相同氧含量醇类混合燃料燃烧和排放特性差异研究

对一台4缸发动机燃用相同氧浓度的不同醇类混合燃料进行了试验研究,以对比不同三元燃料柴油机在相同转速不同负荷情况下的燃烧特性和常规排放的差异。试验结果表明:甲醇混合燃料在醇类混合燃料中获得最高的燃烧压力,而丁醇混合燃料的热释放率最高。与普通柴油相比,戊醇混合燃料在不同混合物中具有相对最佳的CO和未燃碳氢排放,甲醇混合燃料可获得最优的氮氧化物排放;乙醇混合燃料减小颗粒物效果明显,最大可以减少22.4%～55.6%的颗粒物数量浓度和3.4%～12.8%的颗粒物粒径,其中乙醇混合燃料的核态颗粒物和聚集态颗粒物排放量也最低,戊醇混合燃料达到最高(除高负荷外)。     

Autoignition reactivity of blends of diesel and biodiesel fuels with butanol isomers

The effect of n-butanol replacement by iso, sec or tert-butanol on the autoignition reactivity of diesel and biodiesel/butanol blends (the total alcohol content being 40% by vol.) was analysed. The study was performed in a constant volume combustion chamber under different initial temperatures (535 °C, ∼600 °C and 650 °C) and n-butanol substitutions. Results show that the effect of the alcohol in both pseudo-binary (diesel fuel/normal, sec, iso or tert-butanol) and pseudo-ternary (diesel fuel/n-butanol/iso, sec or tert-butanol) blends is not that expected from the autoignition properties of the pure isomers. When blended either with diesel or biodiesel fuels, tert-butanol increases the autoignition reactivity of the blend while the other two isomers reduce it. The partial substitution of n-butanol by tert-butanol could be an attractive method for increasing the alcohol content while keeping safe engine operation. Partial substitutions with iso or sec-butanol would promote partially premixed combustion conditions with limited pressure gradient peaks. Chemical kinetics simulations corroborate that the different consumption rates of active radicals from the butanol isomers are responsible for the observed trends. Biodiesel blends are less sensitive to the isomer replacing n-butanol due to its higher number of secondary CH bonds when compared to diesel fuel.     

Exhaust emission study on neat biodiesel and alcohol blends fueled diesel engine

In this study, neat biodiesel with octanol additive was employed in a diesel engine and its effects on engine emission were studied. The five fuels evaluated were neat palm kernal oil biodiesel, octanol blended with biodiesel by 10%, 20%, and 30% volume, and diesel. All the emissions are reduced by the addition of octanol in biodiesel in all loads owing to the higher oxygen concentration of air/fuel mixtures and improved atomization. Hence, it is concluded that the neat biodiesel and octanol blends can be employed as an alternative fuel for existing unmodified diesel engines owing to its lesser emission characteristics.     

非直喷式增压柴油机燃用生物柴油的性能与排放特性

研究了非直喷式增压柴油机燃用柴油一生物柴油混合燃料的性能和排放特性。未对原机作任何调整和改动,研究了不同生物柴油掺混比例的混合燃料对功率、油耗、烟度和NOx排放的影响。结果表明：非直喷式柴油机燃用生物柴油后柴油机功率略有下降,油耗有所上升,烟度大幅下降,NOx排放增加明显。油耗、烟度和NOx的变化均与生物柴油掺混比例呈线性关系,合适的生物柴油掺混比例即可以保持柴油机的性能,又可有效地降低碳烟排放,且不引起NOx排放的显著变化。对于该增压柴油机,掺混生物柴油对外特性下的排放影响最大,影响最小的为标定转速下的负荷特性。不论是全负荷还是部分负荷,燃用生物柴油时低速下的烟度降低和NOx上升幅度均比高速时大,而同转速下高负荷时烟度降低和NOx上升更为明显。     

