutectic graphite growth rate coefficient; (c) the temperature range between the equilibrium temperature for graphite eutectic and the formation temperature for cementite eutectic; and (d) the liquid volume fraction, after pre-eutectic austenite solidification. In addition, the absolute and the relative chilling tendencies, as well as critical cooling rates including the chill width of the cast iron can be predicted from the current study. The analytic model was experimentally verified for castings with various sulfur contents. It is found that the main role of sulfur on the transition from graphite to cementite eutectic is through its effect on lowering the growth coefficient, and hence, the graphite eutectic growth rate. In addition, it is found that with the increasing sulfur content, the critical cooling rate is significantly reduced, thus increasing the absolute and the relative chilling tendency values, including the chill width.     

球墨铸铁微观组织形成的数值模拟

基于结晶动力学理论,建立了球墨铸铁凝固过程各阶段微观组织形成形核和长大的数学模型;根据该结晶动力学模型,编制了球铁微观组织形成模拟软件FTStructure．该软件可以预测球铁凝固过程中各相的形成以及固态转变中铁素体和珠光体的形成,并进而预测铸态力学性能．模拟了阶梯形试块的冷却曲线、微观组织和布氏硬度．模拟与实测结果符合较好．     

不同卸载应力对层状TiAl基合金损伤程度的影响

通过对层状TiAl基合金进行拉伸卸载试验，研究了不同预损伤对层状TiAl基合金断裂行为的影响。试验结果表明：随着损伤程度增加到一定程度，材料的弹性模量减小；随着预损伤程度的增加，裂纹面密度增大。通过统计分析发现裂纹面密度可以作为衡量损伤程度的损伤参量；但随着预损伤程度的增加，单位面积断裂功基本不变，进一步说明不同预损伤对层状TiAl基合金的最终断裂性能没有影响。     

钛铁矿钛铁连续测定试验研究

在测定方法基本原理不变的基础上提出使用钛一铁连测分析方法,可实现一次称样即可完成钛和铁的测定。在钛铁矿钛铁连测条件试验中,对选定的4个主要因素：硫-磷混酸用量、指示剂二苯胺磺酸钠浓度、溶液体积、滴定温度进行了正交试验研究,选定了最佳试验条件。在此条件下,以钛铁矿样品为基准进行3次实验,验证该实验条件的可行性,钛和铁的回收率在98．0％～102％区间内。应用钛铁连测方法测定结果与标准样对照,测定结果与标准样的结果接近。钛铁连测法测定结果与国标分别测定钛和铁的结果比较差异较小。     

铁液中镁硫平衡

用密闭容器蒸汽法测定了1600℃下,纯铁液中镁硫平衡时的镁硫溶度积为K'_MgS=2.36×10^-4,求得平衡常数K_MgS=2.10×10^-4。     

球墨铸铁轧辊保温冒口研究

球墨铸铁轧辊的补缩,一般是采用砂型明冒口和浇注后每隔20-25分钟用过热铁水点冒口1-2次的办法解决,这样的工艺使冒口金属消耗量占轧辊毛重的15%左右。为了节约金属和提高轧辊上辊颈质量,本研究工作是采用铝型膨胀发热剂单独使用或与绝热套组合成的保温冒口,以取代原工艺以稻草灰覆盖的干砂型冒口。经过实验室及现场对此实验表明:采用保温冒口以后,球墨铸铁共晶凝固时间延长了33-62%,缩孔形状由倒锥形变为盆形,轧辊冒口的致密段高度增加,省去了用过热铁水点冒口的工序。冒口高度可以降低25~50%,节约冒口金属量20~50%。研究工作表明:采用保温冒口是解决球铁轧辊补缩的最合理、经济而简便的措施。     

Solidification and Room Temperature Microstructure of a Fully Pearlitic Compacted Graphite Cast Iron

Compacted graphite cast irons are rapidly developing for they have better mechanical properties than lamellar graphite cast irons and present less porosity than spheroidal graphite cast irons. For many applications, an as-cast fully pearlitic matrix would be desired which can hardly be achieved when graphite is compacted. Addition of manganese, copper and tin are thus made as these elements are known to be pearlite promoters. However, their amount should be limited so as to avoid detrimental effects amongst which are heterogeneities in the matrix properties which impede easy machining. In the present work, a compacted graphite cast iron containing 0.3 wt% Mn, 0.8 wt% Cu and 0.1 wt% Sn was cast in sand mould and in standard thermal analysis cup. The cup sample showed a nearly fully pearlitic matrix and was selected for further study. The characterization consisted of measuring and correlating the distributions of pearlite interlamellar spacings and microhardness values. An attempt was made to look for the effect of solidification microsegregation on microhardness which did not reveal any trend.     

