共查询到18条相似文献,搜索用时 78 毫秒
1.
2.
相容剂在碳酸钙填充聚丙烯中的应用 总被引:4,自引:0,他引:4
本文介绍了以马来酸酐(MAH)接枝聚丙烯为碳酸钙填充聚丙烯的相容剂时,相容剂对两相界面粘接性的影响以及相容剂中接枝单体含量对材料力学性能的影响。另外,也将相容剂法与传统的偶联剂法进行了比较。 相似文献
3.
以马来酸酐(MAH)为接枝单体、丙烯酸-2-羟乙酯为共聚单体,利用熔融接枝技术对聚丙烯(PP)进行改性;以MAH/丙烯酸-2-羟乙酯熔融接枝改性PP为相容剂,研究相容剂对PP/玻璃纤维复合材料结构和性能的影响。结果表明:与未接枝PP相比,熔融接枝PP分子上接枝了MAH和—OH基团,而且熔融接枝反应对PP的熔点和热稳定性具有明显影响。另外,随着接枝PP含量的增加,PP/玻璃纤维复合材料的力学性能明显改善。当接枝PP含量为15%时,复合材料的拉伸强度提高了32%,冲击强度提高了13%,表明采用熔融共接枝工艺制备的PP具有优良的增容、偶联和分散效果。 相似文献
4.
研究了大分子相容剂对聚丙烯(PP)/水镁石粉阻燃复合材料的力学性能、燃烧性能及流变性能的影响.结果表明:马来酸酐接枝聚烯烃弹性体(POE-g-MAH)和马来酸酐接枝乙酸乙烯共聚物(EVA-g-MAH)复合相容剂较单一相容剂对阻燃复合材料有更好的改性效果,当复合相容剂添加量为10.0份时,复合材料的界面相容性和超细水镁石粉在体系中的分散性得到明显改善,复合材料断裂伸长率、冲击强度较未添加相容剂的分别提高了45%和59%,氧指数达到28%,另外复合相容剂的加入能改善复合材料的加工流动性,并且随着其添加量的增多,熔体流动速率先增大后减小. 相似文献
5.
不同相容剂对PP/木粉复合材料力学性能的影响 总被引:12,自引:3,他引:12
研究了3种相容剂和3种偶联剂分别在单独使用和配合使用情况下对PP/木粉(质量比50/50)复合材料力学性能的影响。相容剂PP-g-MAH、PE-g-MAH、SBS-g-MAH单独使用发现:SBS-g-MAH使材料综合性能最好,PE-g-MAH对冲击强度提高明显。硅烷偶联剂HP-172在提高复合材料的冲击强度和拉伸强度方面较好,HP-174对弯曲性能改善较好,钛酸酯偶联剂NDZ-201仅对弯曲模量有所改善,而对其它性能改善不大。相容剂与偶联剂共同使用具有协同效应,其中HP-174与SBS-g-MAH并用效果最好,使各项力学性能都有提高。 相似文献
6.
7.
中空微球填充PP复合材料传热的有限元分析 总被引:8,自引:0,他引:8
应用ANSYS软件对中空微球填充聚丙烯复合材料单元中的热传递进行了有限元模拟,并计算出等效导热系数(keff)。结果表明,keff随着中空微球体积分数的增加呈线性函数形式下降,且随着微球粒径的增加有所减小。此外,三维有限元模拟的keff值高于二维,两者的差异随着中空微球体积分数的增加而增大。 相似文献
8.
9.
10.
木粉填充聚乙烯复合材料的研究 总被引:10,自引:1,他引:10
采用木粉对聚乙烯(PE)进行改性,研究了树脂牌号、引发剂、接枝单体对相容剂性能的影响以及木粉的粒径、水含量及相容剂用量等因素对聚乙烯/木粉复合材料性能的影响,通过SEM(扫描电镜)对材料结构进行了表征。结果表明:复合材料的弯曲性能随木粉用量的增加而大幅度提高,耐热性能也有明显改善,而冲击性能则迅速下降;木粉的粒径对复合材料弯曲性能的改善不大,木粉水含量对复合材料的弯曲性能则有较大影响;相容剂用量在10%以上,可提高复合材料的弯曲性能,对冲击性能影响不大。 相似文献
11.