正丁醇作为生物燃料在生产和应用方面的进展

作为车用替代燃料,丁醇的热值比乙醇高30%左右,挥发性只有乙醇的1/6左右,吸湿性远小于甲醇、乙醇和丙醇,具有适度的水溶性,腐蚀性低,安全性更高。但丁醇直接应用到发动机上也存在一些问题,如其热值比传统汽油或柴油低,使得燃料消耗量增加;燃烧效率低于甲醇、乙醇;当应用于点燃式发动机时,丁醇较高的黏度将产生潜在的沉积或腐蚀等问题。目前许多研究者将正丁醇作为替代生物燃料进行研究,现有的研究主要是将丁醇与汽油或柴油混合应用在发动机上,或是应用在一些基本的燃烧反应器中。综合各方面的研究成果,正丁醇在混合燃料中体积分数小于20%时,无需调整发动机就可获得与汽油燃料相同的发动机功率;当达到30%时,发动机最大功率开始下降;随着正丁醇体积的增加,燃料消耗量增加。CO、THC、NOx排放的减少或增加取决于具体的发动机、操作条件、丁醇-汽油的混合比等。混合燃料与纯汽油相比,未燃烧醇的排放增加,而且丁醇的比例越高,未燃烧醇的排放越高。     

Progress in the production and application of n-butanol as a biofuel

Butanol is a very competitive renewable biofuel for use in internal combustion engines given its many advantages. In this review, the properties of butanol are compared with the conventional gasoline, diesel fuel, and some widely used biofuels, i.e. methanol, ethanol, biodiesel. The comparison of fuel properties indicates that n-butanol has the potential to overcome the drawbacks brought by low-carbon alcohols or biodiesel. Then, the development of butanol production is reviewed and various methods for increasing fermentative butanol production are introduced in detailed, i.e. metabolic engineering of the Clostridia, advanced fermentation technique. The most costive part of the fermentation is the substrate, so methods involved in renewed substrates are also mentioned. Next, the applications of butanol as a biofuel are summarized from three aspects: (1) fundamental combustion experiments in some well-defined burning reactors; (2) a substitute for gasoline in spark ignition engine; (3) a substitute for diesel fuel in compression ignition engine. These studies demonstrate that butanol, as a potential second generation biofuel, is a better alternative for the gasoline or diesel fuel, from the viewpoints of combustion characteristics, engine performance, and exhaust emissions. However, butanol has not been intensively studied when compared to ethanol or biodiesel, for which considerable numbers of reports are available. Finally, some challenges and future research directions are outlined in the last section of this review.     

Combustion and emission characteristics of a turbo-charged common rail diesel engine fuelled with diesel-biodiesel-DEE blends

The combustion and emission characteristics of a turbo-charged, common rail diesel engine fuelled with diesel-biodiesel-DEE blends were investigated. The study reports that the brake-specific fuel consumption of diesel-biodiesel-DEE blends increases with increase of oxygenated fuel fractions in the blends. Brake thermal efficiency shows little variation when operating on different diesel-biodiesel-DEE blends. At a low load, the NO_x emission of the diesel-biodiesel-DEE blends exhibits little variation in comparison with the biodiesel fraction. The NO_x emission slightly increases with increase in the biodiesel fraction in diesel-biodiesel-DEE blends at medium load. However, the NO_x emission increases remarkably with increase of the biodiesel fraction at high load. Particle mass concentration decreases significantly with increase of the oxygenated-fuels fraction at all engine speeds and loads; particle number concentration decreases remarkably with increase of the oxygenated-fuels fraction. HC and CO emissions decrease with increasing oxygenated-fuels fraction in these blends.     

Performance,combustion and exhaust emissions characteristics investigation using Citrullus colocynthis L. biodiesel in DI diesel engine

The aims of this study is to investigate the performance, combustion and exhaust emissions of a single-cylinder, air cooled, direct injection (DI), compression ignition engine using biodiesel from non-edible feedstock. In this work, biodiesel (B100) used to lead this investigation is Citrullus colocynthis L. methyl ester (CCME) and its blends B30 with diesel fuel. The biodiesel is produced via alkaline-catalyzed transesterification process using methanol (6:1 M ratio), 1% of sodium hydroxide at the reaction temperature of 60 °C for 1 h. The important physical and chemical properties of CCME are close to those of diesel fuel. Fuels (diesel fuel, B100 and B30) were tested on a DI diesel engine at 1500 rpm for various power outputs. The results indicated that B100 and B30 exhibit the same combustion characteristics compared to diesel fuel. However, B100 and B30 display earlier start of combustion. At lower engine loads, the peaks of cylinder pressure and heat release rate (HRR) were higher for B30 than B100 and diesel fuel during premixed combustion period. At higher engine loads the peaks of cylinder pressure was higher for B100 than B30 and diesel fuel, but the HRR during diffusion combustion is more considerable than diesel fuel. The brake specific fuel consumption (BSFC) was higher for B100 than diesel fuel at all engine loads while B30 exhibited comparable trends. The thermal efficiency is slightly higher for B100 than B30 and diesel fuel at low loads and increase for B30 at full loads.B30 and B100 provided a higher reduction of hydrocarbons emissions up to 50% for B100. Nitrogen oxides and particulate matter emissions were also reduced.     

