高速电弧喷涂Fe-Al涂层在800℃下的氧化性能

采用高速电弧喷涂技术(HVAS)在20G钢基体上制备了Fe-Al金属间化合物涂层，测试了涂层在800℃下的氧化性能．结果表明，Fe-Al涂层的氧化动力学曲线近似呈现对数规律，其在5h后的氧化增重低于20G钢；涂层的氧化物为Al2O3、Fe2O3、Fe3O4和FeO等，且其分布不均匀；涂层表面优先形成具有保护性的Al2O3膜，阻止了涂层的进一步氧化。     

高速电弧喷涂Fe-Al/WC复合涂层在650℃下的氧化行为

采用高速电弧喷涂技术在20G钢基体上制备了Fe-Al／WC金属间化合物复合涂层，利用热重天平测试了涂层在650℃下的氧化性能。结果表明：Fe-Al／WC复合涂层的氧化动力学曲线近似呈现出对数规律；涂层的氧化物以Al2O3、Fe2O3、Fe3O4和FeO等为主，且其分布不均匀；涂层表面优先形成具有保护性的Al2O3膜，阻止了涂层的进一步氧化。     

高速电弧喷涂Fe-Al/WC复合涂层的组织结构及其滑动磨损性能研究

采用粉芯丝材和高速电弧喷涂技术(HVAS)制备了Fe-Al／WC金属间化合物基复合涂层，并研究了涂层的显微组织和从室温至650℃的滑动磨损性能。结果表明，涂层的成分为Fe-13．87Al-17．27C-3．35W-2．59Ni-1．27Cr-18．140(％)，主要相是Fe3Al、FeAl和α-Fe，还有少量WC、W2C和A12O3；添加WC硬质相后提高了复合涂层的平均硬度，从而提高了复合涂层的耐磨性；高温下磨损面形成了大面积的氧化物保护层，降低了复合涂层的摩擦因数，分析认为剥层磨损是复合涂层的主要磨损机理。涂层中Fe3Al和FeAl金属间化合物相较高的高温强度和硬度，能有效地阻碍裂纹的产生、扩展及扁平颗粒的断裂，从而使复合涂层表现出优异的高温耐磨性。高速电弧喷涂技术配-Fe-Al／WC粉芯丝材是一种新型、优质、高效、低成本的耐高温涂层制备技术，具有很大的应用潜力。     

高速电弧喷涂Fe-Al复合涂层高温腐蚀研究

研究了高速电弧喷涂（HVAS）的几种Fe-Al复合涂层的耐高温腐蚀行为,用SEM观察分析了腐蚀表面的形貌和成分、涂层截面的组织结构.结果表明：随温度升高,4种Fe-Al涂层的腐蚀增重都增加,添加Cr3C2比添加WC或不添加任何增强的Fe-Al涂层有更高的耐腐蚀性. Fe-Al/Cr3C2涂层外表面形成了铝和铬的氧化物,阻止了氧化的进一步进行. 关键词：高速电弧喷涂;高温腐蚀;Fe-Al涂层     

高速电弧喷涂Fe-Al/WC复合涂层在800℃下的氧化行为

采用高速电弧喷涂技术 (HVAS)在 2 0G钢基体上制备了Fe Al/WC金属间化合物复合涂层 ,测试了涂层在 80 0℃下的氧化性能。结果表明 ,Fe Al/WC复合涂层的氧化动力学曲线呈现出近似对数规律 ,5h后的氧化速率低于 2 0G钢 ;涂层的氧化物以Al2 O3、Fe2 O3、Fe3O4 和FeO为主 ,且分布不均匀 ;涂层表面优先形成具有保护性的Al2 O3膜 ,阻止了涂层的进一步氧化。     

