共查询到17条相似文献,搜索用时 140 毫秒
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对新型的5528改性氰酸酯树脂的介电性能、耐热性能、粘温特性和吸湿性能进行了研究,结果表明:5528氰酸酯树脂具有良好工艺性能,适合于湿法预浸和热熔预浸,介电性能优异,介电损耗正切值为0.005 26,远远低于纯氰酸酯固化物,而且对于频率的稳定性更好,适合宽频应用5。528氰酸酯树脂体系是适合高性能透波材料或高频印刷电路板应用的树脂基体。 相似文献
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石英纤维增强氰酸酯树脂基复合材料性能研究 总被引:2,自引:0,他引:2
研究了QF210石英纤维增强新型的改性氰酸酯树脂基复合材料的耐热性、力学性能和介电性能,结果表明5528A/QF210复合材料具有优良的力学性能和优异的介电性能,可在150℃下使用。尤其是5528A/QF210复合材料的介电性能具有极好的频率稳定性,适合作为宽频高透波材料。 相似文献
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对石英纤维布进行了高温脱蜡处理,并制成了石英布增强氰酸酯树脂基预浸料及其复合材料,对比了脱蜡处理前后预浸料的理化性能和工艺性的变化,以及复合材料介电性能和力学性能的变化。结果表明,脱蜡处理后的石英布/氰酸酯预浸料的工艺性能更好,复合材料的介电性能保持不变,力学性能显著提高,其中弯曲强度提高31%,层间剪切强度提高16%,脱蜡后界面结合更好。 相似文献
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以对苯二甲基二甲醚为原料合成了二甲基对苯二甲基型苯酚(DMPXPh)。采用氯化氰-酚方法制备出新型二甲基对苯二甲基型氰酸酯(DMPXCy),并测定了其结构。考察了材料的热性能、耐湿热性、介电性能和力学性能,并与双酚A型氰酸酯(BADCy)进行比较。研究结果表明:(1)红外和核磁氢谱表征证明已经成功地制备出目标酚中间体,并且酚中间体已被氰酸酯化制备成氰酸酯单体。(2)DMPXCy的固化行为和热性能研究表明,DMPXCy反应活性低于BADCy树脂,并且加入有机金属催化剂后,固化温度明显降低,可在280℃内阶梯固化。另外,DMPXCy树脂的玻璃化转变温度比BADCy树脂低,热稳定性基本相同,但DMPXCy的残炭率较高,显示出一定的耐烧蚀性。(3)力学性能研究表明,DMPXCy树脂总体力学强度与BADCy相近,拉伸强度略低。(4)DMPXCy树脂吸湿性和介电性能研究说明,DMPXCy树脂展现出优异的介电性能和低吸湿性,介电常数(ε)与介电损耗角正切(tanδ)分别为2.650和0.004 50,饱和吸湿率为0.70%,远低于BADCy树脂的介电损耗和吸湿率。DMPXCy树脂作为低介电透波材料或... 相似文献
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共聚改性氰酸酯树脂及其性能 总被引:21,自引:0,他引:21
利用环氧树脂和双马来酰亚胺树脂做改性剂,对氰酸酯树脂进行共聚改性,通过对粘度的测量描述了共聚树脂的固化反应情况。性能测试表明内聚改性氰酸酯树脂的冲击强度比纯氰酸酯树脂自聚体提高了2倍多,可达12.3kJ/cm^2,热变形温度高达235℃,并具有优异的介电性能,如10kHz 介电常数为2.25,介电损耗角正切<10^-4。共聚树脂中的配比和固化条件对性能有影响。 相似文献
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改性氰酸酯树脂基复合材料的研究 总被引:3,自引:0,他引:3
本文研究了双酚A型氰酸酯树脂,4,4‘-双马来酰亚胺基二苯甲烷和E-51环氧 脂三元共聚体系的物理性能,反应性以及玻璃布增强复合材料的力学性能和介电性能。 相似文献
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Summary A series of thermosetting polymer/ceramic composites were prepared. Three kinds of thermosetting polymers, i.e. cyanate resin,
bismaleimide resin, and epoxy resin, were used as matrixes, and BaTiO3 particles were as fillers. The dielectric properties of these composites were investigated. Experimental data of the dielectric
constants were fitted to several theoretical equations in order to obtain the best-fitting equations of the dielectric constants
of these composites. The result indicates that the dielectric constants of composites all increase with the increase of BaTiO3 content. Using bismaleimide resin and epoxy resin as matrixes, the dielectric losses both increase obviously as the amount
of BaTiO3 particles is increased, but the dielectric loss of cyanate/BaTiO3 composite decreases. With the increase of the frequency, the variation ranges of the dielectric constant and dielectric loss
of cyanate/BaTiO3 composite are both the smallest. The predications of the effective dielectric constants by Lichterecker mixing rule are in
good agreement with experiment data. 相似文献
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Zhouqiang Sun Pingzhen Huang Aijuan Gu Guozheng Liang Li Yuan Shankai Dai 《应用聚合物科学杂志》2012,123(3):1576-1583
Advanced wave‐transparent composites are the key materials for many cutting‐edge industries including aviation and aerospace, which should have outstanding heat resistance, low dielectric constant and loss as well as good mechanical properties. A novel kind of high‐performance wave‐transparent composites based on surface‐modified aluminum phosphate AlPO4(KH‐550) and cyanate ester (CE) was first developed. The dielectric and dynamic mechanical properties of AlPO4(KH‐550)/CE composites were investigated intensively. Results show that AlPO4(KH‐550)/CE composites have decreased dielectric loss and higher storage moduli than pure CE resin; in addition, the composites with suitable AlPO4(KH‐550) concentration remain the outstanding thermal property and low dielectric constant of pure CE resin. The reasons attributing to these results are discussed from the effects of AlPO4(KH‐550) on the key aspects such as morphology, curing mechanism, and interfacial adhesion of composites. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