Combustion and emissions behaviour for ethanol–gasoline-blended fuels in a multipoint electronic fuel injection engine

The study investigated the combustion and emissions of a gasoline engine using ethanol–gasoline blends. The results indicated that the peak cylinder pressure of E10 is evidently lower, but that of E20 is identical to that of gasoline. At lower engine loads, the combustion velocity of gasoline is faster, and the peak heat release rate (HRR) is higher than that of the blends, but at higher engine loads, E20 shows faster combustion velocity and a little higher peak HRR. The brake thermal efficiency of the blends is almost similar to that of gasoline, but the brake-specific fuel consumption of the blends is slightly higher. With the increase in ethanol content in the blends, CO evidently decreases, HC slightly increases at high engine loads, and NOx depends on the engine operating conditions as well as the ethanol content. The acetaldehyde of the blends is evidently and the ethanol is slightly higher than that of gasoline.     

柴油/正戊醇/甲醇三元微乳化燃料柴油机燃烧与排放特性研究

为了使柴油与甲醇互溶,提高燃料氧含量以控制碳烟排放,以正戊醇作为助溶剂,形成柴油/正戊醇/甲醇三元微乳化燃料,对三元燃料在不同温度下的互溶性进行了研究。在一台电控高压共轨柴油机上测试了1 400r/min转速下柴油/正戊醇/甲醇三元微乳化燃料的燃烧压力和排放特性;计算了瞬时燃烧放热率与燃烧温度,并与柴油进行对比。研究结果表明:甲醇能够以一定比例与柴油/正戊醇互溶,且互溶比例随温度升高而增大。与纯柴油相比,随氧含量的增加,混合燃料的滞燃期延长,燃烧持续期缩短,峰值燃烧温度升高;在中低负荷,峰值燃烧放热率上升;在高负荷,三元微乳化燃料的峰值燃烧放热率下降,但其扩散燃烧强度增加;混合燃料的有效燃油消耗率增加,但是其热值逐渐降低,有效热效率上升;3种含氧燃料的CO排放在低负荷时增加,高负荷时降低;HC及NOx排放升高,NO2在NOx中的比例下降;碳烟排放明显减少。     

正丁醇/柴油发动机燃烧排放特性及喷油、燃烧室形状影响

针对某型号直喷柴油机,建立了该柴油机中单缸完整燃烧室及气道三维模型,使用三维计算流体力学(computational fluid dynamics,CFD)分析软件CONVERGE对其进行模拟计算,研究了正丁醇掺混比例对柴油机燃烧排放的影响。结果表明:随着正丁醇掺混比例的提高,峰值缸压、滞燃期和燃烧速度均呈递增趋势,碳烟及CO排放量逐渐减少,NO_x排放量小幅增加。为了进一步改善缸内燃烧情况和降低污染物排放,对正丁醇掺混时喷油策略、燃烧室几何形状的综合影响进行了研究,结果表明:掺混时多次喷油及采用合适的燃烧室模型可以有效改善掺混后缸内油气混合情况,增加缸内湍动能强度,进一步降低碳烟排放量。与纯柴油工况对比,掺混并采用多次喷油策略后碳烟排放明显下降,且通过掺混能够有效简化喷油策略,但弱化了燃烧室形状对碳烟排放量的影响。     

生物柴油-柴油混合燃料的理化特性研究

对生物柴油-柴油混合燃料直接影响发动机性能和燃料的使用、存储和运输的几种基本物理化学性质进行了研究。通过对不同比例（生物柴油含量分别为0％，20％，100％）的混合燃料的密度、粘度、表面张力、十六烷值、闪点、润滑性、硫含量、冷滤点、凝固点等理化性质的测试和研究，初步探讨了生物柴油含量对混合燃料物性参数的影响规律。     

Assessment of energy performance and air pollutant emissions in a diesel engine generator fueled with water-containing ethanol–biodiesel–diesel blend of fuels