高速电弧喷涂铁铝涂层的组织和性能

采用粉芯丝材和高速电弧喷涂技术（HVAS）原位合成了铁铝金属化合物涂层，并研究了涂层的显微组织和性能。结果表明，铁铝涂层的成分（原子分数，%）为Fe-20.0Al-14.1O，主要相是Fe3Al、FeAl和a-Fe相，还有少量Al2O3。涂层中的Fe3Al和FeAl具有较高的有序度。涂层具有相对较高的结合强度和显微硬度，以及较低的密度和孔隙率。     

金属间化合物NiAl-Ta-Cr高速火焰喷涂工艺及涂层特性

采用高速火焰（HVOF）热喷涂工艺制备了金属间化合物NiAl-Ta-Cr涂层.研究了喷涂距离、氧气流量以及燃气流量等工艺参数对涂层组织结构和性能的影响.用光学显微镜观察涂层的组织结构并测定涂层的孔隙率,用LECOTC316气体抽提仪检测涂层的氧含量.结果表明,氧气流量、喷涂距离等工艺参数对涂层性能的影响比较明显.随着喷涂距离的增加,涂层的氧含量降低;O/H比率越大,涂层的氧含量越高,而孔隙率降低,沉积率越高.涂层经1100℃,4 h真空热处理后,变得更加均匀和致密,孔隙率降低,但涂层的硬度有所降低.涂层经1100℃,100 h高温氧化处理后,在涂层表面生成了连续的氧化铝氧化层,硬度比真空退火后略有下降.     

高速电弧喷涂Fe-Al/Cr3C2复合涂层的组织结构研究

采用粉芯丝材结合高速电弧喷涂(HVAS)技术原位合成了Fe-Al/Cr3C2复合涂层,使用SEM﹑TEM﹑X-Ray等手段研究了涂层的组织和相结构.结果表明,涂层机械结合紧密;涂层具有致密的层状结构,扁平颗粒小,氧化物膜细小,硬质点相分布均匀,孔隙率低;在涂层中存在着多种结构复杂的组织和化合物相,基体相FeAl和Fe3Al,硬质相Cr3C2、Fe3C及AlFe3C0.5,氧化物相FeO·Al2O3、Cr2O3;不同物质相之间存在着平行的晶体学取向关系,从而提高了涂层的力学性能.     

高速电弧喷涂Fe-Al/Cr3C2复合涂层摩擦学特性

使用THT07—135高温磨损实验机对高速电弧喷涂Fe-Al／Cr3C2复合涂层进行了滑动摩擦特性的研究．并在扫描电镜上观察分析了磨斑的形貌和成分、涂层截面的组织结构。结果表明，在常温下涂层具有良好的耐摩擦性能．随着滑动距离的增加，摩擦系数基本无波动；随着温度的增加．涂层耐磨损性能降低较快，并在250℃开始趋于平稳，在550℃后，涂层的耐磨损性能重新增强，剥层磨损是Fe-Al/Cr3C2涂层磨损的主要机理；由于硬质相的阻碍作用以及铁铝金属间化合物本身高的硬度，Fe-Al／CrC3涂层具有优于20钢的耐磨损性能。     

高速电弧喷涂Fe-A1／WC复合涂层在800℃下的氧化行为

采用高速电弧喷涂技术（HVAS）在20G钢基体上制备了Fe-AL/WC金属间化合物复合涂层，测试了涂层在800℃下的氧化性能。结果表明，Fe-AL/WC复合涂层的氧化动力学曲线呈现出近似对数规律，5h后的氧化速率低于20G钢；涂层的氧化物以AL2O3、Fe2O3、Fe3O4和FeO为主，且分布不均匀；涂层表面优先形成具有保护性的Al2O3膜，阻止了涂层的进一步氧化。     

Sliding wear behavior of high velocity arc sprayed Fe-Al coating

The friction and wear behavior of Fe-Al intermetallics based coating produced by high velocity are spraying technique under dry sliding at room temperature were investigated using a ball-on-disc tribotester. The effect of sliding speed on friction coefficient and wear of the coating was studied. The worn surface of the coating was analyzed by scanning electron microscope (SEM) to explore sliding friction and wear mechanism. The results show that the variations of friction coefficient can be divided into three distinct steps during the trail. Both the friction coefficient and the wear of the coating increase with increased sliding speed due to accelerated crack propagation rate and lamellar structure with poor ductility of the coating. The coating surface is subjected to alternately tensile stress and compression stress during sliding wear process, and the predominant wear mechanism of the coatings appears to be brittle fracture and delamination.     

