Reducing the effect of three-body abrasive wear by adding polymeric powder to lubricating grease

The present paper reports on work aimed at improving the abrasive wear resistance of surfaces lubricated with contaminated greases. The intended improvement can be achieved by reducing the effect of wear occurring between the abrasive particles and the rubbing surfaces. Different polymeric thickeners in powder form, such as high-density polyethylene (HDPE), low-density polyethylene (LDPE), polyvinylchloride (PVC), polyamide (PA6) and polymethylmethacrylate (PMMA), were added to lithiumbased grease. The wear resistance and the coefficient of friction of cylindrical steel specimens were examined using a cross-pin test machine. The test machine provides concentrated contact under mixed lubrication conditions. Wear was measured on the stationary test specimen by the wear scar diameter, using an optical microscope, with an accuracy of ±1 μm. The frictional torque generated between the rubbing surfaces was measured using a full bridge strain gauge measuring cell attached to the stationary test specimen holder. The experiments were performed using clean and contaminated lubricating greases to which Air Cleaner Fine Test Dust (SCFTD) was added to the greases at a concentration of 10 wt.%. The results show that the effect of the abrasive contaminants can be reduced by the addition of polymeric powders. However, the addition of polymer to lubricating grease at relatively high concentration (more than 35 wt.%) has no effect on the antiwear action of the lithium grease. Further, the addition of polymeric powder with a particle size relatively greater than that of the contaminant can be considered as a useful method of eliminating the cutting process of the three-body abrasive mechanism introduced by the presence of the hard contaminant particles.     

Starvation and Reflow in a Grease-Lubricated Elastohydrodynamic Contact

The lubrication mechanisms of a grease in a rolling-element bearing has been studied through the measurement of film thickness in a rolling point contact. To simulate bearing conditions the contact runs under fully starved conditions; there is no attempt to maintain bulk flow of the grease into the inlet using an external supply. In consequence the film thickness drops off rapidly as the contact progressively starves. After a few minutes rolling (at constant speed) an equilibrium film thickness is attained which has two components: a residual film (h_R) comprised of degraded grease thickener and a hydrodynamic component (h_EHD) due to the liquid phase from the grease. The hydrodynamic contribution represents a balance between lubricant lost from the contact and replenishment from the grease close to the track. The ability of the grease to replenish the rolling track has been inferred from measurements of lubricant reflow around the static contact. These results are discussed in light of current starvation and grease lubrication models.     

Grease Degradation in Rolling Element Bearings

Grease is degraded during use in rolling element bearings and as a result the lubrication performance can deteriorate. Under severe conditions this can result in lubrication failure and, thus, the grease life will effectively limit the bearing life. At present there is a lack of detailed information regarding the changes that occur in the grease and the way in which this degradation affects lubrication performance and failure.

This paper reports an initial study into grease degradation in bearings. The aim of the work was to characterize the changes that occur to the chemical and physical properties during use. A series of bearing tests using the modified DIN 51 806 test designated R2F(M) have been carried out using two greases: additized and non-additized. The tests have been run for different temperature and speed conditions for up to 300 hours. The aim was to examine the grease during normal running rather than after failure. At the end of the tests the bearings were dismantled and grease taken from different parts of the bearing for infrared spectroscopic analysis. This technique can characterize the degree of oxidation or degradation of the grease both in the bulk sample and from thin grease layers remaining on the bearing surfaces.

The analysis has shown that the condition of the grease varies depending on the distribution within the bearing. The lubricant remaining in the cage pocket region was heavily degraded and contained very little thickener. The grease on the seals contained different amounts of thickener depending on the seal position. The lubricant remaining on the inner raceway surface was predominately base oil although there was some thickener present. These results are discussed in the light of proposed bearing lubrication mechanisms.     

