Dry sliding wear behaviour of PTFE filled with glass and bronze particles

Abstract

The wear behaviour of polytetrafluroethylene (PTFE) filled with 25% glass and 40% bronze particles was studied on a pin on disc test rig. Solid lubricant composite materials were prepared by compression moulding technique. The wear parameters considered for the study were applied load, sliding speed and sliding distance. The experimental results indicate that the weight loss increases with increasing load, sliding speed and sliding distance, as expected. Sliding distance has more effect on weight loss followed by applied load. The 40% bronze+PTFE composite exhibits better wear resistance compared to other types. The dominant interactive wear mechanisms during sliding of PTFE and its composites are discussed in this paper.     

Tribological behavior of spun Kevlar fabric composites filled with fluorinated compounds

The tribological behavior of the spun Kevlar fabric composites filled with polyfluo wax (PFW) and LaF₃ were evaluated using a pin-on-disc friction and wear tester under variable applied load and rotating speed. The worn surface and transfer film of the composites were then examined with SEM. The results indicated that the oxidation of PFW after curing and viscous flow characteristic of PFW in friction process were beneficial to the formation of the compact, uniform and smooth transfer film, corresponding to the excellent wear resistance of the composite filled with 15 wt% PFW. The corresponding wear mechanisms were also discussed.     

Friction and wear properties of metal powder filled PTFE composites under oil lubricated conditions

Four kinds of polytetrafluoroethylene (PTFE)-based composite, pure PTFE, PTFE+30vol.%Cu, PTFE+30vol.%Pb and PTFE+30vol.%Ni composite, were prepared. The friction and wear properties of these metal powder filled PTFE composites sliding against GCr15 bearing steel under both dry and lubricated conditions were studied using an MHK-500 ring-block wear tester. The worn surfaces of the PTFE composites and the transfer films formed on the surface of GCr15 bearing steel were examined using scanning electron microscopy (SEM) and optical microscopy respectively. Experimental results show that the friction and wear properties of the PTFE composites can be greatly improved by liquid paraffin lubrication. The wear of these PTFE composites can be decreased by at least 1 to 2 orders of magnitude compared with that under dry friction conditions, while the friction coefficients can be decreased by 1 order of magnitude, SEM and optical microscopy investigations of the rubbing surfaces show that metal fillers of Cu, Pb and Ni not only raise the load carrying capacity of the PTFE composites, but also promote transfer of the PTFE composites onto the counterfaces, so they greatly reduce the wear of the PTFE composites. However, the transfer of these PTFE composites onto the counterfaces can be greatly reduced by liquid paraffin lubrication, but transfer still takes place.     

Friction and wear of polyphenylene sulfide composites filled with micro and nano CuO particles in water-lubricated sliding

The tribological behavior of polyphenylene sulfide (PPS) composites filled with micro and nano CuO particles in water-lubricated sliding condition were studied. Pin-on-disk sliding tests were performed against a steel counterface of surface roughness 0.09–0.11 μm. The lubrication regimes were established from friction data corresponding to various combinations of loads and sliding speeds. Later experiments were performed using the sliding speed of 0.5 m/s and contact pressure of 1.95 MPa, which corresponded to boundary lubrication regime. Micro CuO particles as the filler were effective in reducing the wear of PPS but nano CuO particles did not reduce wear. The steady state wear rate of PPS-30 vol.% micro CuO composite was about 10% of that of unfilled PPS and the coefficient of friction in this case was the lowest. The examination of the topography of worn pin surfaces of nano CuO-filled PPS by SEM revealed grooving features indicating three-body abrasion. The transfer films formed on the counterfaces during sliding were studied by optical microscopy and AFM. The wear behavior of the composites in water-lubricated sliding is explained using the characteristics of worn pin surfaces and transfer films on the counterface.     

