低温地热有机朗肯循环(ORC)工质选择

对低温(60～150℃)地热有机朗肯循环(ORC)系统,以净输出电功和系统能量损失作为评价指标,分析不同地热流体温度下有机工质R290,R134a,R600a,R600,R601a的做功能力,确定最佳循环工质.分析结果表明:对于湿流体工质,由于临界温度较低,当地热流体温度高于其临界温度20℃时,不存在最佳蒸发温度:对于60～80℃的地热流体,工质R601a的最大净输出电功最大;对于90～120℃的地热流体,工质R134a的最大净输出电功最大;对于125～150℃的地热流体,工质R290的净输出电功最大.这些结果为中低温地热利用提供设计依据.     

有机朗肯循环系统回收低温余热的优势

当前国内传统余热发电系统都是利用水蒸气的朗肯循环。举例分析了目前我国低温余热回收状况,进而通过和传统水蒸气余热发电系统的对比,阐述了有机朗肯循环(ORC)在回收低温余热领域的优势以及国内外实际应用情况。最后提出了对于国内发展ORC余热发电系统的建议。     

低温余热有机朗肯循环发电系统热经济性分析

针对工业中排放的低温烟气,建立有机朗肯循环发电系统的热经济分析模型,分析蒸发压力、热源温度及蒸发器最小传热温差对系统经济性能的影响。分析结果表明:热源温度为140℃,循环采用R123的经济性最佳,相应的发电成本与动态投资回收期分别为0.142元(/kW.h)与3.68年。余热发电系统存在一个经济性最高的蒸发压力,不同工质对应的最佳蒸发压力也不同。蒸发器内最小传热温差为15℃时,系统的经济性较好。烟气温度在100～180℃时,系统采用R123的投资回收期最短,而烟气温度高于180℃时,R141b的经济性更高;不宜采用有机朗肯循环发电技术回收温度低于100℃的低温烟气。     

有机朗肯循环工质的热稳定性分析

利用化学反应的热力学性质,以正戊烷为工质,从理论上分析计算正戊烷在375℃的中温环境中的分解产物,从而为分析系统性能的影响提供理论依据。     

中低温工业余热ORC回收装置的工质发展与应用

工业余热领域热源类型多样,如何筛选安全、稳定、高效的循环工质,成为有机朗肯循环(Organic Rankine Cycle,ORC)研究的关键性问题之一。采用纯工质作为工作流体更有利于工程应用中对系统的维护。本文在综述近五年国内外适用于中低温工业余热有机朗肯循环纯工质研究的基础上,探讨了亚临界循环和超临界循环ORC动力回收装置中循环工质的发展与应用现状。     

基于有机朗肯循环的APU余热回收系统性能分析

为有效利用飞机辅助动力装置（Auxitlary Power Unit , APU）排气余热,基于有机朗肯循环（Organic Rankine Cycle, ORC）发电系统,构建了APU余热回收系统。系统以APU排气余热为输入,驱动ORC做功,输出电能,为机载设备提供二次能源。结合工程热力学原理,建立系统热力学模型,并通过Matlab编程对余热回收系统进行了仿真计算及性能分析。仿真结果表明,系统功率及效率随飞行马赫数增加而降低;APU余热回收系统在飞机低音速飞行时有良好的性能;马赫数小于1时,系统功率在12 kW以上,效率在11%以上,耗气率低于0.0262 kg/kJ。     

基于有机工质朗肯循环系统的低温余热发电技术简述

调整能源结构、推进节能减排是我国工业化的必经之路。我国工业生产产生的中高温余热发电技术较为成熟,而低品位余热发电尚在发展。以低沸点有机物为工质的朗肯循环低温发电技术是回收中低品位热能的有效手段,不仅节能降耗,还能为企业带来可观的经济效益。文中从技术原理、循环工质、关键设备等方面介绍有机工质朗肯循环低温发电技术,并对发展前景作出展望。     

工业余热发电系统的应用及问题分析

工业余热发电特别是低温余热发电具有非常广阔的应用前景。结合国内某集团余热发电系统实际应用案例,经运行发现,余热发电系统可以实现并网发电,但存在热源稳定性、ORC机组可靠性及其冷端配套等问题,并就此做相关分析。余热发电作为工业节能减排的重要手段,需要进一步深入研究探索,对同类型的工程改造及设计具有一定的借鉴意义。     

