Pool boiling characteristics of multiwalled carbon nanotube (CNT) based nanofluids over a flat plate heater

This paper is mainly concerned about the pool boiling heat transfer behavior of multi-walled carbon nanotubes (CNTs) suspension in pure water and water containing 9.0% by weight of sodium lauryl sulphate anionic surfactant (SDS). Three different concentrations of 0.25%, 0.5% and 1.0% by volume of CNT dispersed with water and water containing 9.0% by weight of sodium lauryl sulphate anionic surfactant (SDS) were prepared and boiling experiments were conducted over a stainless steel flat plate heater of size 30 mm² and 0.44 mm thickness. The test results exhibit that the addition of carbon nanotubes increases boiling heat transfer coefficients of the base fluids. At a given heat flux of 500 kW/m², the enhancement of heat transfer coefficient was found to be 1.5, 2.6 and 3.0 times of water corresponding to 0.25%, 0.5% and 1.0% concentration of CNT by volume in water, respectively. In water–CNT–surfactant nanofluid, it was found that 0.5% of CNT concentration gives the highest enhancement of 1.7 compared with water. In both water and water–surfactant base fluids, it was observed that the enhancement factor for 0.25% of CNT first increases up to the heat flux of 66 kW/m² and then decreases for higher heat fluxes. Further, the overall heat transfer coefficient enhancement in the water–CNT nanofluids is approximately two times higher than that in the water–CNT–surfactant nanofluids. With increasing heat flux, however, the enhancement was concealed due to vigorous bubble generation for both water–CNT and water–CNT–surfactant nanofluids. Foaming was also observed over the liquid-free surface in water–CNT–surfactant nanofluids during the investigation. No fouling over the test-section surface was observed after experimentation.     

Heat transfer of aqueous suspensions of carbon nanotubes (CNT nanofluids)

This paper is mainly concerned about the heat transfer behaviour of aqueous suspensions of multi-walled carbon nanotubes (CNT nanofluids) flowing through a horizontal tube. Significant enhancement of the convective heat transfer is observed and the enhancement depends on the flow conditions (Reynolds number, Re), CNT concentration and the pH, with the effect of pH smallest. Given other conditions, the enhancement is a function of axial distance from the inlet, increasing first, reaching a maximum, and then decreasing with increasing axial distance. The axial position of the maximum enhancement increases with CNT concentration and Re. Given CNT concentration and the pH level, there appears to be a Re above which a big increase in the convective heat transfer coefficient occurs. Such a big increase seems to correspond to the shear thinning behaviour. For nanofluids containing 0.5 wt.% CNTs, the maximum enhancement reaches over 350% at Re = 800, which could not be attributed purely to the enhanced thermal conduction. Particle re-arrangement, shear induced thermal conduction enhancement, reduction of thermal boundary due to the presence of nanoparticles, as well as the very high aspect ratio of CNTs are proposed to be possible mechanisms.     

Boiling heat transfer on a high temperature silver sphere in nanofluid

To investigate boiling heat transfer characteristics of nanofluids, transient quenching experiments of a high temperature silver sphere in water-based nanofluids with Ag and TiO₂ nanoparticles were performed. A silver sphere with a diameter of 10 mm and an initial temperature of 700 °C was quenched in these nanofluids at a temperature of 90 °C. The results showed a considerable reduction in the quenching ability of nanofluids compared to that of pure water. The presence of nanoparticles in water caused the film boiling mode to vanish at lower temperatures depending on the mixture concentration. Calculated heat transfer rates in nanofluids were lower than those in pure water. In the quenching experiments with an unwashed heated sphere, the film boiling mode did not appear and the hot sphere quenched more rapidly through nucleate boiling. In this case the sphere surface was covered by a thin layer of nanoparticles. It was evident that nanoparticle deposition on the sphere surface prevented vapor film from forming around it and resulted in quick quenching of the hot sphere.     

Investigation of Thermal Conductivity and Viscosity of Carbon Nanotubes–Ethylene Glycol Nanofluids

Conventional fluids used for heat transfer applications in automobiles limit the performance enhancement and compactness of the heat exchangers. These problems can be overcome by using the technology of nanofluids. The objectives of this work are to prepare nanofluids and to study their dynamic viscosity and thermal conductivity. Chemically treated carbon nanotubes (CNTs) were added with ethylene glycol (EG) and sonicated using a bath sonicator to have a homogeneous dispersion of CNTs in EG. In this study, the nanofluids were prepared with different concentrations of CNTs varying from 0.12 to 0.4 wt%. The dynamic viscosity of nanofluids was measured using a rheometer over a temperature range of 25°C to 60°C. It was observed that the viscosity of nanofluids decreases with an increase of temperature and enhances with CNT concentration. The nanofluid follows the characteristic behavior of Newtonian fluids. A linear rise in thermal conductivity of ethylene glycol was observed with an increase of CNT concentration. It is concluded that EG–CNT nanofluids are promising to meet the challenges required by automobile systems.     