Study on the tribological behavior of hybrid PTFE/cotton fabric composites filled with Sb2O3 and melamine cyanurate

The tribological behavior of the hybrid PTFE/cotton fabric composites filled with microsize Sb₂O₃ and melamine cyanurate (MCA) was investigated. It was found that the wear rate of the hybrid PTFE/cotton fabric composites decreased when Sb₂O₃ was used as the filler but increased with MCA filler. It was also observed that hybrid fillers (consists of Sb₂O₃ and MCA) had a wear reduction effect on the hybrid PTFE/cotton fabric composites at lower loads but increased the wear rate at higher loads. The wear behavior of the composites was explained in terms of the topography of worn surfaces and transfer film formed on the counterpart pin.     

Micromechanical simulations of biaxial yield, hardening and plastic flow in short glass fiber reinforced polyamide

Mean-field homogenization (MFH) is used to predict the biaxial yield behavior, hardening and plastic flow of composite materials made of an elasto-plastic matrix reinforced with misaligned short fibers. The procedure is applied to short glass fiber reinforced polyamide, which represents an important industrial application of those composites. First, MFH is verified against full-field accurate finite element simulations of representative volume elements with multiple fibers. Next, a parametric study is carried out with MFH in order to predict the biaxial plastic behavior of numerous microstructures corresponding to various values of volume fraction, aspect ratio and second-rank orientation tensor components of the glass fibers. Results demonstrate the loss of both isotropic hardening and plastic flow normality, except for 2D random orientation. For illustration, a fit of Hill's orthotropic plasticity criterion is conducted for several orientation tensors.     

The effect of fibre reinforcement on the friction and wear of polyamide 66 under dry rolling–sliding contact

An investigation into the effect of fibre reinforcement on the friction and wear of PA66 in rolling–sliding contact is reported. Three types of short fibre—aramid, carbon and glass—were examined with the composites running against identical materials in a twin disc machine. It was found that the aramid-fibre reinforcement did not significantly alter the friction of the matrix material. However, both the carbon-fibre and glass-fibre reinforcement reduced the coefficient of friction substantially. Wear of the aramid- and carbon-fibre composites was essentially linear with time and generally around ten times greater than that of the unreinforced material. The wear of the glass-fibre composite was complex with an initial period where the wear rate was similar to that of the unreinforced material. After a significant depth of wear had occurred the wear rate changed to a value similar to, but slightly higher than, that of the other reinforced materials.It appears that one of the major benefits of introducing fibre reinforcement, particularly glass, is that it reduces the coefficient of friction and hence allows the material to be used for higher duties without exceeding the softening point of the matrix. This increase in duty is, however, at the expense of an increased wear rate and shorter component life.     

Friction and wear behavior of hybrid glass/PTFE fabric composite reinforced with surface modified nanometer ZnO

Nano-ZnO was successfully grafted with 2,4-toluenediisocyanate (TDI) and β-aminoethyltrimethoxylsilane (OB551) to avoid the agglomeration of nano-ZnO in composite. The hybrid glass/PTFE fabric composites reinforced with the untreated, OB551 and TDI modified nano-ZnO, respectively, were prepared by dip-coating of the hybrid fabric in a phenolic adhesive resin containing the nanoparticles to be incorporated and the successive curing. The friction and wear behaviors of various nano-ZnO reinforced hybrid glass/PTFE fabric composites sliding against AISI-1045 steel in a pin-on-disk configuration were evaluated on a Xuanwu-III high-temperature friction and wear tester, with the unfilled one as a reference. The morphologies of the worn surfaces of the composites and of the counterpart pins were analyzed using scanning electron microscopy. In addition, FTIR spectrum was taken to characterize the untreated and treated nano-ZnO. It is found that the untreated and treated nano-ZnO reinforced hybrid glass/PTFE fabric composites exhibit improved wear resistance and friction-reduction in comparison with the unfilled one. The TDI modified nano-ZnO reinforced composite can obtain the best friction and wear performance under different applied load; followed by the OB551 modified nano-ZnO reinforced one. Sliding conditions, such as environmental temperature and lubricating condition, significantly affect the tribo-performances of the unfilled and filled hybrid glass/PTFE fabric composites.     