低品位热能驱动有机朗肯循环的变工况特性

构建有机朗肯循环变工况分析模型,研究热源条件对系统变工况性能的影响规律。结果表明:随着热源温度升高,系统的最佳蒸发压力线性增大,而涡旋膨胀机的等熵效率逐渐减小。相比额定工况,热源温度变化-30.0K与30.0K时,净输出功率变化了-32.4%与18.4%,热效率降低了4.0%与11.4%,热回收效率变化幅度分别为-9.8%及8.9%;当热源温度从423增大至483K时,系统不可逆损失的变化率为-37.1%与45.5%,火用效率的变化率为6.7%与-17.5%。相比热源流量,热源温度对系统变工况性能的影响更大。     

A comparative study of the carbon dioxide transcritical power cycle compared with an organic rankine cycle with R123 as working fluid in waste heat recovery

The organic rankine cycle (ORC) as a bottoming cycle¹ to convert low-grade waste heat into useful work has been widely investigated for many years. The CO₂ transcritical power cycle, on the other hand, is scarcely treated in the open literature. A CO₂ transcritical power cycle (CO₂ TPC) shows a higher potential than an ORC when taking the behavior of the heat source and the heat transfer between heat source and working fluid in the main heat exchanger into account. This is mainly due to better temperature glide matching between heat source and working fluid. The CO₂ cycle also shows no pinch limitation in the heat exchanger. This study treats the performance of the CO₂ transcritical power cycle utilizing energy from low-grade waste heat to produce useful work in comparison to an ORC using R123 as working fluid.Due to the temperature gradients for the heat source and heat sink the thermodynamic mean temperature has been used as a reference temperature when comparing both cycles. The thermodynamic models have been developed in EES² The relative efficiencies have been calculated for both cycles. The results obtained show that when utilizing the low-grade waste heat with the same thermodynamic mean heat rejection temperature, a transcritical carbon dioxide power system gives a slightly higher power output than the organic rankine cycle.     

水泥厂余热利用研究

本文论述了焦作水泥厂中温烟气余热发电方案研究。讨论了设计方案、设备选型并进行了技术经济分析。本文结论对同类型余热利用工程具有参考价值。     

中低温废热发电的思路与方法

在工业生产过程中,存在着大量具有一定温度品质的热能被放散。实践中,可以通过某种设备系统将其回收利用,既节约了宝贵的一次能源,又改善了环境质量。中低温废热发电就是回收废热而生产二次优质能源的一种方法。     

热源自调节有机朗肯循环发电系统热力性能分析

为提高基本ORC(有机朗肯循环)系统换热器内冷热流体换热温差匹配程度,提升系统热力性能,提出一种ORC-R(热源自调节有机朗肯循环发电)系统,基于热力学第一定律和第二定律,建立了系统的数学模型并编制计算机程序进行分析,研究表明:当热源与有机工质换热温差不匹配时,采用热源自调节方式可有效提升基本ORC系统热力性能;热源自调节系数不同,ORC-R系统热力性能提升程度不同,存在随热源温度不同而有所变化的极限调节值;同时,ORC-R系统较基本ORC系统达到性能最优值时的蒸发温度降低,ORC-R系统净输出功、火用效率随热源自调节系数增加呈现先增加后减小的变化规律,可找到热源自调节系数的最佳值使ORC-R系统热力性能达到最优;热源温度Tg=373、383、393和403 K时,ORC-R系统净输出功Wnet较基本ORC系统分别增加35.52%、42.75%、51.15%和57.63%;ORC-R系统火用效率ηex分别为基本ORC系统的0.879 9倍、1.174 9倍、1.485 8倍和1.807 8倍。     

水泥窑纯低温余热发电有机工质循环技术的应用探讨

针对目前水泥工艺的余热情况及我国水泥窑余热发电的技术现状，提出了采用以有机烷类和有机热载体为循环工质的纯低温发电系统进行纯低温余热回收的方案，以达到节能降耗的目的。     