Heat transfer characteristics of Si and SiC nanofluids during a rapid quenching and nanoparticles deposition effects

Experiments were conducted to investigate the effect of nanofluid on a boiling heat transfer during a rapid quenching of a thin platinum (Pt) wire. The typical overall boiling curves have been successfully obtained from the cooling curves of the Pt wire for the water, the silicon (Si) and the silicon carbide (SiC) nanofluids. Meaningful differences in the behavior of the boiling curves between the water and the nanofluids cannot be identified during a quenching. However, the Si nanofluids reveal a slightly higher CHF (critical heat flux) than that for the water. On the other hand, a slight deterioration of CHF is observed in the case of the SiC nanofluids. When the Si and SiC nanoparticle-coated Pt wires are quenched with water, a very high cooling rate is observed and a very different boiling curve from that of the water and the nanofluids appears. Consequently, a considerably large heat transfer coefficient is obtained in a wide range of the wall superheat in the boiling curve.     

Effects of surface modification on the dispersion and thermal conductivity of CNT/water nanofluids

In the present work, effects of different surface modification methods (surfactant, acid, base, amide, sulfate) on multi walled carbon nanotubes (CNTs) are studied. The dispersion stability of CNTs in aqueous media was confirmed and the effects of the type of treatment on the thermal conductivity of CNT/water nanofluids were investigated. The surface of the CNTs was modified with acid mixtures (H₂SO₄–HNO₃), potassium persulfate (KPS), tetrahydrofuran (THF), octadecylamine and sodium dodecyl sulfate (SDS). UV–visible spectral data indicate that the CNTs treated first with the acid mixture and then with KPS show the best dispersion stability. The basic treatment and SDS treated CNT/water nanofluids (SDS-KCNT/water) showed the highest conductivity of 0.765 W/mK which increases 24.9% of water as a base fluid conductor.     

Preparation and pool boiling characteristics of copper nanofluids over a flat plate heater

The copper nanoparticles of average size of 10 nm have been prepared by the sputtering method and characterized through atomic force microscopy (AFM), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The pool boiling heat transfer characteristics of 0.25%, 0.5% and 1.0% by weight concentrations of copper nanoparticles has been studied. Different copper based nanofluids were prepared in both, distilled water and distilled water with 9.0 wt% of sodium lauryl sulphate anionic surfactant (SDS). The pool boiling heat transfer data were acquired for the boiling of nanofluids over a 30 mm square and 0.44 mm thick stainless steel plate heater. The experimental results show that for the critical heat flux of pure water is 80% higher than that of water–surfactant fluid. Also, it was found that the critical heat flux for 0.25%, 0.5% and 1.0% concentrations of copper nanoparticles in copper–water nanofluids are 25%, 40% and 48% higher than that of pure water. But in the case of copper–water with surfactant nanofluids comparing with pure water, the CHF decreases to 75%, 68%, and 62% for respective concentrations of copper nanoparticles. The heat transfer coefficient decreases with increase of nanoparticles concentration in both water–copper and water–copper with surfactant nanofluids.     

Heat transfer and entropy generation for laminar forced convection flow of graphene nanoplatelets nanofluids in a horizontal tube

The results are reported of an investigation of the heat transfer characteristics and entropy generation for a graphene nanoplatelets (GNP) nanofluid with specific surface area of 750 m²/g under laminar forced convection conditions inside a circular stainless steel tube subjected to constant wall heat flux. The analysis considers constant velocity flow and a concentration range from 0.025 wt.% to 0.1 wt.%. The impact of the dispersed nanoparticles concentration on thermal properties, convective heat transfer coefficient, thermal performance factor and entropy generation is investigated. An enhancement in thermal conductivity for GNP of between 12% and 28% is observed relative to the case without nanoparticles. The convective heat transfer coefficient for the GNP nanofluid is found to be up to 15% higher than for the base fluid. The heat transfer rate and thermal performance for 0.1 wt.% of GNP nanofluid is found to increase by a factor of up to 1.15. For constant velocity flow, frictional entropy generation increases and thermal entropy generation decreases with increasing nanoparticle concentration. But, the total entropy generation tends to decrease when nanoparticles are added at constant velocity and to decrease when velocity rises. Finally, it is demonstrated that a GNP nanofluid with a concentration between 0.075 wt.% and 0.1 wt.% is more energy efficient than for other concentrations. It appears that GNP nanofluids can function as working fluids in heat transfer applications and provide good alternatives to conventional working fluids in the thermal fluid systems.     