Starved Grease Lubrication of Rolling Contacts

Many grease lubricated roller bearings operate in the starved elastohydrodynamic (EHL) regime where there is a limited supply of lubricant to the contact (1). Under these conditions the film thickness drops to a fraction of the fully flooded value (2) and, thus, it is difficult to predict lubrication performance, or bearing life, from conventional EHL models. In this regime film thickness depends on the ability of the grease to replenish the track rather than the usual EHL considerations. The conventional view of grease lubrication is that base oil bleeds from the bulk reservoir close to the track, replenishing the inlet and forming a fluid EHL film (3). Resupply, under starved conditions, will thus depend on both operating conditions and grease parameters. The aim of this paper is to evaluate the influence of these parameters on starved lubrication in a rolling contact. Starved film thickness has been measured for a series of greases and the results have been compared to the fully flooded values. These show that the degree of starvation increases with increasing rolling speed, base oil viscosity and thickener content but decreases at higher temperatures. In many cases an increase in absolute film thickness is obtained when moving from high viscosity base oil to a low one, this result is the reverse of normally accepted EHL rules. Taking the fully flooded film thickness as a guide to lubrication performance is therefore not valid as grease film thickness in the starved regime is determined by local replenishment rather than bulk rheological properties.     

Condition monitoring of electric motor ball bearings for the detection of grease contaminants

Grease used in the ball bearings of electric motors often get contaminated either from external particles or particles generated within these bearings. The effectiveness of vibration, stator current, acoustic emission and shock pulse measurements in detecting the presence of contaminant particles in bearing grease has been investigated. Silica and ferric oxide particles were used to contaminate grease. The levels of vibration, stator current, acoustic emission and shock pulse appreciably increased as contaminant level and contaminant size increased. Acoustic emission peak amplitude proved to be the best condition monitoring technique for the detection of grease contaminants in motor bearings. It is followed by shock pulse maximum value and carpet value in terms of effectiveness.     

The use of acoustic emission information to distinguish between dry and lubricated rolling element bearings in low-speed rotating machines

Bearings are known as the vital parts of machines, and their condition is often critical to the success of an operation or process. Presence of a film of lubricant such as grease between the bearing surfaces minimizes the friction and surface wear. Contaminated grease or lack of lubricant may lead to an ineffective bearing performance or malfunction of the machinery parts. Therefore, in order to avoid unexpected breakdowns, reliable and robust bearing condition monitoring techniques are demanded. According to previous studies, acoustic emission (AE) signals contain valuable information that can be used for bearing condition monitoring and fault detection. The main objective of this study is to evaluate the effectiveness of AE signal parameters to distinguish between lubricated and dry bearings under similar operating conditions. To this end, a low-speed rotating test rig is manufactured and used. Eight levels of rotational speeds and four levels of radial loads were applied to the test rig shaft end, which is connected to the testing bearing. In each test, seven time domain AE parameters were computed. The statistical tools were also used to present the dominant experimental variables on AE signal parameters. According to experimental results, it was found that four AE parameters can be used to distinguish between dry and lubricated bearings.     

Wear properties of DLC-coated steel rollers running with highly contaminated lubrication

The presence of hard contaminants in lubrication can lead to the premature failure of rolling bearings. To reduce the negative effect of such contaminants, hard carbon-based coatings (diamond-like carbon; DLC) can be applied to the surfaces of steel bearings. DLC coatings generate a low friction and a high sliding wear resistance to enhance the tribological properties and improve the durability of running components. This work explores the merits of DLC coatings for use in very demanding applications, such as in highly contaminated environments. The wear properties of DLC-coated bearing rollers were evaluated by comparing them with uncoated rollers. The degree of wear found on the coated rollers was serious, especially under relatively high contaminant concentrations. The three-body abrasive wear produced a relatively coarse scoring of the coating surface, which caused the corresponding disc to suffer more damage than the disc running against an uncoated roller under the same operating conditions. The results indicate that supposedly wear-protective coatings cause even more damage to running surfaces once they have been broken up by hard contaminants, and highlight the importance of keeping the bearing coating intact. In practise, it is important to eliminate contaminants from the lubricant of rolling bearings, in particular for bearings with a DLC anti-wear coating.     