垃圾焚烧热电联产蒸汽参数选择

针对垃圾焚烧热电联产时,采用中温中压及中温次高压蒸汽参数对全厂投资及经济性的影响进行研究。以日处理规模为600 t·d^-1的生活垃圾焚烧设施作为研究对象,从主机设备参数、主机设备投资额、经济指标、营业收入及投资回收期等5个方面进行分析。研究结果表明,采用中温次高压参数时,垃圾焚烧设施热电联产全厂热效率较采用中温中压参数时提高1.7%,热电联产时全年总收入较采用中温中压参数时提高11.5%,且经济性更好,静态投资回收期约为4.73年。     

Experimental study on a small‐scale pumpless organic Rankine cycle with R1233zd(E) as working fluid at low temperature heat source

This paper focuses on the novelty pumpless organic Rankine cycle (ORC) and its choice of working fluids. Based on the selection criteria, the refrigerant of R1233zd(E) is firstly chosen and investigated in the pumpless ORC system. In the system, the feed pump is removed, and the refrigerant flows back and forth between two heat exchangers, which act as the evaporator or condenser, respectively. The impacts of the heating water temperature and loads on the system performance are studied to find out the best operating conditions. The low‐grade heat source is simulated by an electric boiler. The temperature of the heat resource ranges from 80°C to 100°C with the interval of 5°C. The temperature of the cooling water inlet is 10°C and is kept constant. The largest average power output is 127 W under the condition of 100°C heating water with nine loads. Because the cycle efficiency with heating steam temperature of 100°C cannot be determined, the highest energy and exergy efficiencies are 3.5% and 17.1%, respectively, for heating water of 95°C with seven loads. The experimental results show that the energy and exergy efficiencies increase with the increase of the heating temperature. The power and current outputs increase when the loads increase under the condition of the constant heating water temperature, whereas the voltage output decreases meanwhile. The generating time increases when the loads increase. This phenomenon is mainly caused by the increasing evaporating pressure and decreasing condensing pressure when the loads increases.     

Experimental investigation on heat recovery from condensation of thermal power plant exhaust steam by a CO2 vapor compression cycle

In this paper, a method that utilizes CO₂ vapor compression thermodynamic cycle to recover low‐temperature heat from exhausted water steam of fossil fuel thermal power plants is reported. Experimental investigation was carried out to study the characteristics of low‐temperature heat recovery by liquid CO₂ evaporation process from vacuum exhausted steam condensation occurring at the turbine exit. Furthermore, measured heat recovery performances over one whole year are presented and discussed. Experimental results show that the present heat recovery process by CO₂ vapor compression cycle is able to operate stably. The yearly averaged water temperature at the CO₂ condenser outlet was measured at 87.5 °C with a COP value above 5.0. This high energy efficiency ratio is found to be mainly due to two factors: the transcritical CO₂ vapor compression and steam condensation phase change occurring on the CO₂ evaporator. The findings from this paper provide helpful guidelines for low‐temperature heat recovery system design and improving fossil fuel utilization efficiency. Copyright © 2013 John Wiley & Sons, Ltd.     

回热燃气轮机余热利用进气冷却的研究

本文研究了利用余热制冷进气冷却的回热燃气轮机系统,并对该系统性能进行了模拟计算,得到了压比、流量比等参数对系统性能的影响规律。并通过与常规回热循环比较,指出利用余热制冷来进气冷却的方式能使系统效率提高11%,是提高燃气轮机系统性能的有效途径之一。     

有机朗肯循环工质热源转折温度的新求解法及应用

为获取热源和有机工质的最佳匹配规律,提高系统热力性能,提出求解工质热源转折温度的新方法及基于工质热源转折温度的工质与热源最优匹配新方法。首先,通过定义潜热熵差比推导出工质热源转折温度的理论公式,并采用蜻蜓算法进行精确求解;其次,与文献[14]对比,验证模型准确性;最后,对比工质热源转折温度与热源温度筛选最优工质。结果表明：选用的15种工质的热源转折温度与文献[14]的对比误差不超过1.62%,验证了工质热源转折温度求解公式的准确性;当热源温度确定时,选择热源转折温度小于热源温度的工质可获得最佳工况;当工质确定时,选择高于该工质热源转折温度的热源温度可获得最佳工况。