Microstructure and texture of rolled and annealed β titanium alloy Ti–10V–4.5Fe–1.5Al

This work describes the evolution of texture during cold rolling and annealing of a hot rolled and solution treated sheet of a low cost β titanium alloy Ti–10V–4.5Fe–1.5Al. The alloy was cold rolled up to 60% reductions and then annealed in β phase field at different temperatures to study the re-crystallisation textures. The rolling and re-crystallisation textures obtained in this study are compared with those of other β titanium alloys and bcc metals and alloys such as tantalum and low carbon steel.     

Hot compressive deformation behavior and microstructure evolution of Ti–6Al–2Zr–1Mo–1V alloy at 1073 K

Hot compressive behaviors of Ti–6Al–2Zr–1Mo–1V alloy at 1073 K, as well as the evolution of microstructure during deformation process, were investigated in this paper. The results shows that flow stress increases up to a peak stress, then decease with increasing strain, and forms a stable stage at last. The grain size also shows an decrease at first and increase after a minimum value. Dislocations are observed to produce at the interface of α/β phase, and the phase interface and dislocation circle play an important role in impeding the movement of dislocation. As strain increase, micro-deformation bands with high-density dislocation are founded, and dynamic recrystallization occurs.     

Thermomechanical processing of Ti–5Al–5Mo–5V–3Cr

The constitutive behaviour and microstructural evolution of the near-β alloy Ti–5Al–5Mo–5V–3Cr in the α + β condition has been characterised during isothermal subtransus forging at a range of temperatures and strain rates. The results indicate that Ti–5Al–5Mo–5V–3Cr has a shallower approach curve, and therefore, offers a more controllable microstructure than the near-β alloy Ti–10V–2Fe–3Al. Flow softening is small in magnitude in both alloys in the α + β condition. The steady state flow stresses obey a Norton–Hoff constitutive law with an activation energy of Q = 183 kJ mol⁻¹, which is similar to the activation energy for self-diffusion in the β phase, suggesting deformation is dominated by dynamic recovery in the β matrix. Good evidence is found for the existence of ω phase after both air cooling and water quenching from above the β transus. In addition, dissolution of the α phase is found to be slow at near-transus temperatures.     

Flow behavior and microstructural evolution of Al–Cu–Mg–Ag alloy during hot compression deformation

The flow behavior of Al–Cu–Mg–Ag alloy and its microstructural evolution during hot compression deformation were studied by thermal simulation test. The flow stress increased with increasing the strain rate, and decreased with increasing the deforming temperature, which can be described by a constitutive equation in hyperbolic sine function with the hot deformation activation energy 196.27 kJ/mol, and can also be described by a Zener–Hollomon parameter. The dynamic recrystallization only occurred at low Z values, which must be below or equal to a constant of 5.31 × 10¹³ s⁻¹. With decreasing Z value, the elongated grains coarsed and the tendency of dynamic recrystallization enhanced. Correspondingly, the subgrain size increased and the dislocation density decreased. And the main soften mechanism of the alloy transformed from dynamic recovery to dynamic recrystallization.     

Fatigue strength of Ti–6Al–4V at very long lives

The objective of this research was to investigate the fatigue strength of Ti–6Al–4V using an ultrasonic fatigue system. Fatigue testing up to 10⁹ cycles under fully reversed loading was performed to determine the ultra-high cycle fatigue behavior of Ti–6Al–4V. Endurance limit results were compared to similar data generated on conventional servohydraulic test systems and electromagnetic shaker systems to determine if there are any frequency effects. Fatigue specimens were tested with and without cooling air to determine the effects of increased specimen temperature caused by internal damping due to cycling at a very high frequency. An infrared camera was also used to record specimen temperatures at various load levels. Results indicate that the effects of frequency, including internal heating, on the very high cycle fatigue behavior of Ti–6Al–4V are negligible under fully reversed loading conditions.     