Numerical investigation of effective parameters in convective heat transfer of nanofluids flowing under a laminar flow regime

This article presents a numerical investigation on heat transfer performance and pressure drop of nanofluids flows through a straight circular pipe in a laminar flow regime and constant heat flux boundary condition. Al₂O₃, CuO, carbon nanotube (CNT) and titanate nanotube (TNT) nanoparticles dispersed in water and ethylene glycol/water with particle concentrations ranging between 0 and 6 vol.% were used as working fluids for simulating the heat transfer and flow behaviours of nanofluids. The proposed model has been validated with the available experimental data and correlations. The effects of particle concentrations, particle diameter, particles Brownian motions, Reynolds number, type of the nanoparticles and base fluid on the heat transfer coefficient and pressure drop of nanofluids were determined and discussed in details. The results indicated that the particle volume concentration, Brownian motion and aspect ratio of nanoparticles similar to flow Reynolds number increase the heat transfer coefficient, while the nanoparticle diameter has an opposite effect on the heat transfer coefficient. Finally, the present study provides some considerations for the appropriate choice of the nanofluids for practical applications.     

Enhanced specific heat and thermal conductivity of ternary carbonate nanofluids with carbon nanotubes for solar power applications

Specific heat and thermal conductivity are important thermal properties of high-temperature heat transfer fluids and thermal storage materials for supercritical solar power plants. In the present work, nanofluids composed of ternary carbonate Li₂CO₃-K₂CO₃-Na₂CO₃ (4:4:2, mass ratio) and 1.0 wt.% carbon nanotubes (CNT) were prepared to obtain high-temperature heat transfer and storage media with enhanced specific heat and thermal conductivity. The dispersion of CNTs in the nanofluids was tuned by changing the evaporation temperature (100, 140, 180 and 220 °C) and adding surfactants such as sodium dodecyl benzene sulfonate (SDBS), sodium dodecyl sulfate (SDS), or gum Arabic (GA). The results showed that GA and SDS facilitate good dispersion of CNT in nanofluids at the evaporation temperatures of 140 °C and 180 °C, resulting in the formation of more needle-like nanostructures. The higher increase in the specific heat and thermal conductivity of the nanofluids with SDS at 500 °C was 78.3% and 149.2%, respectively. Additionally, the specific heat of as-prepared ternary carbonate nanofluids exhibits a good thermal stability after 30 cycles of thermal shock experiments.     

Effect of functionalized MWCNTs/water nanofluids on thermal resistance and pressure fluctuation characteristics in oscillating heat pipe

An influence of multi-walled carbon nanotube (MWCNT) based aqueous nanofluids with different concentrations on the heat transport and the relevant pressure distribution in oscillating heat pipe (OHP) has been investigated. The present paper describes the heat transfer phenomena in terms of thermal resistance, pressure and frequency of pressure fluctuation in multi-loop oscillating heat pipe (OHP) charged by aqueous nanofluids with MWCNT loadings of 0.05 wt.%, 0.1 wt.%, 0.2 wt.% and 0.3 wt.%. The multi-loop OHP with 3 mm inner diameter has been conducted in the experiment at 60% filling ratio. Experimental results show that thermal characteristics are significantly inter-related with pressure distribution and strongly depend upon the number of pressure fluctuations with time. The investigation shows that the 0.2 wt.% MWCNTs based aqueous nanofluids obtain maximum number of the fluctuation frequency and low thermal resistance at any evaporator power input. Based on the experimental results, we discuss the reasons for enhancement and decrement of thermal characteristics of the nanofluids.     

Numerical investigation of heat transfer enhancement using carbon nanotube-based non-Newtonian nanofluids

In this study convective heat transfer of multi-wall carbon nanotube (MWCNT)-based nanofluids in a straight tube under constant wall heat flux condition is numerically investigated. To achieve this goal Navier–Stokes equations are solved using the finite volume technique with considering CNT-based nanofluids as non-Newtonian fluids of shear-thinning character using the non-Newtonian power law model. The objectives of this research are to provide detailed information of non-Newtonian behavior of CNT nanofluids, comparison of the numerical simulation predictions to the experimental measurements and investigation of non-Newtonian effects on the local heat transfer of the CNT nanofluid and compare the thermal performance of the CNT nanofluids and conventional fluids. As a result the heat transfer coefficient is dominated by the wall region due to non-Newtonian behavior of CNT nanofluid. The results reported in this paper illustrate that the numerical simulation can be one of the most powerful and beneficial tools for the CNT nanofluids optimization and performance analysis.     