滚动轴承润滑脂耐高温性能的试验及评价

比较了润滑脂耐高温性能的静态和动态试验方法,说明润滑脂的耐高温性能应该采用动态试验方法,以试验后润滑脂润滑功能的劣化程度即轴承摩擦力矩的升高程度或手感的加重程度来评价,强调试验后润滑脂色变与否及色变程度与其润滑功能没有必然联系,不宜作为润滑脂耐高温性能的评价依据.     

脂润滑轴承静置状态下漏油机理及对策

脂润滑轴承在静置状态下的漏油问题一直是一个难题。枯文旨在地润滑脂的分油及基础油在固体壁面的迁移分析，来探求脂润滑轴承润滑剂泄漏机理；同时介绍了在润滑脂中加入氟表面活性剂、改善轴承壁面结构设计两项措施来降低脂润滑轴承在静置状态下的漏油。     

High‐pressure short time behavior of traction fluids

The squeeze film formation ability of traction fluids is studied under impact load by dropping a steel ball‐bearing against a flat anvil made of mild steel. The effect of the pressure–viscosity coefficient and of the viscosity is investigated for plastic impact. The depth difference between the lubricated surface dent and the dry dent increases linearly with the product αη of the pressure–viscosity coefficient α and the viscosity η. The importance of the lubricant parameter αη is observed under the squeeze film formation ability from contact voltage or elastohydrodynamic lubrication central film thickness measurement at rolling condition. The intensity of each impact collision is measured by means of an acoustic emission (AE) sensor. The high‐pressure short‐time solidification of traction fluids was confirmed by dent analysis after the impact tests and AE analysis under impact loads. Copyright © 2006 John Wiley & Sons, Ltd.     

Particle Damage in Hertzian Contacts and Life Ratings of Rolling Bearings

Particle denting, and contamination marks found on bearing raceways, can induce stress concentrations and facilitate surface initiated fatigue. The lubricant film developed at the dent and related local surface stresses are also significant to the crack initiation mechanism. In this article, a new methodology is presented to link the micro-EHL film and related local stresses to the fatigue life of rolling bearings. The applied methodology is based on Fourier analysis of the harmonic components of the surface microgeometry to predict stresses and induced lubricant film. The application of this method to actual bearing surfaces is discussed and analyzed in relation to some existing microcontact EHL solutions. A global evaluation of the use of the method to rolling bearings dynamic load ratings is also carried out. A comparison between experimentally obtained rolling bearing life and lives predicted using the present theory indicate the global ability of the model to describe the effect of the lubrication quality on the life expectancy of rolling contacts. From this analysis, an assessment of some typical equations used in rolling bearing dynamic ratings is carried out. It is found that the degree of lubrication of the rolling contact and the cleanliness conditions of the oil are indeed significant to the prediction of the life expectancy of the bearing.     

Film thickness in a ball-on-disc contact lubricated with greases,bleed oils and base oils

Three different lubricating greases and their bleed and base oils were compared in terms of film thickness in a ball-on-disc test rig through optical interferometry. The theoretical values calculated according to Hamrock's equation are in close agreement with the base oil film thickness measurements, which validates the selected experimental methodology.The grease and bleed oil film thickness under fully flooded lubrication conditions presented quite similar behaviour and levels. Therefore, the grease film thickness under full film conditions might be predicted using their bleed oil properties, namely the viscosity and pressure-viscosity coefficient. The base and bleed oil lubricant parameter LP are proportional to the measured film thickness.A relationship between grease and the corresponding bleed oil film thickness was evidenced.     