Effects of stress ratio and temperature on fatigue crack growth in a Ti–6Al–4V alloy

Fatigue thresholds and fatigue crack growth (FCG) rates in corner notched specimens of a forged Ti–6Al–4V aero-engine disk material were investigated at room temperature and 350 °C. The threshold stress intensity range, ΔK_th, was determined by a method involving a step change in stress ratio (the ‘jump in’ method). It was found that for three high stress ratios (R=0.7–0.9), where crack closure effects are widely accepted to be negligible, there were similar ΔK_th values at room temperature and 350 °C under the same R. For a given temperature, ΔK_th was observed to decrease from 3.1 to 2.1 MPam with R increasing from 0.7 to 0.9. The fatigue crack growth rate was influenced by increasing temperature. For high stress ratios, FCG rate at 350 °C was higher than that at room temperature under the same ΔK. For a low stress ratio (R=0.01), higher temperature led to higher FCG rates in the near-threshold regime, but showed almost no effect at higher ΔK. The influence of stress ratio and temperature on threshold and FCG rates was analysed in terms of a K_max effect and the implication of this effect, or related mechanisms, are discussed. In light of this, an equation incorporating the effects of the K_max and fatigue threshold, is proposed to describe FCG rates in the near-threshold and Paris regimes for both temperatures. The predictions compare favourably with experimental data.     

The influence of microstructure on dwell sensitive fatigue in Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy

The fatigue behaviour of titanium alloy Ti–6.5Al–3.5Mo–1.5Zr–0.3Si (TC11) was examined at 520°C to study the effects of microstructural variation on the dwell sensitivity. Three microstructures (equiaxed, tri-modal and basketweave) were used in this study. When a 3-min dwell time was imposed at the peak of each cycle a significant fatigue life reduction was observed for all microstructures tested. Among the three microstructures, equiaxed microstructure showed the strongest fatigue life reduction. The basketweave microstructure had a little higher dwell-time fatigue life than tri-modal microstructure at low maximum stress levels. In all cases, extensive quasi-cleavage facets and planar slips with track-like dislocations have been intimately linked with the dwell sensitive fatigue response. The amount of quasi-cleavage facets and planar slips decreased with a decrease of the α phase content. A rationalization for planar slip was proposed based on the mechanism of dislocations shearing α₂ particles. It is believed that α₂ particle formation and oxidization effects played an important role in dislocation planar slip.     

Hot Deformation Behavior,Dynamic Recrystallization,and Texture Evolution of Ti–22Al–25Nb Alloy

The hot deformation behavior, dynamic recrystallization, and texture evolution of Ti–22Al–25Nb alloy in the temperature range of 950–1050 °C and strain rate range of 0.001–1 s^?1 is investigated by plane‐strain compression testing on the Gleeble‐3500 thermo‐mechanical simulator. The results show that the flow stress decreases with the increase of temperature and decrease of strain rate. Besides, the flow curves appear a serrate oscillation at a strain rate of 0.1 s^?1 for all the temperature ranges, which may result from instability such as flow localization or micro‐cracking. The flow behavior can be expressed by the conventional hyperbolic sine constitutive equation and the calculated deformation activation energy Q in the (α₂ + B2) and B2 regions are 631.367 and 304.812 kJ mol^?1, respectively. The microstructure evolution is strongly dependent on the deformation parameters, and dynamic recrystallization (DRX) is the dominant softening mechanism in the (α₂ + B2) region, including discontinuous dynamic recrystallization (DDRX), and continuous dynamic recrystallization (CDRX). In addition, the η_bcc‐fiber of {110} <001> is the dominant texture component in deformed Ti–22Al–25Nb alloy. It is observed that the weakening of the deformation texture is accompanied by the occurrence of DRX, which can be attributed to the large misorientation between DRX grains and neighboring B2 matrix induced by the rotation of DRX grains toward the preferred slip systems.

     

On the validity of Hall–Petch equation for single-phase β Ti–Al–Nb alloys undergoing stress-induced martensitic transformation

The yield strengths of Ti–Al–Nb alloys, which undergo stress-induced martensitic transformation, prior to the onset of plastic deformation during tensile testing, were found to obey the Hall–Petch relationship with grain size. The overall friction stress was observed to decrease with increase in Nb content while it remained more or less unchanged with increase in Al content in these alloys. On the other hand, the overall , the unpinning constant, which is an index of the efficiency of boundaries as obstacle to dislocation motion, was found to increase with increase in Nb and decrease with increase in Al content in these alloys.     