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High performance expanded graphite (EG)–multiwalled carbon nanotube (MWCNT)/cyanate ester (CE) composites with very high dielectric constant, low dielectric loss and low percolation threshold were developed. In order to understand the electric and dielectric behavior of EG–MWCNT/CE composites, EG/CE and MWCNT/CE binary composites were also prepared for comparison. Results show that the ternary composites have greatly different electric and dielectric properties from the binary composites. The percolation threshold of the EG–MWCNT/CE composite is much lower than that of either the EG/CE or MWCNT/CE composite. With the same content of conductive fillers, the EG–MWCNT/CE composite shows a much higher dielectric constant than EG/CE and MWCNT/CE composites. In addition, to obtain the same dielectric constant, the dielectric loss of the EG–MWCNT/CE composite is lower than that of either binary composite. The difference is attributed to the synergistic effect between EG and MWCNT. The addition of EG not only improves the dispersion of MWCNTs in the resin matrix, but also helps to form conductive networks. An equivalent circuit model is proposed. 相似文献
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通过多步接枝制得系列表面有机化的掺杂TiO2粒子(M系列粒子),制备了系列氰酸酯树脂(CE)基复合材料。结果表明,M系列掺杂粒子的引入,在降低复合材料活化能,有利于复合材料固化成型的同时,未改变复合材料的固化机理。定量M系列粒子(质量分数≤3%)的引入,优化了复合材料的介电性能,使复合材料介电常数增大66.2%,介电损耗减小50%。 相似文献
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环氧树脂基介电复合材料的制备和性能研究 总被引:1,自引:1,他引:0
以环氧树脂(EP)为基体树脂、经硅烷偶联剂改性后的压电陶瓷钛酸钡(BaTiO3)为增强填料,采用浇铸法制备了有机/无机介电复合材料。研究了填料用量对复合材料介电性能、力学性能和热性能的影响。实验结果表明,BaTiO3能显著提高材料的介电常数,当w(BaTiO3)=60%时,复合材料的介电常数为23.6,比纯EP的介电常数(4.0)提高了近6倍,而且复合材料的介电常数受频率影响较小,具有较好的频率稳定性;随着BaTiO3含量的增加,材料的弯曲强度和冲击强度都呈先增后减的趋势,最大弯曲强度和冲击强度分别为123.8 MPa和26.3 kJ/m2;材料的热稳定性研究表明,材料的起始热分解温度随着BaTiO3含量的增加而提高,材料的耐热性能得到改善。 相似文献
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In this work, Phthalonitrile containing benzoxazine (BA-ph) and Bisphenol A based cyanate ester (CE) were chosen as the matrix resin. Various amount of nano-SiO2 was incorporated into BA-ph/CE and their glass fiber-reinforced composite laminates were fabricated. Curing reaction and processability of BA-ph/CE/SiO2 blends were studied by differential scanning calorimetry and dynamic rheological analysis. Results showed that BA-ph and CE exhibited good processability and curing reaction of BA-ph/CE was not obviously affected by SiO2. Scanning electron microscope images of the composites showed that SiO2 particles were well dispersed in BA-ph/CE matrix. Moreover, SiO2 could act as physical crosslinking points and diluent in matrix as well as between the glass fibers to improve the mechanical properties of composite laminates. As the results of dynamic mechanical analysis and thermogravimetry analysis, composite laminates possessed satisfactory Tg and good thermal stability. With incorporation SiO2 particles into matrix resin, dielectric constant and dielectric loss of BA-ph/CE/SiO2/GF composites were increased and showed frequency dependence. 相似文献
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玻璃纤维布增强EP/PPO复合材料性能及应用 总被引:3,自引:2,他引:1
利用材料试验机、扫描电镜、高频微波仪及差示扫描量热仪研究了玻璃纤维布增强环氧树脂(EP)/聚苯醚(PPO)复合材料的弯曲性能、相态、介电性能和耐热性。结果表明,树脂含量对EP/PPO复合材料的弯曲强度和介电性能影响很大,在树脂质量分数约为40%时,复合材料的弯曲强度最大;当树脂质量分数大于30%时,介电常数的理论预测值与实验结果基本符合;硅烷偶联剂KH-550处理玻璃纤维布制得复合材料的弯曲性能较优;玻璃纤维布增强EP/PPO复合材料的热性能比纯EP/PPO树脂的热稳定性好。 相似文献