Biomass based oxygenated fuels have been identified as possible replacement of fossil fuel due to pollutant emission reduction and decrease in over-reliance on fossil fuel energy. In this study, 4 v% water-containing ethanol was mixed with (65–90%) diesel using (5–30%) biodiesel (BD) and 1 v% butanol as stabilizer and co-solvent respectively. The fuels were tested against those of biodiesel–diesel fuel blends to investigate the effect of addition of water-containing ethanol for their energy efficiencies and pollutant emissions in a diesel-fueled engine generator. Experimental results indicated that the fuel blend mix containing 4 v% of water-containing ethanol, 1 v% butanol and 5–30 v% of biodiesel yielded stable blends after 30 days standing. BD1041 blend of fuel, which composed of 10 v% biodiesel, 4 v% of water-containing ethanol and 1 v% butanol demonstrated −0.45 to 1.6% increase in brake-specific fuel consumption (BSFC, mL kW⁻¹ h⁻¹) as compared to conventional diesel. The better engine performance of BD1041 was as a result of complete combustion, and lower reaction temperature based on the water cooling effect, which reduced emissions to 2.8–6.0% for NO_x, 12.6–23.7% particulate matter (PM), 20.4–23.8% total polycyclic aromatic hydrocarbons (PAHs), and 30.8–42.9% total BaPeq between idle mode and 3.2 kW power output of the diesel engine generator. The study indicated that blending diesel with water-containing ethanol could achieve the goal of more green sustainability.     

Effect of diethyl ether and ethanol additives on the combustion and emission characteristics of biodiesel-diesel blended fuel engine

An experimental investigation is conducted to evaluate the effects of using diethyl ether and ethanol as additives to biodiesel/diesel blends on the performance, emissions and combustion characteristics of a direct injection diesel engine. The test fuels are denoted as B30 (30% biodiesel and 70% diesel in vol.), BE-1 (5% diethyl ether, 25% biodiesel and 70% diesel in vol.) and BE-2 (5% ethanol, 25% biodiesel and 70% diesel in vol.) respectively. The results indicate that, compared with B30, there is slightly lower brake specific fuel consumption (BSFC) for BE-1. Drastic reduction in smoke is observed with BE-1 and BE-2 at higher engine loads. Nitrogen oxide (NOx) emissions are found slightly higher for BE-2. Hydrocarbon (HC) emissions are slightly higher for BE-1 and BE-2, but carbon monoxide (CO) are slightly lower. The peak pressure, peak pressure rise rate and peak heat release rate of BE-1 are almost similar to those of B30, and higher than those of BE-2 at lower engine loads. At higher engine loads the peak pressure, peak pressure rise rate and peak heat release rate of BE-1 are the highest and those of B30 are the lowest. BE-1 reflects better engine performance and combustion characteristics than BE-2 and B30.     

生物柴油对直喷式柴油机燃烧和排放的影响

列举了生物柴油的基本物化特性。介绍了生物柴油对直喷式柴油机燃烧和排放的影响。相比普通柴油,燃用生物柴油可以减少CO、CO_2、SO_2、HC、微粒以及碳烟的排放且不会影响柴油机工作性能。采用EGR、乳化油、多次喷射及微粒捕捉器等措施可以进一步降低使用生物柴油的微粒和NOx排放。生物柴油作为一种可再生的替代能源,以其良好的环境效应受到越来越多的关注。     

Biodiesel fuel in diesel micro-turbine engines: Modelling and experimental evaluation

Many performance and emission tests have been carried out in reciprocating diesel engines that use biodiesel fuel over the past years and very few in gas turbine engines. This work aims at assessing the thermal performance and emissions at full and partial loads of a 30 kW diesel micro-turbine engine fed with diesel, biodiesel and their blends as fuel. A cycle simulation was performed using the Gate Cycle GE Enter software to evaluate the thermal performance of the 30 kW micro-turbine engine. Performance and emission tests were carried out on a 30 kW diesel micro-turbine engine installed in the NEST laboratories of the Federal University of Itajubá, and the performance results were compared with those of the simulation. There was a good agreement between the simulations and the experimental results from the full load down to about 50% of the load for diesel, biodiesel and their blends. The biodiesel and its blends used as fuel in micro-turbines led to no significant changes in the engine performance and behaviour compared to diesel fuel. The exhaust emissions were evaluated for pure biodiesel and its blends and conventional diesel. The results revealed that the use of biodiesel resulted in a slightly higher CO, lower NO_x and no SO₂ emissions.     