Nanograin layer formation at crack initiation region for very‐high‐cycle fatigue of a Ti–6Al–4V alloy

The microstructural features and the fatigue propensities of interior crack initiation region for very‐high‐cycle fatigue (VHCF) of a Ti–6Al–4V alloy were investigated in this paper. Fatigue tests under different stress ratios of R = ?1, ?0.5, ?0.1, 0.1 and 0.5 were conducted by ultrasonic axial cycling. The observations by SEM showed that the crack initiation of VHCF presents a fish‐eye (FiE) morphology containing a rough area (RA), and the FiE and RA are regarded as the characteristic regions for crack initiation of VHCF. Further examinations by TEM revealed that a layer of nanograins exists in the RA for the case of R = ?1, while nanograins do not appear in the FiE outside RA for the case of R = ?1, and in the RA for the case of R = 0.5, which is explained by the Numerous Cyclic Pressing model. In addition, the estimations of the fatigue propensities for interior crack initiation stage of VHCF indicated that the fatigue life consumed by RA takes a dominant part of the total fatigue life and the related crack propagation rate is rather slow.     

A study of tensile properties in Al–Si–Cu and Al–Si–Mg alloys: Effect of β-iron intermetallics and porosity

The effect of β-iron intermetallics and porosity on the tensile properties in cast Al–Si–Cu and Al–Si–Mg alloys were investigated for this research study, using experimental and industrial 319.2 alloys, and industrial A356.2 alloys. The results showed that the alloy ductility and ultimate tensile strength (UTS) were subject to deterioration as a result of an increase in the size of β-iron intermetallics, most noticeable up to β-iron intermetallic lengths of 100 μm in 319.2 alloys, or 70 μm in A356.2 alloys. An increase in the size of the porosity was also deleterious to alloy ductility and UTS. Although tensile properties are interpreted by means of UTS vs. log elongation plots in the present study, the properties for all sample conditions were best interpreted by means of log UTS vs. log elongation plots, where the properties increased linearly between conditions of low cooling rate–high Fe and high cooling rate–low Fe. The results are explained in terms of the β-Al₅FeSi platelet size and porosity values obtained.     

O Phase Precipitation and Variant Selection in Ti–22Al–25Nb Alloy during the Hot Shear Spinning

O phase precipitation and variant selection in Ti–22Al–25Nb alloy during the hot shear spinning are investigated using scanning electron microscope (SEM), electron backscattered second diffraction (EBSD), and transmission electron microscope (TEM). The results show that the random O phase precipitates from the B2 matrix during the hot shear spinning. With the increase of reduction ratio, the average thickness of O precipitates increases from ≈0.18 to ≈0.50 μm. Meanwhile, the O precipitates show various morphologies, including lamella, short rod, and sphere. Twelve O variants simultaneously form in the parent B2 phase and the orientation relationship between the B2–O phases is confirmed as [?111] B2//[1–10] O and (110) B2//(001) O. Different patterns of dislocation are also found in the B2 matrix, such as dislocation tangles, dislocation nets, and dislocation arrays. They play an important role in the variant selection of O precipitates, resulting in the different angled combinations of O variants. In addition, massive dislocation piles up along the O/B2 interface and some dislocation wall generates within the O phase, which are benefit for the globularization of O precipitates.

     

Variability in room temperature fatigue life of alpha + beta processed Ti–6Al–4V

The variability in fatigue behavior is often what drives the design of components such as turbine engine blades and disks. These components are critical and must be designed with a very low probability of failure over the lifetime of the system. To meet that design criterion, the lower limit of fatigue life capability is typically used. The challenge is to reliably predict the lower limit of fatigue behavior. This study investigates the fatigue variability of an alpha + beta processed Ti–6Al–4V turbine engine alloy by conducting a statistically significant number of repeated tests at a few conditions. Testing includes three conditions including two maximum stresses, 675 and 635 MPa; and two surface conditions, electropolished and low stress grinding. All tests are constant amplitude with a stress ratio of 0.1. A similar approach has been performed on several other turbine engine material systems often revealing a bimodal behavior. It is proposed that crack propagation using small crack growth data can be used to predict the low life behavior mode and is demonstrated with the Ti–6Al–4V data.     