Effect of thermal properties on laser cutting of continuous glass and carbon fiber-reinforced polyamide 6 composites

The single mode fiber laser cutting of two types of continuous fiber-reinforced thermoplastic composites (TPC) with polyamide 6 (PA6) matrix and a fiber content of 60 wt% was investigated: a glass fiber-reinforced composite (PA6/GF60) and a carbon fiber-reinforced composite (PA6/CF60). Preliminary, the thermal properties of the composites were analyzed to derive the cutting mechanisms. Thermogravimetric Analysis (TGA) showed decomposition onset temperatures of 457.6°C for the PA6 matrix and 737.3°C for the carbon fibers, while no thermal decomposition of the glass fibers was detected up to 1,000°C. In consequence, the single mode fiber laser cutting of the PA6/GF60 composites required a significantly higher number of cutting cycles in conjunction with an increased heat affected zone (HAZ) as compared to the PA6/CF60 composites. Analysis of the HAZ and the mechanical properties of the laser cut composites by optical microscopy and uniaxial tensile testing showed an anisotropy and dependency on the laminate structure. However, the obtained mechanical properties of the laser cut composites were found comparable to their water jet cut counterparts.     

聚四氟乙烯与超细高岭土填充聚甲醛复合材料的摩擦学性能

用聚四氟乙烯(PTFE)和超细高岭土填充聚甲醛(POM),采用热模压成型工艺制备出四种不同成分的试样,在往复式滑动摩擦试验机上进行摩擦磨损试验,并对磨损表面形貌进行了分析.结果表明:只填充PTFE的复合材料的摩擦因数和磨损率较纯POM均有较大幅度的下降,7.5%高岭土与20%PTFE复合填充的复合材料摩擦因数最小,耐磨性最好;纯POM的磨损机制是粘着磨损和磨粒磨损,POM复合材料的磨损机制以粘着磨损为主.     

Tribological Behavior of PTFE Composites Filled with PEEK and Nano-Al2O3

In this study, the tribological properties of polytetrafluoroethylene (PTFE) composites filled with polyetheretherketone (PEEK) and nano-Al₂O₃ particles were studied using a block-on-ring wear tester. The tribological performance of the composites was affected by the experimental parameters (sliding speed, normal load, and environmental temperature) and the composites achieved a high-speed sliding friction state. The results showed that the PEEK and nano-Al₂O₃ particles significantly improved the wear resistance of the PTFE composites. In addition, the nano-Al₂O₃ particles increased the hardness of the composites and enhanced the mechanical properties to enable applications in a wider range of industrial fields. The effects of the sliding speed and normal load on the tribological properties were more significant than that of the environmental temperature. In addition, the entire wear process was divided into three stages (the initial wear stage, severe wear transition stage, and ultralow stable wear stage), according to the evolution of the tribological characteristics (wear rate, morphology of the worn surface and transfer film, and wear debris morphology).     

Microstructure,Physical Properties,and Tribological Characteristics of Composite Solid Lubricant Coatings with Gas Atomized BaF2-CaF2

PS304 is a NASA-developed composite solid lubricant for friction and wear reduction at high temperatures. The microstructure, physical properties, and tribological performance of PS304 using standard comminuted BaF₂-CaF₂ and novel gas atomized BaF₂-CaF₂ were compared. Two atomized BaF₂-CaF₂ particle size distributions were used. Overall, feedstock powder with atomized BaF₂-CaF₂ flowed more freely than standard PS304 feedstock. The cohesion strength of coatings with atomized BaF₂-CaF₂ was lower than that of standard PS304, while the hardness of all of the studied coatings was essentially the same (approximately 58 HRA). Pin wear was lower against the new coatings and the coefficients of friction were essentially the same for all coatings. These results indicate that atomized BaF₂-CaF₂ can be substituted for comminuted BaF₂-CaF₂, providing a high-volume BaF₂-CaF₂ fabrication technique to reduce the cost of PS304 and improve its commercial availability.     