Heat transfer performance and exergy analyses of a corrugated plate heat exchanger using metal oxide nanofluids

Heat exchangers have been widely used for efficient heat transfer from one medium to another. Nanofluids are potential coolants, which can afford excellent thermal performance in heat exchangers. This study examined the effects of water and CuO/water nanofluids (as coolants) on heat transfer coefficient, heat transfer rate, frictional loss, pressure drop, pumping power and exergy destruction in the corrugated plate heat exchanger. The heat transfer coefficient of CuO/water nanofluids increased about 18.50 to 27.20% with the enhancement of nanoparticles volume concentration from 0.50 to 1.50% compared to water. Moreover, improvement in heat transfer rate was observed for nanofluids. On the other hand, exergy loss was reduced by 24% employing nanofluids as a heat transfer medium with comparing to conventional fluid. Besides, 34% higher exergetic heat transfer effectiveness was found for 1.5 vol.% of nanoparticles. It has a small penalty in the pumping power. Hence, the plate heat exchanger performance can be improved by adapting the working fluid with CuO/water nanofluids.     

Influence of carbon nanotube suspension on the thermal performance of a miniature thermosyphon

An experimental study was carried out to understand the heat transfer performance of a miniature thermosyphon using water-based carbon nanotube (CNT) suspensions as the working fluid. The suspensions consisted of deionized water and multi-wall carbon nanotubes with an average diameter of 15 nm and a length range of 5–15 μm. Experiments were performed under three steady operation pressures of 7.4 kPa, 13.2 kPa and 20 kPa, respectively. Effects of the CNT mass concentration and the operation pressure on the average evaporation and condensation heat transfer coefficients, the critical heat flux and the total heat resistance of the thermosyphon were investigated and discussed. Experimental results show that CNT suspensions can apparently improve the thermal performance of the thermosyphon and there is an optimal CNT mass concentration (about 2.0%) to achieve the maximum heat transfer enhancement. The operation pressure has a significant influence on the enhancement of the evaporation heat transfer coefficient, and slight influences on the enhancement of the critical heat flux. The enhanced heat transfer effect is weak at low heat fluxes while it is increased gradually with increasing the heat flux. The present experiment confirms that the thermal performance of a miniature thermosyphon can be strengthened evidently by using CNT suspensions.     

Surface effects of ribbon heaters on critical heat flux in nanofluid pool boiling

This paper deals with a study of enhanced critical heat flux (CHF) and burnout heat flux (BHF) in pool boiling of water with suspended silica nanoparticles using Nichrome wires and ribbons. Previously the current authors and other researchers have reported three-digit percentage increase in critical heat flux in silica nanofluids. This study investigates the effect of various heater surface dimensions, cross-sectional shapes as well as surface modifications on pool boiling heat transfer characteristics of water and water-based nanofluids. Our data suggest that the CHF and BHF decrease as heater surface area increases. For concentrations from 0.1 vol% to 2 vol%, the deposition of the particles on the wire allows high heat transfer through inter-agglomerate pores, resulting in a nearly 3-fold increase in burnout heat flux at very low concentrations. The nanoparticle deposition plays a major role through variation in porosity. The CHF enhancement is non-monotonic with respect to concentration. As the concentration is increased, the CHF and BHF decrease prior to increasing again at higher concentrations. Results show a maximum of 270% CHF enhancement for ribbon-type heaters. The surface morphology of the heater was investigated using SEM and EDS analyses, and it was inferred that the 2 vol% concentration deposition coating had higher porosity and rate of deposition compared with 0.2 vol% case.     

Thermal performance of multi-walled carbon nanotubes (MWCNTs) in aqueous suspensions with surfactants SDBS and SDS

The surfactants of sodium dodecylbenzene sulfonate (SDBS) and sodium dodecyl sulfate (SDS) are used in multi-walled carbon nanotubes (MWCNT) aqueous solution respectively due to the hydrophobic nature of MWCNT. Thermal conductivities of nanofluid solutions are measured via the LAMBDA measuring system by transient hot wire method and compared as function of dispersing two different surfactants. MWCNT (hereinafter sometime referred to as CNTs) nanofluid gets a good dispersion and long time stability with both surfactants within 3/1 relative ratio mixture. However, the thermal conductivity of nanofluid decreases with increasing the concentration of both surfactants, and CNT nanofluid with SDBS exhibits better thermal conductivity than that with SDS dispersant. Finally the proper mixture ratio of CNT nanofluid with SDBS and pH value is examined and results show that 0.5 wt.% CNT nanofluids with 0.25 wt.% SDBS, at pH ≈ 9.0 condition display the best thermal performance which increases by 2.8% totally on thermal conductivity compared with that of base fluid distilled water (DW).     