高速电弧喷涂FeCrAl/Ni95Al复合涂层的性能

利用电弧喷涂技术在45钢基体表面制备了FeCrAl/Ni95 Al复合涂层,先喷涂Ni95Al打底层增强涂层的结合强度,FeCrAl涂层作为工作层.利用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪、拉伸试验机、显微硬度计和CETR微动摩擦磨损试验机研究了涂层的显微组织、力学性能及摩擦磨损性能.结果表明,复合涂层组织均匀致密,主要由Fe3Al金属间化合物、(Fe,Cr)固溶在涂层基体中.涂层结合强度为43 MPa,硬度值为530 HVO.1,涂层磨损失效形式为剥落和氧化磨损.     

Study on microstructure and properties of high velocity arc sprayed Fe3 Al intermetallic coating

Coating structural materials with Fe3Al based intermetallics may rapidly lend to industrial application of their environment and wear resistant features. In the present study, high velocity arc spraying (HVAS) was used to in-situ synthesize Fe3Al intermetallic coating. The microstructural characterization and properties of the coating have been investigated. The microstructure was found to consist of Fe3A1 based intermetallic ( 1303 and B2 ) and a-Fe regions together with fine oxide ( ct-Al2 03 ) layers. TEM images of coating show that the solidified lamellae are polycrystalline and have a grain size of the order of about 150 rim, and there also exists amorphous state in some areas. It can be concluded that a very high cooling rate has been obtained during HVAS process. Moreover, the coating has relatively higher ndhesion strength and microhardness, as well as lower density and porosity.     

Configuration optimization of high velocity arc spraying gun

In order to improve the in-flight characteristics of the atomizing droplets during high velocity wire arc spraying (HVAS), some changes have been operated on the original design of the HVAS gun configuration. A comparative study was carried out to investigate the microstructure and properties of the coatings produced by the original design spraying gun and the modified one, using 3Cr13 wires of 3 mm in diameter. The characteristics of their jets were examined during spraying. The results indicate that, the included angle between the two wires and the distance from the nozzle to the meeting point of the two vires may have a strong influence on the characteristics of the in-flight droplets and then the coatings. The jet divergence is found to be lower than that of the original one (about 12° against 25°). By modified gun, the adhesion strength, the microhardness and porosity of the coating deposited by modified gun are increased by 39% and 9% respectively. And the porosity of the coatings is decreased by 57%.     

高速电弧喷涂FeCrBSiMo涂层抗高温氧化性能

采用高速电弧喷涂工艺在20钢基体上制备铁基FeCrBSiMo涂层,孔隙率为3.64%,显微维氏硬度为9 002.5 MPa,结合强度达52 MPa;采用扫描电镜、能谱分析仪和X射线衍射仪对涂层的显微组织和抗高温氧化性能进行了研究,并与锅炉管道常用20钢的相关性能进行了比较.结果表明,FeCrBSiMo涂层组织结构致密,在450~750℃下氧化80 h后其氧化增重均明显低于锅炉管道用20钢增重,其中750℃时的氧化增重仅是20钢的1/25.高温氧化时,涂层表面生成连续致密的铁,铬氧化物膜,能阻碍O元素从涂层表面扩散渗入涂层内部,防止涂层的进一步氧化,具有很好的保护性.     