Friction torque in grease lubricated thrust ball bearings

Thrust ball bearings lubricated with several different greases were tested on a modified Four-Ball Machine, where the Four-Ball arrangement was replaced by a bearing assembly. The friction torque and operating temperatures in a thrust ball bearing were measured during the tests. At the end of each test a grease sample was analyzed through ferrographic techniques in order to quantify and evaluate bearing wear.A rolling bearing friction torque model was used and the coefficient of friction in full film lubrication was determined for each grease, depending on the operating conditions.The experimental results obtained showed that grease formulation had a very significant influence on friction torque and operating temperature. The friction torque depends on the viscosity of the grease base oil, on its nature (mineral, ester, PAO, etc.), on the coefficient of friction in full film conditions, but also on the interaction between grease thickener and base oil, which affected contact replenishment and contact starvation, and thus influenced the friction torque.     

Enhanced Performance of Pennzane® Greases for Space Applications by Both Additive Formulations and Smooth Hard Coatings

Tribological requirements of the moving mechanical assemblies (MMAs) of spacecraft are usually satisfied by a variety of lubricants and materials. When the lubricant elastohydrodynamic film is broken, metal-to-metal contact occurs in the MMAs. This may lead to lubricant overheating, and breakdown, and then to increased wear and failure. Wear related failure can also occur due to evaporation and/or creep of the lubricant over the lifetime of space assembly. As requirements for spacecraft performance and lifetime increase, improved lubrication systems for MMAs are needed. A considerable amount of progress has been made in developing improved lubricants with advanced additives; however, their performance has not been evaluated and ranked. In the present work, four-ball and reciprocating tribometer tests were conducted to evaluate and rank the performance of various Pennzane® based greases. Employing the reciprocating tribometer technique, Pennzane® based greases were also evaluated with hard coatings such as titanium nitride (TiN) and titanium carbonitride (TiCN) in a metal-on-coating configuration. Viability of a filtered cathodic arc technique for obtaining very smooth, hard coatings is demonstrated. The importance of coating deposition temperature for certain bearing steel materials is also discussed. It is demonstrated that wear is substantially reduced with an optimized Pennzane® grease formulation on a smooth, hard TiCN surface coating.     

Grease lubrication of rolling element bearings — role of the grease thickener

The contribution of grease thickener to lubricant film formation was examined in this paper. Lubricant film thickness and friction were measured for different grease thickener types in a bearing simulation device. The results showed that the greases formed thick (20–80nm), low friction surface layers at low speeds, which were much greater than the corresponding base oil film. These films appeared to be formed by the physical deposition of thickener in the track during overrolling of the grease. This was confirmed by infrared reflection analysis, which showed the deposited films to have increased thickener content. The ability of grease to form renewable physically deposited solid films has significant implications for optimising lubricant formulation for certain applications, e.g. bearings operating at high temperatures and low speeds where a conventional elastohydrodynamic lubricating film would be inadequate. Copyright © 2007 John Wiley & Sons, Ltd.     

Study of solid contamination in ball bearings through vibration and wear analyses

In rolling bearings, contamination of lubricant oil by solid particles is one of the main reasons for early bearing failure. In order to deal with this problem, it is fundamental not only the use of reliable techniques concerning detection of solid contamination but also the investigation of the effects of certain contaminant characteristics on bearing performance. Nowadays, non-invasive techniques, such as vibration measurements, are being increasingly used for on-time monitoring of machinery performance. In this context, the present work investigates the effect of lubricant contamination by solid particles on the dynamical behavior of rolling bearings, in order to determine the trends in the amounts of vibration affected by contamination in the oil and by the bearing wear itself. Experimental tests were performed with radial ball bearings lubricated by oil bath. Quartz powder in three concentration levels and different particle sizes was used to contaminate the oil. Vibration signals were analyzed in terms of the root mean square (rms) values. The results show that changes in the rms values of vibration in the high-frequency band, from 600 to 10,000 Hz, were associated to the changes in oil lubrication in the bearing contacts, caused by oil contamination and wear damage on the bearing surfaces.     