On dry sliding friction and wear behavior of PPESK filled with PTFE and graphite

Novel poly(phthalazinone ether sulfone ketone) (PPESK) resins have become of great interest in applications such as bearing and slider materials. In this paper, dry sliding wear of polytetrafluoroethylene (PTFE) and graphite-filled PPESK composites against polished steel counterparts were investigated on a block-on-ring apparatus at the same sliding velocities and different loads. The results indicated that the addition of 5–25 wt% PTFE and 5–30 wt% graphite contribute to an obvious improvement of tribological performance of PPESK at room temperature. Worn surfaces were investigated using a scanning electron microscope (SEM). As a result, the friction coefficient and wear rate of the PPESK composites decreased gradually with addition of fillers. A moderately low friction coefficient and specific wear rate were reached when the filler contents were above 20 wt%. The mechanical properties of PPESK composites were also investigated. The tensile and impact strength of PPESK composites decrease slightly as the addition of fillers contents were below 15 wt%.     

On the friction and wear behavior of PTFE composite filled with rare earths treated carbon fibers under oil-lubricated condition

Carbon fibers (CF) were surface treated with air-oxidation, air-oxidation followed by rare earths (RE) treatment and RE treatment, respectively. The friction and wear properties of the polytetrafluoroethylene (PTFE) composites filled with differently surface treated carbon fibers, sliding against GCr15 steel under oil lubrication, were investigated on a reciprocating ball-on-disk UMT-2MT tribometer. The worn surfaces of the PTFE composites were examined using a scanning electron microscopy (SEM). Experimental results revealed that surface treatment of carbon fibers reduced the wear of CF-reinforced PTFE composites. Among all the treatments to carbon fibers, RE treatment was the most effective and lowest friction and wear rate of CF-reinforced PTFE composite was exhibited, owing to the effective improvement of the interfacial adhesion between the carbon fibers and PTFE matrix.     

Tribological behavior and topography of friction surfaces of diamond-like coatings in contact with steel,silicon nitride,and quartz glass

The paper presents the study results of the tribological behavior and surface topography formed at friction of diamond-like coatings against indenters made of silicon nitride, quartz glass, and steel. It is shown that the tribological behavior depends on the nature and hardness of the counterbody material whose wear causes changes in the surface topography of the diamond-like coating at the nanometer level. At friction of the diamond-like coating against the silicon nitride indenter surface asperities are deformed plastically and the deformation rate is governed by the coating structure.     

Abrasive wear studies on composites of PEEK and PES with modified surface of carbon fabric

Carbon fabric (CF) being inert towards the matrix, the quality of its adhesion with the matrix is poor and hence, needs treatment to enhance fiber-matrix bonding. In this paper, cold remote nitrogen oxygen plasma (CRNOP) treatment to CF was employed to improve fiber-matrix adhesion. Composites were developed using CF with polyethersulphone (PES) and polyetheretherketone (PEEK) matrices. Performance enhancement due to CF treatment was quantified by improvement in mechanical and wear resistance (W_R) properties. A fairly good linearity was observed for specific wear rate (K₀×ILSS) as a function of a factor (μP/E).     

Effect of transfer film structure, composition and bonding on the tribological behavior of polyphenylene sulfide filled with nano particles of TiO2, ZnO, CuO and SiC

The tribological behavior of polyphenylene sulfide (PPS) filled with inorganic nano particles was studied. The fillers investigated were TiO₂, ZnO, CuO and SiC whose sizes varied from 30 to 50 nm. The polymer composites were compression molded with varying proportions of these fillers. Wear and friction tests were performed in a pin-on-disk configuration at a sliding speed of 1.0 m/s, nominal pressure of 0.65 MPa, and counterface roughness of 0.10 μm Ra. The polymer composite pins slid against hardened tool steel counterfaces. The transfer films of the composite materials formed on the counterfaces during sliding were studied by optical microscopy and X-ray photoelectron spectroscopy (XPS) and the adhesion between the transfer film and counterface was measured in terms of the peel strength. It was found that the wear rate of PPS decreased when TiO₂ and CuO were used as the fillers but increased with ZnO and SiC fillers. The optimum wear resistance was obtained with 2 vol.% CuO or TiO₂. These filled composites had the coefficients of friction lower than that of the unfilled PPS. The wear behavior of the composites is explained in terms of the topography of transfer film and adhesion of transfer film to the counterface as observed from peel strength studies. There is a good correlation observed between the transfer film-counterface bond strength and wear resistance.