Heat transfer of nanofluids in the mini-rectangular fin heat sinks

In the present study, the heat transfer characteristics of nanofluids cooling in the mini-rectangular fin heat sink are studied. The heat sinks with three different channel heights are fabricated from the aluminum by the wire electrical discharge machine with the length, width and base thickness of 110, 60, and 2 mm, respectively. The nanofluids are the mixture of de-ionized water and nanoscale TiO₂ particles. The results obtained from the nanofluids cooling in mini-rectangular fin heat sink are compared with those from the de-ionized water cooling method. Effects of the inlet temperature of nanofluids, nanofluid Reynolds number, and heat flux on the heat transfer characteristics of mini-rectangular fin heat sink are considered. It is found that average heat transfer rates for nanofluids as coolant are higher than those for the de-ionized water as coolant. The results of this study are of technological importance for the efficient design of cooling systems of electronic devices to enhance cooling performance.     

Effects of carbon nanotube arrays on nucleate pool boiling

Experiments were performed to assess the impact coating silicon and copper substrates with nanotubes (CNTs) have on pool boiling performance. Different CNT array densities and area coverages were tested on 1.27 × 1.27 mm² samples in FC-72. The CNT preparation techniques used provided strong adherence of CNTs to both substrate materials. Very small contact angle enabled deep penetration of FC-72 liquid inside surface cavities of smooth uncoated silicon surfaces, requiring unusually high surface superheat to initiate boiling. Fully coating the substrate surface with CNTs was highly effective at reducing the incipience superheat and greatly enhancing both the nucleate boiling heat transfer coefficient and critical heat flux (CHF). Efforts to further improve boiling performance by manipulating CNT area coverage of the substrate surface proved ineffective; best results were consistently realized with full surface coverage. Greater enhancement was achieved on silicon than on copper since, compared to uncoated copper surfaces, the uncoated silicon surfaces were very smooth and void of any sizeable nucleation sites to start with. This study is concluded with detailed metrics to assess the enhancement potential of the different CNT array densities and area coverages tested.     

Nanofluids and critical heat flux,experimental and analytical study

In recent years, nanofluids have been attracting significant attention in the heat transfer research community. These fluids are obtained by suspending nanoparticles having sizes between 1 and 100 nm in regular fluids. It was found by several researchers that the thermal conductivity of these fluids can be significantly increased when compared to the same fluids without nanoparticles. Also, it was found that pool boiling critical heat flux increases in nanofluids. In this paper, our objective is to evaluate the impact of different nanoparticle characteristics including particle concentration, size and type on critical heat flux experimentally at saturated conditions. As a result, this work will document our experimental findings about pool boiling critical heat flux in different nanofluids. In addition, we will identify reasons behind the increase in the critical heat flux and present possible approaches for analytical modeling of critical heat flux in nanofluids at saturated conditions.     

Experimental investigation of heat transfer and friction factor with water–propylene glycol based CuO nanofluid in a tube with twisted tape inserts

Convective heat transfer and friction factor characteristics of water/propylene glycol (70:30% by volume) based CuO nanofluids flowing in a plain tube are investigated experimentally under constant heat flux boundary condition. Glycols are normally used as an anti-freezing heat transfer fluids in cold climatic regions. Nanofluids are prepared by dispersing 50 nm diameter of CuO nanoparticles in the base fluid. Experiments are conducted using CuO nanofluids with 0.025%, 0.1% and 0.5% volume concentration in the Reynolds numbers ranging from 1000 < Re < 10000 and considerable heat transfer enhancement in CuO nanofluids is observed. The effect of twisted tape inserts with twist ratios in the range of 0 < H/D < 15 on nanofluids is studied and further heat transfer augmentation is noticed. The increment in the pressure drop in the CuO nanofluids over the base fluid is negligible but the experimental results have shown a significant increment in the convective heat transfer coefficient of CuO nanofluids. The convective heat transfer coefficient increased up to 27.95% in the 0.5% CuO nanofluid in plain tube and with a twisted tape insert of H/D = 5 it is further increased to 76.06% over the base fluid at a particular Reynolds number. The friction factor enhancement of 10.08% is noticed and increased to 26.57% with the same twisted tape, when compared with the base fluid friction factor at the same Reynolds number. Based on the experimental data obtained, generalized regression equations are developed to predict Nusselt number and friction factor.