Numerical analysis of grease thermal elastohydrodynamic lubrication problems using the Herschel-Bulkley model

Grease thermal elastohydrodynamic lubrication (TEHL) problems of line contacts are analysed numerically. The effects of temperature and rheological parameters on grease TEHL are investigated using the Herschel-Bulkley model as a rheological model of greases. The pressure distribution, the shape of grease film, mean film temperature and surface temperature of solid wall in line contacts are obtained. It is found that thermal effects on the minimum film thickness become remarkable at high rolling speeds. The effect of yield stress of the Herschel-Bulkley model on minimum film thickness is negligible, while the flow index and viscosity parameter have significant effects on minimum film thickness.     

Total vegetable oil greases

A grease has two major constituents, namely, a lubricant, that performs the function of lubrication; and a gellant, that provides a solid continuous phase, occludes the lubricant, and gives apparent physical structure to the grease. Generally, the gellant is 5–30% and the lubricant 65–90%, additives and fillers making up the rest. In conventional greases, the gellant is a vegetable oil soap, and the lubricant is a liquid oil of petroleum origin or is a synthetic. Such greases have limited biodegradability, because the major constituent, i.e., the lubricant, is normally not biodegradable. In total vegetable oil grease, both the gellant and the lubricant are derived from vegetable oils, giving a grease of potentially high eco‐compatibility. Esters, dibasic acid esters, and alkylated esters of vegetable oil are known to be high‐quality lubricants. These can be used with soap stocks prepared from vegetable oils to give a grease of total vegetable oil origin. The vegetable‐oil based lubricants and soaps are prepared separately and combined in appropriate proportions to give a grease of the required specifications. Alternatively, esterification and saponification can be carried out simultaneously to give a grease of the desired specifications, where an alkali will be the catalyst for esterification, and reactant for saponification. In this paper, the process parameters, and kinetics of these simultaneous reactions are discussed. The results of experimental evaluation of some of these greases are also presented.     

石墨干膜润滑剂在碳钢表面摩擦磨损性能试验研究*

传统油或脂润滑剂在极端工况环境下无法满足碳钢类零件的减摩要求,采用干膜润滑剂是提高极端工况环境下碳钢表面摩擦磨损性能的可行性方法。采用超声波分散方法制备以石墨粉末为基体的干膜润滑剂,使用压力喷涂技术使其沉积在碳钢试件表面,在端面摩擦试验仪中开展干摩擦和石墨干膜润滑剂润滑下摩擦磨损性能对比性试验研究。试验结果表明：石墨干膜润滑剂在碳钢表面的沉积效果较好,沉积的石墨干膜润滑剂具有较好的润滑性能,可以有效地保护碳钢表面不被过度磨损;喷涂石墨干膜润滑剂的碳钢试件的工作寿命随着压力载荷和主轴转速的增大而缩短,负载和滑动速度的联合作用会加速涂层向稳定方向的过渡;磨损过程中形成的微观润滑剂颗粒会形成颗粒流润滑,适当添加石墨颗粒粉末可能会延长润滑剂正常发挥减摩作用的时间。制备的石墨干膜润滑剂为碳钢在极端工况环境下的减摩提供了支持。     

A new class of lubricants based on stable dispersions of solid nanosized powders

At present, the possibilities of improvement of the operating characteristics of greases via application of traditional technologies, including introduction of powder fillers of soft metals and solid lubricants, are exhausted. The paper reports the findings of experimental testing of a grease obtained by chemical grinding of aggregates of solid aluminosilicate nanosized powders and their uniform distribution through the volume by wave technology. It is found that the wear resistance of the steel friction surfaces increases at least two-fold and the coefficient of friction of the studied pairs declines with application of the grease containing solid nanosized aluminosilicate particles. The efficiency of lubrication with the tested grease after a single application significantly surpasses the respective characteristics of the best commercial greases.