高温下奥—贝蠕铁的组织与性能

奥—贝蠕铁是继奥—贝球铁之后发展起来的新型工程材料之一，也是世界上正在开发的材料。本文系统地提供了奥—贝蠕铁的制取工艺，奥—贝蠕铁的组织特征及其在常温及随温度提高力学性能变化的规律。研究表明，以稀土硅铁为蠕化剂，所制取的蠕化率大于９０％、基体以铁素体为主的蠕墨铸铁，经等温淬火后，可稳定地获得奥氏体—贝氏体基体（以下简称奥—贝蠕铁），它有较好的综合性能，在常温下σｂ＝８２０～９３７．５ＭＰａ，δ＝０．４０％～０．７８％；在６００℃时，σｂ＝１５８～１８７ＭＰａ，δ＝４．００％～７．８４％，仍超过ＨＴ１５０的常温性能。当低于３００℃时组织和性能稳定性较好，是适宜的工作温度范围     

玻璃模具用梯度石墨铸铁的组织与性能

国内外广泛采用梯度石墨结构铸铁作为瓶罐类玻璃模具材料,但使用寿命存在显著差距。对实际使用的梯度石墨铸铁模具进行了对比分析,结果表明:国内外模具材料石墨形态与分布相似,由内侧的D型石墨过渡到外侧的A型石墨时,材料抗压强度下降;石墨形态为D型时,抗压强度与基体显微硬度呈线性关系;进口玻璃模具材料基体组织基本为铁素体,塑性较好,国产玻璃模具材料基体含约10%(体积分数)的片状珠光体,强度高,但是塑性较差;玻璃模具使用寿命与模拟热疲劳寿命趋势一致,均属于低周疲劳破坏,寿命主要决定于模具材料的塑性。     

TC10钛合金高温变形行为和组织演变的研究

通过恒应变压缩实验研究了锻态TC10钛合金的高温变形行为和组织演变规律,变形温度为800~920℃,应变速率为0.01~10 s~(-1),变形量为60%。研究结果表明:降低变形温度、提高应变速率,流变应力会在变形初期迅速增加,而显微组织没有明显变化,当流变应力达到最大值后随着动态再结晶的发生而逐渐降低。提高变形温度、降低应变速率,能够为动态再结晶提供能量,细化组织并降低流变应力。综合分析表明:在变形温度为840~900℃,应变速率为0.01~0.1 s~(-1)的参数范围内进行热变形可以获得性能优良的TC10钛合金产品。     

球墨铸铁液压件发热冒口的研究

耐高压的液压件采用球墨铸铁（简称“球铁”）材质是一项先进技术。但是球铁的补缩困难,特别是对薄壁、复杂的液压件,热节处易产生缩松而导致铸件的渗漏,这是采用球铁生产液压件的关键问题。我们采用发热冒口解决球铁液压件的补缩问题。研究结果表明:发热冒口套热损失率比普通砂型冒口降低53%,等效模数约为几何模数（砂型冒口的模数）的两倍。节约冒口金属的50～80%,解决了普通砂型冒口解决不了的球铁液压件的补缩问题。     

悬浮液进样石墨炉原子吸收法测定钛白粉中铁

使用悬浮液进样 ,不进行溶样处理 ,最低限度地减少了样品处理过程中的沾污。选用乙醇作溶剂 ,降低了空白。方法操作简便 ,测定下限低     

稀土对球墨铸铁中共存As、Sn、Pb、Ti的中和作用

全部采用龙岩生铁，制取球墨铸铁。球化剂为镁硅铁合金，同时分别添加０．００％、０．０１％、０．０２％、０．０３％、０．０４％、０．０５％、０．０７％稀土硅铁合金进行球化处理。结果表明，稀土不能完全消除与中和高含量微量元素共存对石墨球化的干扰作用。但适量稀土可部分中和微量元素、促进形核、改善球状石墨的表面形貌。削弱微量元素的有害作用。     

Effect of Sulfur and Antimony on the Intergranular Fracture of Iron at Cathodic Potentials

Antimony, segregated to grain boundaries of iron, was found to be five times more effective than sulfur in promoting intergranular fracture of iron when tested in IN H₂SO₄ at cathodic potentials. A decrease in the ductility of iron accompanied the fracture mode change at increasing cathodic potentials. The effectiveness of antimony relative to sulfur was determined from straining electrode tests on iron and iron + 250 appm antimony alloys heat treated at 800 °C and 600 °C to produce different grain boundary chemical compositions. Grain boundary compositions were determined by Auger Electron Spectroscopy (AES). Similar grain boundary sulfur concentrations of 0.2 monolayers were observed by AES for the iron and iron + 250 appm antimony alloy after an anneal of 240 hours at 600 °C, while 0.08 monolayers of antimony was observed for the iron + 250 appm antimony alloy. These results suggest that sulfur and antimony do not compete for grain boundary sites.     

微钛处理对含磷钢薄钢板组织和性能的影响

以低碳含磷钢为研究对象,通过分析不同卷取温度时(分别为600、650和700 ℃)热轧态和冷轧退火态的显微组织和力学性能以及退火再结晶动力学行为,研究了微钛(0.015%)处理对钢的组织和性能的影响.研究结果表明,热轧卷取温度对低碳含磷钢的显微组织和力学性能影响很小,但微钛处理后,低碳含磷钢的再结晶动力学受到延迟,特别当卷取温度为600 ℃时,不但热轧态和冷轧退火态的强度提高,而且力学性能对卷取温度和退火温度的敏感性增加;随着卷取温度的降低,热轧态和冷轧退火态的强度提高,且冷轧退火态强度随着退火温度升高而降低的幅度增加.微钛处理对含磷钢组织和性能的影响与钛析出相的粗化行为有关.     

Effect of Rare Earths and Nitrogen on Graphite Structure of Gray Cast Iron

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Effect of Graphite Nodule Diameter on Water Embrittlement of Austempered Ductile Iron

DuctileironwasdevelopedbyMorrogh[1]in 1940s.Theappearanceofaustemperedductileiron (ADI)in1970sessentiallyaffectedthemetallurgical researchofductileiron[2,3].ADIhasverygood properties[4-15].Itisproducedbyaustemperingcon ventionalductileiron,andthemicrostr…