生物柴油/甲醇混合燃料对柴油机性能与排放的影响研究

在一台4缸直喷式柴油机上研究了超低硫柴油、生物柴油及后者与甲醇的混合燃料对发动机性能、气体及微粒排放的影响。生物柴油由餐饮废油制取,除单独使用外和甲醇按体积比90：10和80：20混合后使用。在最大扭矩转速1800 r.m in-1时,在5个不同负荷下,比较了不同燃料热效率及CO、HC、NOx以及微粒质量浓度,微粒的总数量及平均几何粒径。结果表明,和超低硫柴油相比,生物柴油及其和甲醇的混合燃料的热效率增加,NOx和微粒质量、数量浓度的排放降低,但HC、CO和NO2排放升高;同时,随着甲醇混合比例的增加,HC、CO和NO2的排放成比例增加,微粒的质量浓度及数量浓度进一步降低,热效率及NOx几乎保持不变。     

Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation)

The effects of biodiesel (rapeseed methyl ester, RME) and different diesel/RME blends on the diesel engine NO_x emissions, smoke, fuel consumption, engine efficiency, cylinder pressure and net heat release rate are analysed and presented. The combustion of RME as pure fuel or blended with diesel in an unmodified engine results in advanced combustion, reduced ignition delay and increased heat release rate in the initial uncontrolled premixed combustion phase. The increased in-cylinder pressure and temperature lead to increased NO_x emissions while the more advanced combustion assists in the reduction of smoke compared to pure diesel combustion. The lower calorific value of RME results in increased fuel consumption but the engine thermal efficiency is not affected significantly. When similar percentages (% by volume) of exhaust gas recirculation (EGR) are used in the cases of diesel and RME, NO_x emissions are reduced to similar values, but the smoke emissions are significantly lower in the case of RME. The retardation of the injection timing in the case of pure RME and 50/50 (by volume) blend with diesel results in further reduction of NO_x at a cost of small increases of smoke and fuel consumption.     

The effect of biodiesel oxidation on engine performance and emissions

Biodiesel is an alternative fuel consisting of the alkyl monoesters of fatty acids from vegetable oils or animal fats. Previous research has shown that biodiesel-fueled engines produce less carbon monoxide, unburned hydrocarbons, and particulate emissions compared to diesel fuel. One drawback of biodiesel is that it is more prone to oxidation than petroleum-based diesel fuel. In its advanced stages, this oxidation can cause the fuel to become acidic and to form insoluble gums and sediments that can plug fuel filters. The objective of this study was to evaluate the impact of oxidized biodiesel on engine performance and emissions. A John Deere 4276T turbocharged DI diesel engine was fueled with oxidized and unoxidized biodiesel and the performance and emissions were compared with No. 2 diesel fuel. The neat biodiesels, 20% blends, and the base fuel (No. 2 diesel) were tested at two different loads (100 and 20%) and three injection timings (3° advanced, standard; 3° retarded). The tests were performed at steady-state conditions at a single engine speed of 1400 rpm. The engine performance of the neat biodiesels and their blends was similar to that of No. 2 diesel fuel with the same thermal efficiency, but higher fuel consumption. Compared with unoxidized biodiesel, oxidized neat biodiesel produced 15 and 16% lower exhaust carbon monoxide and hydrocarbons, respectively. No statistically significant difference was found between the oxides of nitrogen and smoke emissions from oxidized and unoxidized biodiesel.     

Experimental investigation on the performance and emissions of a diesel engine fuelled with ethanol–diesel blends

An experimental investigation on the application of the blends of ethanol with diesel to a diesel engine was carried out. First, the solubility of ethanol and diesel was conducted with and without the additive of normal butanol (n-butanol). Furthermore, experimental tests were carried out to study the performance and emissions of the engine fuelled with the blends compared with those fuelled by diesel. The test results show that it is feasible and applicable for the blends with n-butanol to replace pure diesel as the fuel for diesel engine; the thermal efficiencies of the engine fuelled by the blends were comparable with that fuelled by diesel, with some increase of fuel consumptions, which is due to the lower heating value of ethanol. The characteristics of the emissions were also studied. Fuelled by the blends, it is found that the smoke emissions from the engine fuelled by the blends were all lower than that fuelled by diesel; the carbon monoxide (CO) were reduced when the engine ran at and above its half loads, but were increased at low loads and low speed; the hydrocarbon (HC) emissions were all higher except for the top loads at high speed; the nitrogen oxides (NO_x) emissions were different for different speeds, loads and blends.