Effect of precipitates on damping capacity and mechanical properties of Ti–6Al–4V alloy

The present study was concerned with the effects of over-aging on damping property and fracture toughness in Ti–6Al–4V alloy. Damping property and toughness become important factors for titanium implants, which have big modulus difference between bone and implant, and need high damping capacity for bone-implant compatability. Widmanstätten, equiaxed, and bimodal microstructures containing fine α₂ (Ti₃Al) particles were obtained by over-aging a Ti–6Al–4V alloy. Over-aging heat treatment was conducted for 200 h at 545 °C. Fracture toughness, Charpy impact, and bending vibration tests were conducted on the unaged and the over-aged six microstructures, respectively. Charpy absorption energy and apparent fracture toughness decreased as over-aging was done, even if the materials were strengthened by precipitation of very fine and strong α₂-Ti₃Al particles. On the other hand, damping properties were enhanced by over-aging in Widmanstätten and equiaxed microstructures, but was weakened in bimodal microstructure due to the softening of tempered martensite and the decreasing of elastic difference between tempered martensite and α phase contained α₂ particles, etc. These data can provide effective information to future work about internal damping and fracture properties of Ti–6Al–4V alloy.     

Properties of Ti–6Al–4V non-stochastic lattice structures fabricated via electron beam melting

This paper addresses foams which are known as non-stochastic foams, lattice structures, or repeating open cell structure foams. The paper reports on preliminary research involving the design and fabrication of non-stochastic Ti–6Al–4V alloy structures using the electron beam melting (EBM) process. Non-stochastic structures of different cell sizes and densities were investigated. The structures were tested in compression and bending, and the results were compared to results from finite element analysis simulations. It was shown that the build angle and the build orientation affect the properties of the lattice structures. The average compressive strength of the lattice structures with a 10% relative density was 10 MPa, the flexural modulus was 200 MPa and the strength to density ration was 17. All the specimens were fabricated on the EBM A2 machine using a melt speed of 180 mm/s and a beam current of 2 mA. Future applications and FEA modeling were discussed in the paper.     

A multiphase mechanical model for Ti–6Al–4V: Application to the modeling of laser assisted processing

A multiphase model for Ti–6Al–4V is proposed. This material is widely used in industrial applications and so needs accurate behaviour modeling. Tests have been performed in the temperature range from 25 °C to 1020 °C and at strain rates between 10⁻³ s⁻¹ and 1 s⁻¹. This allowed the identification of a multiphase mechanical model coupled with a metallurgical model. The behaviour of each phase is calibrated by solving an inverse problem including a phase transformation model and a mechanical model to simulate tests under thermomechanical loadings. A scale transition rule (β-rule) is proposed in order to represent the redistribution of local stresses linked to the heterogeneity of plastic strain. Finally this model is applied to two laser assisted processes: direct laser fabrication and laser welding.     

Low-temperature compaction of Ti–6Al–4V powder using equal channel angular extrusion with back pressure

Equal channel angular extrusion (ECAE), with simultaneous application of back pressure, has been applied to the consolidation of 10 mm diameter billets of pre-alloyed, hydride–dehydride Ti–6Al–4V powder at temperatures ≤400 °C. The upper limit to processing temperature was chosen to minimise the potential for contamination with gaseous constituents potentially harmful to properties of consolidated product. It has been demonstrated that the application of ECAE with imposed hydrostatic pressure permits consolidation to in excess of 96% relative density at temperatures in the range 100–400 °C, and in excess of 98% at 400 °C with applied back pressure ≥175 MPa. ECAE compaction at 20 °C (back pressure = 262 MPa) produced billet with 95.6% relative density, but minimal green strength. At an extrusion temperature of 400 °C, the relative density increased to 98.3%, for similar processing conditions, and the green strength increased to a maximum 750 MPa. The relative density of compacts produced at 400 °C increased from 96.8 to 98.6% with increase in applied back pressure from 20 to 480 MPa, while Vickers hardness increased from 360 to 412 HV. The key to the effective low-temperature compaction achieved is the severe shear deformation experienced during ECAE, combined with the superimposed hydrostatic pressure.