以氨基功能化聚丙烯(PP-g-NH2)作为PP/纳米SiO2复合材料的反应性增容剂,研究了其对复合材料力学性能的影响。结果表明,反应性增容剂的加入能较大幅度提高纳米复合材料的拉伸强度、拉伸模量,尤其是冲击性能,在环氧功能化改性纳米SiO2粒子含量为3%、反应性增容剂含量为10%时,冲击强度提高87%,拉伸强度提高了13%,表现出明显的增强增韧作用。 相似文献
12.
通过添加不同含量的粘土制备了三个不同类型(PP/DK1,PP/PPMA/DK1,PP/PPMA+DK1)纳米粘七/聚丙烯复合材料。使用力学性能测试对实验样品进行力学性能分析,结果表明:相对于纯聚丙烯,复合材料的拉伸强度、断裂伸长率随着粘土含量的增加呈先增加后下降趋势;而随着PPMA量的增加,基体的总体性能都呈现下降的趋势。 相似文献
13.
14.
Juan Guillermo Martínez-Colunga Saul Sanchez-Valdes Luis Francisco Ramos-deValle Odilia Perez-Camacho Eduardo Ramirez-Vargas Roberto Benavides-Cantú 《Polymer-Plastics Technology and Engineering》2018,57(13):1360-1366
Maleic anhydride-grafted polypropylene (PP-g-MA) was reacted with aniline (NH2C6H5) to produce PP-g-NHC6H5 and used as a compatibilizer in polypropylene/carbon nanotube composites. Infrared spectroscopy (FTIR) and nuclear magnetic resonance confirmed the reaction between PP-g-MA and aniline. PP-g-NHC6H5 resulted a better compatibilizer than PP-g-MA, producing good dispersion and homogeneous distribution of the carbon nanotubes with less agglomerates, as observed by SEM analysis. Improved dispersion and distribution is assumed to be due to the π–π interactions between the –C6H5 ring in the prepared compatibilizer and the hexagonal carbon structure in the nanotubes. In addition, a higher degree of crystallinity (12%) was promoted, since it was favored by π–π interactions. This achieved higher crystallinity promoted an increase in tensile modulus, with only slight changes in tensile strength but with an adverse effect on elongation at break. 相似文献
15.
分别采用聚丙烯接枝马来酸酐(PP-g-MAH)和硬脂酸(ST)作为相容剂,通过熔融共混法制备了PA6/PP(聚酰胺6/聚丙烯)合金,研究相容剂用量对该合金性能的影响。结果表明,随着相容剂的增加,PA6/PP合金的吸水性和熔体流动速率下降,拉伸强度和缺口冲击强度先增大后减小。当PP-g-MAH和ST用量分别为PA6/PP合金的4.0%(质量分数,下同)和2.0%时,复合材料的综合性能更佳。 相似文献
16.
Blends of polypropylene homopolymer (PP) and metallocene produced ethylene‐octene copolymer (EOR) with a bimodal particle size distribution were investigated. The aim of the work was to study the influences of EOR characteristics and its concentration on the tensile and impact properties of the blends. The matrix ligament thickness between rubber particles was measured and compared to those predicted using the theoretical models. The relationships between blend morphology and impact property were reported. It was found that the content of comonomer and molecular weight of the EOR as well as its concentration in the blends were the major factors controlling the tensile and impact properties of the blends. These factors became ineffective to impact property when the ligament thickness of the matrix was larger than the critical value (T ~0.3–0.4 μm). To achieve blends of high impact strength, the ligament thickness between rubber particles should be smaller than the critical value, and for a certain ligament thickness, EOR with high octene content and high molecular weight was preferred. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2412–2418, 2002 相似文献
17.
Poly(ethylene terephthalate) and polypropylene (PET/PP) were compounded and pelletized with a single-screw extruder. Standard ASTM tensile test specimens were made by injection moulding. The blends are stronger and stiffer than the plain PP specimens. The addition of a compatibilizer, EPOLENE E-43, is found to improve the strength and stiffness of the blends at loadings of 50% and 70% PET. At 10% PET loading, E-43 has the opposite effect of slightly reducing the tensile properties. All the blends are more brittle relative to either plain PET or PP. The addition of E-43 results in negligible improvement in the elongation at break. E-43 is also found to be an effective lubricant in improving the processability of the blends. The blends with E-43 added have lower viscosities and less shear-thinning characteristics than those without E-43. © 1997 SCI. 相似文献