Structure and sliding wear behavior of 321 stainless steel/Al composite coating deposited by high velocity arc spraying technique

A typical 321 stainless steel/aluminum composite coating （321/Al coating） was prepared by high velocity arc spraying technique （HVAS） with 321 stainless steel wire as the anode and aluminum wire as the cathode. The traditional 321 stainless steel coating was also prepared for comparison. Tribological properties of the coatings were evaluated with the ring-block wear tester under different conditions. The structure and worn surface of the coatings were analyzed by scanning electron microscopy（SEM）, X-ray diffractometry（XRD） and energy dispersion spectroscopy（EDS）. The results show that, except for aluminum phase addition in the 32 l/Al coating, no other phases are created compared with the 321 coating. However, due to the addition of aluminum, the 32 l/Al coating forms a type of ＂ductile/hard phases inter-deposited＂ structure and performs quite different tribological behavior. Under the dry sliding condition, the anti-wear property of 32 l/Al coating is about 42% lower than that of 321 coating. But under the oil lubricated conditions with or without 32 h oil-dipping pretreatment, the anti-wear property of 321/AI coating is about 9% and 5% higher than that of 321 coating, respectively. The anti-wear mechanism of the composite coating is mainly relevant to the decrease of oxide impurities and the strengthening action resulted from the ＂ductile/hard phases inter-deposited＂ coating structure.     

高速电弧喷涂枪结构优化的试验

试验优化了一种高速电弧喷涂枪的结构.用SprayWatch-2i热喷涂监测系统测试了喷枪的雾化熔滴速度,并研究了Al涂层和3Cr13涂层的组织和性能.结果表明,丝材和导电嘴的存在,严重扰动了雾化气流流态,两丝夹角和丝交点离喷管出口距离也显著影响了喷管气流场的分布特征;改进设计喷枪的雾化熔滴速度显著提高,其3Cr13雾化熔滴的最高速度达到210 m/s;涂层组织和力学性能也得到改善,喷涂Al涂层和3Cr13涂层时,结合强度分别提高了55%和39%,硬度值也分别增加了26%和9%,涂层的显微组织更均匀致密,孔隙率更低.     

提高高速电弧喷涂再制造曲轴涂层结合强度的途径

分析了再制造发动机曲轴表面涂层结合强度低的原因,介绍了机器人自动化高速电弧喷涂技术、各种涂层重熔技术、高速电弧喷枪改进技术及复合梯度涂层材料设计在提高高速电弧喷涂再制造曲轴涂层结合强度中的应用。     

Oxidation performance of Fe-Al/WC composite coatings produced by high velocity arc sprayed at 800 ℃

Fe-Al/WC intermetallic composite coatings were prepared by high velocity arc spraying (HVAS) technology on 20G steel and the oxidation performance of Fe-Al/WC composite coatings was studied. The results demonstrate that the kinetics curve of oxidation approximately follows the logarithmic law and the oxidation velocity of Fe-Al/WC composite coatings is less than that of 20G steel after 5 h. The composition of oxidized coating is mainly composed of Al2O3, Fe2O3, Fe3O4 and FeO. These phases distribute unevenly. The protective Al2O3 film firstly forms and preserves the coatings from further oxidation.     

高速电弧喷涂FeMnCrNi/Cr3C2涂层的工艺优化及磨损性能

采用高速电弧喷涂技术在Q235钢表面制备了FeMnCrNi/Cr₃C₂涂层。通过正交试验研究了喷涂电压、喷涂电流和喷涂距离对涂层形貌及性能的影响,获得了涂层制备的最佳工艺参数。利用扫描电镜、X射线衍射仪、能谱仪、显微硬度仪与激光共聚焦显微镜等研究了最佳工艺参数下制备的FeMnCrNi/Cr₃C₂涂层的形貌及性能。结果表明:影响涂层性能的主次因素顺序为:喷涂距离、喷涂电压、喷涂电流。最佳工艺参数为:喷涂电压31 V、喷涂电流240 A、喷涂距离200 mm。采用最佳工艺参数制备的涂层孔隙率为1.99%,显微硬度为719 HV0.1,是Q235钢的3.5倍,涂层的平均磨痕宽度、深度和截面积分别为281.95μm、4.42μm和564.81μm2,相比Q235钢分别减小了60%、72%和89%,具有更优的耐磨性;涂层的主要磨损形式为磨粒磨损。